Unit 1 — Matter and the particle model
Course introduction video — Whole-course introduction

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Intro video — States of matter and classifying matter

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Lesson 1 of 55 · MPM-001

Solid, liquid, or gas
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Have You Ever Wondered?
Wonder this:

Pour dry sand from a bucket into a jar. It flows, it settles, and it takes the shape of the jar — exactly what water does. So is sand a liquid?

You already sort everyday things into solids, liquids, and gases by gut feeling. Chemistry needs a test that still works when gut feeling fails.

The idea

Ask two questions about any sample: does it keep its own shape, and does it keep its own volume?

A solid keeps both — its shape and its volume stay the same in any container and on any surface.

A liquid keeps its own volume but not its own shape — it flows until it matches the shape of its container.

A gas keeps neither — it spreads out to take both the shape and the entire volume of its container.

The two-question test

StateKeeps its own shape?Keeps its own volume?
solidyesyes
liquidno — matches its containeryes
gasno — matches its containerno — fills its container
Two questions settle the state of any sample.

Apply the two questions to the material itself, not to a heap of pieces.

One grain of sand keeps its own shape and its own volume anywhere you put it, so sand is a solid — a jarful of sand is just many small solids.

Worked examples

Worked example 1. Cooking oil is poured from a bottle into a frying pan. It spreads out flat to match the pan, but the amount of space it takes up does not change. Is the oil a solid, a liquid, or a gas?

Step 1

Does it keep its own shape? No — it flowed to match the pan.

Step 2

Does it keep its own volume? Yes — it takes up the same amount of space as before.

Step 3

The oil keeps its volume but not its shape, so it is a liquid.

Worked example 2. The contents of a camping stove's small canister are released into a large empty tank. They spread out until they fill the whole tank. Solid, liquid, or gas?

Step 1

Does the sample keep its own shape? No — it took the tank's shape.

Step 2

Does it keep its own volume? No — it spread out to fill the whole tank.

Step 3

It keeps neither shape nor volume, so it is a gas.

Worked example 3. Dry rice poured from a bag flows and takes the shape of its jar. Solid, liquid, or gas?

Step 1

The jar-shaped heap is many separate pieces, so test the material itself: one grain.

Step 2

One grain of rice keeps its own shape on any surface.

Step 3

One grain keeps its own volume anywhere.

Step 4

Each grain keeps its shape and its volume, so rice is a solid.

You can now classify a sample as a solid, a liquid, or a gas from whether its shape and its volume are fixed.

Check your understanding

Honey poured from a jar slowly spreads out to cover the bottom of a bowl, but the amount of space it takes up stays the same. Is honey a solid, a liquid, or a gas?

AA liquid.correct
BA solid.
This option is wrong — you asked only the volume question, or judged by how slowly honey flows — a liquid also keeps its volume, and the shape question settles it: honey flowed to match the bowl.
CA gas.
This option is wrong — you asked only the shape question — a gas also changes its volume, and honey's volume stayed the same.
DNone of the above.
This option is wrong — you rejected all three states — every everyday sample lands in one of them; honey kept its volume but not its shape, which is the liquid behavior.
Ask the two questions. Does honey keep its own shape? No — it flowed to match the bowl. Does honey keep its own volume? Yes — the space it takes up stayed the same. Volume kept, shape not kept: honey is a liquid, however slowly it flows.
Check your understanding

The helium inside a party balloon spreads out to take the balloon's shape and fills however much space the balloon allows. Is the helium a solid, a liquid, or a gas?

AA gas.correct
BA liquid.
This option is wrong — you asked only the shape question, or treated anything that flows as a liquid — a liquid keeps its own volume, and the helium's volume changed to fill the balloon.
CA solid.
This option is wrong — you tested the container instead of the sample — the balloon's shape belongs to the balloon, not to the helium inside it.
DBoth a liquid and a gas.
This option is wrong — you split the verdict between two states — one sample gets one state, and the helium kept neither its shape nor its volume, which is the gas behavior alone.
Test the helium, not the balloon. Does the helium keep its own shape? No — it matches the balloon. Does the helium keep its own volume? No — it fills whatever space the balloon allows. Neither is kept, so the helium is a gas.
Check your understanding

Table sugar poured from a bag flows and takes the shape of its bowl. One sugar crystal, on its own, keeps its shape and its volume on any surface. Is table sugar a solid, a liquid, or a gas?

AA solid.correct
BA liquid.
This option is wrong — you tested the heap instead of the material — a heap of small solids flows and takes its bowl's shape, but each crystal keeps its own shape and volume.
CA gas.
This option is wrong — you treated spreading during a pour as the gas behavior — a gas spreads to fill its whole container even without being poured.
DBoth a solid and a liquid.
This option is wrong — you gave the flowing heap its own state — the state belongs to the material, and each crystal keeps its shape and its volume, so sugar is a solid.
Apply the two questions to the material itself, not to the heap. One crystal keeps its own shape on any surface. One crystal keeps its own volume anywhere. Both are kept, so sugar is a solid — the bowlful is many small solids.

Lesson 2 of 55 · MPM-002

Particles in the three states
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All matter is made of particles far too small to see. What separates a solid, a liquid, and a gas is what those particles are doing.

The idea

In a solid, the particles are packed tightly together in fixed positions, usually in a regular pattern.

Solid particles cannot swap places — each one only vibrates in place.

In a liquid, the particles are still touching, but they sit in no fixed positions and no pattern.

Liquid particles slide past one another.

In a gas, the particles are far apart, with empty space between them.

Gas particles move fast in all directions, spreading through all the space available.

Three boxes of identical circles: solid particles packed in neat touching rows, liquid particles touching in a jumble at the bottom, gas particles far apart across the whole box with motion arrowsSolidpacked tightly in fixedpositions — each particlevibrates in placeLiquidtouching, no pattern —particles slide past oneanotherGasfar apart — particles movefast in all directions
Worked examples

Worked example 1. The honey in a jar is a liquid. How are its particles arranged, and how do they move?

Step 1

Answer: touching, in no fixed positions and no pattern — the particles slide past one another.

Worked example 2. The helium in a filled party balloon is a gas. How are its particles arranged, and how do they move?

Step 1

Answer: far apart, with empty space between them — the particles move fast in all directions.

You can now state how the particles are arranged and how they move in a solid, a liquid, and a gas.

Check your understanding

Which description matches the particles of a solid?

APacked tightly in fixed positions, each vibrating in place.correct
BTouching one another, sliding past one another.
This option is wrong — you gave the liquid picture — in a solid the particles hold fixed positions and only vibrate.
CFar apart, moving fast in all directions.
This option is wrong — you gave the gas picture — solid particles are packed tightly together.
DPacked tightly in a regular pattern, sliding past one another.
This option is wrong — you mixed the two pictures — particles that hold a regular pattern cannot slide past one another; they vibrate in place.
In a solid, the particles are packed tightly together in fixed positions, usually in a regular pattern. Each particle only vibrates in place — none of them swap places.
Check your understanding

Which description matches the particles of a gas?

AFar apart, moving fast in all directions.correct
BTouching one another, sliding past one another.
This option is wrong — you gave the liquid picture — gas particles are far apart, not touching.
CFar apart, each vibrating around one fixed spot.
This option is wrong — you kept the solid's movement — gas particles do not hold positions; they move fast in all directions.
DPacked tightly in fixed positions, vibrating in place.
This option is wrong — you gave the solid picture — gas particles are far apart with empty space between them.
In a gas, the particles are far apart, with empty space between them. They move fast in all directions, spreading through all the space available.
Check your understanding

In which state do the particles stay touching one another yet keep changing places by sliding?

AIn a liquid.correct
BIn a solid.
This option is wrong — you let solid particles change places — they are locked in fixed positions and only vibrate.
CIn a gas.
This option is wrong — you kept gas particles touching — they are far apart, with empty space between them.
DIn both a liquid and a gas.
This option is wrong — you included the gas — its particles change places, but they are not touching one another.
Touching plus sliding is the liquid picture. Solid particles touch but cannot swap places; gas particles change places but are far apart.

Lesson 3 of 55 · MPM-003

Why solids keep their shape
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Tip a glass of water and it pours; tip a glass marble and it just falls. Both keep their volume — so why does only one of them keep its shape?

The idea

A solid keeps its own shape because its particles are locked in fixed positions.

Each particle of a solid can only vibrate in place, so the whole solid holds one shape.

A liquid flows because its particles can slide past one another.

When you pour a liquid into a container, its sliding particles rearrange until the liquid matches the container's shape.

Worked examples

Worked example 1. Milk poured from a jug into a glass takes the glass's shape. Why?

Step 1

Milk is a liquid, so its particles can slide past one another.

Step 2

The sliding particles rearrange until the milk matches the glass.

Step 3

The milk takes the glass's shape because its particles slide past one another and rearrange.

Worked example 2. A wooden block dropped into the same glass keeps its own shape. Why?

Step 1

Wood is a solid, so its particles are locked in fixed positions.

Step 2

Each particle only vibrates in place, so no rearranging can happen.

Step 3

The block keeps its shape because its particles are locked in fixed positions.

You can now explain why a solid keeps its own shape while a liquid flows to fit its container, because a solid's particles are locked in fixed positions while a liquid's particles can slide past one another.

Check your understanding

Why does orange juice take the shape of any glass it is poured into?

AIts particles slide past one another and rearrange until the juice matches the glass.correct
BIts particles are far apart, so they spread out in every direction to fill the glass.
This option is wrong — you gave the gas account — a liquid's particles stay touching; they take the shape by sliding, not by spreading apart.
CEach of its particles changes shape to match the glass.
This option is wrong — you reshaped the particles themselves — the particles stay the same; only their positions rearrange.
DIts particles stop moving once the juice settles in the glass.
This option is wrong — you stopped the particles — liquid particles keep sliding past one another even after the juice settles.
Juice is a liquid, so its particles can slide past one another. The sliding particles rearrange until the juice matches the glass's shape. The particles themselves never change or stop — only their positions rearrange.
Check your understanding

Why does a stone pebble keep its own shape on any surface?

AIts particles are locked in fixed positions and can only vibrate in place.correct
BIts particles are far too heavy for anything to move them out of place.
This option is wrong — you explained the fixed shape by particle weight — the particles hold their positions, and even they still vibrate.
CIts particles do not move at all, in any way.
This option is wrong — you stopped the particles completely — solid particles vibrate in place; what they cannot do is swap places.
DIts particles slide past one another, but far too slowly for the eye to ever see.
This option is wrong — you gave the pebble a very slow liquid account — solid particles never slide past one another; they hold fixed positions.
The pebble is a solid, so its particles are locked in fixed positions. Each particle vibrates in place but cannot move past its neighbors. With no particle able to change places, the whole pebble holds one shape.
Check your understanding

A juice carton holds a plastic straw and the juice around it. Why does the juice, but not the straw, match the carton's shape?

AThe juice's particles slide past one another, while the straw's particles are locked in fixed positions.correct
BThe juice's particles are far apart, while the straw's particles are touching.
This option is wrong — you pulled the liquid's particles apart — both samples' particles are touching; sliding against locked positions is the difference.
CThe juice's particles are smaller than the straw's, so they fit the carton's corners.
This option is wrong — you explained the shapes by particle size — the difference is whether the particles can change places, not how big they are.
DThe straw's particles slide past one another as well, only far more slowly than the juice's particles do.
This option is wrong — you made the straw a slower liquid — its particles do not slide at all; they hold fixed positions.
Both samples are made of touching particles. The juice's particles can slide past one another, so the juice rearranges to match the carton. The straw's particles are locked in fixed positions, so the straw keeps its own shape.

Lesson 4 of 55 · MPM-004

Why gases can be squeezed
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Have You Ever Wondered?
Wonder this:

Seal the tip of a syringe full of air and you can push the plunger halfway in. Fill the same syringe with water, and the plunger will not move at all. What is the air hiding that the water is not?

The difference is in the empty space — or the lack of it — between the particles.

The idea

A gas's particles are far apart, with empty space between them.

Squeezing a gas pushes its particles closer together into that empty space, so the same particles fit in a smaller volume.

Two syringes: before the push, ten widely spaced particles fill the barrel; after the push, the same ten particles sit closer together in half the barrelBefore the pushsealed tipAfter the pushsealed tipSame 10 particles — only closer together
Compressing a gas pushes the same particles into the empty space between them.

Squeezing a sample into a smaller volume is called 'compressing' it.

A solid's or a liquid's particles are already touching, so there is no empty space to push them into.

That is why a gas can be compressed while a solid or a liquid cannot.

Compressing a gas changes nothing about the particles themselves — the same number of identical particles simply sit closer together.

Worked examples

Worked example 1. Squeezing a sealed balloon pushes the air inside into a smaller space. Why is that possible?

Step 1

Air is a gas, so its particles are far apart, with empty space between them.

Step 2

The squeeze pushes the particles closer together, into the empty space.

Step 3

The same particles now fit in a smaller volume.

Step 4

The air compresses because its particles have empty space to move into.

Worked example 2. A sealed juice pouch cannot be squeezed into a smaller volume, however hard you press. Why not?

Step 1

Juice is a liquid, so its particles are already touching one another.

Step 2

There is no empty space between them for the particles to move into.

Step 3

The juice cannot compress because its particles have no empty space to move into.

You can now explain why a gas can be compressed into a smaller volume while a solid or a liquid cannot, because a gas's particles are far apart with empty space between them.

Check your understanding

Why can the air inside a bicycle pump be squeezed into a smaller volume?

AIts particles are far apart, so squeezing pushes them closer together into the empty space between them.correct
BIts particles shrink when they are squeezed, so the same number takes less room.
This option is wrong — you shrank the particles — the particles stay exactly the same size; only the empty space between them shrinks.
CIts particles are soft, so each one squashes down into a smaller particle.
This option is wrong — you squashed the particles themselves — compressing changes the spacing between particles, not the particles.
DSome of its particles are pushed out of existence when you squeeze, so the fewer that remain need less room.
This option is wrong — you destroyed particles — the same number of particles is there after the squeeze, just closer together.
Air is a gas, so its particles are far apart, with empty space between them. Squeezing pushes the same particles closer together, into that empty space. The particles themselves never shrink, squash, or disappear.
Check your understanding

A glass bottle filled to the brim with olive oil and tightly capped cannot be squeezed to a smaller volume. Why not?

AThe oil's particles are already touching, so there is no empty space to push them into.correct
BThe oil's particles are locked in fixed positions, like a solid's.
This option is wrong — you gave the solid picture — a liquid's particles slide past one another; what blocks the squeeze is that they are already touching.
CThe oil's particles are harder than air particles, so they cannot be pressed any closer.
This option is wrong — you explained the difference by particle hardness — the difference is spacing: touching particles leave no room, far-apart particles do.
DThe oil's particles are too heavy to be pushed closer together.
This option is wrong — you explained the difference by particle weight — the particles are already touching, so there is simply no space left.
Olive oil is a liquid, so its particles are already touching one another. Compressing needs empty space between the particles, and a liquid has none. That is why the full, capped bottle cannot be squeezed smaller.
Check your understanding

Three sealed containers hold air, water, and a steel block. Which sample can be squeezed to half its volume, and why?

AThe air — its particles are far apart, leaving empty space for them to be pushed into.correct
BThe water — its particles slide past one another, so they can slide closer.
This option is wrong — you turned sliding into room to compress — liquid particles slide while staying in touch, so there is no empty space to close up.
CThe steel block — its particles sit in a regular pattern, so they can pack more neatly.
This option is wrong — you invented spare room in the solid — its particles are already packed tightly against one another.
DNone of the three — particles can never be pushed closer together.
This option is wrong — you ruled out compressing entirely — gas particles are far apart, and squeezing does push them closer together.
Only the gas has empty space between its particles. Squeezing pushes the air's particles closer together into that space. The water's and the steel's particles are already touching, so neither can be squeezed to half its volume.

Lesson 5 of 55 · MPM-005

Reading particle diagrams
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No one can see particles, so chemists draw them: each particle becomes a small circle, and the container becomes a box. A drawing like this is called a 'particle diagram'.

The idea

To read a particle diagram, ask two questions about the circles: are they touching, and are they arranged in a pattern?

Circles touching and arranged in a regular pattern show a solid.

Circles touching but jumbled, filling the bottom of the box, show a liquid.

Circles far apart, spread through the whole box, show a gas.

Three particle diagrams: solid as touching circles in neat rows, liquid as touching jumbled circles at the bottom of the box, gas as far-apart circles across the whole boxSolidtouching + regular patternLiquidtouching + jumbled, bottomof boxGasfar apart, whole box

The circles' spacing and arrangement carry the answer — the number of circles does not.

Worked examples

Worked example 1. Which state does the particle diagram in the figure show?

particle diagram — 8 single circles scattered far apart throughout the box
Step 1

Touching? No — the circles are far apart.

Step 2

Far-apart circles filling the whole box match the gas picture.

Step 3

The diagram shows a gas.

Worked example 2. Which state does the particle diagram in the figure show?

particle diagram — 13 single circles jumbled touching at the bottom
Step 1

Touching? Yes.

Step 2

In a pattern? No — the circles are jumbled, and they fill only the bottom of the box.

Step 3

Touching but jumbled at the bottom — the diagram shows a liquid.

Worked example 3. Which state does the particle diagram in the figure show?

particle diagram — 12 single circles in neat touching rows at the bottom
Step 1

Touching? Yes.

Step 2

In a pattern? Yes — the rows repeat regularly.

Step 3

Touching and patterned — the diagram shows a solid.

You can now identify the state of matter shown in a particle diagram.

Check your understanding

The figure shows a particle diagram of a sample. Which state of matter does it show?

particle diagram — 8 single circles scattered far apart throughout the box
AA gas.correct
BA liquid.
This option is wrong — you judged by imagined movement or by the small number of circles — read the drawing itself: these circles are far apart, and far-apart circles spread through the whole box show a gas.
CA solid.
This option is wrong — you read identical circles as a solid — identical circles only mean one kind of particle; spacing and arrangement give the state.
DToo few particles to tell.
This option is wrong — you asked for a bigger count before deciding — the number of circles carries no state information; these far-apart circles filling the whole box show a gas.
Ask the two reading questions. Touching? No — the circles are far apart, with space between them. Far-apart circles spread through the whole box show a gas.
Check your understanding

The figure shows a particle diagram of a sample. Which state of matter does it show?

particle diagram — 16 single circles in neat touching rows at the bottom
AA solid.correct
BA liquid.
This option is wrong — you stopped at the touching question, or counted the many circles — touching circles can be a solid or a liquid, and the regular repeating pattern settles it as a solid.
CA gas.
This option is wrong — you read filling the drawn shape as gas behavior — a gas's circles are far apart; these are touching in neat rows.
DNone of the above.
This option is wrong — you rejected all three states — touching circles in a regular pattern are exactly the solid convention.
Touching? Yes. In a pattern? Yes — the rows repeat regularly. Touching plus a regular pattern shows a solid.
Check your understanding

The figure shows a particle diagram of a sample. Which state of matter does it show?

particle diagram — 14 single circles jumbled touching at the bottom
AA liquid.correct
BA solid.
This option is wrong — you stopped at the touching question, or read same-size circles as the solid cue — a solid's circles also hold a regular pattern, and these are jumbled.
CA gas.
This option is wrong — you read the empty top of the box as gas evidence — a gas's circles spread through the WHOLE box; circles pooled at the bottom show a liquid.
DA liquid and a gas together.
This option is wrong — you read the empty space above the circles as a second, gas sample — empty space is just empty, and the touching, jumbled circles pooled at the bottom show one liquid.
Touching? Yes. In a pattern? No — the circles are jumbled and fill only the bottom of the box. Touching but jumbled at the bottom shows a liquid.

Lesson 6 of 55 · MPM-006

Drawing particle diagrams of states
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You can read particle diagrams. Now you draw them — and a drawing is only correct if it shows every feature the state requires.

The idea

Draw every particle as a circle of the same size, and draw the container as a box.

For a solid: circles touching, arranged in a regular repeating pattern, at least two rows deep.

For a liquid: circles touching but jumbled, filling the bottom of the box with a roughly level top.

For a gas: a few circles far apart, spread through the whole box — corners and top included.

Three model particle diagrams showing the required drawing features for solid, liquid, and gasSolid — correct drawingtouching, regular pattern,two or more rowsLiquid — correct drawingtouching, jumbled, bottomof box, level topGas — correct drawingfew circles, far apart,whole box

Three drawing mistakes to avoid: gaps between a liquid's circles, a gas's circles bunched in one part of the box, and circles that change size.

Worked examples

Worked example 1. Draw a particle diagram of liquid water in a beaker.

Step 1

Draw the beaker as a box.

Step 2

Draw same-size circles that touch one another.

Step 3

Jumble the circles — no rows, no repeating pattern.

Step 4

Fill the bottom of the box, and keep the top of the circles roughly level.

Step 5

Touching, jumbled, same-size circles filling the bottom of the box — a correct liquid diagram.

Worked example 2. Draw a particle diagram of the air inside a sealed jar.

Step 1

Draw the jar as a box.

Step 2

Draw a few same-size circles — about six to eight.

Step 3

Spread them far apart through the whole box, top and corners included.

Step 4

Leave clear empty space between every pair of circles.

Step 5

A few far-apart circles spread through the whole box — a correct gas diagram.

You can now draw a particle diagram of a named state of matter, showing the particle spacing and arrangement that state requires.

Your turn

On paper, draw a particle diagram of a solid block of copper. Draw the container edge as a box. When your drawing is finished, reveal the model answer and check your drawing against the checklist.

Model answer. A box containing about sixteen same-size circles that touch their neighbors, arranged in a regular repeating pattern at least two rows deep, forming one block.

  • All circles are about the same size.
  • Every circle touches its neighbors — no gaps inside the block.
  • The circles sit in a regular repeating pattern.
  • The pattern is at least two rows deep.
  • The circles form one block rather than being scattered around the box.
particle diagram — 16 single circles in neat touching rows at the bottom
Your turn

On paper, draw a particle diagram of the milk in a half-full glass. Draw the glass as a box. When your drawing is finished, reveal the model answer and check your drawing against the checklist.

Model answer. A box with about twelve to fourteen same-size circles that touch one another in a jumble — no rows, no repeating pattern — filling the bottom of the box with a roughly level top and clear empty space above.

  • All circles are about the same size.
  • Every circle touches its neighbors — no gaps between a liquid's circles.
  • The circles are jumbled — no rows or repeating pattern.
  • The circles fill the bottom of the box, with a roughly level top.
  • The top part of the box is empty — the liquid does not fill the whole container.
particle diagram — 14 single circles jumbled touching at the bottom
Your turn

On paper, draw a particle diagram of the helium gas sealed inside a storage tank. Draw the tank as a box. When your drawing is finished, reveal the model answer and check your drawing against the checklist.

Model answer. A box containing about six to eight same-size circles, far apart, with clear empty space between every pair, spread through the whole box — top, bottom, and corners included.

  • All circles are about the same size.
  • Only a few circles are drawn — about six to eight.
  • The circles are far apart, with clear empty space between every pair.
  • The circles spread through the whole box — top, bottom, and corners included.
  • No region of the box is left as the only crowded or the only empty part.
particle diagram — 7 single circles scattered far apart throughout the box

Lesson 7 of 55 · MPM-007

Naming state changes
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Ice turns to water, puddles dry up, mirrors fog over. Matter moves between states all the time, and chemists have one name for each direction of change.

The idea

The change from solid to liquid is called 'melting' — an ice cube melts into water.

The change from liquid to solid is called 'freezing' — water in the tray freezes into ice.

The change from liquid to gas is called 'evaporation' — a puddle evaporates into water vapor.

The change from gas to liquid is called 'condensation' — water vapor condenses into the fog on a cold mirror.

The change from solid straight to gas, skipping the liquid state, is called 'sublimation' — dry ice, which is solid carbon dioxide, sublimes into gas without ever being wet.

The change from gas straight to solid, skipping the liquid state, is called 'deposition' — water vapor deposits as frost on a freezing-cold window.

The six names form three opposite pairs: melting and freezing, evaporation and condensation, sublimation and deposition.

A diagram of three labeled states — solid, liquid, gas — connected by six labeled arrows: melting, freezing, evaporation, condensation, sublimation, depositionmeltingfreezingevaporationcondensationsublimationdepositiongassolidliquid
Six state changes: three opposite pairs.
Worked examples

Worked example 1. Ice builds up on the inside walls of a freezer straight from the moist air, with no liquid water forming at any point. What is the change called?

Step 1

Answer: deposition — a gas turned straight into a solid, skipping the liquid state.

Worked example 2. A solid air-freshener block hanging in a car slowly shrinks away, leaving no liquid behind. What is the change called?

Step 1

Answer: sublimation — a solid turned straight into a gas, skipping the liquid state.

You can now identify the name of the state change between two named states of matter, choosing among melting, freezing, evaporation, condensation, sublimation, and deposition.

Check your understanding

Water droplets form on the outside of a cold soda can on a warm day. The droplets come from water vapor in the air. What is the change called?

ACondensation.correct
BEvaporation.
This option is wrong — you named the opposite direction — evaporation turns a liquid into a gas, and here a gas turned into a liquid.
CDeposition.
This option is wrong — you sent the vapor straight to a solid — the droplets are liquid water, so the gas became a liquid.
DFreezing.
This option is wrong — you treated 'cold' as the cue for freezing — freezing starts from a liquid, and this change started from water vapor, a gas.
Name the starting and ending states first. Start: water vapor, a gas. End: liquid droplets. Gas to liquid is condensation.
Check your understanding

After a candle is blown out, the pool of liquid wax at the top hardens into solid wax. What is the change called?

AFreezing.correct
BMelting.
This option is wrong — you named the opposite direction — melting turns a solid into a liquid, and here the liquid wax became solid.
CCondensation.
This option is wrong — you started from a gas — condensation turns a gas into a liquid, and this change started from liquid wax.
DDeposition.
This option is wrong — you started from a gas — deposition turns a gas straight into a solid, and this change started from a liquid.
Start: liquid wax. End: solid wax. Liquid to solid is freezing — whatever the temperature feels like. Wax freezes at ordinary room temperature; 'freezing' names the direction of change, not coldness.
Check your understanding

A mothball in a closet slowly shrinks away over the weeks and finally disappears, without ever leaving any liquid behind. What is the change called?

ASublimation.correct
BEvaporation.
This option is wrong — you started from a liquid — evaporation is liquid to gas, and the mothball went from solid straight to gas with no liquid stage.
CMelting.
This option is wrong — you stopped at solid-to-liquid — no liquid ever appeared; the solid went straight to gas.
DDeposition.
This option is wrong — you named the opposite direction — deposition is gas straight to solid, and here a solid became a gas.
Start: solid mothball. End: gas in the closet air — and no liquid in between. Solid straight to gas is sublimation. Its opposite, gas straight to solid, is deposition.

Lesson 8 of 55 · MPM-008

State changes at the particle level
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Did You Know?

You can name all six state changes. Here is what each one actually is: the same particles, changing only how they sit and move.

The idea

Heating a solid makes its particles vibrate faster.

When the particles vibrate hard enough to break out of their fixed positions and start sliding past one another, the solid melts.

Heating a liquid makes its particles move faster still, until they fly apart from one another and spread out — the liquid evaporates.

Three particle boxes connected by heating arrows: the same twelve circles packed in rows, then jumbled and touching, then far apart across the whole boxSame 12 particles in every panel — only spacing and movement changeSolidheatingLiquidheatingGas
Heating carries the same particles from fixed positions, to sliding contact, to flying far apart.

Cooling runs each change in reverse.

In condensation, gas particles slow down until they crowd back into touching, sliding contact.

In freezing, liquid particles slow down until they lock into fixed positions.

Every state change works this way because the particles themselves do not change — only their spacing and movement change.

Worked examples

Worked example 1. What happens to the particles of an iron bar as it melts in a furnace?

Step 1

The particles vibrate faster and faster as the iron heats up.

Step 2

They break out of their fixed positions.

Step 3

They begin sliding past one another.

Step 4

Each particle is still the same iron particle it was in the solid bar.

Step 5

Melting: the particles leave fixed positions and begin sliding — the particles themselves never change.

Worked example 2. Overnight, water vapor in the air forms dew drops on cool blades of grass. What happens to the particles?

Step 1

The fast, far-apart gas particles slow down at the cool surface.

Step 2

They crowd back together until they are touching.

Step 3

They keep sliding past one another — the dew is liquid water.

Step 4

Condensation: the particles slow, crowd into touching contact, and slide — the particles themselves never change.

You can now explain how the spacing and movement of the particles change during a named state change.

Check your understanding

As a bar of candle wax melts, what happens to its particles?

AThey break out of their fixed positions and begin sliding past one another.correct
BEach solid particle changes into a liquid particle.
This option is wrong — you changed the particles' kind — the particles themselves do not change; only their spacing and movement change.
CThe particles soften and lose their shape.
This option is wrong — you softened the particles — melting rearranges the particles' positions; each particle stays exactly as it was.
DThe particles fly far apart from one another and spread out through the room.
This option is wrong — you went one state too far — flying apart is evaporation; melting only frees the particles to slide while still touching.
Heating makes the wax's particles vibrate faster. At melting, they break out of their fixed positions and begin sliding past one another. The particles themselves do not change — only their spacing and movement change.
Check your understanding

A puddle dries up on a warm day. What happens to the water particles as the puddle evaporates?

AThey move faster, fly apart from one another, and spread into the air.correct
BThey are destroyed, one after another, as the puddle slowly disappears.
This option is wrong — you destroyed the particles — every water particle still exists; it has flown into the air as gas.
CThey change into air particles.
This option is wrong — you changed the particles' kind — each one is still a water particle, now far apart among the air's particles.
DThey slow down and lock into fixed positions.
This option is wrong — you ran the change in the cooling direction — locking into fixed positions is freezing, not evaporation.
Heating makes the liquid's particles move faster. Fast enough, they fly apart from one another and spread into the air as gas. The particles themselves do not change — only their spacing and movement change.
Check your understanding

A tray of water is put in the freezer. What happens to the water particles as the water freezes?

AThey slow down and lock into fixed positions.correct
BThey stop moving completely.
This option is wrong — you stopped the particles — frozen particles still vibrate in place; what they lose is the ability to slide past one another.
CEach water particle turns into an ice particle.
This option is wrong — you changed the particles' kind — ice is made of exactly the same water particles, locked in fixed positions.
DThey fly apart from one another and spread out.
This option is wrong — you ran the change in the heating direction — flying apart is evaporation; freezing locks the particles into fixed positions.
Cooling makes the liquid's particles slower and slower. Slow enough, they lock into fixed positions and can only vibrate in place. The particles themselves do not change — only their spacing and movement change.

Lesson 9 of 55 · MPM-009

Plasma, the fourth state
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Did You Know?
Wonder this:

A lightning bolt is matter. Try the two-question test on it: it keeps neither its own shape nor its own volume, so the test says gas. But no ordinary gas glows and crackles like that.

The three everyday states are not the whole story.

The idea

Some matter is so hot and so energetic that it no longer behaves like any of the three everyday states.

A gas heated until its particles become electrically charged has turned into a fourth state of matter, called 'plasma'.

Plasma glows — a lightning bolt, the Sun and the stars, and the glowing gas inside a lit neon sign are all plasma.

Almost all the ordinary matter in the universe is plasma, because the stars are made of it.

What 'electrically charged' means for a particle is a story for the atomic-structure unit — for now, charged particles are what make plasma different from a gas.

Worked examples

Worked example 1. What is the glowing matter inside a lightning bolt?

Step 1

Answer: plasma.

Worked example 2. The Sun is neither solid, liquid, nor ordinary gas. What state is it in?

Step 1

Answer: plasma — like every star, the Sun is mostly plasma.

You can now identify plasma as the fourth state of matter, a gas so energetic that its particles have become electrically charged.

Check your understanding

Which state of matter is the Sun mostly made of?

APlasma.correct
BGas.
This option is wrong — you stopped at gas — the Sun's particles are electrically charged, which makes its matter plasma, the fourth state.
CLiquid.
This option is wrong — you pictured the Sun as glowing liquid — its matter is far too hot and energetic for the liquid state.
DSolid.
This option is wrong — you gave the Sun a solid surface — its matter holds no fixed shape at all; it is plasma.
The Sun is so hot that its particles are electrically charged. Matter like that is plasma — the fourth state. The stars are why almost all the ordinary matter in the universe is plasma.
Check your understanding

What makes plasma different from an ordinary gas?

AIts particles are electrically charged.correct
BIts particles are packed touching one another.
This option is wrong — you packed the particles — plasma is like a gas in its spread-out particles; the charge is what is different.
CIt is a blend of the three other states.
This option is wrong — you built plasma out of the other states — plasma is its own fourth state, made from a gas whose particles became charged.
DIts particles have stopped moving.
This option is wrong — you slowed plasma down — plasma is the most energetic state, with fast-moving charged particles.
Plasma is a gas heated until its particles become electrically charged. The charge — not the spacing — is what separates plasma from an ordinary gas.
Check your understanding

Which of these is plasma?

AThe glowing matter inside a lightning bolt.correct
BRed-hot flowing lava.
This option is wrong — you took glowing as proof of plasma — lava glows but is a very hot liquid; plasma needs electrically charged particles.
CThe steam rising from a kettle of boiling water.
This option is wrong — you took hot as proof of plasma — steam is hot water in the gas state; its particles are not electrically charged.
DThe white smoke from a campfire.
This option is wrong — you took rising, drifting matter for plasma — smoke is not glowing charged matter; the lightning bolt is.
The plasma test is charged particles, not glow or heat. A lightning bolt's particles are electrically charged — it is plasma. Lava is a glowing liquid, and steam is a hot gas; neither has charged particles.

Lesson 10 of 55 · MPM-010

Pure substance or mixture
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Did You Know?
Wonder this:

Two glasses hold clear, colorless liquids. One holds nothing but water; the other holds water with salt dissolved in it. Look as hard as you like — your eyes cannot tell them apart.

The difference only shows up at the particle level.

The idea

Zoom in on the first glass, and every particle is the same: each one is a water molecule.

Zoom in on the salt water, and two kinds of particles are mingled together: water molecules and salt particles.

Two zoomed particle boxes: plain water with only one kind of particle, and salt water with salt particles mingled among the water moleculesNothing but water — apure substanceone kind of particleSalt water — a mixturetwo kinds of particlesmingled together

Matter made of only one kind of particle is called a 'pure substance'.

Matter containing more than one kind of particle mingled together is called a 'mixture'.

The helium in a party balloon is a pure substance — every particle is a helium atom.

Air is a mixture — nitrogen particles, oxygen particles, and several other kinds, all mingled together.

'Pure' here means one kind of particle only — it does not mean clean, natural, or safe to drink.

Worked examples

Worked example 1. Every particle in a tank of argon is an argon atom. Is the argon a pure substance or a mixture?

Step 1

Count the kinds of particles: one kind only.

Step 2

One kind of particle — the argon is a pure substance.

Worked example 2. Sparkling water contains water molecules with carbon dioxide molecules mingled through them. Pure substance or mixture?

Step 1

Count the kinds of particles: water molecules and carbon dioxide molecules — two kinds.

Step 2

The two kinds are mingled together, not joined into one new particle.

Step 3

More than one kind of particle mingled together — sparkling water is a mixture.

You can now classify matter as a pure substance or a mixture from whether it contains one kind of particle or more than one kind mingled together.

Check your understanding

A sealed flask holds a gas in which every particle is an identical methane molecule. Is the gas a pure substance or a mixture, and why?

AA pure substance, because it contains only one kind of particle.correct
BA mixture, because each particle contains carbon and hydrogen atoms.
This option is wrong — you counted the atoms inside one particle — the test counts KINDS of particles, and every particle here is the same kind.
CA mixture, because the gas particles are spread far apart.
This option is wrong — you read the spacing as the test — spacing gives the state; counting the kinds of particles gives pure substance or mixture.
DA pure substance, because the gas is colorless.
This option is wrong — you judged by appearance — the right classification for the wrong reason; only the count of particle kinds settles it.
Count the kinds of particles. Every particle in the flask is the same kind of particle. One kind of particle means a pure substance — whatever sits inside each particle.
Check your understanding

A cup of sweet tea contains water molecules, sugar molecules, and particles from the tea leaves, all mingled together. Is the tea a pure substance or a mixture, and why?

AA mixture, because it contains more than one kind of particle mingled together.correct
BA pure substance, because the sugar and the tea have both dissolved completely.
This option is wrong — you let dissolving erase the sugar's particles — dissolved particles are still there, mingled among the water molecules.
CA pure substance, because the tea looks the same in every sip.
This option is wrong — you judged by appearance — evenly mingled particles still make a mixture; the test is how many kinds there are.
DA mixture, because it is a liquid.
This option is wrong — you used the state as the test — liquids can be pure substances or mixtures; the count of particle kinds decides.
Count the kinds of particles: water molecules, sugar molecules, tea particles — three kinds at least. More than one kind mingled together means a mixture. Dissolving mingles particles; it never makes them disappear.
Check your understanding

A bottle of spring water is labeled '100% pure and natural'. Along with its water molecules, it contains small amounts of dissolved rock particles. To a chemist, is the spring water a pure substance or a mixture, and why?

AA mixture, because it contains water molecules and rock particles mingled together.correct
BA pure substance, because the label says it is pure.
This option is wrong — you used the label's everyday meaning of 'pure' — to a chemist, pure means one kind of particle, and this water has two or more.
CA pure substance, because everything in it is natural.
This option is wrong — you treated natural as pure — where the particles came from does not matter; how many kinds there are does.
DA pure substance, because the rock particles are dissolved and completely invisible.
This option is wrong — you let dissolving erase the particles — dissolved rock particles are still a second kind of particle in the water.
Count the kinds of particles: water molecules plus dissolved rock particles. More than one kind mingled together means a mixture. A chemist's 'pure' means one kind of particle — not clean, natural, or safe to drink.

Lesson 11 of 55 · MPM-011

Elements at the particle level
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Did You Know?

Some pure substances are as simple as matter gets.

The idea

A bar of pure gold contains only gold atoms — one kind of atom and nothing else.

A pure substance made of only one kind of atom is called an 'element'.

Helium, gold, copper, iron, oxygen, and nitrogen are all elements.

The periodic table you have seen on classroom walls is the complete list of the elements.

An element's atoms may travel joined in pairs — oxygen gas is molecules of two oxygen atoms joined together — but with only one kind of atom, it is still an element.

Worked examples

Worked example 1. Every atom in a bar of tin is a tin atom. Is tin an element?

Step 1

Answer: yes — one kind of atom makes tin an element.

Worked example 2. Hydrogen gas consists of molecules, each made of two hydrogen atoms joined together. Is hydrogen still an element?

Step 1

Answer: yes — every atom is a hydrogen atom, so hydrogen is an element even though its atoms travel in joined pairs.

You can now state the particle-level definition of an element as a pure substance made of only one kind of atom.

Check your understanding

Every atom in a lump of sulfur is a sulfur atom. What does that make sulfur, and why?

AAn element, because it is a pure substance made of only one kind of atom.correct
BA mixture, because the lump contains a very large number of atoms.
This option is wrong — you counted atoms instead of KINDS of atoms — countless identical atoms are still one kind.
CNot an element, because sulfur atoms differ from every other kind of atom.
This option is wrong — you compared sulfur's atoms with other substances' atoms — the test looks only inside the sample: one kind of atom means an element.
DA mixture, because the atoms are jumbled together rather than lined up.
This option is wrong — you used the arrangement as the test — arrangement gives the state; the count of atom kinds gives the classification.
Count the kinds of atoms in the sample. Every atom is a sulfur atom — one kind. A pure substance made of only one kind of atom is an element.
Check your understanding

Chlorine gas consists of molecules, each made of two chlorine atoms joined together. Is chlorine an element? Why, or why not?

AYes — every atom is a chlorine atom, one kind of atom, even though the atoms travel in joined pairs.correct
BNo — a substance whose particles are molecules can never be an element.
This option is wrong — you ruled out molecules — an element's atoms may travel joined in pairs; the test is still the kinds of atoms.
CNo — the two atoms joined in each particle make the gas a mixture of two kinds of particles.
This option is wrong — you read one joined pair as two mingled particles — joined atoms form ONE particle, and both atoms are the same kind.
DYes — but only because chlorine is a gas, and every gas is an element.
This option is wrong — you used the state as the test — plenty of gases contain two or more kinds of atoms; the atom count is what makes chlorine an element.
The particles are molecules — two atoms joined. Count the kinds of atoms anyway: every atom is a chlorine atom. One kind of atom, even in joined pairs, means an element.
Check your understanding

Four samples are described at the particle level. Which one is an element?

AA bar in which every atom is a silver atom.correct
BA liquid whose every particle is one oxygen atom joined to two hydrogen atoms.
This option is wrong — you accepted two kinds of atoms — an element has only one kind, and this liquid's particles each hold two kinds.
CA gas of helium atoms with neon atoms mingled among them.
This option is wrong — you accepted mingled kinds — two kinds of atoms mingled together make a mixture, not an element.
DA white solid whose every particle is one sodium atom joined to one chlorine atom.
This option is wrong — you accepted joined different atoms — joining does not help; an element's atoms are all the same kind.
Count the kinds of atoms in each sample. Only the silver bar has a single kind of atom. Two kinds — joined or mingled — can never be an element.

Lesson 12 of 55 · MPM-012

Compounds at the particle level
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Did You Know?

Pure water is a pure substance — every particle of it is identical. But look inside one of those particles, and it is built from atoms of two different elements.

The idea

One particle of pure water contains two hydrogen atoms joined to one oxygen atom.

Every particle of pure water is built exactly the same way — always two hydrogen atoms and one oxygen atom, never one, never three.

A pure substance whose particles each contain atoms of two or more different elements chemically joined together is called a 'compound'.

In a compound, the ratio of atoms is fixed: every particle of the compound is built to the same recipe.

Carbon dioxide is a compound — each of its particles is one carbon atom joined to two oxygen atoms.

Table salt is a compound — sodium and chlorine atoms joined in a fixed one-to-one ratio.

A compound is one pure substance, not a mixture: its different atoms are chemically joined into a single kind of particle, not mingled loosely.

Worked examples

Worked example 1. Every particle of ammonia contains one nitrogen atom joined to three hydrogen atoms. Is ammonia a compound?

Step 1

Answer: yes — atoms of two different elements, chemically joined in a fixed ratio, make ammonia a compound.

Worked example 2. A jar holds nitrogen molecules and hydrogen molecules mingled together, not joined. Is the jar's content a compound?

Step 1

Answer: no — without chemical joining there is no compound; the jar holds a mixture.

You can now state the particle-level definition of a compound as a pure substance whose particles each contain atoms of two or more different elements chemically joined in a fixed ratio.

Check your understanding

Every particle of methane contains one carbon atom joined to four hydrogen atoms. What does that make methane, and why?

AA compound, because its particles join atoms of two different elements in a fixed ratio.correct
BA mixture, because it contains atoms of two different elements, carbon and hydrogen.
This option is wrong — you stopped at 'two elements present' — in methane the different atoms are chemically joined into one kind of particle, not mingled loosely.
CAn element, because every particle of methane is identical.
This option is wrong — you used identical particles as the element test — identical particles show a pure substance; an element needs one kind of ATOM, and methane's particles hold two kinds.
DA mixture, because the carbon and hydrogen atoms can be counted separately.
This option is wrong — you treated countable ingredients as mingled ones — the atoms are joined into single particles, which is what makes a compound.
Look inside one particle: one carbon atom joined to four hydrogen atoms. Atoms of two different elements, chemically joined, in a fixed ratio — that is a compound. Every methane particle is built to the same recipe, so methane is one pure substance.
Check your understanding

Which statement correctly describes a compound?

AA substance whose particles each contain atoms of two or more different elements joined in a fixed ratio.correct
BAny matter that contains atoms of two or more different elements, joined or not.
This option is wrong — you dropped the joining — two kinds of atoms merely mingled together make a mixture, not a compound.
CA pure substance whose particles are each made of only one kind of atom.
This option is wrong — you gave the element definition — a compound's particles contain two or more DIFFERENT kinds of atoms.
DA blend of two pure substances, stirred together carefully until the blend looks the same throughout.
This option is wrong — you described careful mixing — stirring mingles particles; a compound needs the atoms chemically joined into new particles.
A compound is a pure substance. Its particles each contain atoms of two or more different elements, chemically joined. The ratio of atoms is fixed — every particle is built to the same recipe.
Check your understanding

Every particle of sulfur dioxide contains exactly one sulfur atom and two oxygen atoms — never one oxygen, never three. What does this show about sulfur dioxide, and why?

AIt is a compound, whose atoms are joined in a fixed ratio.correct
BIt is a mixture whose ingredients happen to be measured out very evenly.
This option is wrong — you explained the fixed ratio as careful measuring — a mixture's makeup can vary; only chemical joining fixes the ratio in every particle.
CIt is an element, because all of its particles are exactly alike.
This option is wrong — you used identical particles as the element test — identical particles mean a pure substance; the two kinds of atoms inside make it a compound.
DIt shows nothing — the ratio of atoms varies from sample to sample.
This option is wrong — you denied the fixed ratio — in a compound every particle everywhere carries the same fixed recipe of atoms.
A fixed recipe in every particle is the mark of a compound. One sulfur joined to two oxygens, in every particle of every sample. Mixtures have no fixed recipe — their makeup can vary batch to batch.

Lesson 13 of 55 · MPM-013

Why a compound is a new substance
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Wonder this:

Sodium is a soft gray metal that bursts into flame in water. Chlorine is a poisonous yellow-green gas. Chemically join their atoms, and you get the white crystals you shake onto fries: table salt.

How can a safe kitchen ingredient be built from a violent metal and a poisonous gas?

The idea

Chemically joining atoms makes a new kind of particle.

A new kind of particle means a new substance, and a new substance has its own properties.

A particle of table salt is not a bit of sodium plus a bit of chlorine — it is a different particle, so salt behaves like salt and like nothing else.

The elements' old properties belong to the elements' own particles, and those particles are gone once the atoms are joined into the compound.

The same holds for every compound: water is nothing like hydrogen, a gas that burns explosively, or oxygen, a gas that feeds flames — water puts flames out.

Worked examples

Worked example 1. Sugar's particles are built from carbon, hydrogen, and oxygen atoms chemically joined. Carbon by itself is a black powder; hydrogen and oxygen are colorless gases. Why is sugar a white, sweet solid?

Step 1

Joining the atoms made a new kind of particle: the sugar particle.

Step 2

A new kind of particle means a new substance with its own properties.

Step 3

Black powder and colorless gas belonged to the elements' own particles, which are gone once the atoms are joined.

Step 4

Sugar's behavior belongs to sugar — not to the carbon, hydrogen, or oxygen inside it.

Worked example 2. Iron is a strong, gray, magnetic metal. Rust forms when iron atoms join chemically with oxygen atoms. Why is rust a crumbly, reddish-brown solid instead of a strong gray one?

Step 1

Joining the iron and oxygen atoms made a new kind of particle.

Step 2

A new kind of particle means a new substance: rust.

Step 3

Strong, gray, and magnetic belonged to iron's own particles, which are gone once the atoms are joined.

Step 4

Rust's properties are rust's own — not iron's.

You can now explain why a compound has its own properties different from the properties of the elements that formed it, because chemically joining atoms makes a new substance.

Check your understanding

Chalk's particles are built from calcium, carbon, and oxygen atoms chemically joined. Calcium is a soft gray metal, carbon is a black powder, and oxygen is a colorless gas. Why is chalk a crumbly white solid that is nothing like any of them?

AJoining the atoms made a new kind of particle, so chalk is a new substance with its own properties.correct
BChalk keeps a little of each of its elements' properties, all blended together into one substance.
This option is wrong — you averaged the elements' properties — a compound's properties are its own, not a blend of its ingredients'.
CThe atoms changed into different kinds of atoms when they joined.
This option is wrong — you changed the atoms themselves — the same calcium, carbon, and oxygen atoms are all still there, only joined into new particles.
DThe black color of the carbon is hidden inside each chalk particle.
This option is wrong — you kept the elements' properties alive inside the compound — blackness belonged to carbon's own particles, which are gone once the atoms are joined.
Chemically joining atoms makes a new kind of particle. A new kind of particle means a new substance with its own properties. Crumbly and white belong to chalk; the gray metal and the black powder belonged to the elements' own particles, which chalk does not contain.
Check your understanding

Silver is a shiny white metal, and sulfur is a crumbly yellow solid. Tarnish forms when silver atoms join chemically with sulfur atoms. Why is the tarnish a dull black layer instead of shiny or yellow?

AThe joined atoms form a new kind of particle, so tarnish is a new substance with its own properties.correct
BThe tarnish is still ordinary silver, just with a surface stain picked up from the air.
This option is wrong — you kept tarnish as silver with a coat of color — tarnish is a different substance, built from a different kind of particle.
CThe tarnish's properties are the average of silver's and sulfur's properties.
This option is wrong — you averaged the elements' properties — a compound's properties are its own, not a blend.
DThe silver atoms in the tarnish have become duller atoms.
This option is wrong — you changed the atoms themselves — the silver atoms are unchanged; joining them to sulfur atoms made a new kind of particle.
Silver atoms joined to sulfur atoms form a new kind of particle. A new kind of particle means a new substance: tarnish. Shiny belonged to silver and yellow to sulfur; dull black belongs to the tarnish.
Check your understanding

Which statement about a compound's properties is correct?

AThey are the compound's own, and can be completely unlike its elements' properties.correct
BThey are a blend of the properties of the elements that formed it.
This option is wrong — you averaged the ingredients — the elements' particles are gone once the atoms are joined, and their properties go with them.
CThey match the properties of whichever element the compound contains the most of.
This option is wrong — you let the biggest ingredient rule — no element's own particles exist in the compound, so no element's properties carry over.
DThey are the same as the elements' properties, only weaker.
This option is wrong — you diluted the elements' properties — the compound is a new substance, not a weakened version of its ingredients.
Chemically joining atoms makes a new kind of particle, and a new kind of particle is a new substance. A new substance has its own properties. Salt is nothing like sodium or chlorine; water is nothing like hydrogen or oxygen.

Lesson 14 of 55 · MPM-014

Identifying elements, compounds, and mixtures
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Did You Know?

You can read a particle diagram's state from spacing and arrangement. The same diagram also tells you WHAT the matter is — element, compound, or mixture.

The idea

In a particle diagram, different kinds of atoms are drawn as circles of different sizes or shades.

Circles drawn touching-and-fused belong to one joined particle; particles with clear space between them are separate.

Ask two questions: how many kinds of particles are in the box, and what is each particle built from?

One kind of particle, each built from one kind of atom — alone or in identical joined pairs — shows an element.

One kind of particle, each built from two or more different kinds of atoms joined together, shows a compound.

More than one kind of particle mingled loosely in the box shows a mixture.

Four particle diagrams: an element as single identical circles, an element as fused identical pairs, a compound as fused large-and-small circles, and a mixture of two different particle kinds mingledElement — single atomsone kind of particle, onekind of atomElement — joinedidentical pairsstill one kind of atomCompoundone kind of particle,different atoms joinedMixturetwo kinds of particlesmingled
Worked examples

Worked example 1. The figure shows a particle diagram. Element, compound, or mixture?

particle diagram — 5 two joined circles scattered far apart throughout the box
Step 1

Kinds of particles: one — every pair looks the same.

Step 2

Inside each particle: two atoms of the SAME kind.

Step 3

One kind of particle, one kind of atom — the diagram shows an element, even though its atoms travel in joined pairs.

Worked example 2. The figure shows a particle diagram. Element, compound, or mixture?

particle diagram — 5 two joined circles scattered far apart throughout the box
Step 1

Kinds of particles: one — every particle looks the same.

Step 2

Inside each particle: two DIFFERENT kinds of atoms, joined.

Step 3

One kind of particle built from different atoms joined — the diagram shows a compound.

Worked example 3. The figure shows a particle diagram. Element, compound, or mixture?

particle diagram — 3 single circles scattered far apart throughout the box; 3 two joined circles scattered far apart throughout the box
Step 1

Kinds of particles: two — lone large circles and small joined pairs.

Step 2

The two kinds sit mingled loosely, not joined to each other.

Step 3

Two kinds of particles mingled — the diagram shows a mixture.

You can now classify the matter shown in a particle diagram as an element, a compound, or a mixture.

Check your understanding

The figure shows a particle diagram. Classify the matter it shows.

particle diagram — 6 two joined circles scattered far apart throughout the box
AAn element.correct
BA compound.
This option is wrong — you made joining alone the compound test, or counted two atoms per particle — a compound needs DIFFERENT kinds of atoms joined, and these fused circles are identical.
CA mixture.
This option is wrong — you counted particles instead of KINDS of particles — every particle here is the same kind.
DNone of the above.
This option is wrong — you rejected all three classes — one kind of particle built from one kind of atom is exactly what an element's diagram shows.
Kinds of particles: one — every joined pair is identical. Inside each particle: two atoms of the SAME kind. One kind of atom, even in joined pairs, shows an element.
Check your understanding

The figure shows a particle diagram. Classify the matter it shows.

particle diagram — 6 two joined circles scattered far apart throughout the box
AA compound.correct
BA mixture.
This option is wrong — you counted kinds of atoms instead of kinds of particles, or read the wide spacing as mingling — the different atoms are fused into ONE kind of particle, which is a compound.
CAn element.
This option is wrong — you used identical particles as the element test — identical particles show a pure substance; the two different atoms inside make it a compound.
DNone of the above.
This option is wrong — you rejected all three classes — one kind of particle built from two different atoms joined is exactly what a compound's diagram shows.
Kinds of particles: one — every particle looks the same. Inside each particle: one large and one small circle, fused — two DIFFERENT kinds of atoms joined. Different atoms joined into one kind of particle shows a compound.
Check your understanding

The figure shows a particle diagram. Classify the matter it shows.

particle diagram — 4 single circles scattered far apart throughout the box; 4 single circles scattered far apart throughout the box
AA mixture.correct
BA compound.
This option is wrong — you stopped at 'two kinds of atoms present', or read even spreading as joining — a compound needs the atoms JOINED into one kind of particle, and these particles are separate.
CAn element.
This option is wrong — you used lone atoms as the element test — the box holds TWO different kinds of circles, so two kinds of particles are mingled.
DNone of the above.
This option is wrong — you rejected all three classes — more than one kind of particle mingled loosely is exactly what a mixture's diagram shows.
Kinds of particles: two — small circles and large circles, all separate. Nothing is fused: the two kinds are only mingled. More than one kind of particle mingled loosely shows a mixture.

Lesson 15 of 55 · MPM-015

Drawing particle diagrams of elements, compounds, and mixtures
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Did You Know?

You've already seen how to read a particle diagram as an element, a compound, or a mixture. Now you draw those diagrams yourself.

The idea

Before you draw, decide two things: how many kinds of circles the diagram needs, and which circles are joined.

Use circles of different sizes or shading for different kinds of atoms, exactly as in the diagrams you've already read.

For an element, draw only one kind of circle.

Every particle of the element must look the same — single circles, or identical joined groups of that one circle.

For a compound, draw one kind of particle, with every particle built from the same two or more different circles joined together.

No lone circles may be left over in a compound — every atom belongs to an identical joined particle.

For a mixture, draw two or more different kinds of particles mingled through the same box, with the different kinds not joined to each other.

element, compound, and mixture drawing targets — Element; one kind of circle; Compound; one kind of particle, two kinds of atoms joined; Mixture; more than one kind of particle, mingled; 8 single circles scattered far apart throughout the box; 6 two joined circles scattered far apart throughout the box; 4 single cir…Elementone kind of circleCompoundone kind of particle, twokinds of atoms joinedMixturemore than one kind ofparticle, mingled
The three drawing targets. Different circle sizes and shading stand for different kinds of atoms.

The state rules you've already used still apply — tightly packed rows for a solid, touching circles in no fixed pattern gathered at the bottom for a liquid, widely spaced circles filling the whole box for a gas.

Worked examples

Worked example 1. Draw a particle diagram of a compound in the gas state.

Step 1

A compound needs two or more different circles joined into one repeating particle — say, one large circle joined to one small circle.

Step 2

Every particle must be that same joined pair, with no lone circles left over.

Step 3

The gas state spreads the particles far apart, filling the whole box.

Step 4

Six identical large-plus-small joined particles, widely spaced through the whole box.

Worked example 2. Draw a particle diagram of a mixture of two elements in the gas state.

Step 1

A mixture of two elements needs two different kinds of circles — say, small dark circles and large light circles.

Step 2

The two kinds mingle through the same region, and none of them are joined to each other.

Step 3

The gas state spreads all the circles far apart, in no pattern, through the whole box — every circle keeps clear space around it.

Step 4

Four small dark circles and four large light circles, far apart, mingled through the whole box, none joined or touching.

You can now draw a particle diagram of a named class of matter, an element, a compound, or a mixture.

Check your understanding

Panels A to D each show one particle diagram. A student is asked to draw a compound. Which panel shows what the student should draw?

particle diagram — A; B; C; D; box A: 8 single circles scattered far apart throughout the box; box B: 6 two joined circles scattered far apart throughout the box; box C: 4 single circles scattered far apart throughout the box; 4 single circles scattered far apart throughout the box; box D: 3 two joined circles scat…ABCD
APanel Bcorrect
BPanel A
This option is wrong — you drew an element — a compound needs two or more different kinds of atoms joined in every particle.
CPanel C
This option is wrong — you mingled the two kinds of atoms without joining them — that is a mixture, not a compound.
DPanel D
This option is wrong — you left lone circles over — in a compound every atom belongs to an identical joined particle.
A compound is one kind of particle, with every particle built from the same two or more different circles joined together. Panel B shows identical joined particles, each made of one medium and one small circle. Unjoined mingled circles are a mixture, and leftover lone circles mean the sample is not a pure compound.
Your turn

On paper, draw a particle diagram of a mixture of an element and a compound in the gas state. Draw at least six particles, then select Continue to compare your drawing with the model answer.

Model answer. A box containing three single large light circles (the element) and three identical joined particles, each one medium shaded circle joined to two small dark circles (the compound). All six particles are widely spaced and spread through the whole box.

  • Two kinds of particles appear: single circles of one kind, and joined particles built from two different circles.
  • Every joined particle looks the same — the same combination of circles each time.
  • The single circles are not joined to the joined particles — the two kinds are mingled, not combined.
  • The particles are widely spaced and fill the whole box, because the mixture is a gas.
model answer particle diagram — 3 single circles scattered far apart throughout the box; 3 two joined circles scattered far apart throughout the box
Your turn

On paper, draw a particle diagram of the element neon — a gas whose particles are single atoms — in a sealed box. Draw at least six particles, then select Continue to compare your drawing with the model answer.

Model answer. A box containing six identical medium shaded circles, none joined to anything, widely spaced and spread through the whole box.

  • Only one kind of circle appears — the same size and shading throughout.
  • No circle is joined to a circle of a different kind.
  • Every particle looks the same as every other particle.
  • The particles are widely spaced and fill the whole box, because neon is a gas.
model answer particle diagram — 6 single circles scattered far apart throughout the box

Lesson 16 of 55 · MPM-016

Homogeneous and heterogeneous mixtures
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Wonder this:

Take two sips from a glass of salt water — one from the top, one from the bottom. The two sips taste exactly the same. Now take two spoonfuls from a bowl of vegetable soup. One spoonful is all broth; the next is crowded with carrots and noodles. Both are mixtures — yet one is the same everywhere, and the other changes spoonful to spoonful.

You've already seen that a mixture contains more than one kind of particle mingled together. Mixtures come in the two kinds you just tasted, and each kind has a name.

The idea

Salt water is the same throughout — every part of it has the same makeup and the same properties.

A mixture that is the same throughout is called a 'homogeneous mixture'.

Air with no dust or smoke is also homogeneous — every breath in a room has the same makeup.

Vegetable soup keeps visibly different parts — one region is broth, another is carrot.

A mixture whose parts remain visibly different is called a 'heterogeneous mixture'.

Muddy water is also heterogeneous — solid specks drift through the liquid as separate visible parts.

two particle boxes — Homogeneous — salt water; the same throughout; Heterogeneous — muddy water; visibly different parts; 12 single circles jumbled touching filling the box; 6 single circles evenly mingled through the box; 12 single circles jumbled touching filling the box; 9 single circles gathered in clumpsHomogeneous — salt waterthe same throughoutHeterogeneous — muddywatervisibly different parts
Two mixtures of two particle kinds. Only the left one has the same makeup everywhere.

In the names, 'homo-' means same and 'hetero-' means different.

The two names answer one question about any mixture: is it the same throughout, or do its parts remain visibly different?

Worked examples

Worked example 1. A pitcher of lemonade has all its sugar dissolved, and every sip from first to last tastes exactly the same. Which kind of mixture is it?

Step 1

Answer: a homogeneous mixture — it is the same throughout.

Worked example 2. A chocolate-chip cookie has chips crowded in some bites and missing from others. Which kind of mixture is it?

Step 1

Answer: a heterogeneous mixture — its parts remain visibly different.

You can now state the difference between a homogeneous mixture, which is the same throughout, and a heterogeneous mixture, whose parts remain visibly different.

Check your understanding

Filtered apple juice is a homogeneous mixture. What does 'homogeneous' say about the juice?

AIt is the same throughout — every part has the same makeup.correct
BIt contains only one kind of particle.
This option is wrong — you described a pure substance — every mixture, homogeneous or not, contains more than one kind of particle.
CIts parts remain visibly different from one another.
This option is wrong — you gave the meaning of heterogeneous — homogeneous is the opposite.
DThe dissolved ingredients have turned into water, so only water remains.
This option is wrong — you treated dissolving as the ingredients becoming water — their particles are still there, mingled among the water particles.
Homogeneous means the same throughout — every part of the mixture has the same makeup and the same properties. The juice still contains water particles, sugar particles, and other kinds, evenly mingled. Visibly different parts would make the mixture heterogeneous instead.
Check your understanding

Trail mix is a heterogeneous mixture. What does 'heterogeneous' say about the trail mix?

AIts parts remain visibly different from one another.correct
BIt is the same throughout, in every handful.
This option is wrong — you gave the meaning of homogeneous — heterogeneous is the opposite.
CIt contains only one kind of particle.
This option is wrong — you described a pure substance — a mixture always contains more than one kind of particle.
DIt must contain at least one liquid.
This option is wrong — you tied heterogeneous to liquids — an all-solid mix of visibly different pieces is heterogeneous too.
Heterogeneous means the parts remain visibly different — a peanut here, a raisin there. The word says nothing about which states are present, only that the parts stay visibly distinct. A mixture that is the same throughout is homogeneous instead.
Check your understanding

Sweetened iced tea, with all its sugar dissolved, and a fruit salad are both mixtures. What is the difference between them?

AThe tea is the same throughout, while the fruit salad keeps visibly different parts.correct
BThe tea is a pure substance, while the fruit salad is a mixture.
This option is wrong — you treated the uniform mixture as pure — the tea still contains sugar particles and water particles mingled.
CThe tea contains only one kind of particle, while the fruit salad contains many kinds.
This option is wrong — you forgot that the tea holds sugar, water, and tea particles — being the same throughout does not mean one particle kind.
DThe sugar in the tea has stopped being sugar, while the salad's parts stay themselves.
This option is wrong — you treated dissolving as a change of substance — the dissolved sugar particles are unchanged.
Both are mixtures — each contains more than one kind of particle mingled together. The sweetened tea is homogeneous: the same throughout, every sip alike. The fruit salad is heterogeneous: its parts remain visibly different.

Lesson 17 of 55 · MPM-017

Classifying real mixtures
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Did You Know?

You've already seen the two kinds of mixture: homogeneous means the same throughout, and heterogeneous means the parts remain visibly different. Real mixtures arrive as descriptions — a glass of this, a bowl of that — and you classify them.

The idea

To classify a mixture, ask one question: does every part of it have the same makeup, or can you see or pick out different parts?

If every part is the same — every sip, every spoonful, every sample — the mixture is homogeneous.

If different parts remain visible — layers, pieces, specks, or regions — the mixture is heterogeneous.

Judge the mixture as a whole, not its ingredient list — a homogeneous mixture still contains more than one kind of particle.

Counting ingredients does not decide the answer; a mixture of many ingredients is still homogeneous when it is the same throughout.

Solids and gases classify the same way as liquids — a metal blend with its atoms evenly mingled is homogeneous, and dust swirling in air is heterogeneous.

Worked examples

Worked example 1. Orange juice with pulp has soft solid pieces drifting through the liquid. Classify the mixture.

Step 1

Ask the question: can you see or pick out different parts?

Step 2

The pulp pieces are visible parts, distinct from the liquid around them.

Step 3

Orange juice with pulp is a heterogeneous mixture.

Worked example 2. Sweet tea has its sugar fully dissolved, and every sip tastes equally sweet. Classify the mixture.

Step 1

Ask the question: does every part have the same makeup?

Step 2

Every sip is alike — no part of the tea differs from another.

Step 3

Sweet tea is a homogeneous mixture.

You can now classify a mixture as homogeneous or heterogeneous from a description of its appearance and makeup.

Check your understanding

A sports drink has all of its ingredients fully dissolved, and every mouthful from the bottle is the same. Classify the drink.

AA homogeneous mixture.correct
BA heterogeneous mixture.
This option is wrong — you counted ingredients instead of checking uniformity — many ingredients can still be evenly mingled, making every mouthful the same.
CA pure substance.
This option is wrong — you judged purity by appearance — the clear drink still contains several kinds of particles mingled together.
DA compound.
This option is wrong — you treated mingling as chemical joining — the dissolved particles stay their own kinds, so the drink is a mixture.
Ask the one question: is the mixture the same throughout? Every mouthful is the same, so the drink is homogeneous. Ingredient count does not matter, and dissolved ingredients are mingled, not joined.
Check your understanding

A bottle of salad dressing stands with a layer of oil floating on top of a layer of vinegar. Classify the dressing.

AA heterogeneous mixture.correct
BA homogeneous mixture.
This option is wrong — you assumed all-liquid mixtures are uniform, or classified one layer instead of the whole bottle — the oil layer and the vinegar layer are visibly different parts.
CA pure substance.
This option is wrong — you classified the ingredients instead of the mixture — two liquids together are a mixture.
DA compound.
This option is wrong — you treated standing together in one bottle as chemical joining — the oil and vinegar particles are not joined into one kind of particle.
Judge the mixture as a whole: the oil layer and the vinegar layer are visibly different parts. Visibly different parts make the dressing heterogeneous. Uniformity within one layer does not make the whole bottle the same throughout.
Check your understanding

Brass is a solid made of copper atoms and zinc atoms evenly mingled, so every part of a brass block has the same makeup. Classify brass.

AA homogeneous mixture.correct
BA heterogeneous mixture.
This option is wrong — you counted components instead of checking uniformity — the two kinds of atoms are evenly mingled everywhere.
CA compound.
This option is wrong — you treated mingling as chemical joining — the copper and zinc atoms are not joined into one kind of particle.
DAn element.
This option is wrong — you treated every metal as one element — brass contains two kinds of atoms, so it cannot be an element.
Solids classify the same way as liquids: ask whether the sample is the same throughout. Every part of the block has the same makeup, so brass is homogeneous. The copper and zinc atoms are mingled, not joined — brass stays a mixture, not a compound.

Lesson 18 of 55 · MPM-018

The full classification scheme
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You've already met all four classes of matter one at a time: elements, compounds, homogeneous mixtures, and heterogeneous mixtures. Two questions, asked in order, sort any sample into exactly one of them.

The idea

First question: does the sample contain one kind of particle, or more than one kind mingled together?

One kind of particle means a pure substance; more than one kind means a mixture.

For a pure substance, ask the second question: are its particles made of one kind of atom, or of two or more kinds joined together?

One kind of atom means an element; two or more kinds joined in every particle means a compound.

For a mixture, ask the second question: is it the same throughout, or do its parts remain visibly different?

The same throughout means a homogeneous mixture; visibly different parts mean a heterogeneous mixture.

Every sample of matter lands in exactly one of the four classes.

decision tree: Classifying a sample of matterClassifying a sample of matterHow many kinds of particle?one kindpure substancemore than one kind, mingledmore than one kind, mingledmixturePure substance: how many kinds of atom ineach particle?one kindELEMENTtwo or more kinds, joinedtwo or more kinds, joinedCOMPOUNDMixture: same throughout?same throughoutHOMOGENEOUS MIXTUREvisibly different partsHETEROGENEOUSMIXTURE
Two questions, asked in order, sort any sample into one of four classes.
Worked examples

Worked example 1. Clean air is several kinds of gas particles mingled together, and every breath in a room has the same makeup. Classify clean air.

Step 1

First question: more than one kind of particle, mingled — so clean air is a mixture.

Step 2

Second question: every sample has the same makeup — the mixture is the same throughout.

Step 3

Clean air is a homogeneous mixture.

Worked example 2. In carbon dioxide gas, every particle is identical: one carbon atom joined to two oxygen atoms. Classify carbon dioxide.

Step 1

First question: one kind of particle only — so carbon dioxide is a pure substance.

Step 2

Second question: each particle contains two different kinds of atoms, joined together.

Step 3

Carbon dioxide is a compound.

You can now classify a sample as an element, a compound, a homogeneous mixture, or a heterogeneous mixture from a description of its makeup.

Check your understanding

Aluminum foil contains only aluminum atoms, all alike, none joined to atoms of any other kind. Classify the foil.

AAn element.correct
BA compound.
This option is wrong — you treated the tight packing of the atoms as chemical joining between different kinds — a compound needs two or more different kinds of atoms joined, and every atom here is aluminum.
CA homogeneous mixture.
This option is wrong — you skipped the first question — one kind of particle makes the foil a pure substance, and 'same throughout' only sorts mixtures.
DA heterogeneous mixture.
This option is wrong — you counted the separate aluminum atoms as visibly different parts — the parts of a heterogeneous mixture must be different kinds of matter.
First question: one kind of particle, so the foil is a pure substance. Second question: one kind of atom, so the pure substance is an element. Uniformity matters only after a sample is known to be a mixture.
Check your understanding

Filtered seawater contains several kinds of dissolved particles mingled with water particles, and every drop has the same makeup. Classify the filtered seawater.

AA homogeneous mixture.correct
BA compound.
This option is wrong — you treated dissolving as joining — the dissolved particles mingle among the water particles and stay their own kinds.
CA heterogeneous mixture.
This option is wrong — you counted the many particle kinds instead of checking uniformity — every drop of the seawater is the same, so the mixture is homogeneous.
DAn element.
This option is wrong — you judged by the clear look — several particle kinds are still present, so the seawater is not a pure substance at all.
First question: more than one kind of particle, so the sample is a mixture. Second question: every drop has the same makeup, so the mixture is homogeneous. Dissolved particles are mingled with the water, never joined to it.
Check your understanding

Granite is a rock in which pink, gray, and black mineral grains are locked together, each grain visible and distinct. Classify granite.

AA heterogeneous mixture.correct
BA homogeneous mixture.
This option is wrong — you treated being one solid piece as being the same throughout — the pink, gray, and black grains stay visible and distinct.
CA compound.
This option is wrong — you treated the grains being locked together as chemical joining — the minerals are separate materials, not one kind of particle.
DAn element.
This option is wrong — you classified by the everyday name 'rock' — the visibly different grains show several components.
First question: the different grains are different components, so granite is a mixture. Second question: the grains remain visibly different, so the mixture is heterogeneous. Being solid and stuck together does not make a sample one substance.
Summary video — States of matter and classifying matter

Watch in David’s player

End of Topic Test

End of Topic Test — five interchangeable forms, delivered separately.

Intro video — Physical and chemical changes and the measurement toolkit

Watch in David’s player

Lesson 19 of 55 · MPM-019

Physical and chemical properties
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Wonder this:

You can find the temperature at which candle wax melts and keep every bit of the wax — the melted wax is still wax. Try instead to learn whether the wax burns, and the wax you test is gone: the flame turns it into something new. Some properties can be checked while the substance stays itself; others only show up as the substance becomes something else.

Every substance has properties — its color, its hardness, how it melts, whether it burns. Chemists split these properties into two kinds.

The idea

Some properties can be observed or measured while the substance stays itself — checking them turns the substance into nothing new.

A property like that is called a 'physical property'.

Color, hardness, and the state at room temperature are physical properties.

The temperature at which a solid melts is called its 'melting point', and the temperature at which a liquid boils is called its 'boiling point'.

Melting point and boiling point are physical properties — the melted or boiled substance is still the same substance.

Other properties describe how a substance can turn into a different substance.

A property like that is called a 'chemical property'.

Flammability — the ability to burn — is a chemical property, because burning turns a substance into new substances.

The ability of iron to rust is also a chemical property, because rust is a new substance formed from the iron.

Worked examples

Worked example 1. The melting point of ice is 0 °C. Why is melting point a physical property?

Step 1

Answer: measuring it only turns the ice to liquid water — the same substance, so nothing new forms.

Worked example 2. Gasoline is flammable. Why is flammability a chemical property?

Step 1

Answer: it describes the gasoline turning into new substances when it burns.

You can now state the difference between a physical property, which can be observed or measured without turning the substance into anything new, and a chemical property, which describes how a substance can turn into a different substance.

Check your understanding

What makes a property of a substance a physical property?

AIt can be observed or measured while the substance turns into nothing new.correct
BIt describes how the substance can turn into a different substance.
This option is wrong — you gave the meaning of a chemical property — physical properties leave the substance itself.
CIt can only be seen while the substance is melting or boiling.
This option is wrong — you tied physical properties to state changes alone — color and hardness are physical properties too.
DIt can be observed without using any instrument.
This option is wrong — you made instrument-free observation the test — measuring a melting point uses a thermometer and is still physical.
A physical property can be observed or measured while the substance stays itself. Color, hardness, state at room temperature, melting point, and boiling point are all physical properties. A property about turning into a different substance is chemical instead.
Check your understanding

What makes a property of a substance a chemical property?

AIt describes how the substance can turn into a different substance.correct
BIt can be observed or measured while the substance stays itself.
This option is wrong — you gave the meaning of a physical property — chemical properties are about becoming something new.
CIt describes the chemicals the substance contains.
This option is wrong — you read 'chemical' as meaning made of chemicals — the word marks properties about turning into new substances.
DIt can only be observed with laboratory instruments.
This option is wrong — you made instrument use the test — watching wood burn needs no instrument and reveals a chemical property.
A chemical property describes how a substance can turn into a different substance. Flammability and the ability of iron to rust are chemical properties. Whether instruments are involved does not decide the kind of property.
Check your understanding

A student measures the temperature at which a butter sample melts. The melted butter is still butter. Which kind of property did the student measure, and why?

AA physical property, because the butter turned into nothing new during the measurement.correct
BA chemical property, because the butter changed from solid to liquid.
This option is wrong — you treated a change of state as a change of substance — melted butter is still butter.
CA chemical property, because heating was needed for the measurement.
This option is wrong — you made the use of heat the test — heat can drive physical and chemical events alike.
DA chemical property, because the liquid butter is a new substance.
This option is wrong — you treated liquid butter as different from solid butter — the state changed, the substance did not.
The test for a physical property: the substance stays itself while you observe or measure. The melted butter is still butter, so the melting point is a physical property. Neither the state change nor the heating turns the butter into a new substance.

Lesson 20 of 55 · MPM-020

Classifying properties
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Did You Know?

You've already seen the two kinds of property: physical properties can be checked while the substance stays itself, and chemical properties describe how it can turn into a different substance. Now you classify whatever property you are given.

The idea

To classify a property, ask one question: can it be observed or measured while the substance stays the same substance?

If yes, the property is physical.

If the property only shows itself as the substance turns into a different substance, the property is chemical.

The tools involved do not decide the answer — thermometers, flames, and instruments can appear in checks of either kind.

State changes do not make a property chemical — a substance that melts, boils, or freezes is still the same substance.

Worked examples

Worked example 1. Classify this property of sulfur: it is bright yellow.

Step 1

Ask the question: can the color be observed while the sulfur stays sulfur?

Step 2

Looking at the sample changes nothing — the sulfur stays itself.

Step 3

The yellow color is a physical property.

Worked example 2. Classify this property of natural gas: it can burn.

Step 1

Ask the question: does the property only show itself as the gas turns into something new?

Step 2

Burning turns the gas into new substances — the property is about becoming something else.

Step 3

The ability to burn is a chemical property.

Worked example 3. Classify this property of copper: it slowly turns green in damp air.

Step 1

The green layer is a new substance formed from the copper — the copper does not stay itself.

Step 2

The property only shows itself as the copper turns into something new.

Step 3

Turning green in damp air is a chemical property.

You can now classify a property of a substance as physical or chemical.

Check your understanding

Which of these is a chemical property of silver?

AIt slowly turns dark when left out in the air.correct
BIt is shiny.
This option is wrong — you picked a property observable while the silver stays itself — that makes it physical.
CIt is hard enough to scratch wax.
This option is wrong — you picked a property measurable with the silver unchanged — hardness is physical.
DIt melts at 962 °C.
This option is wrong — you treated melting as becoming a new substance — melted silver is still silver, so melting point is physical.
Ask of each property: does it only show itself as the silver turns into something new? The dark layer is a new substance formed from the silver, so that property is chemical. Shine, hardness, and melting point can all be checked while the silver stays silver.
Check your understanding

Which of these is a physical property of cooking oil?

AIt flows more slowly than water does.correct
BIt can catch fire when overheated.
This option is wrong — you picked a property about the oil turning into new substances — catching fire is chemical.
CIt slowly goes rancid, forming sour-smelling new substances.
This option is wrong — you picked a property about new substances forming — going rancid is chemical.
DIt reacts with strong cleaners to form soap.
This option is wrong — you picked a property about turning into a different substance — forming soap is chemical.
Ask of each property: can it be measured while the oil stays oil? How quickly the oil flows can be watched while the oil stays oil — nothing new forms, so it is physical. Catching fire, going rancid, and forming soap all describe the oil becoming new substances.
Check your understanding

When strongly heated, sugar chars — it turns into black material and steamy vapor that are no longer sugar. Classify this property of sugar.

AChemical, because charring turns the sugar into new substances.correct
BPhysical, because the sugar only changes color.
This option is wrong — you read charring as a color change alone — the black material is a new substance, not dark sugar.
CPhysical, because heating drives the change and heating is physical.
This option is wrong — you made heat the test — heat can drive physical and chemical events alike.
DChemical, because every change caused by strong heat is chemical.
This option is wrong — you used a false rule — strong heat also just melts many substances, which is physical; what decides is that new substances formed.
Ask the question: does the property only show itself as the sugar turns into something new? The black material and the vapor are no longer sugar, so new substances formed. That makes charring a chemical property — the heat is only the trigger, not the test.

Lesson 21 of 55 · MPM-021

Physical and chemical changes
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Wonder this:

Crush an empty aluminum can flat. It looks completely different — yet every bit of it is still aluminum. Now strike a match and let it burn out. The head and the wood become black, crumbly material and smoke, and nothing you do brings the match back. Both are changes, but only one of them made new substances.

You've already sorted properties into physical and chemical. Changes — events that happen to a substance — sort into the same two kinds.

The idea

In some changes, the substance keeps its identity — it is the same substance before and after, in a new shape, size, or state.

A change like that is called a 'physical change'.

Crushing, tearing, melting, freezing, boiling, and dissolving are physical changes.

In other changes, one or more new substances form — the starting substance stops being itself.

A change like that is called a 'chemical change'.

Burning and rusting are chemical changes — the materials left behind are new substances.

One question separates the two kinds: did a new substance form?

Worked examples

Worked example 1. A stick of chalk is snapped in half. Is the change physical or chemical?

Step 1

Answer: physical — every piece is still chalk, so no new substance formed.

Worked example 2. A cut avocado's surface slowly turns brown, and the brown layer is a new substance the fresh fruit did not contain. Is the change physical or chemical?

Step 1

Answer: chemical — a new substance formed.

You can now state the difference between a physical change, in which the substance keeps its identity, and a chemical change, in which one or more new substances form.

Check your understanding

What happens to a substance during a physical change?

AIt keeps its identity — it is the same substance afterward.correct
BOne or more new substances form from it.
This option is wrong — you gave the meaning of a chemical change — physical changes leave the substance itself.
CIt must change from one state to another.
This option is wrong — you made state change the only physical change — crushing and tearing are physical changes with no state change.
DIts particles are destroyed and replaced.
This option is wrong — you treated a physical change as destroying particles — the substance, and its particles, stay what they were.
In a physical change, the substance is the same substance before and after. Only its shape, size, or state is different. New substances forming would make the change chemical instead.
Check your understanding

What marks a change as a chemical change?

AOne or more new substances form.correct
BThe substance changes shape or size.
This option is wrong — you gave marks of a physical change — a reshaped substance is still itself.
CThe substance melts or boils.
This option is wrong — you listed state changes — melting and boiling leave the same substance, so they are physical.
DThe change is fast, hot, or loud.
This option is wrong — you judged by drama — quiet, slow rusting is chemical, and violent shattering is physical.
The one question: did a new substance form? If the starting substance stopped being itself, the change is chemical. Speed, heat, and noise decide nothing.
Check your understanding

Hammering a gold nugget flat into a thin sheet is a physical change. What makes it physical?

AThe flattened sheet is still gold — no new substance formed.correct
BThe nugget's shape changed only a little.
This option is wrong — you graded the change by size — even a drastic reshaping is physical when the substance stays itself.
CHammering cannot be undone, so nothing new could have formed.
This option is wrong — you tied the classification to undoing — whether a change can be reversed is not the test.
DGold is a metal, and metals only change physically.
This option is wrong — you used a false rule about metals — iron rusting is a chemical change in a metal.
Ask the one question: did a new substance form? Every bit of the flattened sheet is still gold, so no new substance formed. How drastic the change looks, and whether it can be undone, decide nothing.

Lesson 22 of 55 · MPM-022

Why state changes are physical
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Did You Know?

You've already seen that melting, freezing, boiling, and dissolving are physical changes — the substance keeps its identity. The particle model says why.

The idea

During a state change, every particle keeps being exactly the particle it was.

Melting ice loosens the water particles from their fixed positions so they can slide past one another — but each particle is still a water particle.

two particle boxes — Solid ice; fixed positions; Liquid water; sliding past one another; same particles — only their spacing and movement change; 16 single circles in neat touching rows at the bottom; 14 single circles jumbled touching at the bottomsame particles — only their spacing and movement changeSolid icefixed positionsmeltingLiquid watersliding past one another
Count the circles: the same particles appear in both boxes.

Boiling spreads the water particles far apart so they fly freely — but each particle is still a water particle.

State changes are physical changes because the particles themselves do not change — only their spacing and movement change.

Dissolving works the same way: sugar particles spread out and mingle among water particles, and both kinds stay exactly what they were.

The sweet taste of sugar water is the unchanged sugar particles at work.

A chemical change is different — new substances form, so the particles present afterward are no longer the particles you started with.

Worked examples

Worked example 1. Melted candle wax is still wax. Why?

Step 1

Melting moved the wax particles out of their fixed positions so they slide past one another.

Step 2

Each particle is still a wax particle.

Step 3

Melting is a physical change because the particles themselves do not change — only their spacing and movement change.

Worked example 2. A puddle dries up on a warm sidewalk. Why is the drying a physical change?

Step 1

The water particles escaped into the air as a gas, spreading far apart.

Step 2

Each escaped particle is still a water particle — the water has moved, not become something new.

Step 3

Evaporation is a physical change because the particles themselves do not change — only their spacing and movement change.

You can now explain why state changes and dissolving are physical changes, because the particles themselves do not change — only their spacing and movement change.

Check your understanding

A bar of gold melts in a jeweler's furnace. Why is the melting a physical change?

ABecause the particles themselves do not change — only their spacing and movement change.correct
BBecause the solid's particles are destroyed and liquid particles are created.
This option is wrong — you replaced the particles — the very same gold particles are there before and after.
CBecause the particles melt into smaller, softer particles.
This option is wrong — you melted the particles — particles do not melt; the arrangement loosens while each particle stays the same.
DBecause melting can always be reversed by freezing.
This option is wrong — you made reversibility the reason — the reason is that the particles stay unchanged.
Melting loosens the gold's particles from their fixed positions so they slide past one another. Each particle is still a gold particle — nothing about the particle itself is different. That is the mark of a physical change: only spacing and movement change.
Check your understanding

A spoonful of drink-mix crystals stirred into a glass of water seems to vanish. Why is the dissolving a physical change?

AThe drink mix's particles are unchanged — only spread out among the water particles.correct
BThe drink mix's particles break apart and become water particles.
This option is wrong — you turned the drink mix into water — its particles keep their own identity, mingled among the water particles.
CThe drink mix turns into a new liquid substance mixed with the water.
This option is wrong — you created a new substance — dissolving only mingles the existing particles.
DThe drink mix's particles dissolve away to nothing.
This option is wrong — you destroyed the particles — every one of them is still in the glass, spread among the water particles.
Dissolving spreads the drink mix's particles out among the water particles. Both kinds of particles stay exactly what they were. Physical change: the particles themselves do not change — only their spacing and movement change.
Check your understanding

When rubbing alcohol is warmed, the liquid boils away into a gas. Why is the boiling a physical change?

AThe particles spread far apart and move freely, but each one is still an alcohol particle.correct
BThe alcohol particles split into two different gases.
This option is wrong — you split the particles — boiling does not take particles apart; the vapor is still alcohol.
CThe heat creates new vapor particles to replace the alcohol particles.
This option is wrong — you replaced the particles — the vapor is made of the very same particles that were in the liquid.
DBoiling is actually a chemical change, because a gas forms.
This option is wrong — you treated any gas as a new substance — this gas is the same substance in a new state.
Boiling spreads the alcohol's particles far apart so they fly freely. Each particle in the vapor is still an alcohol particle. The particles themselves do not change — only their spacing and movement change — so boiling is physical.

Lesson 23 of 55 · MPM-023

Signs of a chemical change
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Particles are far too small to watch, so nobody ever sees new substances form directly. Yet a chemist watching a beaker can still call out 'chemical change!' — because chemical changes leave clues big enough to see.

You've already seen the test for a chemical change: one or more new substances form. Five kinds of observation are the standard clues that it may have happened.

The idea

A color change is a sign — a sliced apple slowly turning brown.

A new gas is a sign — fizzing or bubbles appearing in a liquid that is not being boiled.

A new solid is a sign — a solid appearing when two liquids are mixed.

A temperature change is a sign — a mixture growing hot or cold on its own, with no outside heating or cooling.

Given-off light is a sign — a material glowing or flaming.

Each sign says 'a chemical change MAY have happened' — the signs are clues, not proof.

Worked examples

Worked example 1. Baking soda stirred into vinegar erupts in bubbles, with no heating anywhere. Which sign of a possible chemical change is this?

Step 1

Bubbles stream out of a liquid that is not being boiled.

Step 2

A gas is appearing where there was none.

Step 3

The sign is a new gas.

Worked example 2. Two clear liquids are mixed, and the mixture instantly turns deep orange. Which sign of a possible chemical change is this?

Step 1

Both starting liquids were clear, and the mixture is now orange.

Step 2

The color of the matter in the beaker has changed.

Step 3

The sign is a color change.

You can now identify observations that signal a possible chemical change, including a color change, a new gas, a new solid forming in a mixed liquid, a temperature change, and given-off light.

Check your understanding

Two clear liquids are mixed, and a bright yellow solid appears and settles to the bottom. Which sign of a possible chemical change was observed?

AA new solid forming in a mixed liquid.correct
BA color change of the liquids.
This option is wrong — you read the yellow solid as the liquid changing color — the observation is a solid appearing, not the liquid recoloring.
CA new gas appearing.
This option is wrong — you picked a sign that was not observed — nothing fizzed or bubbled.
DGiven-off light.
This option is wrong — you picked a sign that was not observed — nothing glowed or flamed.
Match the observation to the sign list. A solid appeared where two liquids were mixed — that is the new-solid sign. The liquid itself did not change color, and no gas or light appeared.
Check your understanding

A cold pack is squeezed so the pouches inside it mix. The pack turns icy cold, with no refrigeration anywhere. Which sign of a possible chemical change was observed?

AA temperature change happening on its own.correct
BA new gas appearing.
This option is wrong — you picked a sign that was not observed — nothing fizzed or bubbled.
CA color change.
This option is wrong — you picked a sign that was not observed — nothing changed color.
DA new solid forming in a mixed liquid.
This option is wrong — you picked a sign that was not observed — no solid appeared.
The mixed contents grew cold on their own — no refrigerator, no ice, no outside cooling. A temperature change with no outside cause is one of the five signs. The other four signs need something to appear or change that was not observed here.
Check your understanding

Which observation is a sign of a possible chemical change?

AA dull gray strip slowly turns green over several weeks.correct
BAn ice cube softens into a puddle of water.
This option is wrong — you picked a state change — melting is a physical change, not a sign of a chemical one.
CA sugar cube seems to vanish when stirred into tea.
This option is wrong — you picked dissolving — the sugar particles are unchanged, so nothing signals a new substance.
DA puddle shrinks away on a hot afternoon.
This option is wrong — you picked evaporation — the water is escaping as a gas, not becoming a new substance.
Check each observation against the five signs. The gray-to-green change is a color change — one of the five signs. Melting, dissolving, and evaporating are physical events, not signs of a chemical change.

Lesson 24 of 55 · MPM-024

When signs can fool you
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You've already seen the five signs of a possible chemical change. Sometimes a sign appears — and no chemical change is happening at all.

The idea

A sign is a clue, not proof — bubbles rise through boiling water, yet no new substance is forming.

The gas in those bubbles is water vapor: still water, only in the gas state.

To judge a sign, ask the deciding question: did a new substance actually form?

If the 'new' material is the same substance in a new state or a new place, the change is physical and the sign fooled you.

If the material really is a different substance from everything you started with, the sign is confirmed.

Outside causes can fake a sign too — a mixture warmed by a stove shows a temperature change without any chemical change.

Worked examples

Worked example 1. A pot of water boils, and big bubbles rise through it. A student says the bubbles prove a chemical change. Judge the claim.

Step 1

Apply the deciding question: did a new substance actually form?

Step 2

The gas in the bubbles is water vapor — still water, only in the gas state.

Step 3

The claim fails — no new substance formed, so the new-gas sign fooled the student.

Worked example 2. Wet laundry hung on a line dries in the warm sun. A friend says the water in the cloth was destroyed by a chemical change. Judge the claim.

Step 1

Apply the deciding question: did a new substance actually form?

Step 2

The water particles escaped from the cloth into the air as a gas — the water moved, it did not become something new.

Step 3

The claim fails — the water is still water, spread through the air, so the change is physical.

You can now judge whether an observed sign proves that a chemical change occurred, checking whether a new substance actually formed.

Check your understanding

A cold soda is opened and bubbles stream upward. The fizz is gas that was dissolved into the drink at the factory. Does the bubbling prove a chemical change?

ANo — the gas already existed and is escaping the liquid, so no new substance formed.correct
BYes — a new gas is one of the five signs, so the change must be chemical.
This option is wrong — you treated a sign as proof — the deciding question is whether a new substance actually formed.
CYes — bubbles always mean a new substance has formed.
This option is wrong — you used a false rule — dissolved gas escaping and boiling both bubble without any new substance.
DNo — but only because the bubbles are too small to count as a gas.
This option is wrong — you dismissed the observation instead of checking identity — the bubbles are gas, just not a NEW gas.
Ask the deciding question: did a new substance actually form? The gas was already in the drink, dissolved — it is escaping, not forming. A sign is a clue, not proof; here the new-gas sign fooled anyone who skipped the check.
Check your understanding

During a hot shower, a bathroom mirror fogs with tiny droplets. A student says the fog proves a chemical change created a new liquid. Judge the claim.

AThe claim fails — the droplets are water from the steam, the same substance in a new state.correct
BThe claim holds — a liquid appeared where there was none.
This option is wrong — you treated appearing somewhere new as being a new substance — the water only moved and changed state.
CThe claim holds — the mirror's surface reacted with the steam.
This option is wrong — you invented a reaction — the mirror only gave the steam a cold surface to condense on.
DThe claim fails — but only because the droplets disappear again later.
This option is wrong — you used disappearance as the check — the deciding question is whether a new substance formed, not whether the material lasts.
Ask the deciding question: did a new substance actually form? The droplets are water that left the shower's steam and condensed on the cold mirror. Same substance, new state and new place — a physical change.
Check your understanding

A spoonful of sugar heated gently in a pan turns into a clear, runny liquid that is still sugar. A student says a chemical change happened because the solid became something new. Judge the claim.

AThe claim fails — the liquid is still sugar, so only the state changed and no new substance formed.correct
BThe claim holds — turning from solid to liquid always makes a new substance.
This option is wrong — you treated a state change as a change of substance — melted sugar is still sugar.
CThe claim holds — the heat of the pan makes the change chemical.
This option is wrong — you made outside heating the mark of a chemical change — outside heat explains the melting without anything new forming.
DThe claim fails — but only because gentle heat is too weak for chemistry.
This option is wrong — you judged by strength of heating — the reason the claim fails is that the liquid is still sugar.
Ask the deciding question: did a new substance actually form? The runny liquid is still sugar — the same substance in a new state. Melting is physical, however the heat that caused it was supplied.

Lesson 25 of 55 · MPM-025

Classifying changes
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You've already seen the boundary between physical and chemical change, the particle reason behind it, the five signs, and the check that keeps signs from fooling you. Classifying a described change uses all of it.

The idea

To classify a described change, ask the one deciding question: did a new substance form?

Judge by the evidence, not the drama — a slow, quiet change can be chemical, and a sudden, violent one can be physical.

Check each sign before trusting it — a gas that is just the boiled starting substance, or warmth from an outside heater, proves nothing.

Changes of shape, size, state, or mixing leave the substance itself, so they are physical.

Evidence that a genuinely different substance appeared makes the change chemical.

Worked examples

Worked example 1. A frying egg turns from a clear liquid to a white solid, and no cooling ever turns it back. Classify the change.

Step 1

Apply the deciding question: did a new substance form?

Step 2

The white solid behaves like nothing that was in the raw egg — the egg's substances have become new substances.

Step 3

Frying the egg is a chemical change.

Worked example 2. A sheet of paper is fed through a shredder and comes out as thin strips. Classify the change.

Step 1

Apply the deciding question: did a new substance form?

Step 2

The strips are still paper — only the size and shape changed.

Step 3

Shredding the paper is a physical change.

You can now classify a described change as physical or chemical from the evidence given.

Check your understanding

A bicycle chain left out in the rain grows patches of flaky orange rust that were not there before. Classify the change.

AChemical — the rust is a new substance formed from the metal.correct
BPhysical — only the chain's surface was affected.
This option is wrong — you judged by how much of the object changed — even a thin surface layer of new substance makes the change chemical.
CPhysical — the chain is still a chain.
This option is wrong — you classified the object instead of the substance — some of the metal is now rust, a different substance.
DChemical — because any change caused by water is chemical.
This option is wrong — you used a false rule — water also just dissolves sugar or freezes, which is physical; here it is the new substance that decides.
Ask the deciding question: did a new substance form? Flaky orange rust is a new substance the shiny metal did not contain. The change is chemical, however slowly and quietly it happened.
Check your understanding

Juice poured into a tray freezes solid in the freezer, and it thaws back into the same juice. Classify the freezing.

APhysical — the frozen juice is still juice; only its state changed.correct
BChemical — a solid formed where there was only liquid.
This option is wrong — you treated the new state as a new substance — the solid is the same juice with its particles locked in place.
CChemical — the juice can no longer be poured, so it must be something new.
This option is wrong — you classified by behavior of the state — a substance in a different state behaves differently while staying itself.
DPhysical — because cold can never cause a chemical change.
This option is wrong — you used a false rule — temperature does not decide the class; the unchanged substance does.
Ask the deciding question: did a new substance form? The solid is the same juice — thawing returns it unchanged. Freezing changes spacing and movement of the particles, nothing else.
Check your understanding

Slices of bread toast to a brown, crisp surface with a new smell that fresh bread does not have. Classify the change.

AChemical — the brown material and new smell show new substances formed.correct
BPhysical — the bread only dried out in the heat.
This option is wrong — you explained away the evidence — drying alone would not create a brown material and a smell the bread never had.
CPhysical — the toast is still bread, just crisper.
This option is wrong — you classified by the everyday name — the browned surface is made of new substances, whatever the slice is called.
DChemical — because heat always causes chemical change.
This option is wrong — you used a false rule — heat also just melts butter; here it is the new substances that decide.
Ask the deciding question: did a new substance form? The brown, crisp material and the new smell are evidence of substances fresh bread does not contain. The change is chemical — the heat is the trigger, and the new substances are the proof.

Lesson 26 of 55 · MPM-026

Qualitative and quantitative data
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One lab partner writes: 'the water got pretty warm.' The other writes: 'the water reached 38.5 °C.' A scientist on the other side of the world can check the second entry exactly — the first, they can only guess at.

Both entries are observations, and both are useful evidence. Chemists sort observations into two kinds.

The idea

An observation that describes a quality in words — a color, a smell, a texture, a behavior — is called 'qualitative data'.

'The liquid turned cloudy' is qualitative: it records what was seen, with no number.

An observation that records a measured number or a count is called 'quantitative data'.

'The water reached 38.5 °C' is quantitative: it records a measured number.

The test is the record itself — does the observation contain a measured number or count?

What could have been measured does not matter: 'the beaker felt hot' is qualitative, even though a thermometer could have given a number.

Worked examples

Worked example 1. Classify the observation: 'the flame burned bright orange.'

Step 1

Apply the test: does the record contain a measured number or count?

Step 2

It contains none — it describes a color in words.

Step 3

'The flame burned bright orange' is qualitative data.

Worked example 2. Classify the observation: 'the powder's mass was 12.4 g.'

Step 1

Apply the test: does the record contain a measured number or count?

Step 2

It records a measured number — 12.4 g.

Step 3

'The powder's mass was 12.4 g' is quantitative data.

You can now classify an observation as qualitative or quantitative.

Check your understanding

Which observation is quantitative?

AThe mixture's temperature rose to 31.0 °C.correct
BThe mixture foamed up suddenly.
This option is wrong — you picked a worded quality — no number or count was recorded.
CThe mixture smelled sharp.
This option is wrong — you picked a worded quality — a smell described in words carries no measurement.
DThe mixture fizzed for a long time.
This option is wrong — you treated 'a long time' as a measurement — without a number, duration in words is qualitative.
Apply the test: does the record contain a measured number or count? Only 'rose to 31.0 °C' records a measured number. Foaming, sharp-smelling, and 'a long time' are qualities in words.
Check your understanding

Classify the observation: 'the powder is bright white.'

AQualitative — it describes a quality in words, with no measured number or count.correct
BQuantitative — 'bright' compares how much light the powder reflects.
This option is wrong — you treated a describing word as a measurement — no number was recorded.
CQuantitative — color can be measured with instruments.
This option is wrong — you classified what COULD be measured — the test is what the record contains, and this record has no number.
DQuantitative — 'bright white' names an exact shade.
This option is wrong — you treated an exact-sounding phrase as a count — words alone, however precise they sound, are qualitative.
Apply the test: does the record contain a measured number or count? 'Bright white' is a quality in words — no number, no count. What an instrument could have measured does not change what was recorded.
Check your understanding

A student records: 'exactly 3 drops of the liquid were added.' Classify the observation.

AQuantitative — it records a count.correct
BQualitative — no instrument was used to take it.
This option is wrong — you required an instrument — a count is quantitative however it was obtained.
CQualitative — drops vary in size, so the number is not exact.
This option is wrong — you judged the precision instead of the kind — an imprecise count is still a count.
DQualitative — the observation is written as a sentence, not as a data table.
This option is wrong — you judged the format — a sentence containing a count records quantitative data.
Apply the test: does the record contain a measured number or count? 'Exactly 3 drops' records a count — quantitative data. Instruments, precision, and formatting play no part in the test.

Lesson 27 of 55 · MPM-027

Units for mass, volume, and temperature
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A bread recipe calls for 'one cup' of flour — but cups in different kitchens hold different amounts, and the loaves come out different. A measurement is only useful if everyone who reads it gets exactly the same amount.

Quantitative data needs units that read the same to every scientist on Earth. Chemists take theirs from one shared system.

The idea

Scientists everywhere share one set of measurement units, called the 'International System of Units' — 'SI' for short.

For mass, chemists record grams (g), and kilograms (kg) for larger amounts.

For volume, chemists record liters (L) and milliliters (mL), and cubic centimeters (cm³) work for solids and liquids alike.

One milliliter is exactly one cubic centimeter — 1 mL = 1 cm³ — so a volume keeps the same number in either unit.

For temperature, chemists record degrees Celsius (°C) in everyday lab work.

The SI base unit for temperature is the 'kelvin' (K) — for now only its name matters; the course returns to it with gases.

The chemist's everyday units

QuantityUnits chemists recordNote
massgrams (g), kilograms (kg)grams for small amounts
volumeliters (L), milliliters (mL), cubic centimeters (cm³)1 mL = 1 cm³
temperaturedegrees Celsius (°C)SI base unit: the kelvin (K)
One shared system — a measurement reads the same to any scientist anywhere.
Worked examples

Worked example 1. A chemist weighs out a small pile of powder. Which unit belongs on the recorded mass?

Step 1

Answer: grams (g) — the chemist's unit for small masses.

Worked example 2. A metal cube has a volume of 8 cm³. What is that volume in milliliters?

Step 1

Answer: 8 mL — one milliliter is exactly one cubic centimeter, so the number stays the same.

You can now state the units chemists use for mass, volume, and temperature from the International System of Units (SI) and its everyday companions: grams and kilograms for mass; liters, milliliters, and cubic centimeters for volume, where one milliliter equals one cubic centimeter; and degrees Celsius for temperature, with the kelvin as the SI base unit.

Check your understanding

A chemist measures how much space a sample of cooking oil takes up. Which unit belongs on the record?

Amilliliters (mL)correct
Bgrams (g)
This option is wrong — you picked a mass unit — grams record how much matter is present, not how much space it takes up.
Cdegrees Celsius (°C)
This option is wrong — you picked a temperature unit — degrees Celsius record hotness, not space.
Dkilograms (kg)
This option is wrong — you picked a mass unit — kilograms record large masses, and the quantity here is volume.
How much space a sample takes up is its volume. Chemists record liquid volumes in liters and milliliters. Grams and kilograms are for mass, and degrees Celsius is for temperature.
Check your understanding

A syringe holds 12 cm³ of liquid. What is that volume in milliliters?

Answer: 12 mL
One milliliter is exactly one cubic centimeter — 1 mL = 1 cm³. So a volume keeps the same number in either unit. 12 cm³ is 12 mL.
Check your understanding

Which statement about temperature units is correct?

AChemists record everyday lab temperatures in degrees Celsius, and the SI base unit is the kelvin.correct
BChemists record everyday lab temperatures in kelvins, and the SI base unit is the degree Celsius.
This option is wrong — you swapped the two units' roles — the kelvin is the SI base unit, and °C is the everyday lab unit.
CDegrees Celsius and the kelvin are two names for the same unit.
This option is wrong — you merged two different units — they are related, and the course returns to how with gases.
DSI has no temperature unit, so chemists borrow degrees Celsius from everyday life.
This option is wrong — you left temperature out of SI — the kelvin is SI's base unit for temperature.
In everyday lab work, chemists record temperature in degrees Celsius (°C). The SI base unit for temperature is the kelvin (K). For now only the kelvin's name matters — the course returns to it with gases.

Lesson 28 of 55 · MPM-028

Unit prefixes
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Wonder this:

A medicine label reads '0.005 L'. Miscount one zero, and the dose is ten times wrong. Chemists write very small and very large measurements a safer way — they attach a word to the unit instead of a string of zeros.

You've already seen the unit set. The words attached to those units come next.

The idea

A word attached to the front of a unit to resize it is called a 'unit prefix'.

'kilo-' means one thousand: one kilogram is one thousand grams.

'centi-' means one hundredth: one centimeter is one hundredth of a meter.

'milli-' means one thousandth: one milliliter is one thousandth of a liter.

'nano-' means one billionth: one nanometer is one billionth of a meter.

The four prefixes this course uses

PrefixMeaningExample
kilo- (k)one thousand1 kg = 1000 g
centi- (c)one hundredth1 cm = one hundredth of a meter
milli- (m)one thousandth1 mL = one thousandth of a liter
nano- (n)one billionth1 nm = one billionth of a meter
The same prefix keeps its meaning on any unit.

A prefix keeps its meaning on any unit — a milligram is one thousandth of a gram, just as a milliliter is one thousandth of a liter.

That medicine label can read '5 mL' instead of '0.005 L' — the prefix carries the zeros.

Worked examples

Worked example 1. One kilometer is how many meters?

Step 1

Answer: one thousand meters — kilo- means one thousand on any unit.

Worked example 2. What fraction of a gram is one centigram?

Step 1

Answer: one hundredth of a gram — centi- keeps its meaning on any unit.

You can now state the meaning of the unit prefixes kilo- (one thousand), centi- (one hundredth), milli- (one thousandth), and nano- (one billionth).

Check your understanding

How many grams are in one kilogram?

Answer: 1000 g
kilo- means one thousand. So one kilogram is one thousand grams. 1 kg = 1000 g.
Check your understanding

What does the prefix milli- mean?

Aone thousandthcorrect
Bone hundredth
This option is wrong — you gave the meaning of centi- — milli- is the smaller step, one thousandth.
Cone thousand
This option is wrong — you gave the meaning of kilo- — milli- makes the unit smaller, not larger.
Done billionth
This option is wrong — you gave the meaning of nano- — milli- is one thousandth.
milli- means one thousandth. One milliliter is one thousandth of a liter, and one milligram is one thousandth of a gram. centi- is one hundredth, kilo- is one thousand, and nano- is one billionth.
Check your understanding

One centimeter is what fraction of a meter?

Aone hundredthcorrect
Bone thousandth
This option is wrong — you gave the milli- meaning — centi- is one hundredth.
Cone tenth
This option is wrong — you made centi- one tenth — it means one hundredth, as a cent is to a dollar.
Done billionth
This option is wrong — you gave the nano- meaning — centi- is one hundredth.
centi- means one hundredth. So one centimeter is one hundredth of a meter. milli- would be one thousandth, and nano- one billionth.

Lesson 29 of 55 · MPM-029

Converting to base units
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Did You Know?

You've already seen the four unit prefixes: kilo- means one thousand, centi- means one hundredth, milli- means one thousandth, and nano- means one billionth. A measurement often arrives in a prefixed unit, but a calculation usually needs the base unit.

The idea

To convert a measurement to its base unit, replace the prefix with the number it means.

First write what one prefixed unit equals in the base unit.

milli- means one thousandth, so 1 mL = 0.001 L.

Then multiply the measured number by that meaning.

The converted value is the same measurement written in a different unit — nothing about the sample changed.

Worked examples

Worked example 1. Convert 250 mL to liters.

Step 1

Write down the values in the question

V = 250 mL

milli- means one thousandth, so 1 mL = 0.001 L

Step 2

Write down the equation

1 mL = 0.001 L

Step 3

Substitute in the values, and calculate

V = 250 × 0.001 L

V = 0.250 L

Worked example 2. Convert 2.5 kg to grams.

Step 1

Write down the values in the question

m = 2.5 kg

kilo- means one thousand, so 1 kg = 1000 g

Step 2

Write down the equation

1 kg = 1000 g

Step 3

Substitute in the values, and calculate

m = 2.5 × 1000 g

m = 2500 g

You can now calculate the base-unit value of a measurement given in a prefixed unit.

Check your understanding

A tablet contains 500 mg of calcium carbonate. Convert 500 mg to grams.

Answer: 0.5 g (tolerance ±0.0005)
Write down the value in the question: m = 500 mg Write down what the prefix means: milli- means one thousandth, so 1 mg = 0.001 g Substitute in the meaning, and calculate: m = 500 × 0.001 g m = 0.5 g
Check your understanding

A trail marker says the lake is 3.2 km away. Convert 3.2 km to meters.

Answer: 3200 m (tolerance ±0.5)
Write down the value in the question: d = 3.2 km Write down what the prefix means: kilo- means one thousand, so 1 km = 1000 m Substitute in the meaning, and calculate: d = 3.2 × 1000 m d = 3200 m
Check your understanding

A strip of magnesium ribbon is 84 cm long. Convert 84 cm to meters.

Answer: 0.84 m (tolerance ±0.0005)
Write down the value in the question: l = 84 cm Write down what the prefix means: centi- means one hundredth, so 1 cm = 0.01 m Substitute in the meaning, and calculate: l = 84 × 0.01 m l = 0.84 m

Lesson 30 of 55 · MPM-030

Converting from base units
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Did You Know?

You've already seen how to convert a prefixed unit to its base unit. Measurements often need to travel the other way — the value is in the base unit, and the label or instrument uses the prefixed unit.

The idea

The prefix meanings you've already seen work in both directions.

milli- means one thousandth, so 1 mL = 0.001 L — read the other way, one liter holds 1000 mL.

To convert a base-unit value to a prefixed unit, find how many prefixed units fit in it.

Multiply the base-unit value by how many prefixed units make up one base unit.

One liter holds 1000 mL, so multiply a value in liters by 1000 to write it in milliliters.

One thousand grams make a kilogram, so only 0.001 kilograms fits in one gram — multiplying by 0.001 is the same as dividing by 1000, so divide a value in grams by 1000 to write it in kilograms.

The converted value is still the same measurement — only the unit changed.

Worked examples

Worked example 1. Convert 1.5 L to milliliters.

Step 1

Write down the values in the question

V = 1.5 L

milli- means one thousandth, so one liter holds 1000 mL

Step 2

Write down the equation

1 L = 1000 mL

Step 3

Substitute in the values, and calculate

V = 1.5 × 1000 mL

V = 1500 mL

Worked example 2. Convert 3000 g to kilograms.

Step 1

Write down the values in the question

m = 3000 g

kilo- means one thousand, so 1000 g make one kilogram

Step 2

Write down the equation

1 kg = 1000 g

Step 3

Substitute in the values, and calculate

m = 3000 ÷ 1000 kg

m = 3.0 kg

You can now calculate the prefixed-unit value of a measurement given in a base unit.

Check your understanding

A flask holds 0.85 L of solution. Convert 0.85 L to milliliters.

Answer: 850 mL (tolerance ±0.5)
Write down the value in the question: V = 0.85 L Write down what the prefix means: milli- means one thousandth, so one liter holds 1000 mL Substitute in the meaning, and calculate: V = 0.85 × 1000 mL V = 850 mL
Check your understanding

A crate of glassware has a mass of 4200 g. Convert 4200 g to kilograms.

Answer: 4.2 kg (tolerance ±0.0005)
Write down the value in the question: m = 4200 g Write down what the prefix means: kilo- means one thousand, so 1000 g make one kilogram Substitute in the meaning, and calculate: m = 4200 ÷ 1000 kg m = 4.2 kg
Check your understanding

A piece of rubber tubing is 0.36 m long. Convert 0.36 m to centimeters.

Answer: 36 cm (tolerance ±0.05)
Write down the value in the question: l = 0.36 m Write down what the prefix means: centi- means one hundredth, so one meter holds 100 cm Substitute in the meaning, and calculate: l = 0.36 × 100 cm l = 36 cm

Lesson 31 of 55 · MPM-031

Reading a graduated cylinder
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You've already seen that chemists record liquid volume in milliliters. In the laboratory that number has to come from an instrument.

The idea

A tall container with volume marks up its side is called a 'graduated cylinder' — it is the standard tool for measuring liquid volume.

A graduated cylinder marked from 40 to 50 milliliters. The curved water surface, labeled meniscus, rests on the 43 mark, and a dashed eye-level sightline points at the bottom of the curve.404550mLmeniscus — read at thebottom of the curveeye level with thesurface43.0 mL

Water in a graduated cylinder does not sit flat.

The surface climbs slightly where the water touches the glass walls, so the surface dips into a curve.

That curved surface is called the 'meniscus'.

Read the volume at the bottom of the meniscus — the lowest point of the curve.

Keep your eye level with the water surface when you read.

Looking down from above or up from below shifts which mark the meniscus appears to touch, so the reading comes out wrong.

Worked examples

Worked example 1. The figure's graduated cylinder has a mark at every 1 mL between 40 mL and 50 mL. The bottom of the meniscus rests exactly on the third mark above 40 mL. What is the volume?

Step 1

The marks step by 1 mL, so the third mark above 40 mL is the 43 mL mark.

Step 2

The bottom of the meniscus sits exactly on that mark.

Step 3

The volume is 43.0 mL.

You can now identify the volume of a liquid in a graduated cylinder by reading the bottom of the meniscus at eye level.

Check your understanding

The figure shows water in a graduated cylinder. What is the volume of the water?

graduated cylinder from 20 to 30 mL202530mL
A26.0 mLcorrect
B26.5 mL
This option is wrong — you read the top edge of the curve where it touches the glass instead of the bottom of the meniscus.
C27.0 mL
This option is wrong — you counted one mark too many above the labeled 25 mL line.
D25.0 mL
This option is wrong — you read the nearest labeled mark instead of the mark the meniscus actually rests on.
Find the bottom of the meniscus — the lowest point of the curved surface. The marks step by 1 mL, and the bottom of the curve rests on the first mark above the labeled 25 mL line. The volume is 26.0 mL.
Check your understanding

The figure shows water in a graduated cylinder. What is the volume of the water?

graduated cylinder from 30 to 45 mL30354045mL
A38.0 mLcorrect
B38.5 mL
This option is wrong — you read the raised edge of the curve at the glass instead of the bottom of the meniscus.
C42.0 mL
This option is wrong — you counted marks downward from the 40 mL label instead of upward.
D39.0 mL
This option is wrong — you counted one mark too many above the labeled 35 mL line.
Find the bottom of the meniscus — the lowest point of the curved surface. The marks step by 1 mL, and the bottom of the curve rests on the third mark above the labeled 35 mL line. The volume is 38.0 mL.
Check your understanding

The figure shows a student's eye position and the water in a graduated cylinder. The dashed sightline is level with the bottom of the meniscus. What is the volume of the water?

graduated cylinder from 10 to 25 mL10152025mLeye level with thesurface
A17.0 mLcorrect
B17.5 mL
This option is wrong — you read the top edge of the curve where it touches the glass instead of the bottom of the meniscus.
C16.0 mL
This option is wrong — you counted one mark too few above the labeled 15 mL line.
D20.0 mL
This option is wrong — you read the nearest labeled mark instead of the mark the meniscus actually rests on.
The sightline is already at eye level, so read straight along it. The marks step by 1 mL, and the bottom of the meniscus rests on the second mark above the labeled 15 mL line. The volume is 17.0 mL.

Lesson 32 of 55 · MPM-032

Counting significant figures
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Wonder this:

The figure's graduated cylinder has a mark at every 1 mL. The bottom of the meniscus sits between the 36 and 37 marks — about halfway. No mark tells you the exact digit that comes next.

You read the certain digits, 3 and 6, straight from the marks. The next digit is your best estimate: the water looks halfway, so you record 36.5 mL. Which digits of that measurement can another scientist actually trust?

The idea

The digits a measurement vouches for — every certain digit plus the one estimated digit at the end — are called its 'significant figures'.

A graduated cylinder whose meniscus sits halfway between the 36 and 37 milliliter marks, annotated to show the recorded value 36.5 milliliters with the final 5 marked as the estimated digit.303540mLbetween 36 and 37 —estimate the last digitrecorded: 36.5 mL3 and 6: certain5: estimated

All nonzero digits are significant, so 36.5 mL has three significant figures.

Zeros sitting between nonzero digits are significant, so 205 g has three significant figures.

Zeros in front of the first nonzero digit are not significant — they only place the decimal point.

So counting in 0.0250 g starts at the 2.

Zeros at the end of a number that has a decimal point are significant — the instrument really did vouch for them.

So 0.0250 g has three significant figures: the 2, the 5, and the final 0.

Worked examples

Worked example 1. How many significant figures does the measurement 0.0730 g have?

Step 1

The two zeros in front of the 7 only place the decimal point — not significant.

Step 2

The 7 and the 3 are nonzero digits — significant.

Step 3

The final 0 comes after the decimal point at the end of the number — significant.

Step 4

0.0730 g has three significant figures.

Worked example 2. How many significant figures does the measurement 4051 mL have?

Step 1

The 4, 5, and 1 are nonzero digits — significant.

Step 2

The 0 sits between nonzero digits — significant.

Step 3

4051 mL has four significant figures.

You can now identify the number of significant figures in a measured value.

Check your understanding

How many significant figures does the measurement 0.0082 g have?

Answer: 2
The three zeros in front of the 8 only place the decimal point — not significant. The 8 and the 2 are nonzero digits — significant. 0.0082 g has two significant figures.
Check your understanding

How many significant figures does the measurement 40.7 mL have?

Answer: 3
The 4 and the 7 are nonzero digits — significant. The 0 sits between nonzero digits — significant. 40.7 mL has three significant figures.
Check your understanding

How many significant figures does the measurement 3.600 g have?

Answer: 4
The 3 and the 6 are nonzero digits — significant. The two zeros at the end come after the decimal point — significant, because the balance vouched for them. 3.600 g has four significant figures.

Lesson 33 of 55 · MPM-033

Rounding calculated results
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You've already seen that a measurement's significant figures show which digits it vouches for. A calculator does not know that — it prints digits no measurement ever vouched for.

The idea

When you multiply or divide measurements, count the significant figures in each measurement first.

Round the calculator's result to the same number of significant figures as the measurement with the fewest.

The least precise measurement sets the precision of the result.

A result can never be more trustworthy than the shakiest measurement that went into it.

Worked examples

Worked example 1. A student divides a sample's mass, 15.0 g, by its volume, 4.0 cm³. What result should be recorded, in g/cm³?

Step 1

Write down the values in the question

m = 15.0 g — three significant figures

V = 4.0 cm³ — two significant figures

Step 2

Write down the equation

divide the mass by the volume, then round to the fewest significant figures

Step 3

Substitute in the values, and calculate

15.0 ÷ 4.0 = 3.75

recorded result = 3.8 g/cm³

Worked example 2. A student divides a sample's mass, 8.10 g, by its volume, 4.0 cm³. What result should be recorded, in g/cm³?

Step 1

Write down the values in the question

m = 8.10 g — three significant figures

V = 4.0 cm³ — two significant figures

Step 2

Write down the equation

divide the mass by the volume, then round to the fewest significant figures

Step 3

Substitute in the values, and calculate

8.10 ÷ 4.0 = 2.025

recorded result = 2.0 g/cm³

You can now calculate the result of multiplying or dividing measurements, rounded to the number of significant figures in the least precise measurement.

Check your understanding

A student divides a sample's mass, 15.5 g, by its volume, 4.0 cm³. The calculator shows 3.875. What result should be recorded, in g/cm³?

Answer: 3.9 g/cm³ (tolerance ±0.005)
Count the significant figures in each measurement: 15.5 g — three significant figures 4.0 cm³ — two significant figures Divide, then round to the fewest significant figures: 15.5 ÷ 4.0 = 3.875 recorded result = 3.9 g/cm³
Check your understanding

A student divides a sample's mass, 22.5 g, by its volume, 8.0 cm³. What result should be recorded, in g/cm³?

Answer: 2.8 g/cm³ (tolerance ±0.005)
Count the significant figures in each measurement: 22.5 g — three significant figures 8.0 cm³ — two significant figures Divide, then round to the fewest significant figures: 22.5 ÷ 8.0 = 2.8125 recorded result = 2.8 g/cm³
Check your understanding

A student multiplies two measured lengths of a metal plate, 1.25 cm and 3.0 cm, to find its area. What result should be recorded, in cm²?

Answer: 3.8 cm² (tolerance ±0.005)
Count the significant figures in each measurement: 1.25 cm — three significant figures 3.0 cm — two significant figures Multiply, then round to the fewest significant figures: 1.25 × 3.0 = 3.75 recorded result = 3.8 cm²
Summary video — Physical and chemical changes and the measurement toolkit

Watch in David’s player

End of Topic Test

End of Topic Test — five interchangeable forms, delivered separately.

Intro video — Density as identity evidence

Watch in David’s player

Lesson 34 of 55 · MPM-034

What density measures
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Wonder this:

Here are two cubes, exactly the same size — 10.0 cm³ each. One is lead and one is plastic foam. Pick them up, and the lead cube feels far, far heavier.

The balance agrees: the lead cube reads 113.4 g, the foam cube reads 0.5 g. Same volume, wildly different mass — so something about the materials themselves must differ.

The idea

The lead cube packs far more mass into the same 10.0 cm³ of space than the foam cube does.

Two same-size cubes on two balances. The lead cube's balance reads 113.4 grams; the plastic foam cube's balance reads 0.5 grams.113.4 glead — 10.0 cm³0.5 gplastic foam — 10.0cm³
Same volume. Different mass.

How much mass a material packs into each unit of volume is called its 'density'.

Lead has a high density — each cubic centimeter of lead carries a lot of mass.

Plastic foam has a low density — each cubic centimeter of foam carries very little mass.

Density is a physical property — you can measure it without turning the material into anything new.

Worked examples

Worked example 1. Two blocks are exactly the same size. The steel block feels much heavier than the wooden block. Which material has the greater density, and what does that mean?

Step 1

The blocks have the same volume.

Step 2

The steel block has more mass in that same volume.

Step 3

Steel packs more mass into each unit of volume, so steel has the greater density.

You can now state that density measures how much mass is packed into each unit of volume of a material.

Check your understanding

What does a material's density measure?

AHow much mass the material packs into each unit of volume.correct
BHow much mass the whole sample of the material has.
This option is wrong — you described mass alone — density compares the mass with the space it occupies.
CHow much space the whole sample of the material takes up.
This option is wrong — you described volume alone — density compares the mass with the space it occupies.
DHow heavy the material feels when you lift it in your hand.
This option is wrong — you described a felt impression — density is a measured amount of mass per unit of volume, not a sensation.
Density is about packing: how much mass sits in each unit of volume. Mass alone or volume alone describes the sample; density describes the material.
Check your understanding

Granite has a higher density than cork. What does that statement mean?

AEach unit of volume of granite carries more mass than the same volume of cork.correct
BAny piece of granite has more mass than any piece of cork, whatever their sizes.
This option is wrong — you ignored sample size — a huge cork slab can outweigh a granite pebble; density compares equal volumes.
CGranite takes up more space than the same mass of cork.
This option is wrong — you inverted the comparison — the same mass of granite takes up less space, not more.
DGranite is harder to break than cork.
This option is wrong — you swapped in a different property — hardness is not density.
Density compares equal volumes: one cubic centimeter of granite carries more mass than one cubic centimeter of cork. Statements about whole samples, hardness, or feel are different claims.
Check your understanding

Two same-size cubes sit on a table. The aluminum cube has more mass than the ice cube. Which statement uses the word density correctly?

AAluminum has a greater density than ice, because it packs more mass into the same volume.correct
BThe aluminum cube has a greater density because it is bigger.
This option is wrong — you tied density to size — the cubes are the same size, and density is about packing, not amount.
CIce has a greater density because it freezes solid at a much lower temperature.
This option is wrong — you tied density to temperature of freezing — density is mass packed per unit of volume.
DThe cubes have the same density because they take up exactly the same volume.
This option is wrong — you treated equal volume as equal density — with equal volumes, the cube with more mass is denser.
The cubes occupy equal volumes, and the aluminum cube carries more mass in that volume. Packing more mass into the same volume is exactly what greater density means.

Lesson 35 of 55 · MPM-035

More mass in the same volume
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You've already seen that density is the mass a material packs into each unit of volume. A fair comparison of two materials starts by holding one quantity the same for both.

The idea

Hold the volume the same: here are two cubes, each exactly 5.0 cm³.

Two same-size cubes labeled copper, 44.5 grams, and aluminum, 13.5 grams, illustrating that with equal volumes the greater mass means the greater density.44.5 gcopper — 5.0 cm³13.5 galuminum — 5.0 cm³
Same volume — the greater mass means the greater density.

The copper cube has a mass of 44.5 g.

The aluminum cube has a mass of 13.5 g.

The copper cube packs more mass into the same 5.0 cm³, so copper is the denser material.

When two samples have equal volumes, the one with the greater mass has the greater density.

Worked examples

Worked example 1. Two blocks have the same volume, 20.0 cm³. Block A has a mass of 54.0 g. Block B has a mass of 158 g. Which block is made of the denser material?

Step 1

The volumes are equal, so the masses can be compared directly.

Step 2

Block B carries more mass in the same 20.0 cm³.

Step 3

Block B is made of the denser material.

You can now predict which of two samples with equal volumes has the greater density from their masses, holding volume constant.

Check your understanding

Two solid balls have the same volume, 30.0 cm³. Ball X has a mass of 85.0 g. Ball Y has a mass of 42.0 g. Which ball is made of the denser material?

ABall Xcorrect
BBall Y
This option is wrong — you inverted the rule — packing more mass into the same volume is what greater density means.
CNeither ball
This option is wrong — you treated equal volume as equal density — the masses in that volume differ.
DIt cannot be decided from the information given
This option is wrong — you asked for the material names — equal volumes and the two masses already settle the comparison.
The volumes are equal, so compare the masses directly. Ball X packs more mass into the same 30.0 cm³. Ball X is made of the denser material.
Check your understanding

A full 500 mL bottle of honey has more mass than a full 500 mL bottle of water. The bottles are identical. Which liquid is denser?

AThe honeycorrect
BThe water
This option is wrong — you tied density to how easily a liquid flows — density is mass per unit of volume, not runniness.
CNeither liquid
This option is wrong — you treated equal volume as equal density — the masses in that volume differ.
DIt cannot be decided from the information given
This option is wrong — you asked for extra data — the bottles are identical and full, so the volumes are equal, and the honey's greater mass settles the comparison.
Both bottles hold the same volume, 500 mL. The honey puts more mass into that same volume. The honey is the denser liquid.
Check your understanding

Three cubes all have the same volume, 10.0 cm³. Cube A has a mass of 89 g, cube B has a mass of 27.0 g, and cube C has a mass of 105 g. Rank the materials from most dense to least dense.

AC, then A, then Bcorrect
BB, then A, then C
This option is wrong — you inverted the rule — with equal volumes the greater mass, not the smaller, means the greater density.
CAll three tie
This option is wrong — you treated equal volume as equal density — the masses in that volume differ.
DA, then C, then B
This option is wrong — you misread the masses — 105 g is greater than 89 g.
The volumes are all equal, so rank by mass directly. 105 g is the greatest, then 89 g, then 27.0 g. Most dense to least dense: C, A, B.

Lesson 36 of 55 · MPM-036

Same mass in less volume
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Did You Know?

You've already compared materials by holding volume the same and comparing masses. The other fair comparison holds mass the same and compares volumes.

The idea

Hold the mass the same: here are two solid blocks, each exactly 100 g.

Two blocks with equal 100 gram mass tags. The smaller block, 20 cubic centimeters, is labeled denser than the larger block, 50 cubic centimeters.100 gblock A — 20.0 cm³100 gblock B — 50.0 cm³
Same mass — the smaller volume means the greater density.

Block A takes up 20.0 cm³.

Block B takes up 50.0 cm³.

Block A squeezes the same 100 g into less space, so block A is made of the denser material.

When two samples have equal masses, the one with the smaller volume has the greater density.

Worked examples

Worked example 1. Two solid samples each have a mass of 60.0 g. Sample 1 occupies 8.0 cm³. Sample 2 occupies 24.0 cm³. Which sample is made of the denser material?

Step 1

The masses are equal, so the volumes can be compared directly.

Step 2

Sample 1 fits the same 60.0 g into less space.

Step 3

Sample 1 is made of the denser material.

You can now predict which of two samples with equal masses has the greater density from their volumes, holding mass constant.

Check your understanding

Two solid pieces each have a mass of 250 g. Piece X occupies 90.0 cm³. Piece Y occupies 30.0 cm³. Which piece is made of the denser material?

APiece Ycorrect
BPiece X
This option is wrong — you inverted the rule — squeezing the same mass into less space is what greater density means.
CNeither piece
This option is wrong — you treated equal mass as equal density — the volumes holding that mass differ.
DIt cannot be decided from the information given
This option is wrong — you asked for the material names — equal masses and the two volumes already settle the comparison.
The masses are equal, so compare the volumes directly. Piece Y fits the same 250 g into less space. Piece Y is made of the denser material.
Check your understanding

A kilogram of iron and a kilogram of feathers have exactly the same mass. The feathers fill a large sack; the iron fits in your hand. Which material is denser, and why?

AThe iron — it fits the same mass into a far smaller volume.correct
BThe feathers — filling a whole sack shows they hold more material.
This option is wrong — you read a larger volume as more material — the masses are identical; the feathers just spread that mass over more space.
CNeither — a kilogram is a kilogram, so the densities are equal.
This option is wrong — you treated equal mass as equal density — density also depends on the volume holding that mass.
DThe iron, because metals are always denser than plant material.
This option is wrong — you answered from a rule of thumb about metals — the evidence here is the volume comparison at equal mass, and rules of thumb have exceptions.
The masses are equal — one kilogram each. The iron squeezes that kilogram into a hand-sized volume; the feathers spread it through a sack. The smaller volume at equal mass means iron is denser.
Check your understanding

Three statues each have a mass of 1.2 kg. The resin statue occupies 1000 cm³, the ceramic statue 480 cm³, and the bronze statue 140 cm³. Rank the materials from most dense to least dense.

ABronze, then ceramic, then resincorrect
BResin, then ceramic, then bronze
This option is wrong — you inverted the rule — at equal mass the smaller volume, not the larger, means the greater density.
CAll three tie
This option is wrong — you treated equal mass as equal density — the volumes holding that mass differ.
DBronze, then resin, then ceramic
This option is wrong — you misread the volumes — 480 cm³ is smaller than 1000 cm³.
The masses are all equal, so rank by volume — smallest volume first. 140 cm³ is the smallest, then 480 cm³, then 1000 cm³. Most dense to least dense: bronze, ceramic, resin.

Lesson 37 of 55 · MPM-037

The density equation
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Did You Know?

You've already compared density two ways: more mass in the same volume, and the same mass in less volume. One equation captures both comparisons at once.

The equation

Density is the mass divided by the volume.

D = m / V

D stands for density, measured in grams per cubic centimeter (g/cm³).

The density equation D equals m over V, annotated: D is density in grams per cubic centimeter, m is mass in grams, V is volume in cubic centimeters.D=m/Vdensity (g/cm³)mass (g)volume (cm³)
Ddensity (g/cm³)
mmass (g)
Vvolume (cm³)

m stands for mass, measured in grams.

V stands for volume, measured in cubic centimeters.

Dividing the mass by the volume shares the mass out over every cubic centimeter, so D is the mass packed into each one — exactly what density means.

When the volume is held the same, a greater mass makes D greater.

When the mass is held the same, a smaller volume makes D greater.

Worked examples

Worked example 1. In the equation D = m/V, what does each symbol stand for, and what unit does it carry?

Step 1

Write down the values in the question

D is the density, in grams per cubic centimeter (g/cm³).

m is the mass, in grams.

V is the volume, in cubic centimeters.

The density is the mass divided by the volume.

Step 2

Write down the equation

D = m / V

Step 3

Substitute in the values, and calculate

You can now state the density equation D = m/V, naming density D, mass m, and volume V.

Check your understanding

Which equation gives a material's density?

AD = m / Vcorrect
BD = V / m
This option is wrong — you flipped the division — density is the mass divided by the volume, not the volume divided by the mass.
CD = m × V
This option is wrong — you multiplied instead of dividing — multiplying mass by volume does not share the mass over the space.
DD = m − V
This option is wrong — you subtracted — mass and volume are different kinds of quantity, and density is their ratio, not their difference.
Density is the mass divided by the volume. D = m / V Dividing shares the mass out over every cubic centimeter.
Check your understanding

In the equation D = m/V, what does the symbol m stand for, and in what unit?

AThe mass, in grams.correct
BThe volume, in cubic centimeters.
This option is wrong — you swapped the symbols — V is the volume; m is the mass.
CThe density, in grams per cubic centimeter.
This option is wrong — you read m as the result — D is the density; m is the mass that goes into it.
DThe number of milliliters in the sample.
This option is wrong — you tied m to the milliliter — m is the mass in grams, not a volume count.
In D = m/V, m is the mass, measured in grams. V is the volume in cubic centimeters, and D is the density in g/cm³.
Check your understanding

A sample's mass is measured in grams and its volume in cubic centimeters. What unit does the density D = m/V carry?

Ag/cm³ — grams per cubic centimeter.correct
Bg — grams.
This option is wrong — you kept the mass unit alone — dividing by the volume puts cm³ underneath, giving grams per cubic centimeter.
Ccm³/g — cubic centimeters per gram.
This option is wrong — you flipped the ratio — mass sits on top, so the unit is grams per cubic centimeter.
Dg·cm³ — gram cubic centimeters.
This option is wrong — you multiplied the units — the division in D = m/V divides the units too.
D = m/V divides grams by cubic centimeters. The unit divides the same way: g/cm³. Read it as the mass carried by each cubic centimeter.

Lesson 38 of 55 · MPM-038

Calculating density
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Did You Know?

You've already seen the density equation, D = m/V. Now use it: a balance gives the mass, the volume is measured, and one division gives the density.

The equation

Write down the mass and the volume from the question.

Write down the equation, D = m/V.

The density equation D equals m over V with the worked example twenty-seven point zero grams divided by ten point zero cubic centimeters equals two point seven zero grams per cubic centimeter.D=m/Vdensity (g/cm³)mass (g)volume (cm³)D = 27.0 / 10.0 = 2.70 g/cm³
Ddensity (g/cm³)
mmass (g)
Vvolume (cm³)

Substitute the values and calculate.

The result carries the unit g/cm³.

Round the result to the significant figures of the least precise measurement, as you've already practiced.

Worked examples

Worked example 1. A block of aluminum has a mass of 27.0 g and a volume of 10.0 cm³. What is its density?

Step 1

Write down the values in the question

m = 27.0 g

V = 10.0 cm³

Step 2

Write down the equation

D = m / V

Step 3

Substitute in the values, and calculate

D = 27.0 / 10.0

D = 2.70 g/cm³

Worked example 2. A piece of copper has a mass of 44.5 g and a volume of 5.00 cm³. What is its density?

Step 1

Write down the values in the question

m = 44.5 g

V = 5.00 cm³

Step 2

Write down the equation

D = m / V

Step 3

Substitute in the values, and calculate

D = 44.5 / 5.00

D = 8.90 g/cm³

You can now calculate the density of a sample from its mass and volume.

m/V gives g ÷ cm³ → g/cm³ ✓ correct

m×V gives g × cm³ → g·cm³ ✗ you multiplied instead of dividing

V/m gives cm³ ÷ g → cm³/g ✗ you divided the wrong way

Check your understanding

A sample of water has a mass of 25.0 g and a volume of 25.0 cm³. Calculate its density, in g/cm³, to 3 significant figures.

Answer: 1.00 g/cm³ (tolerance ±0.005)
Write down the values in the question: m = 25.0 g V = 25.0 cm³ Write down the equation: D = m / V Substitute in the values, and calculate: D = 25.0 / 25.0 D = 1.00 g/cm³
Check your understanding

An iron bolt has a mass of 39.5 g and a volume of 5.0 cm³. Calculate its density, in g/cm³, to 2 significant figures.

Answer: 7.9 g/cm³ (tolerance ±0.05)
Write down the values in the question: m = 39.5 g V = 5.0 cm³ Write down the equation: D = m / V Substitute in the values, and calculate: D = 39.5 / 5.0 D = 7.9 g/cm³
Check your understanding

A gold pendant has a mass of 96.5 g and a volume of 5.00 cm³. Calculate its density, in g/cm³, to 3 significant figures.

Answer: 19.3 g/cm³ (tolerance ±0.05)
Write down the values in the question: m = 96.5 g V = 5.00 cm³ Write down the equation: D = m / V Substitute in the values, and calculate: D = 96.5 / 5.00 D = 19.3 g/cm³

Lesson 39 of 55 · MPM-039

Mass from density and volume
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You've already calculated a density from a mass and a volume. Questions often run the other way: the material's density is known, and you need the mass a measured volume will have.

The equation

Use the density equation you've already seen: D = m/V.

The density equation rearranged: m equals D times V, with the worked example one point zero zero times fifty point zero equals fifty point zero grams.D = m / Vm=D×Vmass (g)density (g/cm³)volume (cm³)m = 1.00 × 50.0 = 50.0 g
Ddensity (g/cm³)
mmass (g)
Vvolume (cm³)

The question gives D and V and asks for m, so rearrange the equation.

Make m the subject by multiplying both sides by V, giving m = D × V.

Then substitute and calculate — the mass comes out in grams.

It is one equation, rearranged when needed, not a second equation to memorize.

Worked examples

Worked example 1. What is the mass of 50.0 cm³ of water? (Density of water = 1.00 g/cm³)

Step 1

Write down the values in the question

D = 1.00 g/cm³

V = 50.0 cm³

Step 2

Write down the equation

D = m / V

Step 3

Make the unknown the subject

m = D × V

Step 4

Substitute in the values, and calculate

m = 1.00 × 50.0

m = 50.0 g

Worked example 2. What is the mass of 10.0 cm³ of copper? (Density of copper = 8.9 g/cm³)

Step 1

Write down the values in the question

D = 8.9 g/cm³

V = 10.0 cm³

Step 2

Write down the equation

D = m / V

Step 3

Make the unknown the subject

m = D × V

Step 4

Substitute in the values, and calculate

m = 8.9 × 10.0

m = 89 g

You can now calculate the mass of a sample from its density and volume by rearranging D = m/V.

Check your understanding

What is the mass, in grams, of 20.0 cm³ of aluminum? (Density of aluminum = 2.70 g/cm³.) Give your answer to 3 significant figures.

Answer: 54.0 g (tolerance ±0.05)
Write down the values in the question: D = 2.70 g/cm³ V = 20.0 cm³ Write down the equation: D = m / V Make m the subject: m = D × V Substitute in the values, and calculate: m = 2.70 × 20.0 m = 54.0 g
Check your understanding

What is the mass, in grams, of 2.00 cm³ of gold? (Density of gold = 19.3 g/cm³.) Give your answer to 3 significant figures.

Answer: 38.6 g (tolerance ±0.05)
Write down the values in the question: D = 19.3 g/cm³ V = 2.00 cm³ Write down the equation: D = m / V Make m the subject: m = D × V Substitute in the values, and calculate: m = 19.3 × 2.00 m = 38.6 g
Check your understanding

A bottle is filled with 350 cm³ of water. What is the mass of the water, in grams? (Density of water = 1.00 g/cm³.) Give your answer to 3 significant figures.

Answer: 350 g (tolerance ±0.5)
Write down the values in the question: D = 1.00 g/cm³ V = 350 cm³ Write down the equation: D = m / V Make m the subject: m = D × V Substitute in the values, and calculate: m = 1.00 × 350 m = 350 g

Lesson 40 of 55 · MPM-040

Volume from mass and density
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You've already used D = m/V in two directions. The last direction: the density is known, the balance gives the mass, and you need the space the sample takes up.

The equation

Use the density equation you've already seen: D = m/V.

The density equation rearranged: V equals m over D, with the worked example twenty-one point six divided by two point seven zero equals eight point zero zero cubic centimeters.D = m / VV=m/Dvolume (cm³)mass (g)density (g/cm³)V = 21.6 / 2.70 = 8.00 cm³
Ddensity (g/cm³)
mmass (g)
Vvolume (cm³)

The question gives D and m and asks for V, so rearrange the equation.

Make V the subject: multiply both sides by V, then divide both sides by D, giving V = m / D.

Then substitute and calculate — the volume comes out in cubic centimeters.

It is still the one density equation, rearranged for the quantity you need.

Worked examples

Worked example 1. What volume does 21.6 g of aluminum occupy? (Density of aluminum = 2.70 g/cm³)

Step 1

Write down the values in the question

D = 2.70 g/cm³

m = 21.6 g

Step 2

Write down the equation

D = m / V

Step 3

Make the unknown the subject

V = m / D

Step 4

Substitute in the values, and calculate

V = 21.6 / 2.70

V = 8.00 cm³

Worked example 2. What volume does 57.9 g of gold occupy? (Density of gold = 19.3 g/cm³)

Step 1

Write down the values in the question

D = 19.3 g/cm³

m = 57.9 g

Step 2

Write down the equation

D = m / V

Step 3

Make the unknown the subject

V = m / D

Step 4

Substitute in the values, and calculate

V = 57.9 / 19.3

V = 3.00 cm³

You can now calculate the volume of a sample from its mass and density by rearranging D = m/V.

Check your understanding

What volume, in cm³, does 17.8 g of copper occupy? (Density of copper = 8.9 g/cm³.) Give your answer to 2 significant figures.

Answer: 2.0 cm³ (tolerance ±0.05)
Write down the values in the question: D = 8.9 g/cm³ m = 17.8 g Write down the equation: D = m / V Make V the subject: V = m / D Substitute in the values, and calculate: V = 17.8 / 8.9 V = 2.0 cm³
Check your understanding

A recipe for hand sanitizer needs 125 g of water measured out by volume. What volume, in cm³, should be measured? (Density of water = 1.00 g/cm³.) Give your answer to 3 significant figures.

Answer: 125 cm³ (tolerance ±0.5)
Write down the values in the question: D = 1.00 g/cm³ m = 125 g Write down the equation: D = m / V Make V the subject: V = m / D Substitute in the values, and calculate: V = 125 / 1.00 V = 125 cm³
Check your understanding

What volume, in cm³, does 23.7 g of iron occupy? (Density of iron = 7.9 g/cm³.) Give your answer to 2 significant figures.

Answer: 3.0 cm³ (tolerance ±0.05)
Write down the values in the question: D = 7.9 g/cm³ m = 23.7 g Write down the equation: D = m / V Make V the subject: V = m / D Substitute in the values, and calculate: V = 23.7 / 7.9 V = 3.0 cm³

Lesson 41 of 55 · MPM-041

Volume by water displacement
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Wonder this:

The density equation needs a volume. A rectangular block is easy — measure its sides. But here is a lumpy stone: no flat sides, no length or width to measure. How do you find the volume of a shape like that?

The answer uses the graduated cylinder you've already read — and the fact that a solid pushes water out of its way.

The equation

Partly fill a graduated cylinder with water and read the level at the bottom of the meniscus.

Two views of one graduated cylinder. Before: water at 20.0 milliliters. After: a stone rests underwater and the level reads 27.5 milliliters. The rise is labeled as the stone's volume.15202530mL15202530mLbeforeafter20.0 mL27.5 mLrise = volumeof the stone

Lower the solid gently until it is fully underwater.

The solid pushes the water aside, so the water level rises.

The rise in the level equals the volume of the solid — the water moved up exactly as much space as the solid took.

Finding a volume this way is called 'water displacement'.

Volume of the solid = final level − starting level.

The levels are read in milliliters, and one milliliter is one cubic centimeter, so the volume comes out in cm³.

Worked examples

Worked example 1. The figure shows a graduated cylinder before and after a stone is lowered in. The level reads 20.0 mL before and 27.5 mL after. What is the stone's volume?

Step 1

Write down the values in the question

starting level = 20.0 mL

final level = 27.5 mL

Step 2

Write down the equation

V = final level − starting level

Step 3

Substitute in the values, and calculate

V = 27.5 − 20.0

V = 7.5 cm³

Worked example 2. A steel bolt is lowered into a cylinder. The level reads 50.0 mL before and 62.0 mL after. What is the bolt's volume?

Step 1

Write down the values in the question

starting level = 50.0 mL

final level = 62.0 mL

Step 2

Write down the equation

V = final level − starting level

Step 3

Substitute in the values, and calculate

V = 62.0 − 50.0

V = 12.0 cm³

You can now calculate the volume of an irregular solid from the rise in water level when it is submerged in a graduated cylinder.

Check your understanding

The figure shows a graduated cylinder before and after a pebble is lowered in. Read both levels and calculate the pebble's volume, in cm³.

before and after cylinders, pebble submerged in the after panel2530354045mL2530354045mLbeforeafter
Answer: 8.5 cm³ (tolerance ±0.05)
Read the values from the figure: starting level = 30.0 mL final level = 38.5 mL Write down the equation: V = final level − starting level Substitute in the values, and calculate: V = 38.5 − 30.0 V = 8.5 cm³
Check your understanding

The figure shows a graduated cylinder before and after a brass nut is lowered in. Read both levels and calculate the nut's volume, in cm³.

before and after cylinders, brass nut submerged in the after panel10152025mL10152025mLbeforeafter
Answer: 4.0 cm³ (tolerance ±0.05)
Read the values from the figure: starting level = 15.0 mL final level = 19.0 mL Write down the equation: V = final level − starting level Substitute in the values, and calculate: V = 19.0 − 15.0 V = 4.0 cm³
Check your understanding

The figure shows a graduated cylinder before and after a glass marble is lowered in. Read both levels and calculate the marble's volume, in cm³.

before and after cylinders, glass marble submerged in the after panel3540455055mL3540455055mLbeforeafter
Answer: 6.5 cm³ (tolerance ±0.05)
Read the values from the figure: starting level = 40.0 mL final level = 46.5 mL Write down the equation: V = final level − starting level Substitute in the values, and calculate: V = 46.5 − 40.0 V = 6.5 cm³

Lesson 42 of 55 · MPM-042

Why density identifies a substance
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Wonder this:

A chip of aluminum fits on a fingertip. An aluminum brick needs two hands to lift. The brick has far more mass and far more volume — yet one measurement comes out exactly the same for both.

Measure them and check.

The idea

The chip: m = 5.40 g, V = 2.00 cm³, and dividing gives D = 2.70 g/cm³.

The brick: m = 5400 g, V = 2000 cm³, and dividing gives D = 2.70 g/cm³.

A tiny aluminum chip and a large aluminum brick, each annotated with its mass, volume, and the division showing both densities equal 2.70 grams per cubic centimeter.m = 5.40 gV = 2.00 cm³D = 5.40 / 2.00 = 2.70 g/cm³aluminum chipm = 5400 gV = 2000 cm³D = 5400 / 2000 = 2.70 g/cm³aluminum brick
Different sample — same density.

Scaling a sample up or down changes its mass and its volume together, by the same factor.

Every cubic centimeter of aluminum holds the same particles packed the same way, so every cubic centimeter carries the same mass.

So the ratio m/V comes out the same for every sample of aluminum, whatever its size.

Mass alone cannot identify a material — a big enough foam block outweighs a small lead pellet.

Volume alone cannot identify a material either — samples of any material come in every size.

Density can, because every sample of one substance gives the same value.

Properties that stay the same whatever the sample size are sometimes called 'intensive', and ones that grow with the sample, like mass and volume, 'extensive' — you'll see those labels, but you won't be asked to use them.

Worked examples

Worked example 1. A 10.0 cm³ splash of water has a mass of 10.0 g. A full 500 cm³ bottle of water has a mass of 500 g. Show that both samples have the same density, and explain why they must.

Step 1

Write down the values in the question

Splash: D = 10.0 / 10.0 = 1.00 g/cm³

Bottle: D = 500 / 500 = 1.00 g/cm³

Both samples are water, and every cubic centimeter of water carries the same mass.

Fifty times the volume brings fifty times the mass, so the ratio m/V is unchanged.

Step 2

Write down the equation

D = m / V

Step 3

Substitute in the values, and calculate

Both samples: D = 1.00 g/cm³

You can now explain why density can identify a substance while mass and volume alone cannot, because every sample of the same substance has the same density whatever its size.

Check your understanding

A copper statue is cut exactly in half. What happens to the density of each half compared with the whole statue?

AIt stays 8.9 g/cm³.correct
BIt halves.
This option is wrong — you tracked only the mass — the volume halves too, so the ratio m/V is unchanged.
CIt doubles.
This option is wrong — you counted pieces instead of comparing mass with volume — each piece still packs the same mass into each cubic centimeter.
DIt cannot be predicted without measuring each half.
This option is wrong — you treated density as a per-object surprise — every sample of copper measures 8.9 g/cm³, whatever its size.
Cutting the statue halves its mass AND its volume, by the same factor. The ratio m/V is therefore unchanged. Every sample of copper measures 8.9 g/cm³, whatever its size.
Check your understanding

Why can a measured density identify a material when a measured mass cannot?

AEvery sample of one substance has the same density, while its mass can be anything.correct
BA density is easier to measure accurately than a mass, so it makes a better test.
This option is wrong — you ranked the measurements by ease — the reason is that density is the same for every sample of a substance, not that it is easier to measure.
CA sample's mass slowly changes over time while its density never changes.
This option is wrong — you made mass unstable — a sample's mass stays put; the problem is that any material can come in any mass.
DOnly solids have a definite mass, while every material has a definite density.
This option is wrong — you denied liquids and gases a definite mass — all matter has a definite mass; the issue is that any material can come in any mass.
A mass of 50 g could be a little lead or a lot of foam — mass depends on how much sample you have. Density does not depend on sample size: every sample of one substance gives the same value. A size-independent value is what makes a fingerprint.
Check your understanding

A thin copper wire and a solid copper doorstop are both pure copper. Which comparison of their densities is correct?

ABoth measure 8.9 g/cm³.correct
BThe doorstop's density is the higher.
This option is wrong — you tracked only the mass — the doorstop has more volume in the same proportion, so the ratio matches the wire's.
CThe wire's density is the higher.
This option is wrong — you treated reshaping as repacking — drawing copper into wire changes its shape, not how its particles pack.
DThe densities differ, but which is higher depends on the objects' exact sizes.
This option is wrong — you made density depend on size — size cancels out of m/V for samples of one substance.
Both objects are pure copper, and every cubic centimeter of copper holds the same particles packed the same way. More copper brings more mass and more volume in the same proportion. Both objects measure 8.9 g/cm³.

Lesson 43 of 55 · MPM-043

Identifying a substance by density
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Have You Ever Wondered?
Wonder this:

A jeweler offers you a heavy gray pendant as pure silver. Looks can be faked — is there a measurement that cannot?

You've already seen that every sample of a substance has the same density, whatever the sample's size. That means a measured density can name the substance.

The equation

A reference table lists the known density of each substance, measured at room temperature.

Densities of common substances (room temperature)

SubstanceDensity (g/cm³)
ethanol0.79
water1.00
aluminum2.70
zinc7.1
iron7.9
copper8.9
silver10.5
lead11.3
gold19.3
Density reference table. The worked examples and every check read from this table.

To identify an unknown sample, measure its density and find the matching value in the table.

Measure the mass on a balance.

Measure the volume — for an irregular solid, use the water-level rise in a graduated cylinder.

Calculate the density with D = m/V, rounded to the correct number of significant figures.

Find the table value closest to the measured density — that row names the substance.

A real measurement carries small error, so an exact match is rare — the closest value is the identification.

Worked examples

Worked example 1. A metal block has a mass of 21.6 g. Lowered into a graduated cylinder, it raises the water level from 30.0 mL to 38.0 mL. Use the density table to identify the metal.

Step 1

Write down the values in the question

m = 21.6 g

V = 38.0 − 30.0 = 8.0 cm³ (1 mL = 1 cm³)

Step 2

Write down the equation

D = m / V

Step 3

Substitute in the values, and calculate

D = 21.6 / 8.0

D = 2.7 g/cm³ — the closest table value is aluminum's 2.70 g/cm³, so the block is aluminum

Worked example 2. The pendant sold as pure silver has a mass of 113.0 g and raises the water level in a graduated cylinder from 15.0 mL to 25.0 mL. Is it silver?

Step 1

Write down the values in the question

m = 113.0 g

V = 25.0 − 15.0 = 10.0 cm³

Step 2

Write down the equation

D = m / V

Step 3

Substitute in the values, and calculate

D = 113.0 / 10.0

D = 11.3 g/cm³ — the table gives silver as 10.5 g/cm³ and lead as 11.3 g/cm³, so the pendant is lead, not silver

You can now identify an unknown substance by comparing its measured density with a supplied reference table of reference densities.

Check your understanding

A solid block has a mass of 63.0 g and a volume of 6.0 cm³. Use the density table to identify the substance.

Densities of common substances (room temperature)

SubstanceDensity (g/cm³)
ethanol0.79
water1.00
aluminum2.70
zinc7.1
iron7.9
copper8.9
silver10.5
lead11.3
gold19.3
density in g/cm³ at room temperature
ASilvercorrect
BGold
This option is wrong — you looked for the block's mass in the table instead of calculating the density — the table lists densities in g/cm³, not masses.
CEthanol
This option is wrong — you divided the volume by the mass instead of the mass by the volume — 6.0 ÷ 63.0 is about 0.1, which sits nearest ethanol's 0.79.
DThe block cannot be identified from mass and volume alone
This option is wrong — you stopped at mass and volume — dividing mass by volume gives density, and density identifies the substance.
Write down the values in the question: m = 63.0 g V = 6.0 cm³ Write down the equation: D = m / V Substitute in the values, and calculate: D = 63.0 / 6.0 D = 10.5 g/cm³ The table value 10.5 g/cm³ is silver.
Check your understanding

An irregular lump of metal has a mass of 44.5 g. Lowered into a graduated cylinder, it raises the water level from 11.5 mL to 16.5 mL. Use the density table to identify the metal.

Densities of common substances (room temperature)

SubstanceDensity (g/cm³)
ethanol0.79
water1.00
aluminum2.70
zinc7.1
iron7.9
copper8.9
silver10.5
lead11.3
gold19.3
density in g/cm³ at room temperature
ACoppercorrect
BAluminum
This option is wrong — you divided by the final cylinder reading instead of the water-level rise — 44.5 ÷ 16.5 = 2.7 g/cm³, which matches aluminum, but the lump's volume is the rise, 5.0 cm³.
CZinc
This option is wrong — you compared the water-level rise with the density column — 5.0 is a volume in cm³, not a density.
DGold
This option is wrong — you looked for the lump's mass in the table instead of calculating the density.
Write down the values in the question: m = 44.5 g V = 16.5 − 11.5 = 5.0 cm³ Write down the equation: D = m / V Substitute in the values, and calculate: D = 44.5 / 5.0 D = 8.9 g/cm³ The table value 8.9 g/cm³ is copper.
Check your understanding

A student measures a metal's density as 7.8 g/cm³. Use the density table to decide which metal the sample most likely is.

Densities of common substances (room temperature)

SubstanceDensity (g/cm³)
ethanol0.79
water1.00
aluminum2.70
zinc7.1
iron7.9
copper8.9
silver10.5
lead11.3
gold19.3
density in g/cm³ at room temperature
AIroncorrect
BZinc
This option is wrong — you matched to the lower neighbor — 7.8 is 0.7 away from zinc's 7.1 but only 0.1 away from iron's 7.9.
CCopper
This option is wrong — you matched to the higher neighbor — copper's 8.9 is 1.1 away, while iron's 7.9 is only 0.1 away.
DNone of the metals
This option is wrong — you demanded an exact match — a real measurement carries small error, so the closest table value identifies the metal.
A real measurement rarely lands exactly on the table value. Compare the measured 7.8 g/cm³ with the nearby table values: zinc 7.1, iron 7.9, copper 8.9. Iron's 7.9 g/cm³ is only 0.1 away — the closest value — so the metal is most likely iron.
Summary video — Density as identity evidence

Watch in David’s player

End of Topic Test

End of Topic Test — five interchangeable forms, delivered separately.

Intro video — Separating mixtures and conservation of mass

Watch in David’s player

Lesson 44 of 55 · MPM-044

Why mixtures can be separated
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Have You Ever Wondered?
Wonder this:

Stir a spoonful of salt into a glass of water and the salt seems to vanish. If you ever want that salt back, has mixing destroyed it?

You've already seen that a mixture holds more than one kind of particle mingled together, and that mixing is a physical change.

The idea

Every sip of salt water still tastes salty, so the salt is still there, unchanged.

Because mixing is a physical change, no new substance forms — each component keeps its own properties in the mixture.

Salt still dissolves in water, sand still does not, and water still evaporates — mixed or not.

Because each component keeps its own properties, a physical change can pull the components apart again.

A compound is different: its elements are chemically joined, so taking a compound apart needs a chemical change.

Worked examples

Worked example 1. Why can the sugar in sugar water be recovered unchanged, while the hydrogen in pure water cannot be poured out?

Step 1

Sugar water is a mixture — sugar particles mingled among water particles, each kind unchanged.

Step 2

Pure water is a compound — hydrogen and oxygen atoms chemically joined in every particle.

Step 3

Recovering the sugar needs only a physical change; splitting water needs a chemical change.

Step 4

A mixture's components separate by physical changes; a compound's elements do not.

Worked example 2. Chalk powder stirred into water slowly settles to the bottom, still white and unchanged. What does that show about mixtures?

Step 1

The chalk particles did not dissolve and did not change.

Step 2

Each component kept its own properties in the mixture.

Step 3

Settling — a physical change — is already starting to separate them.

Step 4

Because each component keeps its own properties, physical changes can separate a mixture.

You can now explain why the components of a mixture can be separated by physical changes, because each component keeps its own properties in the mixture.

Check your understanding

A bag of trail mix holds raisins and peanuts. You can pick out every raisin, and each raisin is still a raisin. Which statement explains why?

AMixing changed neither component — each keeps its own properties, so a physical change separates them.correct
BThe raisins and peanuts slowly became one new substance in the bag, and picking them out reverses that change.
This option is wrong — you treated mixing as making a new substance — mixing is a physical change, and no new substance forms.
CEach raisin loses its properties in the bag and regains them once removed.
This option is wrong — you let the mixture hide the components' properties — each component keeps its properties even while mixed.
DPicking out the raisins is a chemical change that re-forms them.
This option is wrong — you classified separation as a chemical change — nothing new forms when a mixture is taken apart.
Mixing is a physical change, so no new substance forms. Each component keeps its own properties in the mixture. That is why a physical change — here, simply picking — can separate the components again.
Check your understanding

A student stirs cherry drink-mix powder into water until the powder disappears from view. Which statement about the mixture is correct?

AThe drink-mix particles are unchanged and keep their own properties, so a physical change can recover the powder.correct
BThe powder and the water have become a single new compound, so only a chemical change can ever separate them.
This option is wrong — you treated dissolving as chemically joining the substances — dissolving only mingles the particles.
CThe powder no longer exists as a substance until something recreates it.
This option is wrong — you read the disappearance as destruction — the powder's particles are only mingled among the water particles.
DThe powder keeps its properties only if the water is not stirred again.
This option is wrong — you made the powder's survival depend on stirring — the particles stay unchanged however the mixture is handled.
Dissolving is a physical change — the powder's particles are mingled among the water particles, not changed. Each component keeps its own properties in the mixture, which is why the drink still tastes of cherry. Because the powder is unchanged, a physical change can recover it.
Check your understanding

Why can the components of any mixture be separated by physical changes?

AEach component keeps its own properties, and a property difference lets a physical change pull them apart.correct
BPhysical changes break the chemical bonds holding the mixture's components together, freeing each substance.
This option is wrong — you pictured a mixture's components as chemically bonded — they are only mingled, so no bonds need breaking.
CEvery mixture separates on its own with time, and physical changes only speed the wait.
This option is wrong — you generalized from settling — many mixtures, such as salt water, never separate on their own.
DSeparating a mixture is itself a chemical change, one that turns the mixture back into the original substances.
This option is wrong — you classified separation as chemical — the components never stopped being the original substances.
Mixing is a physical change, so each component keeps its own properties in the mixture. A property that one component has and another lacks gives a physical change something to work on. That is why physical changes can separate any mixture.

Lesson 45 of 55 · MPM-045

Filtration
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Did You Know?
Wonder this:

A bucket of river water is cloudy with sand. Picking the grains out one by one would take a lifetime.

You've already seen why a mixture can be separated: each component keeps its own properties. Sand and water differ in one useful way — sand does not dissolve.

The idea

Sand never dissolves in water, however long you stir — a solid that does not dissolve in a liquid is 'insoluble'.

Pour the sandy water through a paper cone with tiny holes, and the water runs through while the sand stays on the paper.

A filtration setup: a beaker pours sandy water into a filter-paper cone sitting in a funnel; sand collects on the paper while clear water drips into a flask belowsand and water poured infilter paper — its holesare too small for thesand's particlessand collects on thepaperclear water dripsthrough
Filtration separating sand from water.

This separation method is 'filtration', and the paper is 'filter paper'.

Filtration works because the solid's particles are too large to pass through the filter's holes while the liquid's particles pass through.

The insoluble solid collects on the paper; the liquid drips through into the container below.

Filtration cannot remove a dissolved solid — dissolved particles are as small as the liquid's own particles, so they pass through the holes too.

Worked examples

Worked example 1. Powdered chalk does not dissolve in water. A chalk-and-water mixture is poured through filter paper. What ends up where, and why?

Step 1

Chalk is insoluble, so its particles stay whole and large.

Step 2

The chalk's particles are too large to pass through the filter's holes.

Step 3

The water's particles pass through.

Step 4

Chalk collects on the paper; clear water collects in the container below.

Worked example 2. Salt water is poured through filter paper. Does the salt collect on the paper?

Step 1

The salt is dissolved — its particles are mingled among the water particles and just as small.

Step 2

Particles that small pass through the filter's holes.

Step 3

No — everything passes through, and the liquid below is still salt water.

You can now explain how filtration separates an insoluble solid, one that does not dissolve, from a liquid, because the solid's particles are too large to pass through the filter's holes while the liquid's particles pass through.

Check your understanding

Garden soil is stirred into water; the soil does not dissolve. The mixture is poured through filter paper. What collects in the flask below?

AClear watercorrect
BSoil and water together
This option is wrong — you let pouring force large particles through — a particle larger than the holes cannot pass, however hard you pour.
CClear water at first, then soil as well
This option is wrong — you treated an insoluble solid as eventually dissolving — insoluble means it does not dissolve, however long you wait.
DNothing
This option is wrong — you made the filter block everything — the liquid's particles are small enough to pass through the holes.
The soil is insoluble, so its particles stay whole and large. Filtration works because the solid's particles are too large to pass through the filter's holes while the liquid's particles pass through. So the soil collects on the paper and clear water collects in the flask.
Check your understanding

Sugar is fully dissolved in water, and the mixture is poured through filter paper. What is the result?

ANothing separates — the liquid below is still sugar water.correct
BThe sugar collects on the paper and pure water drips through.
This option is wrong — you extended filtration to all solids — it traps only insoluble solids, whose particles stay large.
CThe heaviest sugar particles collect on the paper while the rest pass through.
This option is wrong — you made weight the filter's test — the filter tests particle size against hole size, and dissolved particles are all small enough to pass.
DThe water stays on the paper and the sugar passes through.
This option is wrong — you swapped the two components — the liquid passes through, and only particles larger than the holes are caught.
Dissolved sugar particles are mingled among the water particles and just as small. Particles that small pass through the filter's holes. So the liquid below is still sugar water — filtration cannot remove a dissolved solid.
Check your understanding

Powdered charcoal is insoluble in water. Why does filtration separate a charcoal-and-water mixture?

ABecause the charcoal's particles are too large to pass through the filter's holes while the water's particles pass through.correct
BBecause the filter paper soaks up the water like a sponge does and leaves the dry charcoal powder sitting on top of it.
This option is wrong — you used a soaking-up picture — the water passes through the holes; it is not absorbed and held by the paper.
CBecause the charcoal's particles stick to the paper's surface while the water slides off it.
This option is wrong — you swapped in stickiness — hole size against particle size does the separating, not attraction to the paper.
DBecause charcoal is denser than water, and the denser component of a mixture always stays behind.
This option is wrong — you reasoned from density — the filter compares particle size with hole size, not densities.
Filtration works because the solid's particles are too large to pass through the filter's holes while the liquid's particles pass through. The paper neither soaks up the water nor grips the solid — hole size does the work. Charcoal's particles are larger than the holes, so they stay on the paper.

Lesson 46 of 55 · MPM-046

Evaporation
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Wonder this:

Filter salt water and you collect… salt water. The dissolved salt slips straight through the paper. How do you get the salt back?

You've already seen that the salt in salt water is unchanged, and that its dissolved particles pass through any filter.

The idea

Gently heat salt water in a shallow dish, and the water evaporates — its particles escape into the air as a gas.

Two panels: first a dish of salt water gently heated with vapor rising; second the same dish holding only white salt crystalsBeforeAftersalt watergentle heatwater particlesescaping as a gassolid salt crystals leftbehind
Evaporation recovers the dissolved salt; the water escapes as a gas.

The salt cannot evaporate at these temperatures, so its particles stay in the dish.

When the last of the water has gone, solid salt crystals cover the dish.

Evaporating the liquid recovers a dissolved solid, because the liquid's particles escape as a gas while the solid's particles stay behind.

The recovered solid is the very substance that was dissolved — dissolving never changed it.

Evaporation keeps the solid but loses the liquid to the air.

Worked examples

Worked example 1. Sea salt is made by letting shallow pools of seawater sit in the sun. Explain why solid salt appears as the water disappears.

Step 1

Sun-warmed water evaporates — its particles escape into the air as a gas.

Step 2

The dissolved salt's particles cannot escape as a gas at these temperatures, so they stay behind.

Step 3

As more water leaves, the salt left behind builds up into solid crystals.

Step 4

The water's particles escape as a gas while the salt's particles stay behind, so solid salt collects in the pool.

Worked example 2. A student wants to recover dissolved sugar from sugar water. Filtration failed. What should she do, and what will she get?

Step 1

Warm the sugar water gently in a shallow dish.

Step 2

The water's particles escape as a gas; the sugar's particles stay behind.

Step 3

Gentle evaporation leaves solid sugar in the dish.

You can now explain how evaporating the liquid recovers a dissolved solid from a mixture, because the liquid's particles escape as a gas while the solid's particles stay behind.

Check your understanding

A dish of baking-soda solution — baking soda fully dissolved in water — is left on a sunny windowsill for a week. What remains in the dish?

ASolid baking sodacorrect
BNothing at all
This option is wrong — you let the solid escape as a gas — at these temperatures only the water's particles can escape.
CThe solution, unchanged
This option is wrong — you required a flame — water particles escape as a gas even at room temperature, just more slowly.
DA new substance
This option is wrong — you treated evaporation as a chemical change — the baking soda is the same substance that was dissolved.
Evaporation happens even without a flame — the water's particles escape into the air as a gas. The baking soda's particles cannot escape as a gas at these temperatures, so they stay behind. When the water has gone, the dish holds solid baking soda — the same substance that was dissolved.
Check your understanding

A student must recover a blue solid that is fully dissolved in water. Which plan works, and why?

AHeat the mixture gently until the water has evaporated — the blue solid's particles cannot escape as a gas, so they stay in the dish.correct
BPour the mixture through filter paper — the blue solid will collect on the paper while the water runs through into the flask below.
This option is wrong — you asked the filter to catch a dissolved solid — its particles are as small as the water's and pass through the holes.
CBoil the mixture hard and collect the escaping gas — the gas is the blue solid, driven out of the water.
This option is wrong — you sent the solid off with the gas — the escaping gas is the water; the solid stays behind.
DLet the mixture stand for a day until the blue solid settles to the bottom on its own.
This option is wrong — you treated a dissolved solid like an insoluble one — dissolved particles stay mingled and never settle out.
A dissolved solid passes through filter paper and never settles, so neither plan can work. Evaporating the liquid recovers a dissolved solid, because the liquid's particles escape as a gas while the solid's particles stay behind. Gentle heating leaves the blue solid in the dish, unchanged.
Check your understanding

Why does evaporating the water recover the salt from salt water?

ABecause the water's particles escape as a gas while the salt's particles stay behind.correct
BBecause the heat chemically splits the salt away from the water.
This option is wrong — you made evaporation a chemical change — the salt and water were only mingled, and both stay the same substances.
CBecause the salt's particles escape into the air first and then fall back into the dish.
This option is wrong — you sent the salt's particles into the air — they cannot escape as a gas at these temperatures.
DBecause the water soaks down into the dish, leaving the salt on top.
This option is wrong — you used a soaking-up picture — the water leaves upward as a gas, particle by particle.
Evaporation is a physical change — nothing is chemically split. The liquid's particles escape as a gas while the solid's particles stay behind. That one-way escape is the whole separation.

Lesson 47 of 55 · MPM-047

Distillation
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Wonder this:

A sailor surrounded by seawater can still die of thirst. Evaporating the seawater would throw away the one component he needs — the water.

You've already seen that evaporation keeps the dissolved solid and loses the liquid as a gas. Sometimes the liquid is what you want.

The idea

Heat the salt water in a flask until the water boils and leaves as a gas.

A distillation setup: a heated flask of salt water, a thermometer reading 100 degrees Celsius, a sloped tube cooled by a cold-water jacket, and a collecting flask receiving drops of pure watersalt water boils — thesalt stays here100 °C — the water'sboiling pointtube cooled by cold water— the gas condenses backinto liquidpure water collects
Distillation of salt water: the water boils away, condenses in the cooled tube, and is collected.

Water boils at 100 °C, and the salt stays far below its own boiling point, so only the water leaves as a gas.

Lead the escaping gas through a tube that is cooled on the outside by cold water.

Inside the cooled tube the gas condenses — it turns back into liquid water, which drips into a collecting flask.

This method — boil the liquid off, cool its gas back into a liquid, and collect it — is 'distillation'.

Distillation separates a liquid from a mixture because the liquid with the lower boiling point boils away first and its gas is then cooled back into a liquid and collected.

The salt stays behind in the heated flask, so distillation recovers both components — pure water in one flask, salt in the other.

Worked examples

Worked example 1. Sugar water is distilled. Explain where the pure water comes from and where the sugar ends up.

Step 1

The water has the lower boiling point, so it boils away first, leaving as a gas.

Step 2

The cooled tube condenses that gas back into liquid water, which drips into the collecting flask.

Step 3

The sugar cannot boil at these temperatures, so it stays in the heated flask.

Step 4

Pure water collects in the collecting flask; the sugar stays behind in the heated flask.

Worked example 2. A mixture of ethanol (boils at 78 °C) and water (boils at 100 °C) is distilled slowly. Which liquid is collected first?

Step 1

Ethanol has the lower boiling point — 78 °C against 100 °C.

Step 2

The liquid with the lower boiling point boils away first, and its gas is cooled back into a liquid and collected.

Step 3

Ethanol collects in the collecting flask first; most of the water stays behind.

You can now explain how distillation separates a liquid from a mixture, because the liquid with the lower boiling point boils away first and its gas is then cooled back into a liquid and collected.

Check your understanding

Mineral water — water with dissolved minerals — is distilled. What collects in the collecting flask?

APure watercorrect
BMineral water, unchanged
This option is wrong — you sent the dissolved minerals off with the gas — they stay far below their boiling points and never leave the heated flask.
CThe minerals
This option is wrong — you swapped the two components — the liquid with the lower boiling point is the one that boils away and is collected.
DNothing
This option is wrong — you skipped the cooled tube's job — it condenses the gas back into a liquid so the liquid can be collected.
The water has the lower boiling point, so it boils away first as a gas. The cooled tube condenses that gas back into liquid water. Pure water drips into the collecting flask; the minerals stay in the heated flask.
Check your understanding

What is the job of the cooled tube in a distillation apparatus?

AIt condenses the escaping gas back into a liquid so the liquid can be collected.correct
BIt filters the escaping gas, trapping any salt particles inside the tube.
This option is wrong — you gave the tube a filter's job — the salt never leaves the heated flask, and the tube only cools the gas.
CIt pulls the escaping gas along the apparatus, making the liquid boil faster.
This option is wrong — you made the tube drive the boiling — the heat under the flask does that; the tube's job is cooling.
DIt keeps the heated flask from getting too hot.
This option is wrong — you pointed the cooling at the flask — the cold water cools the escaping gas, not the flask.
Boiling turns the liquid into a gas that would otherwise drift away. The cooled tube condenses the gas back into a liquid. That condensed liquid drips into the collecting flask — collection is the whole point of distillation.
Check your understanding

A mixture of acetone (boils at 56 °C) and water (boils at 100 °C) is distilled slowly. Which liquid is collected first, and why?

AAcetone — the liquid with the lower boiling point boils away first, and its gas is cooled and collected.correct
BWater — the liquid with the higher boiling point holds more heat, so it is the first to escape the flask.
This option is wrong — you inverted the rule — the lower boiling point is reached first as the mixture heats, so that liquid boils away first.
CBoth together in equal amounts — boiling mixes the two gases evenly.
This option is wrong — you boiled both liquids at once — at 56 °C the acetone boils while the water is still far below its boiling point.
DAcetone — denser liquids always boil away first.
This option is wrong — you reasoned from density — the order of boiling is set by boiling point, not density; acetone is in fact the less dense of the two liquids.
Compare the boiling points: acetone 56 °C, water 100 °C. The liquid with the lower boiling point boils away first, and its gas is then cooled back into a liquid and collected. So acetone collects first, while most of the water stays behind.

Lesson 48 of 55 · MPM-048

Paper chromatography
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Wonder this:

Is the black ink in a marker really one black dye? Every dye in it is dissolved and colored, so filtering catches nothing and evaporating leaves them all behind together.

You've already seen separations that use solubility and boiling point. Telling dyes apart needs a different property difference — how strongly each dye holds to paper.

The idea

Put a small spot of the ink near the bottom of a strip of paper.

A paper strip standing in shallow water; from a pencil start line, three separated dye spots sit at increasing heights: blue lowest, red in the middle, yellow highest, with an arrow showing water climbing the stripwater — the spot starts abovethe water levelpaper stripstart line, where the blackink spot beganyellow dye — holds weakly,traveled farred dyeblue dye — holds strongly,traveled leastwater climbs the paper
Paper chromatography pulling a black ink apart into three dye spots.

Stand the strip upright in a little water, keeping the spot above the water level.

The water climbs the paper and carries the dissolved dyes upward.

Each dye also holds to the paper — some dyes strongly, some weakly.

Because dyes that hold to the paper more strongly travel shorter distances up the paper, the dyes pull apart into separate spots.

This method is 'paper chromatography'.

The finished strip, with its pattern of spots, is a 'chromatogram'.

Worked examples

Worked example 1. A strip carrying a spot of black ink stands in water. After ten minutes the strip shows a yellow spot high up, a red spot in the middle, and a blue spot just above the start. What happened?

Step 1

The climbing water carried each dissolved dye up the strip.

Step 2

The yellow dye holds to the paper weakly, so it traveled far.

Step 3

The blue dye holds to the paper most strongly, so it traveled least.

Step 4

The black ink was a blend of dyes, now pulled apart into separate spots.

Worked example 2. On a finished chromatogram, dye A sits higher up the strip than dye B. Which dye holds to the paper more strongly?

Step 1

Dyes that hold to the paper more strongly travel shorter distances up the paper.

Step 2

Dye B traveled the shorter distance.

Step 3

Dye B holds to the paper more strongly.

You can now explain how paper chromatography separates dissolved dyes, because dyes that hold to the paper more strongly travel shorter distances up the paper.

Check your understanding

Why do the dyes in an ink pull apart into separate spots during paper chromatography?

ABecause dyes that hold to the paper more strongly travel shorter distances up the paper.correct
BBecause heavier dyes sink down the strip while lighter dyes float up.
This option is wrong — you sorted the dyes by weight — the climbing water carries every dye upward, and the strength of each dye's hold on the paper sets its distance.
CBecause the water chemically changes each dye into a different-colored substance.
This option is wrong — you made the separation a chemical change — each dye is unchanged; the spots are the original dyes, pulled apart.
DBecause each dye boils away at a different temperature.
This option is wrong — you imported distillation's mechanism — nothing boils in chromatography; the hold on the paper does the separating.
The climbing water carries all the dissolved dyes up the strip. Each dye holds to the paper with its own strength. Dyes that hold to the paper more strongly travel shorter distances up the paper — so the dyes end up at different heights.
Check your understanding

A green ink separates into a blue spot near the start line and a yellow spot high on the strip. Which dye holds to the paper more strongly?

AThe blue dyecorrect
BThe yellow dye
This option is wrong — you inverted the rule — a stronger hold on the paper means a shorter distance traveled, not a longer one.
CBoth dyes hold equally
This option is wrong — you gave the water all the control — the water carries every dye, and each dye's own hold on the paper sets its distance.
DIt cannot be told from the spots' positions
This option is wrong — you made color the cause — color is just what you see; the strength of the hold on the paper sets the position.
Dyes that hold to the paper more strongly travel shorter distances up the paper. The blue spot sits near the start line — the shortest distance. So the blue dye holds to the paper more strongly.
Check your understanding

In paper chromatography, why must the ink spot start above the water level in the beaker?

AA spot sitting in the water would dissolve straight into the beaker's water instead of being carried up the paper.correct
BThe spot must stay completely dry from the start of the run to the finish.
This option is wrong — you kept the water away from the spot entirely — the climbing water must reach the spot to carry its dyes upward.
CWater sitting below the level of the spot would push the dyes down the strip instead of carrying them upward.
This option is wrong — you sent the water downhill — the water climbs the paper upward from wherever it touches.
DStarting the spot higher up gives every dye a stronger hold on the paper during the run.
This option is wrong — you tied the hold to the starting position — each dye's hold on the paper is a property of the dye, not of where the spot sits.
The dyes are dissolved, so open water dissolves the spot away — into the beaker, not up the strip. Placed above the water level, the spot waits for the climbing water to reach it. The climbing water then carries the dyes up the paper, where the separation happens.

Lesson 49 of 55 · MPM-049

Reading a chromatogram
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Did You Know?

You've already seen how a chromatogram forms. A finished chromatogram is a record you can read.

The idea

Each separate spot on a chromatogram is one dye.

Two chromatogram strips: the purple ink strip shows two spots at different heights; the brown ink strip shows three climbing spots plus one spot sitting on the start linePurple inkBrown inkhighest water levelstart line (pencil)
Two finished chromatograms. Count the separate spots — a spot still on the start line counts too.

To find how many dyes a sample contains, count its separate spots.

A spot still sitting on the start line counts too — that dye holds to the paper too strongly to climb.

Two spots of the same color at different heights are two different dyes.

The pencil start line and the mark showing how high the water reached are not spots — do not count them.

A sample that shows one single spot contains one dye.

Worked examples

Worked example 1. A chromatogram of a purple ink shows a pink spot high on the strip and a blue spot lower down. How many dyes does the ink contain?

Step 1

Count the separate spots: pink, blue — two.

Step 2

Each separate spot is one dye.

Step 3

Two dyes.

Worked example 2. A chromatogram of a brown ink shows spots at three different heights, plus one more spot that never left the start line. How many dyes?

Step 1

Three climbing spots, plus one spot still on the start line.

Step 2

A spot on the start line is still a dye — it holds to the paper too strongly to climb.

Step 3

Four dyes.

You can now identify the number of dyes in a sample from its chromatogram.

Check your understanding

The figure shows the chromatogram of ink X. How many dyes does ink X contain?

chromatogram with 3 spots — yellow; green; bluehighest water levelstart line (pencil)
AThreecorrect
BOne
This option is wrong — you judged by the ink's single mixed color — the chromatogram shows three separate spots, and each separate spot is one dye.
CTwo
This option is wrong — you merged the two closest spots into one — they sit at clearly different heights, so they are two different dyes.
DFour
This option is wrong — you counted the marked water level as a spot — that line only records how high the water climbed.
Each separate spot on a chromatogram is one dye. The strip shows three separate spots — the start line and the water-level mark are not spots. So ink X contains three dyes.
Check your understanding

The figure shows the chromatogram of ink Y. How many dyes does ink Y contain?

chromatogram with 3 spots — red; violet; blackhighest water levelstart line (pencil)
AThreecorrect
BTwo
This option is wrong — you left out the spot on the start line — a dye that holds to the paper too strongly to climb is still a dye.
CFour
This option is wrong — you counted the pencil start line itself as a spot — only the dye spots count.
DOne
This option is wrong — you judged by the ink's single mixed color — the chromatogram shows three separate spots.
Count every separate spot, wherever it sits. Two spots climbed the strip, and one spot never left the start line — that one counts too. So ink Y contains three dyes.
Check your understanding

The figure shows the chromatogram of ink Z. How many dyes does ink Z contain?

chromatogram with 3 spots — yellow; redhighest water levelstart line (pencil)
AThreecorrect
BTwo
This option is wrong — you merged the two yellow spots into one dye because they share a color — spots at different heights are different dyes, whatever their colors.
COne
This option is wrong — you treated ink Z as a single pure substance — the chromatogram separated it into multiple spots, showing that it contains multiple dyes.
DFour
This option is wrong — you counted the marked water level as a spot — that line only records how high the water climbed.
Each separate spot is one dye — color does not decide the count. The strip shows two yellow spots at different heights plus one red spot: three separate spots. So ink Z contains three dyes.

Lesson 50 of 55 · MPM-050

Planning a separation
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Wonder this:

You're handed a jar of gray sludge — sand, salt, and water, all mingled. No single technique untangles that in one move.

You've already seen four separation techniques, each built on a different property difference. Choosing well, and in the right order, is a skill of its own.

The idea

Choose the technique from the property difference between the components.

Choosing a separation technique

The mixtureWhat you want to keepTechnique
insoluble solid in a liquidthe solid (or the liquid)filtration
dissolved solid in a liquidthe solidevaporation
dissolved solid in a liquidthe liquid (or both)distillation
dissolved dyeseach dye, seen separatelypaper chromatography
Match the technique to the property difference and to the component you must keep.

An insoluble solid mixed through a liquid — filtration.

A dissolved solid you want to keep — evaporation.

A liquid you want to keep from a solution — distillation.

Dissolved dyes — paper chromatography.

When a mixture holds more than two components, plan a sequence: remove one component, then treat what remains as a new, simpler mixture.

Order matters — a technique works only when the mixture in front of it is the kind that technique needs.

Check the finished plan by tracking where every component ends up.

Worked examples

Worked example 1. A jar holds sand mixed through salt water. Plan a separation that recovers both the sand and the salt.

Step 1

Step 1 — filtration: the sand is insoluble, so it collects on the paper; the salt water passes through.

Step 2

Step 2 — evaporation: gently heat the salt water; the water escapes as a gas and the salt stays in the dish.

Step 3

Track every component: sand — on the paper; salt — in the dish; water — lost to the air.

Step 4

Filter first, then evaporate: sand and salt both recovered.

Worked example 2. Plan a separation that recovers drinkable water and the salt from seawater.

Step 1

The water must be kept, so open-dish evaporation is out — it loses the water to the air.

Step 2

Distillation: the water boils away first, condenses in the cooled tube, and is collected.

Step 3

Track every component: water — in the collecting flask; salt — left in the heated flask.

Step 4

One step — distillation recovers both components.

Worked example 3. A teacher asks whether a green food coloring is one dye or a blend. Which technique answers the question?

Step 1

The candidate dyes are all dissolved and all colored — filtering catches nothing, and evaporating leaves them behind together.

Step 2

Paper chromatography moves each dye its own distance, so a blend shows separate spots.

Step 3

Paper chromatography.

You can now predict which technique, or two-step sequence of techniques, will separate a described mixture, from the properties of its components.

Check your understanding

A solution holds a dissolved white solid in water. You need the solid and do not need to keep the water. Which technique do you choose?

AEvaporationcorrect
BFiltration
This option is wrong — you asked the filter to catch a dissolved solid — its particles are as small as the water's and pass through the holes.
CPaper chromatography
This option is wrong — you reached for the dye technique — chromatography spreads dissolved dyes into spots on paper; it does not recover a bulk solid.
DLetting the solution stand
This option is wrong — you treated a dissolved solid like an insoluble one — dissolved particles stay mingled and never settle out.
The solid is dissolved, so filtration and settling cannot touch it. The water is not needed, so nothing has to be collected. Evaporation fits: the water's particles escape as a gas while the solid's particles stay behind.
Check your understanding

While camping, a student accidentally stirs sugar into the only jug of drinking water. She wants the water back, free of sugar. Which technique should she choose?

ADistillationcorrect
BFiltration
This option is wrong — you asked the filter to catch a dissolved solid — the sugar passes through the holes with the water.
CEvaporation in an open dish
This option is wrong — you chose the technique that loses the water — the goal is to keep the liquid, and an open dish lets it drift away.
DPaper chromatography
This option is wrong — you reached for the dye technique — chromatography reads dyes on a strip; it cannot deliver a jug of drinkable water.
Name the goal first: the component to keep is the liquid. A liquid you want to keep from a solution — distillation. The water boils away first, condenses in the cooled tube, and collects; the sugar stays in the heated flask.
Check your understanding

Gravel and sugar are stirred into water; the sugar dissolves and the gravel does not. Plan a separation that recovers both the gravel and the sugar.

AFilter out the gravel first, then gently evaporate the sugar water — the sugar stays in the dish.correct
BEvaporate the water off first, then filter the two leftover solids apart.
This option is wrong — you evaporated first, stranding the two solids mixed together — filter paper separates a solid from a liquid, not one dry solid from another.
CFilter everything out in a single pass — the gravel and the sugar both collect on the paper.
This option is wrong — you asked the filter to catch the dissolved sugar — its particles pass through the holes with the water.
DDistill the whole mixture, then filter the water that collects in the receiving flask.
This option is wrong — you collected pure water and left the job unfinished — the gravel and sugar stay behind in the flask, still mixed together.
Order matters: while the water still carries the sugar, the gravel can be filtered out alone. Step 1 — filtration: gravel on the paper; sugar water passes through. Step 2 — evaporation: the water escapes as a gas and the sugar stays in the dish. Track every component: gravel — paper; sugar — dish; water — lost to the air, which the goal allows.

Lesson 51 of 55 · MPM-051

The law of conservation of mass
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Have You Ever Wondered?
Wonder this:

Zip 150.0 g of ice inside a sealed bag and let it melt. Will the bag weigh less, more, or the same?

You've already seen physical and chemical changes. One thing about them has been measured so many times that it became a law.

The idea

The melted bag weighs exactly 150.0 g — the same as before.

In a closed container, the total mass stays the same during any physical change.

Two panels showing the same sealed flask on a balance before and after a fizzing reaction; both balance displays read 250.0 gramsBefore250.0 gAfter fizzing250.0 g
A chemical change in a closed container: the total mass does not change.

The same holds for chemical changes: seal vinegar and baking soda in a flask, let them fizz, and the flask still weighs what it did before.

This rule is the 'law of conservation of mass': the total mass in a closed container stays the same during any physical or chemical change.

'Closed' means nothing gets in and nothing gets out.

Every careful measurement ever made on a closed container has confirmed the law.

Worked examples

Worked example 1. A sealed flask holds vinegar and baking soda in separate compartments and weighs 250.0 g. The flask is tipped so they mix and fizz. What does the balance read after the fizzing stops?

Step 1

The flask is closed — nothing entered and nothing left.

Step 2

The law of conservation of mass: the total mass in a closed container stays the same during any physical or chemical change.

Step 3

250.0 g — exactly the reading before.

Worked example 2. A sealed jar of water weighing 400.0 g is left in the freezer until the water freezes solid. What is the jar's mass now?

Step 1

Freezing is a physical change inside a closed container.

Step 2

The total mass stays the same.

Step 3

400.0 g.

You can now state the law of conservation of mass, that the total mass in a closed container stays the same during any physical or chemical change.

Check your understanding

In a sealed flask, a 10.0 g effervescent antacid tablet is dropped into 190.0 g of water and the mixture fizzes. What is the total mass of the sealed flask's contents after the fizzing stops? Give your answer in grams to one decimal place.

Answer: 200.0 g (tolerance ±0.05)
Write down the values in the question: mass of tablet = 10.0 g mass of water = 190.0 g The flask is sealed, so the law of conservation of mass applies: total mass before = total mass after In this problem's substances: mass of tablet + mass of water = total mass after Substitute in the values, and calculate: total mass after = 10.0 + 190.0 total mass after = 200.0 g
Check your understanding

Which statement is the law of conservation of mass?

AThe total mass in a closed container stays the same during any physical or chemical change.correct
BThe total mass in a closed container stays the same during physical changes but falls during chemical changes.
This option is wrong — you carved chemical changes out of the law — it holds for both kinds of change.
CThe total mass in a closed container falls whenever a gas forms, because gases weigh nothing.
This option is wrong — you gave gases zero mass — a gas has mass, and sealed inside, it keeps contributing to the total.
DThe total mass in a closed container stays the same only while nothing inside is changing.
This option is wrong — you reduced the law to 'nothing happened' — the law's whole point is that mass holds steady even while changes happen.
The law of conservation of mass: the total mass in a closed container stays the same during any physical or chemical change. It covers fizzing, burning, melting, dissolving — every change, as long as the container is closed. Gases count in the total like everything else.
Check your understanding

A sealed jar holding a lump of solid wax is warmed until the wax melts completely. What happens to the jar's total mass?

AIt stays exactly the same.correct
BIt decreases.
This option is wrong — you gave the state a weight of its own — the same particles are present, so the mass is unchanged whatever the state.
CIt increases.
This option is wrong — you expected liquid wax to weigh more than solid wax — melting rearranges the same particles and adds nothing.
DIt cannot be predicted without weighing the jar again.
This option is wrong — you treated the outcome as unknowable — the law guarantees it in advance for any change in a sealed container.
The jar is sealed — nothing gets in and nothing gets out. Melting is a physical change, and the law of conservation of mass covers it. The reading stays exactly the same.

Lesson 52 of 55 · MPM-052

Why mass is conserved
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Wonder this:

Rust weighs more than the iron nail it grew from. Where could the extra mass possibly come from?

You've already seen the law of conservation of mass, and that every substance is made of atoms.

The idea

During any change — melting, dissolving, fizzing, burning — the atoms regroup into new combinations.

No change creates a single new atom, and no change destroys one.

Each atom keeps its mass, so the same atoms always add up to the same total mass.

Mass is conserved because the atoms are only rearranged — no atoms are created or destroyed, so the total mass stays the same.

The rust's extra mass is not new mass — oxygen atoms from the air joined the iron, and their mass came with them.

Worked examples

Worked example 1. An iron nail rusts, and the rust weighs more than the nail did. Does rusting create mass?

Step 1

Rust forms when oxygen atoms from the air join the iron atoms.

Step 2

Those oxygen atoms existed all along, each with its own mass.

Step 3

Count everything — the nail plus the oxygen that joined — and the total is unchanged.

Step 4

No — the rust gains exactly the mass of the oxygen that joined the iron.

Worked example 2. Sugar dissolves in water inside a sealed jar, and the total mass does not change. Explain why at the particle level.

Step 1

Dissolving only mingles the sugar particles among the water particles.

Step 2

Every atom present before is still present after, each with its mass.

Step 3

The total mass stays the same because the atoms are only rearranged — no atoms are created or destroyed.

You can now explain why mass is conserved during changes, because the atoms are only rearranged — no atoms are created or destroyed, so the total mass stays the same.

Check your understanding

In a sealed flask, vinegar and baking soda fizz and make a gas, yet the total mass is unchanged. Why?

ABecause the atoms are only rearranged — no atoms are created or destroyed, so the total mass stays the same.correct
BBecause the gas that formed weighs nothing, so making it changes nothing on the balance.
This option is wrong — you gave the gas zero mass — a gas is matter, and its atoms carry the same mass they had before the change.
CBecause exactly as many new atoms are created as old atoms are destroyed, so the two effects cancel out.
This option is wrong — you balanced creation against destruction — neither happens; every atom survives the change.
DBecause in a sealed flask no real chemical change can happen in the first place.
This option is wrong — you concluded sealing prevents change — the fizzing is a chemical change; sealing only keeps all the atoms inside.
A chemical change regroups atoms into new combinations. No atom is created and no atom is destroyed, and each atom keeps its mass. The same atoms add up to the same total — that is why the sealed flask's mass is unchanged.
Check your understanding

When ice melts in a sealed bag, the mass stays the same. Which particle-level account is correct?

AThe same water particles are present before and after — only their arrangement changed.correct
BMelting destroys some particles and creates an equal number of new ones.
This option is wrong — you balanced destruction against creation — melting neither destroys nor creates particles.
CThe particles become lighter as they start to move more freely.
This option is wrong — you tied a particle's mass to its motion — moving faster or more freely changes nothing about a particle's mass.
DLiquid particles each weigh less than ice particles, but melting makes more of them.
This option is wrong — you changed both the mass and the count — neither changes; the particles are the same ones, rearranged.
Melting is a physical change: the particles leave their fixed positions and slide past one another. No particle is created or destroyed, and no particle's mass changes. Same particles, same masses — same total.
Check your understanding

Charcoal burns away completely inside a sealed container of air, yet the container's total mass is unchanged. Why?

AThe charcoal's atoms did not vanish — they joined oxygen atoms to form a gas, and every atom is still inside.correct
BThe flame destroyed the charcoal's atoms, and the container keeps its mass only because it is rigid.
This option is wrong — you let the flame destroy atoms — burning regroups atoms into new combinations; it destroys none.
CThe solid turned into energy, which stays trapped inside the container.
This option is wrong — you turned matter into energy — the charcoal's atoms became part of a gas, and atoms carry the mass.
DThe gas produced weighs nothing, and the oxygen that was used up makes up the difference.
This option is wrong — you gave the gas zero mass and patched the books — the gas holds the carbon and oxygen atoms, mass and all.
Burning joins the charcoal's atoms to oxygen atoms from the air, forming a gas. The solid disappears from view, but its atoms are all still inside the container, inside that gas. The atoms are only rearranged — no atoms are created or destroyed, so the total mass stays the same.

Lesson 53 of 55 · MPM-053

Using conservation of mass
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You've already seen the law of conservation of mass and why it holds. The law is also a calculating tool: weigh everything but one substance, and the law hands you the missing mass.

The equation

Write down the mass of every substance before the change and every substance after it.

The law guarantees the two totals are equal: total mass before = total mass after.

Put the unknown mass into the equation as the one missing value.

Make the unknown the subject, substitute, and calculate.

The answer carries the same unit as the given masses.

Check the answer: every single mass must be smaller than the total on its own side.

Worked examples

Worked example 1. In a sealed container, 4.0 g of hydrogen reacts completely with 32.0 g of oxygen, forming only water. What mass of water forms?

Step 1

Write down the values in the question

mass of hydrogen = 4.0 g

mass of oxygen = 32.0 g

Step 2

Write down the equation

total mass before = total mass after

Step 3

Write it in this problem's terms

mass of hydrogen before + mass of oxygen before = mass of water after

Step 4

Make the unknown the subject

mass of water = mass of hydrogen + mass of oxygen

Step 5

Substitute in the values, and calculate

mass of water = 4.0 + 32.0

mass of water = 36.0 g

Worked example 2. Heated in a closed container, 10.0 g of calcium carbonate breaks down into calcium oxide and 4.4 g of carbon dioxide gas. What mass of calcium oxide forms?

Step 1

Write down the values in the question

mass of calcium carbonate = 10.0 g

mass of carbon dioxide = 4.4 g

Step 2

Write down the equation

total mass before = total mass after

Step 3

Write it in this problem's terms

mass of calcium carbonate before = mass of calcium oxide after + mass of carbon dioxide after

Step 4

Make the unknown the subject

mass of calcium oxide = mass of calcium carbonate − mass of carbon dioxide

Step 5

Substitute in the values, and calculate

mass of calcium oxide = 10.0 − 4.4

mass of calcium oxide = 5.6 g

You can now calculate an unknown mass in a change using conservation of mass.

Check your understanding

In a sealed tube, 5.6 g of iron reacts completely with 3.2 g of sulfur, forming one new substance, iron sulfide. What mass of iron sulfide forms? Give your answer in grams to one decimal place.

Answer: 8.8 g (tolerance ±0.05)
Write down the values in the question: mass of iron = 5.6 g mass of sulfur = 3.2 g Write down the equation: total mass before = total mass after In this problem's substances: mass of iron before + mass of sulfur before = mass of iron sulfide after Make the mass of iron sulfide the subject: mass of iron sulfide = mass of iron + mass of sulfur Substitute in the values, and calculate: mass of iron sulfide = 5.6 + 3.2 mass of iron sulfide = 8.8 g
Check your understanding

In a sealed flask, 6.8 g of hydrogen peroxide breaks down completely into 3.6 g of water and one other substance, oxygen gas. What mass of oxygen forms? Give your answer in grams to one decimal place.

Answer: 3.2 g (tolerance ±0.05)
Write down the values in the question: mass of hydrogen peroxide = 6.8 g mass of water = 3.6 g Write down the equation: total mass before = total mass after In this problem's substances: mass of hydrogen peroxide before = mass of water after + mass of oxygen after Make the mass of oxygen the subject: mass of oxygen = mass of hydrogen peroxide − mass of water Substitute in the values, and calculate: mass of oxygen = 6.8 − 3.6 mass of oxygen = 3.2 g
Check your understanding

In a sealed chamber, 16.0 g of methane gas burns completely in 64.0 g of oxygen, forming 44.0 g of carbon dioxide and one other substance, water. What mass of water forms? Give your answer in grams to one decimal place.

Answer: 36.0 g (tolerance ±0.05)
Write down the values in the question: mass of methane = 16.0 g mass of oxygen = 64.0 g mass of carbon dioxide = 44.0 g Write down the equation: total mass before = total mass after In this problem's substances: mass of methane before + mass of oxygen before = mass of carbon dioxide after + mass of water after Make the mass of water the subject: mass of water = (mass of methane + mass of oxygen) − mass of carbon dioxide Substitute in the values, and calculate: mass of water = (16.0 + 64.0) − 44.0 mass of water = 80.0 − 44.0 mass of water = 36.0 g

Lesson 54 of 55 · MPM-054

Open containers and missing mass
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Wonder this:

A campfire burns a heavy stack of logs down to a double handful of ash. Has the law of conservation of mass failed?

You've already seen that the law promises a constant total in a closed container. A campfire is anything but closed.

The idea

In an open container, gases can leave, and gases from the air can join in.

Two panels of an open beaker on a balance: before, reading 210.0 grams; after fizzing, with an arrow showing gas escaping, reading 207.8 gramsBefore210.0 gAfter fizzing207.8 gescaping gascarries its massaway
An open container: the escaping gas carries 2.2 g away, and the balance shows it.

A gas has mass, and an escaping gas carries its mass away with it.

Burning changes most of the wood into smoke and invisible gases, and in the open they drift away.

The ash weighs less than the wood because the smoke and gases carried mass away.

Mass can also arrive: when iron rusts in open air, oxygen from the air joins the iron, so the solid gains mass.

Track every substance, gases included, and the totals still balance — no mass was created or destroyed.

A changing balance reading on an open container means matter moved in or out, not that the law failed.

Worked examples

Worked example 1. An open beaker of vinegar and baking soda sits on a balance reading 210.0 g. After the fizzing stops, the balance reads 207.8 g. Where did the missing 2.2 g go?

Step 1

The fizzing made a gas.

Step 2

The beaker is open, so the gas escaped into the air.

Step 3

The escaping gas carried its 2.2 g of mass with it.

Step 4

Sealed, the reading would still be 210.0 g.

Step 5

2.2 g left as escaping gas — no mass was destroyed.

Worked example 2. Steel wool left on an open balance pan slowly rusts, and the reading rises. Explain.

Step 1

Rusting joins oxygen from the air to the iron.

Step 2

The arriving oxygen brings its mass with it.

Step 3

The reading rises by exactly the mass of the oxygen that joined — mass moved in from the air.

You can now explain why the measured mass can appear to change in an open container, because a gas can escape to the surroundings or enter from them.

Check your understanding

A glass of water left on a balance for two days shows a slowly falling reading. Why?

AWater particles leave as a gas, and each one carries its mass away.correct
BLight slowly destroys some of the water.
This option is wrong — you destroyed matter — the water still exists, spread through the air as a gas.
CThe reading cannot really change — the balance must be drifting.
This option is wrong — you treated the open glass as a closed container — in the open, matter can leave, and the reading honestly tracks it.
DDissolved air escapes and carries the mass away.
This option is wrong — you blamed the wrong substance — the escaping matter is the water itself, evaporating.
The glass is open, so matter can leave. Evaporating water particles escape as a gas, and a gas has mass. Each escaping particle carries its mass away, so the reading falls — no mass is destroyed.
Check your understanding

A candle burns on a balance in the open air, and the reading falls steadily. What happened to the missing mass?

AThe burning wax became gases that drifted away, taking their mass with them.correct
BThe flame destroyed it — burning removes matter from existence.
This option is wrong — you let the flame destroy atoms — burning only regroups them into gases, which drift off in the open.
CIt became heat and light, which weigh nothing.
This option is wrong — you turned matter into energy — the matter became gases, and gases carry their mass wherever they drift.
DNothing left the candle — melted wax simply weighs less than solid wax.
This option is wrong — you gave the state a weight of its own — melting changes no mass; the loss is matter leaving as gas.
Burning changes the wax into invisible gases. The setup is open, so those gases drift away. A gas has mass — the falling reading is that mass leaving, not mass being destroyed.
Check your understanding

A silver spoon left in open air slowly tarnishes, growing a dark coating, and now weighs slightly more than before. Where did the extra mass come from?

AMatter from the air joined the silver — the arriving atoms brought their mass with them.correct
BThe tarnish itself created the extra mass as it spread across the spoon.
This option is wrong — you let a change create mass — no change creates atoms; the gain arrived from the air.
CThe silver's own atoms slowly grew heavier as the spoon darkened.
This option is wrong — you let atoms gain mass — an atom's mass is fixed; extra mass means extra atoms joined.
DThe measurement must be wrong, because the mass of an object can never increase.
This option is wrong — you applied the closed-container law to an open spoon — in the open, arriving matter can raise the total honestly.
The spoon sits in open air, so matter can join it. Tarnishing joins substances from the air to the silver, and the arriving atoms bring their mass. Count the spoon plus what joined it, and no mass appeared from nowhere.

Lesson 55 of 55 · MPM-055

Hypothesis, theory, or law
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Wonder this:

This unit handed you two heavyweight pieces of science: 'in a closed container, the total mass never changes' and 'all matter is made of tiny moving particles.' They are not the same kind of statement.

Scientific statements are sorted by the job they do and by how much testing they have survived.

The idea

'In a closed container, the total mass stays the same during any change' describes what always happens — it does not say why.

A well-tested statement that describes what always happens is a 'law'.

'Matter behaves as it does because it is made of tiny, constantly moving particles' explains why things happen.

An explanation of why things happen, supported by extensive evidence, is a 'theory'.

'I think the damp crystals pulled water from the air' — proposed before testing — is a testable proposed explanation, a 'hypothesis'.

A hypothesis that survives extensive testing can grow into a theory — but a theory never turns into a law.

A law and a theory answer different questions: the law describes, the theory explains.

To classify a statement, ask two things: does it describe or explain, and is it a fresh proposal or backed by extensive evidence?

Worked examples

Worked example 1. Classify the statement: 'Mass is conserved in every chemical change.'

Step 1

The statement describes what always happens; it does not explain why.

Step 2

It has been confirmed by countless measurements.

Step 3

A law.

Worked example 2. Classify the statement: 'Matter is made of tiny particles in constant motion — this explains melting, evaporation, and dissolving.'

Step 1

The statement explains why things happen.

Step 2

It is supported by an enormous body of evidence.

Step 3

A theory.

Worked example 3. A student finds her salt crystals damp and says: 'I think the crystals pulled water out of the air — I'll weigh them in a dry room and a humid room to check.' Classify her statement.

Step 1

It is a proposed explanation.

Step 2

It is testable, and the test has not happened yet.

Step 3

A hypothesis.

You can now classify a scientific statement as a hypothesis (a testable proposed explanation), a theory (an explanation of why something happens, supported by extensive evidence), or a law (a description of what always happens).

Check your understanding

Classify the statement: 'At sea level, pure water always boils at 100 °C.'

AA lawcorrect
BA theory
This option is wrong — you sorted by the amount of evidence — a theory must explain why, and this statement only describes.
CA hypothesis
This option is wrong — you sorted by history — a hypothesis is an as-yet-untested proposal, and this statement is thoroughly tested.
DNot a scientific statement
This option is wrong — you treated exceptionless as unscientific — describing what always happens is exactly what a law does.
Ask the two questions: does it describe or explain, and how tested is it? It describes what always happens — no why is offered — and it is confirmed by countless measurements. A well-tested description of what always happens is a law.
Check your understanding

Classify the statement: 'A gas is easy to squeeze because its particles are far apart with empty space between them.'

AA theorycorrect
BA law
This option is wrong — you sorted by how widely it holds — laws describe what happens, this statement explains why, and no amount of evidence turns a theory into a law.
CA hypothesis
This option is wrong — you froze explanations at the proposal stage — extensive evidence is what turns a proposed explanation into a theory.
DNot a scientific statement
This option is wrong — you treated an explanation about invisible particles as untestable guesswork — the particle picture is tested through the behavior it predicts.
The statement answers a why question — that is explaining, not describing. The particle picture behind it is supported by an enormous body of evidence. A well-evidenced explanation is a theory, and it stays a theory however strong the evidence grows.
Check your understanding

A student notices windowsill plants leaning toward the glass and says: 'I think they grow toward the light — if I turn the pots around, the stems will bend back within a week.' Classify the statement.

AA hypothesiscorrect
BA theory
This option is wrong — you promoted a fresh proposal — explaining is necessary for a theory, but extensive evidence is required too.
CA law
This option is wrong — you classified the student's untested proposal as a well-tested description — no body of tests stands behind her statement yet.
DA mere guess with no scientific standing
This option is wrong — you demanded certainty — being testable, and possibly wrong, is exactly what gives a hypothesis its scientific standing.
The student proposes an explanation for what she observed. It is testable — she has even named the test — and untested so far. A testable proposed explanation is a hypothesis.
Summary video — Separating mixtures and conservation of mass

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End of Topic Test

End of Topic Test — five interchangeable forms, delivered separately.