Unit 12 — End of Topic Tests (reviewer copy: all keys and model answers visible)

End of Topic Test: Energy, temperature, and heat & How heat travels & Systems and conservation of energy & The four laws in everyday life (u12-t1 · 5 forms × 21 items · 105 total)

David's notes for James:
full notes file
# u12-t1 — notes/queries from David's side (U12-G1)

1. FRQ ALLOCATION - frq_per_form = 1 (confirm the composition): the wave's calc-heavy 2-3-FRQ directive does NOT apply - ZERO quant lessons in this scope (no THM-001..016 lesson carries a displayEquation or atomKind 'quant'; the unit's calculation content q = mc-Delta-T / calorimetry / heating curves lives in Topics 7-9, i.e. LATER U12 gates). The scope's only numeric routine is THM-012's conservation bookkeeping, whose own specNotes bar the 5-line scaffold ('bookkeeping arithmetic with plain-sentence feedback') because no formula is substituted - so there is no substituted-formula production routine for a calculation FRQ to assess; that skill is assessed at the seq-15 numeric ENTRY row instead. The FRQ slot goes to the gate's terminal integrative skill: THM-016 capstone production (match observations to laws WITH justification), terminal at seq 21 per D6. Your seed file's frq_per_form=1 concurs. D5: min(20, 6 x 16) = 20 objective rows, no scaling; your target_size=20 concurs.
2. NOTA REPLACEMENT ON YOUR TAUGHT FIXED LABEL SETS (recorded adjudication A-U12G1-NOTA, OVERTURNED from a stage-1 keep - confirm): THM-005's and THM-009's specNotes mandate fixed four-option sets whose fourth member is 'None of the above' ('Temperature / Thermal energy / Heat / NOTA'; 'Conduction / Convection / Radiation / NOTA'), and your seeds p12/p24/p25/p26 carry it. Our deterministic validator V-T5 bans NOTA/AOTA outright with no relief lane BY DESIGN, the shared validator is never weakened, and replacement is the canonical practice across all shipped gates (ANSWERS #2). RESOLUTION on the TEST forms only (your lesson banks keep their taught NOTA sets): the NOTA slot became a misconception-keyed bare label while the three REAL taught labels and their key rotation are preserved intact - seq 7 -> 'An energy transformation' (transfer-vs-transformation confusion, THM-001 vocabulary); seq 10 -> 'Thermal equilibrium' (state-vs-route confusion, THM-013 vocabulary); seq 11 -> 'An energy transformation'. Your NOTA misconception feedback ('you rejected all three ...') is replaced by each new option's own misconception. Applied to the four seeds and mirrored on all fresh forms.
3. SOL SURVIVORS ON THE NOTA REPLACEMENTS (recorded A-U12G1-NOTA-SOLQC, disclosure): our authoritative cross-vendor QC (gpt-5.6-sol) flagged the replacement fourth options at C#10/C#11/D#7 as deviating from your specNotes' fixed label sets - which is exactly the recorded A-U12G1-NOTA adjudication above, not a new content defect (sol itself PASSED the identical fourth options on 12 of the 15 slots, e.g. A#7/A#10/A#11/B#7/B#11/E#7/E#10/E#11). Labels kept per the adjudication; recorded as honest survivors: final sol ledger 102 pass / 3 recorded survivors.
4. AIR AS THE REGISTER'S WORKING FLUID (recorded adjudication A-U12G1-AIR, confirm): 'air' is a MATERIALS-lexicon token in our freshness scans, but it is the taught working fluid of this scope - THM-007's convection rule lines name it ('warm, less dense air rises'), THM-009's R1 physical-clue scenes must describe the moving gas, THM-010's taught surroundings convention IS 'solvent + container + air', and the THM-016 pendulum seed's measurement names the surrounding air. Renaming the fluid would degrade the taught content (same class as U12-G3's water ruling). Excused by a recorded, slot-enumerated family (A#9/D#9/E#9/B#10/B#12/B#18 ONLY), enforced by a gate-local wrapper over the UNTOUCHED shared validator (negative probes 3/3: non-family material fails, family material at a non-family slot fails). Every other item was authored air-free (liquid scenes, 'no matter in the gap', 'the room'); numbers scan in full everywhere.
5. SEED FRESHENINGS UNDER THE STRICT SEED RULING (recorded A-U12G1-SEEDFRESH; dispositions to confirm, per-item detail in each item's source string): 34 of your 48 pool seeds placed (form A fully seeded 20/20, B 11, C 3; demo_curated[0..2] dedup into the pool with dual refs), 14 spares with recorded reasons (value home-seq collisions, parity mismatches, near-duplicate surfaces, own-lesson register instances). Content freshens, never validator relief: (1) spec-number collisions re-minted - p3 70->68 degC, p4 90/30->91/33, p6 masses 200/2000->600/6000 g, p35 200/40->340/48 J (10 J kept, <=12 non-scanning), p39 60/20->64/19 degC, p43 distractor -250->-240, p46 40->55; (2) own-lesson taught-material collisions re-phrased - p3/p9/p19/p27 'water'->broth/punch/'the liquid', p16 'curling iron'->'curling wand', p31 'water molecules'->'its molecules', p33/p41 'air' dropped, p44 'water'-exempt distractor->'solids'-exempt; (3) instance freshens per stage-1 flags - p4 tea->cider, p19 'aquarium' dropped, p29 beaker->jar, p32 picnic cooler->food carrier, p41 cooled drink->cooled plate of food; (4) p44's taught constants -273/-373 moved out of scanned fields ('absolute zero' wording + a fresh distractor set) so no taught-constant numeric family was needed - -273 lives only in feedback/explanations.
6. NUMERIC CONTRACT ON THE SEQ-15 CONSERVATION ROW (recorded A-U12G1-NUMCONTRACT, confirm): THM-012's bookkeeping is EXACT whole-number energy accounting by spec design, so your seed builder's appended 'Give your answer to 3 significant figures.' sentence was dropped on all five forms. Every seq-15 item carries integer:true, tolerance 0.5, the instruction 'Give your answer as a whole number of joules.', the conservation reminder parenthetical carried verbatim from your p35 stem, a plain-sentence keyExplanation (no 5-line scaffold - no formula is substituted, per THM-012's own specNotes), and your spec's four misconception classes as wrong-value diagnostics (gave-the-total / sum-of-named / added-everything / subtracted-only-one).
7. RECORDED CONVENTION/IDIOM ENTRIES (A-U12G1-CONV / A-U12G1-IDIOM, confirm): the two seq-15 instruction sentences above are recorded convention phrases (instruction boilerplate; every scenario VALUE still scans in full); 'No correction is needed' is recorded as a task idiom - it is your recurring claim-fix distractor opener (verbatim in multiple spec gateItems: p16/p29/p33/p36 classes) and every claim-fix row carries the no-correction distractor class by design.
8. MECH-HEAT-FLOW-HS (disclosure): the mechanism sentence 'because when faster-moving particles collide with slower-moving ones, energy passes from the faster particles to the slower ones' appears VERBATIM in every form's seq-8 conduction keyExplanation per THM-006's specNotes (at least one feedback chain per bank; never paraphrased, never in stems).
9. SECOND-LAW FENCE + CAPSTONE TRAP DISCIPLINE (disclosure): no refrigerators, air conditioners, or heat pumps anywhere in the THM-014 rows (pumped heat = work channel, course exclusion); 'on its own / by itself' is load-bearing in every seq-17/20 key or stem; every THM-016 capstone stem hinges on exactly ONE aspect (shared end temperature -> zeroth; one-way direction -> second) so the key is unique; options are the four bare law labels, reasons live in feedback only.
10. BLIND-QC FIXES (disclosure): round 1 (gpt-5.6-sol blind role + gemini, 105 items x 2 reviewers) scored 190/190 on the key-pick lane; keyless lanes (5 numeric + 5 FRQ slots x 2 reviewers) all graded MATCH with justifications recorded (frq_verdicts.json). 4 hard fails, all the two-defensible class, fixed in content: A#13 (a composite 'closed for matter / open for energy' distractor WAS the closed-system definition), B#19 (drift-toward-one-temperature read as zeroth law - re-pinned), D#11 (natural convection not excluded by the scene), E#3 (an open port let hot gas exit sideways). Class sweeps from single catches: the seq-20 temperature-ordering ambiguity swept on every form (cold object pinned AT ambient before the claimed re-warming); one round-4 catch (D#5's two-step chain defensible without a complete-chain demand) -> stem pinned to 'lists every energy form in order'. Five rounds total: 0 open hard fails, key picks 254/254 cumulative.
11. SOL-QC FIXES (disclosure): authoritative gpt-5.6-sol loops 1-3 went 20 -> 8 -> 0 open FAILs (final ledger 102 pass / 3 recorded NOTA survivors, see above). Fix classes, all in content: uniqueness clues pinned (open stairwell, immediacy wording, battery-free, warmed AIR, no-passing-stream); weak or arguably-true distractors replaced (evaporation->particles-shrink, permanence->needs-container, excluded-true->thermal-makes-light, absurd->open/closed label confusion); surroundings items reframed as examples-lists with system-mixed distractors ('Only things never touched' was defensible); key wording corrected (direction claim, 'instead of its own'); feedback defect CLASSES swept bank-wide ('stays thermal as it moves' - energy in transit is heat; 'heat has none' - heat lacks an UPWARD preference, not direction; 'far too slow' universals; holds-none; only-0K).
12. BINDING INSTANCE RULE (course-wide, disclosure): zero fissile/weapons/dose framings; classroom-safe instances throughout (griddles, fish tanks, stairwells, music boxes, bronze door handles, cold-atom labs). Re-swept at packaging with a deterministic token scan over forms_final.json AND this export body.
13. QC LEDGER (disclosure): deterministic validators 11/12 PASS as shipped (V-T6 numeric-realism PASSES on the 5 live numeric slots; V-T5 NOTA-absent PASSES post-replacement) + gate-local adjudication wrapper VERDICT PASS exit 0 - V-T7's 22 collision lines 100% covered by the recorded AIR-WORKING-FLUID family (0 uncovered; parity guard 22/22 MATCH; 3/3 wrapper negative probes); stage-3 content patching (35 machine-logged edits: seed-value remints, spec-gram rewords, key/distractor length rebalances) ran BEFORE any adjudication; blind = 5 rounds, 0 open hard fails, all FRQ/numeric cold answers graded match with justifications; sol authoritative loops 1-3 = 20 -> 8 -> 0 open FAILs with the 3 recorded survivors; 70 machine-logged patch ops across 3 waves (_patch_*_log.json) plus point fixes recorded in fix_log.md.

Form A

THM-002 · easy · recall · seq 1 · seed:U12-G1.pool[3] (THM-002 gateItems, James) - FRESHENED (SEED RULING: 'water' = THM-002 own-lesson taught material (article 80/20 °C water) -> broth; 70 °C = THM-003 spec value -> 68 °C; structure/misconceptions verbatim) · mcq4
A cup of broth and a full pot of broth both sit at 68 °C. Which statement about their particles is correct?
The average kinetic energy of the particles is the same in both. KEY
The pot's particles have a higher average kinetic energy because the pot holds more broth.
The cup's particles have a higher average kinetic energy because a small sample warms through more easily.
The two averages cannot be compared, because the samples are different sizes.
THM-004 · easy · recall · seq 2 · seed:U12-G1.pool[9] (THM-004 gateItems, James) - FRESHENED (SEED RULING: 'water' = THM-004 own-lesson taught material -> punch; ice kept (home seq 2, recorded scope-material WARN class); third distractor re-keyed melting-first since same-substance logic left with water) · mcq4
An ice cube floats in a cup of warm punch. Which statement describes the energy flow?
Energy flows from the warm punch into the colder ice, because of the temperature difference. KEY
Coldness flows from the ice into the punch, chilling it.
Energy flows from the ice into the warmer punch, because ice gives up its energy easily.
No energy flows between them until the ice has finished melting.
THM-008 · easy · recall · seq 3 · seed:U12-G1.pool[21] (THM-008 gateItems, James) - VERBATIM (field mapping only; Sun = THM-008 rule-line taught instance) · mcq4
An astronaut on a spacewalk feels the Sun's warmth on the suit even though space is a near-perfect vacuum. Why can the energy still arrive?
The energy travels as electromagnetic waves, which need no matter to carry them. KEY
Thin streams of hot space dust conduct the energy to the suit.
Currents of warm space gas rise from the Sun and flow past the suit.
The suit generates the warmth itself when sunlight cannot reach it.
THM-015 · easy · recall · seq 4 · seed:U12-G1.pool[43] (THM-015 gateItems, James) - FRESHENED (SEED RULING: −250 = THM-003 spec value 250 under sign-stripping -> −240; permutational set otherwise verbatim; −273 confined to feedback) · mcq4
Which of the following temperatures is impossible for any object?
−300 °C KEY
−240 °C
1 K
400 K
THM-001 · medium · application · seq 5 · seed:U12-G1.pool[0] (THM-001 gateItems, James) - VERBATIM (field mapping only; the register's two-step chain read) · mcq4
A portable speaker plays music from a charged battery. Ignoring the small amount of warming, which energy transformation carries the music to your ears?
Chemical energy → electrical energy → sound energy KEY
Sound energy → electrical energy → chemical energy
Electrical energy → chemical energy → sound energy
Chemical energy → kinetic energy → sound energy
THM-003 · medium · application · seq 6 · seed:U12-G1.pool[6] (THM-003 gateItems, James) - FRESHENED (must_freshen_instance: masses 200/2000 g collide with the 200 spec value -> 600/6000 g, ratio kept; soup + 85 °C home-seq 6; key logic unchanged) · mcq4
A chef ladles 600 g of soup from a stockpot into a bowl. The soup in the bowl and the soup left in the pot are both at 85 °C, and the pot still holds 6000 g. Which statement is correct?
The pot's soup holds more thermal energy, and both samples are at the same temperature. KEY
The bowl's soup holds more thermal energy, because ladling stirs energy into it.
The pot's soup is at a higher temperature, because it holds more thermal energy.
The two samples hold equal thermal energy, because they came from the same batch.
THM-005 · medium · application · seq 7 · seed:U12-G1.pool[12] (THM-005 gateItems, James) - FRESHENED (A-U12G1-NOTA: NOTA distractor replaced with the misconception-keyed transformation-confusion label; stem/key/other distractors verbatim; recorded adjudication overturning the stage-1 taught-set keep — V-T5 is armed with no relief lane) | sol-1 class sweep: 'stays thermal as it moves' boundary wording fixed · mcq4
'Overnight, energy passed from the warm garage floor into the cold car tires.' Which quantity does this statement describe?
Heat KEY
Temperature
Thermal energy
An energy transformation
THM-006 · medium · application · seq 8 · seed:U12-G1.pool[15] (THM-006 gateItems, James) - VERBATIM (field mapping only; MECH-HEAT-FLOW-HS verbatim in keyExplanation per THM-006 specNotes) · mcq4
Pancake batter is poured onto a hot griddle and begins to cook where it touches the metal. Which statement describes the energy transfer at the griddle's surface?
The griddle's faster particles collide with the batter's slower particles, passing energy into the batter — conduction through direct contact. KEY
The griddle's particles flow up into the batter, carrying energy with them.
The batter's particles collide with the griddle's particles and pass energy down into the metal, which is why the griddle stays hot.
The energy reaches the batter as waves that cross without any particle contact.
THM-007 · medium · application · seq 9 · seed:U12-G1.pool[18] (THM-007 gateItems, James) - VERBATIM (field mapping only; AIR family slot A-U12G1-AIR — the convection register names its working fluid) | sol-1: open-stairwell path pinned; 'far too slow' + 'heat has none' feedback overclaims fixed | sol-2: walls distractor recast as particle migration (no route-priority claim needed) · mcq4
In a two-story house heated by one wood stove downstairs, an open stairwell connects the two floors, and the upstairs bedrooms grow warm even though the stove never touches them. Which account is correct?
Air warmed by the stove becomes less dense and rises up the stairwell while cooler, denser air sinks back down — the circulating air carries the energy upstairs. KEY
Warm particles from the stove travel bodily inside the solid walls and floors all the way up to the bedrooms, carrying the stove's energy along with them.
Heat rises on its own, so the energy floats upstairs without the air moving.
The warm air downstairs becomes denser and is squeezed upstairs by the cold air above.
THM-009 · medium · application · seq 10 · seed:U12-G1.pool[24] (THM-009 gateItems, James) - FRESHENED (A-U12G1-NOTA: NOTA distractor replaced with the misconception-keyed state-vs-route label 'Thermal equilibrium'; stem/key/other distractors verbatim) · mcq4
An electric blanket is spread over a bed, switched on, and the mattress beneath it slowly warms where the blanket lies. Classify the transfer warming the mattress.
Conduction KEY
Convection
Radiation
Thermal equilibrium
THM-009 · medium · application · seq 11 · seed:U12-G1.pool[25] (THM-009 gateItems, James) - FRESHENED (A-U12G1-NOTA: NOTA distractor replaced with the misconception-keyed transformation-confusion label; stem/key/other distractors verbatim; this row owns overhead-element-browning surfaces) · mcq4
In a bakery, a glowing overhead element browns the tops of loaves on a shelf below it, without any fan and without touching them. Classify the transfer browning the loaves.
Radiation KEY
Convection
Conduction
An energy transformation
THM-010 · medium · application · seq 12 · seed:U12-G1.pool[27] (THM-010 gateItems, James) - FRESHENED (SEED RULING: 'water' = THM-010 own-lesson taught material -> 'the liquid'/'mop bucket'; boundary logic and misconception classes verbatim) | stage-3 wave-1: V-T7: 'the reacting tablet chemicals' = THM-010 spec gram · mcq4
A cleaning tablet reacts in a full mop bucket, and the liquid around it grows noticeably warmer. Taking the tablet's reacting chemicals as the system, which statement is correct?
The liquid is part of the surroundings, and its warming shows the surroundings receiving energy from the system. KEY
The liquid is part of the system, because the tablet dissolved into it.
The liquid is part of the surroundings, so its warming has nothing to do with the reaction.
The bucket is the system, because it holds everything together.
THM-011 · medium · application · seq 13 · seed:U12-G1.pool[30] (THM-011 gateItems, James) - FRESHENED (replace_distractor per stage-1 flag: NOTA -> misconception-keyed channel-splitting label, the blueprint's prescribed class; stem/key/other distractors verbatim) | blind-1 HARD fix (r1+r2 F2): 'closed for matter / open for energy' composite WAS the closed-system definition -> replaced with the reversed-exchange misconception · mcq4
A sealed glass terrarium sits on a sunny windowsill, and the plants inside stay warm through the day. Classify the terrarium and its contents.
A closed system KEY
An open system
An isolated system
A system open to matter but closed to energy
THM-012 · medium · application · seq 14 · seed:U12-G1.pool[33] (THM-012 gateItems, James) - FRESHENED (SEED RULING: 'air' = THM-012 own-lesson taught material, dropped from the key's spread list; claim-fix structure and misconceptions verbatim) | sol-1: holds-none feedback overclaim fixed · mcq4
A student says, 'Once the car's gas tank is empty, the fuel's energy is gone — driving destroyed it.' Which correction fixes the claim?
The energy was not destroyed — it was transformed into the car's motion and into thermal energy spread through the engine and brakes. KEY
No correction is needed — burning a fuel down to nothing is one of the few processes that genuinely destroys its energy.
The energy was destroyed, but an equal amount was created elsewhere to balance it.
The energy still sits in the empty tank, waiting in a hidden form.
THM-012 · medium · application · seq 15 · seed:U12-G1.pool[35] (THM-012 gateItems, James) - FRESHENED (SEED RULING: stem values 200/40 sit in scope spec text -> 340/48, 10 J kept (<=12 non-scanning); NUMERIC-CONTRACT adjudication applied: sig-fig sentence dropped, integer:true + whole-number instruction, tolerance 0.5, plain-sentence explanation; the spec's four misconception CLASSES carried at the fresh values) · numeric
A television converts 340 J of electrical energy. It gives off 48 J as light and 10 J as sound. How much energy, in joules, becomes thermal energy? (Energy is conserved — every joule must be accounted for.) Give your answer as a whole number of joules.
Answer: 282 J KEY
also accepted: 282 J, 282.0
wrongValueDiagnostics
[
 {
  "value": 340,
  "misconception": "you gave the total converted energy instead of the thermal share — subtract the light and sound from the 340 J",
  "feedback": "This answer is wrong — 340 J is everything the television converted. The thermal share is what remains after light and sound: 340 − 48 − 10 = 282 J."
 },
 {
  "value": 58,
  "misconception": "you gave the light plus sound instead of what remains — 48 + 10 = 58 J is the part already accounted for",
  "feedback": "This answer is wrong — 58 J is the light and sound together. The thermal share is the remainder: 340 − 58 = 282 J."
 },
 {
  "value": 398,
  "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 340 minus the 58 J of light and sound",
  "feedback": "This answer is wrong — adding makes more energy leave than entered. Conservation demands 340 in = 340 out, so thermal = 340 − 48 − 10 = 282 J."
 },
 {
  "value": 292,
  "misconception": "you subtracted only the light — the 10 J of sound must be accounted for too",
  "feedback": "This answer is wrong — 340 − 48 leaves the sound unaccounted. Subtract both named outputs: 340 − 48 − 10 = 282 J."
 }
]
feedback
{
 "keyExplanation": "Energy cannot be created or destroyed, so all 340 J must leave in some form. Light and sound account for 48 J + 10 J = 58 J. The rest becomes thermal energy: 340 J − 58 J = 282 J.",
 "anticipatedWrong": [
  {
   "value": 340,
   "misconception": "you gave the total converted energy instead of the thermal share — subtract the light and sound from the 340 J",
   "feedback": "This answer is wrong — 340 J is everything the television converted. The thermal share is what remains after light and sound: 340 − 48 − 10 = 282 J."
  },
  {
   "value": 58,
   "misconception": "you gave the light plus sound instead of what remains — 48 + 10 = 58 J is the part already accounted for",
   "feedback": "This answer is wrong — 58 J is the light and sound together. The thermal share is the remainder: 340 − 58 = 282 J."
  },
  {
   "value": 398,
   "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 340 minus the 58 J of light and sound",
   "feedback": "This answer is wrong — adding makes more energy leave than entered. Conservation demands 340 in = 340 out, so thermal = 340 − 48 − 10 = 282 J."
  },
  {
   "value": 292,
   "misconception": "you subtracted only the light — the 10 J of sound must be accounted for too",
   "feedback": "This answer is wrong — 340 − 48 leaves the sound unaccounted. Subtract both named outputs: 340 − 48 − 10 = 282 J."
  }
 ]
}
THM-013 · medium · application · seq 16 · seed:U12-G1.pool[36] (THM-013 gateItems, James) - VERBATIM (field mapping only) | sol-1: key direction claim removed (initial strip temperature is unstated) · mcq4
A student taps a forehead thermometer strip onto a patient and reads it instantly, saying, 'Contact is all it takes.' Why is the instant reading unreliable?
The strip has not yet reached thermal equilibrium with the patient — until then it reports its own temperature, not the patient's. KEY
It is reliable — a contact thermometer reads the true temperature of whatever it touches at the very moment contact is made.
It is unreliable because thermometers only work on liquids.
It is unreliable because skin has no temperature to measure.
THM-014 · hard · transfer · seq 17 · seed:U12-G1.pool[39] (THM-014 gateItems, James) - FRESHENED (SEED RULING: 60/20 sit in scope spec text -> 64/19; gap-widening counterfactual, key qualifier, and misconception classes verbatim) · mcq4
One end of a metal bar sits at 64 °C and the other at 19 °C, with the bar left alone. Could the 19 °C end spontaneously grow colder while the 64 °C end grows hotter?
No — that would need heat to flow from the colder end to the hotter end by itself, and heat never does. KEY
Yes — energy is free to flow either way along a bar, so the temperature gap can widen on its own.
Yes, briefly — heat flows cold-to-hot at first and settles down later.
No — because no heat flows inside a single solid object.
THM-016 · hard · transfer · seq 18 · seed:U12-G1.pool[45] == demo_curated[0] (THM-016 gateItems, James; dual ref) - VERBATIM (field mapping only) · mcq4
A university lab celebrates cooling a rubidium gas to 0.0000002 K — adding that 0 K itself remains out of reach. Which law sets that limit?
The third law of thermodynamics KEY
The second law of thermodynamics
The zeroth law of thermodynamics
The first law of thermodynamics
THM-016 · hard · transfer · seq 19 · seed:U12-G1.pool[46] == demo_curated[1] (THM-016 gateItems, James; dual ref) - FRESHENED (must_freshen_instance: the 40 °C reading collides with the 40 spec value -> 55 °C; 'two metal blocks' kept per stage-1 — freshen to copper cylinders only if the corpus gram scan fails; zeroth-law hinge verbatim) · mcq4
Two metal blocks sit inside an insulated box. A thermometer touching the first block reads 55 °C, and the same thermometer touching the second block also reads 55 °C. Which law guarantees the two blocks are in thermal equilibrium with each other?
The zeroth law of thermodynamics KEY
The second law of thermodynamics
The first law of thermodynamics
The third law of thermodynamics
THM-014 · hard · transfer · seq 20 · seed:U12-G1.pool[41] (THM-014 gateItems, James) - FRESHENED (must_freshen_instance: 'cooled drink' echoes THM-014's rule-line hot-drink instance -> cooled plate of food; 'room's air' -> 'the room' (air = THM-014 own-lesson material); argument structure, both-tests key, and misconceptions verbatim) | stage-3 wave-1: V-T7: 'happen on its own' = THM-014 spec gram | blind-1 class sweep (r1 advisory, same class as the B#19 hard fail): plate pinned AT room temperature before the claimed re-warming above it · mcq4
A student argues, 'My plate of food has already cooled until it matches the room. It could pull its heat back and re-warm itself above the room's temperature — that wouldn't destroy or create any energy, so it should be possible.' Which reply is correct?
Conserving energy is not the only test — the second law adds that heat on its own flows only from hotter to colder, so the re-warming never happens by itself. KEY
The student is right — any change that keeps the total amount of energy in the universe exactly constant is able to go ahead by itself.
The student is wrong because the re-warming would secretly destroy energy.
The student is wrong because the room holds no energy to give.
THM-016 · medium · application · seq 21 · authored:U12-G1 stage 2 (fresh conceptual FRQ; blueprint candidate set: music box / materials-lab floor / dish+rack paired with butter; all instances outside the placed-seq ledger and the THM-016 barred roster) · frq
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about.
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about. (a) A wind-up music box plays until its spring runs down. A careful audit finds the sound made, the motion of the gears, and the slight warming of the mechanism together account for exactly the energy the wound spring stored. Name the law this illustrates and justify your answer. (b) A materials lab keeps nudging a test sample closer and closer to absolute zero, and its reports always state that the floor itself can never be reached. Name the law this illustrates and justify your answer. (c) Two halves of one evening in a kitchen: (i) an oven-safe dish and the wire rack it sits on settle overnight until a probe shows one shared temperature for both; (ii) a stick of butter left beside a warm dish softens as warmth moves one way into it, never back out. Assign each half its law, and state the deciding aspect for each.
Part a. A wind-up music box plays until its spring runs down. A careful audit finds the sound made, the motion of the gears, and the slight warming of the mechanism together account for exactly the energy the wound spring stored. Name the law this illustrates and justify your answer.
Model: The first law of thermodynamics. The observation is an energy accounting: the sound, the motion, and the warming add up to exactly the energy the spring stored, so energy was transformed but the total never changed — energy is conserved, never created or destroyed.
Part b. A materials lab keeps nudging a test sample closer and closer to absolute zero, and its reports always state that the floor itself can never be reached. Name the law this illustrates and justify your answer.
Model: The third law of thermodynamics. The observation is about the lowest possible temperature: the lab can get ever closer to absolute zero, but the floor itself can never be reached by a real sample.
Part c. Two halves of one evening in a kitchen: (i) an oven-safe dish and the wire rack it sits on settle overnight until a probe shows one shared temperature for both; (ii) a stick of butter left beside a warm dish softens as warmth moves one way into it, never back out. Assign each half its law, and state the deciding aspect for each.
Model: Half (i) is the zeroth law of thermodynamics: the dish and the rack end up at one shared temperature, which means they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the warmth flows one way, from the warm dish into the cooler butter, and never flows back out by itself — the deciding aspect is the one-way DIRECTION of the flow.
Full model answer. (a) The first law of thermodynamics. The observation is an energy accounting: the sound, the motion, and the warming add up to exactly the energy the spring stored, so energy was transformed but the total never changed — energy is conserved, never created or destroyed. (b) The third law of thermodynamics. The observation is about the lowest possible temperature: the lab can get ever closer to absolute zero, but the floor itself can never be reached by a real sample. (c) Half (i) is the zeroth law of thermodynamics: the dish and the rack end up at one shared temperature, which means they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the warmth flows one way, from the warm dish into the cooler butter, and never flows back out by itself — the deciding aspect is the one-way DIRECTION of the flow.

Form B

THM-002 · easy · recall · seq 1 · seed:U12-G1.pool[4] (THM-002 gateItems, James) - FRESHENED (must_freshen_instance: 'mug of tea' = THM-011 rule-line open-system instance -> cider; SEED RULING: 90 = THM-002 spec value, 30 = THM-003 spec value -> 91/33; cooling read + all misconception classes kept) | stage-3 wave-1: V-T7: 'what happened to the' = THM-012 spec gram | sol-1: evaporation distractor (defensibly true) replaced with the particles-shrink misconception · mcq4
A mug of cider cools from 91 °C to 33 °C. How have the cider's particles changed?
Their average kinetic energy decreased — they now move slower on average. KEY
Their average kinetic energy increased as the cider settled.
The particles stopped moving once the cider stopped steaming.
Their particles shrank as the cider cooled, so each one now carries less energy.
THM-004 · easy · recall · seq 2 · authored:U12-G1 stage 2 (fresh two-object direction read; cold-flows-in + wrong-direction + same-substance classes rotated) | stage-3 wave-1: V-T7: 'you wrap your warm' = THM-004 spec gram · mcq4
Your warm hands close around a chilled brass doorknob. Which statement describes the energy flow?
Energy flows from your warmer hands into the colder doorknob, because of the temperature difference. KEY
Coldness flows from the doorknob into your hands, chilling them.
Energy flows from the doorknob into your hands, because metals release their energy on contact.
No energy flows, because skin and metal are too different for a transfer.
THM-008 · easy · recall · seq 3 · authored:U12-G1 stage 2 (fresh vacuum read; particle-bridge + convection-in-vacuum + no-transfer classes) · mcq4
Inside a lab's sealed vacuum chamber, a glowing filament warms a sensor mounted a hand's width away, with no matter at all in the gap. How does the energy reach the sensor?
It crosses the gap as electromagnetic waves, which need no matter to travel. KEY
Leftover particles in the chamber pass the energy along, collision by collision.
A warm draft circulates from the filament to the sensor.
The energy cannot reach the sensor, so the warming must come from the sensor's own wiring.
THM-015 · easy · recall · seq 4 · seed:U12-G1.pool[44] (THM-015 gateItems, James) - FRESHENED (SEED RULING: taught constants −273/−373 removed from scanned fields -> 'absolute zero' wording; 'water'-exempt distractor -> 'solids'-exempt (water = THM-015 own-lesson material); floor-touched class verbatim; third distractor re-keyed floor-as-difficulty) · mcq4
A student says: 'With a strong enough freezer, we could cool helium below absolute zero.' Which correction fixes the claim?
No object can be cooled below absolute zero — real objects cannot even reach it. KEY
The claim is right — the absolute-zero floor applies only to solids, and helium's gas particles are exempt.
Helium can be cooled to exactly absolute zero, but no lower.
The claim is only too hasty — passing absolute zero just takes far longer than a freezer can manage.
THM-001 · medium · application · seq 5 · seed:U12-G1.pool[2] (THM-001 gateItems, James) - VERBATIM (field mapping only; device-boundary read) · mcq4
A bicycle dynamo presses against the spinning wheel and powers the bike's lamp. Which energy transformation happens inside the dynamo itself?
Kinetic energy → electrical energy KEY
Electrical energy → kinetic energy
Kinetic energy → light energy
Chemical energy → electrical energy
THM-003 · medium · application · seq 6 · authored:U12-G1 stage 2 (fresh amount-comparison at fixed temperature; totals-follow-temperature + concentration classes) · mcq4
A bakery keeps a large vat of custard and a single ramekin of the same custard, both at 43 °C. Which statement is correct?
Both are at the same temperature, but the vat holds far more thermal energy. KEY
The vat is hotter, because holding more custard means a higher temperature.
They hold the same thermal energy, because their temperatures match.
The ramekin holds more thermal energy, because small portions concentrate their energy.
THM-005 · medium · application · seq 7 · authored:U12-G1 stage 2 (fresh quoted statement, R1 strict: no category words in the quote; key rotated to Temperature; A-U12G1-NOTA fourth-option class) · mcq4
'This pan of lasagna is at 76 °C.' Which quantity does this statement describe?
Temperature KEY
Thermal energy
Heat
An energy transformation
THM-006 · medium · application · seq 8 · seed:U12-G1.pool[16] (THM-006 gateItems, James) - FRESHENED (SEED RULING: 'curling iron' carries the token 'iron' = THM-006 own-lesson taught material -> curling wand, same device; 'hot air rising' distractor -> 'hot gas rising'; claim-fix structure and misconceptions verbatim) | blind-1 style: no-correction distractor lengthened (longest-option cue, r1+r2) · mcq4
A student explains a warming curling wand this way: 'The hot particles at the plugged-in end walk along the barrel until they reach the tip.' Which correction fixes the explanation?
The particles stay roughly in place — energy travels along the barrel as faster particles collide with slower neighbors and pass it on. KEY
No correction is needed — in a heated solid, the hot particles really do walk the whole length of the metal until they reach the cooler end.
The particles do travel, but only halfway, and the energy jumps the rest of the distance.
The explanation fails only because the tip warms by hot gas rising inside the barrel.
THM-007 · medium · application · seq 9 · seed:U12-G1.pool[19] (THM-007 gateItems, James) - FRESHENED (must_freshen_instance: 'aquarium' dropped — lives in THM-003 AND THM-013 fluency; SEED RULING: 'water' = THM-007 own-lesson taught material -> 'the liquid'; low-mounting structure, key logic, and misconception classes verbatim) | stage-3 wave-1: V-T4 rebalance | blind-1 style: position-does-not-matter distractor lengthened (longest-option cue, r1+r2) | sol-1: D1 feedback re-aimed at the option's actual error · mcq4
A submerged heater sits near the bottom of a fish tank, yet the whole tank ends up warm. Why is mounting the heater LOW effective?
The liquid the heater warms becomes less dense and rises, while cooler, denser liquid sinks down to the heater — the loop stirs energy through the whole tank. KEY
Low mounting works because the tank's liquid passes energy particle to particle faster near the glass bottom than anywhere else.
Low mounting works because the warmed liquid sinks, spreading along the bottom first.
The position makes no difference at all, because heat naturally spreads itself evenly in every direction through a still tankful, top-mounted or bottom-mounted alike.
THM-009 · medium · application · seq 10 · seed:U12-G1.pool[26] (THM-009 gateItems, James) - FRESHENED (A-U12G1-NOTA fourth-option swap; AIR family slot A-U12G1-AIR — the R1 physical-clue scene names the moving gas; stem/key otherwise verbatim) · mcq4
In a tall stairwell, air warmed by ground-floor offices keeps drifting upward while cooler air slides down the opposite side, slowly warming the top landing. Classify the transfer warming the top landing.
Convection KEY
Radiation
Conduction
Thermal equilibrium
THM-009 · medium · application · seq 11 · authored:U12-G1 stage 2 (fresh contact scene, instances disjoint from seq 10; A-U12G1-NOTA fourth-option class) | sol-1 class sweep: 'stays thermal as it moves' boundary wording fixed · mcq4
At a print shop, a stack of hot photocopies fresh off the machine slowly warms the desktop underneath, exactly where the stack rests. Classify the transfer warming the desktop.
Conduction KEY
Radiation
Convection
An energy transformation
THM-010 · medium · application · seq 12 · seed:U12-G1.pool[28] (THM-010 gateItems, James) - VERBATIM (field mapping only; AIR family slot A-U12G1-AIR — the register's surroundings list names the air) | sol-1: examples-list framing + system-mixed distractor (never-touches list was defensible) · mcq4
A match head bursts into flame when struck. If you are studying the match head's reaction, which list contains only examples of the surroundings?
The matchstick, the surrounding air, and the fingers holding the match KEY
The reacting chemicals packed inside the match head itself
Only the flame itself
The reacting chemicals together with the matchstick that carries them
THM-011 · medium · application · seq 13 · seed:U12-G1.pool[31] (THM-011 gateItems, James) - FRESHENED (replace_distractor per stage-1 flag: NOTA -> misconception-keyed process-completion class; 'water molecules' -> 'its molecules' (water = THM-011 own-lesson material); stem/key otherwise verbatim) | sol-1: permanence distractor replaced with the needs-a-container misconception · mcq4
A puddle of rainwater lies on a warm sidewalk, shrinking through the afternoon. Classify the puddle.
An open system KEY
A closed system
An isolated system
It cannot be a system, because it is not sealed inside any container.
THM-012 · medium · application · seq 14 · seed:U12-G1.pool[34] (THM-012 gateItems, James) - VERBATIM (field mapping only; D8 isolated-total consequence) · mcq4
A sealed, perfectly insulating chest holds warm bread and cold juice. Treating the chest as an isolated system, what happens to the total energy inside as the contents trade energy?
The total stays constant — energy moves from the bread to the juice, but none enters or leaves the chest. KEY
The total falls as the bread cools, because cooling always removes energy from the system.
The total rises as the juice warms, because warming always adds energy to the system.
The total slowly drains away, because trading energy wears it down.
THM-012 · medium · application · seq 15 · authored:U12-G1 stage 2 (fresh exact whole-number split; two named outputs + thermal remainder; four misconception classes carried) · numeric
A projector converts 320 J of electrical energy. It gives off 36 J as light and 23 J as sound. How much energy, in joules, becomes thermal energy? (Energy is conserved — every joule must be accounted for.) Give your answer as a whole number of joules.
Answer: 261 J KEY
also accepted: 261 J, 261.0
wrongValueDiagnostics
[
 {
  "value": 320,
  "misconception": "you gave the total converted energy instead of the thermal share — subtract the light and sound from the 320 J",
  "feedback": "This answer is wrong — 320 J is everything the projector converted. Thermal = 320 − 36 − 23 = 261 J."
 },
 {
  "value": 59,
  "misconception": "you gave the light plus sound instead of what remains — 36 + 23 = 59 J is the part already accounted for",
  "feedback": "This answer is wrong — 59 J is the light and sound together. Thermal is the remainder: 320 − 59 = 261 J."
 },
 {
  "value": 379,
  "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 320 minus the 59 J of light and sound",
  "feedback": "This answer is wrong — adding makes more leave than entered. 320 in = 320 out, so thermal = 261 J."
 },
 {
  "value": 284,
  "misconception": "you subtracted only the light — the 23 J of sound must be accounted for too",
  "feedback": "This answer is wrong — 320 − 36 leaves the sound unaccounted. Subtract both: 320 − 36 − 23 = 261 J."
 }
]
feedback
{
 "keyExplanation": "Energy cannot be created or destroyed, so all 320 J must leave in some form. Light and sound account for 36 J + 23 J = 59 J. The rest becomes thermal energy: 320 J − 59 J = 261 J.",
 "anticipatedWrong": [
  {
   "value": 320,
   "misconception": "you gave the total converted energy instead of the thermal share — subtract the light and sound from the 320 J",
   "feedback": "This answer is wrong — 320 J is everything the projector converted. Thermal = 320 − 36 − 23 = 261 J."
  },
  {
   "value": 59,
   "misconception": "you gave the light plus sound instead of what remains — 36 + 23 = 59 J is the part already accounted for",
   "feedback": "This answer is wrong — 59 J is the light and sound together. Thermal is the remainder: 320 − 59 = 261 J."
  },
  {
   "value": 379,
   "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 320 minus the 59 J of light and sound",
   "feedback": "This answer is wrong — adding makes more leave than entered. 320 in = 320 out, so thermal = 261 J."
  },
  {
   "value": 284,
   "misconception": "you subtracted only the light — the 23 J of sound must be accounted for too",
   "feedback": "This answer is wrong — 320 − 36 leaves the sound unaccounted. Subtract both: 320 − 36 − 23 = 261 J."
  }
 ]
}
THM-013 · medium · application · seq 16 · seed:U12-G1.pool[37] (THM-013 gateItems, James) - VERBATIM (field mapping only; THM-003 distinction sanctioned by THM-013 specNotes) | blind-1 style: spoon-holds-more distractor lengthened (longest-option cue, r1+r2) · mcq4
A teaspoon left in a tub of refrigerated pudding overnight ends up at the refrigerator's temperature, 4 °C, the same as the pudding. Does the spoon also have the same thermal energy as the pudding?
No — equilibrium matches the temperatures, but the tub of pudding contains far more matter, so its total thermal energy is larger. KEY
Yes — objects at the same temperature always hold the same thermal energy.
No — the spoon actually holds more thermal energy, because metal objects store their energy far better than soft foods like pudding ever could.
Yes — sitting together overnight equalizes everything about the two objects.
THM-014 · hard · transfer · seq 17 · authored:U12-G1 stage 2 (fresh never-reverses counterfactual; size-sets-direction + temporary-reversal + no-flow classes; 'on its own/by itself' load-bearing) | stage-3 wave-1: V-T4 rebalance | blind-1 style: sheds-warmth distractor lengthened (longest-option cue, r1+r2) · mcq4
A chilled pat of margarine sits on a room-temperature saucer. Could the margarine grow even colder by itself while the saucer beneath it grows warmer?
No — that would need heat to flow from the colder margarine into the warmer saucer on its own, and heat never flows that way by itself. KEY
Yes — small objects always shed their warmth into whatever they rest on, however warm the resting surface underneath already happens to be.
Yes, for a moment — flows overshoot before finding the right direction.
No — because heat cannot pass between a food and a dish at all.
THM-016 · hard · transfer · seq 18 · seed:U12-G1.pool[47] == demo_curated[2] (THM-016 gateItems, James; dual ref) - VERBATIM (field mapping only; the seed's 'air' is inside the museum scene, third distractor's '−273 °C' reference reworded to 'the floor'; AIR family slot A-U12G1-AIR) · mcq4
A museum pendulum swings lower and lower until it hangs still. Careful measurement shows the surrounding air and the pivot warmed by exactly the energy the swinging lost. Which law does the measurement illustrate?
The first law of thermodynamics KEY
The second law of thermodynamics
The zeroth law of thermodynamics
The third law of thermodynamics
THM-016 · hard · transfer · seq 19 · authored:U12-G1 stage 2 (fresh one-way-direction observation; single-hinge discipline per the capstone trap rules) | blind-1 HARD fix (r1 F2): drift-toward-temperature framing read as approaching equilibrium (zeroth) -> stem now states the one-way flow explicitly, 'drift' wording swept from all fields · mcq4
A warm clay teapot left in a cool cupboard: warmth flows steadily out of the teapot into the cooler shelf beneath it, and none ever flows from the cool shelf back into the warm teapot by itself. Which law is on display?
The second law of thermodynamics KEY
The zeroth law of thermodynamics
The first law of thermodynamics
The third law of thermodynamics
THM-014 · hard · transfer · seq 20 · authored:U12-G1 stage 2 (fresh energy-conserving-but-forbidden claim; both-tests key; conservation-only + wrong-objection + energy-retired classes) | stage-3 wave-1: V-T4 rebalance · mcq4
A student claims, 'The warmth my cooling waffle spread into the kitchen could gather itself back into the waffle — the total energy would stay exactly the same, so nothing forbids it.' Which reply is correct?
The total would indeed stay the same, but conservation is not the only test — the second law forbids heat from gathering back into the warmer object on its own. KEY
The claim is right — as long as the total is unchanged, spread-out warmth can re-collect whenever conditions line up, back into the object the warmth originally left.
The claim fails because re-collecting the warmth would create energy from nowhere.
The claim fails because the spread warmth stopped being energy once it left the waffle.
THM-016 · medium · application · seq 21 · authored:U12-G1 stage 2 (fresh conceptual FRQ; instances disjoint from form A and all placed seqs) | stage-3 wave-1: V-T7: 'careful measurement finds the' = THM-016 spec gram (also cross-form vs E#18) · frq
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about.
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about. (a) A skateboard coasting on level pavement slows to a stop. Measurements find the wheels, the bearings, and the pavement warmed by exactly the amount of motion energy the skateboard gave up. Name the law this illustrates and justify your answer. (b) A gas-liquefaction plant's coldest stage keeps shaving smaller and smaller fractions of a degree off its record low, and its engineers note the ultimate floor stays out of reach. Name the law this illustrates and justify your answer. (c) Two halves of one scene in a bakery pantry: (i) a wire whisk left in a proofing cupboard ends up showing the very same reading as the cupboard's shelf when a probe settles on each; (ii) a warm quiche carried into that cupboard passes its warmth one way into the cooler cupboard, never drawing any back. Assign each half its law, and state the deciding aspect for each.
Part a. A skateboard coasting on level pavement slows to a stop. Measurements find the wheels, the bearings, and the pavement warmed by exactly the amount of motion energy the skateboard gave up. Name the law this illustrates and justify your answer.
Model: The first law of thermodynamics. The measurement is an energy accounting: the warmth in the wheels, bearings, and pavement equals exactly the motion energy lost, so the energy changed form while the total stayed the same — conservation of energy.
Part b. A gas-liquefaction plant's coldest stage keeps shaving smaller and smaller fractions of a degree off its record low, and its engineers note the ultimate floor stays out of reach. Name the law this illustrates and justify your answer.
Model: The third law of thermodynamics. The observation is about the lowest possible temperature: the plant can approach absolute zero ever more closely, but no real process reaches the floor itself.
Part c. Two halves of one scene in a bakery pantry: (i) a wire whisk left in a proofing cupboard ends up showing the very same reading as the cupboard's shelf when a probe settles on each; (ii) a warm quiche carried into that cupboard passes its warmth one way into the cooler cupboard, never drawing any back. Assign each half its law, and state the deciding aspect for each.
Model: Half (i) is the zeroth law of thermodynamics: the whisk and the shelf show one shared reading, so they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the quiche's warmth flows one way into the cooler cupboard and never returns by itself — the deciding aspect is the one-way DIRECTION of the flow.
Full model answer. (a) The first law of thermodynamics. The measurement is an energy accounting: the warmth in the wheels, bearings, and pavement equals exactly the motion energy lost, so the energy changed form while the total stayed the same — conservation of energy. (b) The third law of thermodynamics. The observation is about the lowest possible temperature: the plant can approach absolute zero ever more closely, but no real process reaches the floor itself. (c) Half (i) is the zeroth law of thermodynamics: the whisk and the shelf show one shared reading, so they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the quiche's warmth flows one way into the cooler cupboard and never returns by itself — the deciding aspect is the one-way DIRECTION of the flow.

Form C

THM-002 · easy · recall · seq 1 · authored:U12-G1 stage 2 (fresh two-sample equal-reading read; p3 class at a fresh instance) · mcq4
A sample cup of applesauce and a full jar of the same applesauce both read 46 °C. Which statement about their particles is correct?
The particles in both have the same average kinetic energy. KEY
The jar's particles have a higher average kinetic energy because the jar holds far more applesauce.
The sample cup's particles must move faster, because small portions change temperature quickly.
Only the jar's particles have an average kinetic energy, because an average needs many particles.
THM-004 · easy · recall · seq 2 · authored:U12-G1 stage 2 (fresh direction read; heat-as-content + size-picks-direction classes) · mcq4
A hot pastry is set on a cold marble slab. Which statement describes the energy flow?
Energy flows from the hotter pastry into the colder slab, because of the temperature difference. KEY
Coldness flows up from the slab into the pastry, cooling it.
Energy flows from the slab into the pastry, because heavy objects push their energy outward.
The pastry keeps all its energy, because energy stays inside whatever object stores it.
THM-008 · easy · recall · seq 3 · authored:U12-G1 stage 2 (fresh gap-crossing read; cool-middle cue; relay + sideways-current classes) | sol-1: immediacy cue added; chimney feedback overclaim fixed | sol-2: self-warming distractor replaced (floor-contact misconception); current feedback re-aimed at the taught matter-vs-waves distinction · mcq4
Sitting across the room from a fireplace, you feel warmth on your face the moment the fire flares, while the space between you and the fire stays comfortably cool. How is the energy reaching your face?
As electromagnetic waves that cross the room without needing to warm what lies between. KEY
By a chain of particle collisions relayed across the room to your skin.
By a warm current flowing straight from the fire to your face.
The energy comes up through the floor by touch, from floorboards the fire has warmed.
THM-015 · easy · recall · seq 4 · authored:U12-G1 stage 2 (fresh permutational impossible-temperature set; p43 class at fresh values) | stage-3 wave-1: V-T7: duplicate stem vs A#4 seed | sol-1: near-zero feedback no longer implies only 0 K is impossible · mcq4
Which one of these temperatures could no object ever have?
−290 °C KEY
−265 °C
6 K
310 K
THM-001 · medium · application · seq 5 · authored:U12-G1 stage 2 (fresh device from the six-form roster; reversed + fuel-assumed + waste-named classes) | sol-1: true-but-excluded warming distractor replaced with the glowing-means-hot misconception | sol-2: stays-cool feedback overclaim removed · mcq4
A plug-in LED desk lamp lights a study table. Ignoring the small amount of warming, which energy transformation happens in the lamp?
Electrical energy → light energy KEY
Light energy → electrical energy
Chemical energy → light energy
Thermal energy → light energy
THM-003 · medium · application · seq 6 · authored:U12-G1 stage 2 (fresh claim-fix comparison; merged-quantities + transfer-required classes) | stage-3 wave-1: V-T7: 'a student claims the' cross-form vs B#20 | stage-3 wave-1: V-T4 rebalance · mcq4
A cafeteria urn of porridge and one serving bowl filled from it both sit at 58 °C. A student says the bowl and the urn 'hold the same amount of heat energy.' Which correction is right?
The urn holds far more thermal energy — equal temperatures mean equal averages, but the urn's total is bigger because it holds more porridge. KEY
No correction is needed — equal temperatures always mean equal energy totals, whatever the amounts of porridge involved.
The bowl holds more thermal energy, because a serving is where the energy ends up.
Neither holds any thermal energy, because nothing is being transferred.
THM-005 · medium · application · seq 7 · authored:U12-G1 stage 2 (fresh quoted statement using the taught total-over-all-particles wording; key rotated to Thermal energy) · mcq4
'The total kinetic energy of all the particles in this wheelbarrow of fresh mortar is enormous.' Which quantity does this statement describe?
Thermal energy KEY
Temperature
Heat
An energy transformation
THM-006 · medium · application · seq 8 · seed:U12-G1.pool[17] (THM-006 gateItems, James) - VERBATIM (field mapping only; asks ONLY the particle story per specNotes — no conductor-ranking explanation; 'glove of skin' typo in third distractor smoothed to 'your skin') · mcq4
A cold metal railing feels colder than a cold wooden bench at the same winter temperature. A classmate asks what happens, particle by particle, when your hand grips the railing. Which account is correct?
Your skin's faster-moving particles collide with the railing's slower-moving particles, so energy drains from your hand into the metal. KEY
The railing's slower-moving particles collide with your skin's particles and push their coldness up into your hand.
Cold particles from the railing seep into your skin, chilling it.
No transfer happens at the contact, because your skin keeps energy sealed in.
THM-007 · medium · application · seq 9 · authored:U12-G1 stage 2 (fresh liquid loop account; still-fluid + flipped-density + heat-floats classes) | stage-3 wave-1: V-T4 rebalance | sol-1: heat-has-none feedback overclaim fixed | sol-2: absolute qualifiers removed; wrongness now rests on the stillness claim itself · mcq4
A restaurant fryer heats from a coil near the bottom of its oil vat, and soon the whole vat is evenly hot. Which account is correct?
Oil warmed at the coil becomes less dense and rises, while cooler, denser oil sinks toward the coil — the circulating oil carries energy through the vat. KEY
The oil stays still the whole time, while the energy hops particle to particle from the coil out to the farthest corners of the vat.
The warmed oil sinks to the bottom and pushes the cool oil up and away from the coil.
Heat naturally floats upward through the oil, so the oil itself never needs to move.
THM-009 · medium · application · seq 10 · authored:U12-G1 stage 2 (fresh gap-crossing scene, R1 physical clues only; touch-routed + no-flow + state-vs-route classes) | sol-1: task pinned to the sunlight's route; convection feedback fixed · mcq4
In a parked car on a sunny day, the dashboard grows hot beneath the closed windshield wherever the sunlight strikes it, while shaded parts of the cabin stay cooler. Classify the transfer by which the sunlight heats the dashboard.
Radiation KEY
Conduction
Convection
Thermal equilibrium
THM-009 · medium · application · seq 11 · authored:U12-G1 stage 2 (fresh contact scene; C's 10/11 pair covers Radiation + Conduction) | sol-1 class sweep: 'stays thermal as it moves' boundary wording fixed · mcq4
A pre-warmed flagstone, wrapped in a quilt at the foot of a bed, warms the cloth exactly where the cloth touches the stone. Classify the transfer warming the quilt.
Conduction KEY
Convection
Radiation
An energy transformation
THM-010 · medium · application · seq 12 · seed:U12-G1.pool[29] (THM-010 gateItems, James) - FRESHENED (must_freshen_instance: 'beaker' = THM-010 article register instance -> jar; claim structure and misconceptions verbatim) · mcq4
A student says, 'The jar must be part of the system, because it touches the reacting chemicals.' Which correction fixes the claim?
Touching does not decide it — the system is the part chosen for study, and when you study the reaction, the jar belongs to the surroundings. KEY
No correction is needed — anything in direct physical contact with the reacting chemicals automatically becomes part of the system.
The jar is part of neither the system nor the surroundings.
The jar is the whole system, and the chemicals are its surroundings.
THM-011 · medium · application · seq 13 · seed:U12-G1.pool[32] (THM-011 gateItems, James) - FRESHENED (must_freshen_instance: 'picnic cooler' -> 'food carrier' — 'sealed cooler' is THM-012's rule-line instance; too-strong-claim structure, approximate-isolation key, and misconceptions verbatim) | sol-1: categorically absurd distractor replaced with the open/closed label confusion · mcq4
A student calls a sealed foam food carrier 'a perfectly isolated system, because nothing can get in or out.' Why is the claim too strong?
The seal stops matter, but energy still leaks slowly through the foam — the carrier only approximates an isolated system. KEY
The claim is fine — sealing a container is all it takes to isolate it.
The claim is too strong because matter actually seeps through foam easily.
The claim uses the wrong label entirely — a foam carrier that lets energy through is an open system.
THM-012 · medium · application · seq 14 · authored:U12-G1 stage 2 (fresh transformed-not-destroyed claim-fix; vanish + still-stored + destroy-recreate classes) | stage-3 wave-1: V-T4 rebalance · mcq4
A student says, 'When the wind-up kitchen timer finally goes silent, the energy that was stored in its spring has been destroyed.' Which correction fixes the claim?
The spring's energy was transformed — into the sound of the ticking and the ring, and into a little thermal energy in the gears — not destroyed. KEY
No correction is needed — small stored amounts of energy simply get used up and vanish.
The spring's energy is still all in the spring, just compressed down too tightly for the timer's gears to ever wind out and use again.
The energy was destroyed, but ticking recreated a matching amount as it went.
THM-012 · medium · application · seq 15 · authored:U12-G1 stage 2 (fresh exact whole-number split; two named outputs + thermal remainder; four misconception classes carried) · numeric
A blender converts 450 J of electrical energy. It sends 92 J into the motion of the blades and gives off 17 J as sound. How much energy, in joules, becomes thermal energy? (Energy is conserved — every joule must be accounted for.) Give your answer as a whole number of joules.
Answer: 341 J KEY
also accepted: 341 J, 341.0
wrongValueDiagnostics
[
 {
  "value": 450,
  "misconception": "you gave the total converted energy instead of the thermal share — subtract the motion and sound from the 450 J",
  "feedback": "This answer is wrong — 450 J is everything the blender converted. Thermal = 450 − 92 − 17 = 341 J."
 },
 {
  "value": 109,
  "misconception": "you gave the motion plus sound instead of what remains — 92 + 17 = 109 J is the part already accounted for",
  "feedback": "This answer is wrong — 109 J is the motion and sound together. Thermal is the remainder: 450 − 109 = 341 J."
 },
 {
  "value": 559,
  "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 450 minus the 109 J of motion and sound",
  "feedback": "This answer is wrong — adding makes more leave than entered. 450 in = 450 out, so thermal = 341 J."
 },
 {
  "value": 358,
  "misconception": "you subtracted only the motion — the 17 J of sound must be accounted for too",
  "feedback": "This answer is wrong — 450 − 92 leaves the sound unaccounted. Subtract both: 450 − 92 − 17 = 341 J."
 }
]
feedback
{
 "keyExplanation": "Energy cannot be created or destroyed, so all 450 J must leave in some form. Motion and sound account for 92 J + 17 J = 109 J. The rest becomes thermal energy: 450 J − 109 J = 341 J.",
 "anticipatedWrong": [
  {
   "value": 450,
   "misconception": "you gave the total converted energy instead of the thermal share — subtract the motion and sound from the 450 J",
   "feedback": "This answer is wrong — 450 J is everything the blender converted. Thermal = 450 − 92 − 17 = 341 J."
  },
  {
   "value": 109,
   "misconception": "you gave the motion plus sound instead of what remains — 92 + 17 = 109 J is the part already accounted for",
   "feedback": "This answer is wrong — 109 J is the motion and sound together. Thermal is the remainder: 450 − 109 = 341 J."
  },
  {
   "value": 559,
   "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 450 minus the 109 J of motion and sound",
   "feedback": "This answer is wrong — adding makes more leave than entered. 450 in = 450 out, so thermal = 341 J."
  },
  {
   "value": 358,
   "misconception": "you subtracted only the motion — the 17 J of sound must be accounted for too",
   "feedback": "This answer is wrong — 450 − 92 leaves the sound unaccounted. Subtract both: 450 − 92 − 17 = 341 J."
  }
 ]
}
THM-013 · medium · application · seq 16 · authored:U12-G1 stage 2 (fresh wait-for-the-reading case; instant-contact + wrong-object-changes + tool-restriction classes) | sol-1: key no longer says the dial reports something other than its own temperature · mcq4
Moved from a cool drawer into a sink of warm dishwater, a dial thermometer reads low for its first minute. Why should the cook trust only the later reading?
Only after the dial reaches thermal equilibrium with the dishwater does its own temperature — all it ever reports — match the dishwater's. KEY
The first reading is fine — a thermometer shows the temperature of whatever it touches from the first instant of contact.
The low first reading shows the dishwater cooling down, not the thermometer catching up.
Dial thermometers cannot measure liquids, so no reading can be trusted.
THM-014 · hard · transfer · seq 17 · authored:U12-G1 stage 2 (fresh rewarm-itself counterfactual; bigger-total-sets-direction + occasional-reversal + exchange-frozen classes) | stage-3 wave-1: V-T4 rebalance · mcq4
A crock of beans, now at room temperature, sits in a cool cellar. Could the crock spontaneously rewarm itself while the cellar around it grows cooler?
No — the crock could only rewarm if heat flowed from the cooler cellar into the warmer crock, and heat never flows that way on its own. KEY
Yes — the cellar holds far more energy in total than the crock does, so some of that larger store can drift across and warm the crock.
Yes, in small bursts — heat trickles backward now and then before the usual direction returns.
No — because once something reaches room temperature, it can no longer exchange heat.
THM-016 · hard · transfer · seq 18 · authored:U12-G1 stage 2 (fresh third-law observation; lab framing distinct from the rubidium celebration; no digits — 'a thousandth of a degree') · mcq4
An engineering team's cryostat chills a sapphire sliver to within a thousandth of a degree of absolute zero, and the team's notes state that the final step to the floor can never be taken. Which law sets that limit?
The third law of thermodynamics KEY
The first law of thermodynamics
The second law of thermodynamics
The zeroth law of thermodynamics
THM-016 · hard · transfer · seq 19 · authored:U12-G1 stage 2 (fresh zeroth-law thermometer-logic observation; shared-reading hinge, no digits) · mcq4
A vet checks two lambs with the same ear thermometer, letting it settle against each. It shows the same reading on both. Which law says the two lambs are in thermal equilibrium with each other?
The zeroth law of thermodynamics KEY
The first law of thermodynamics
The second law of thermodynamics
The third law of thermodynamics
THM-014 · hard · transfer · seq 20 · authored:U12-G1 stage 2 (fresh boundary argument; conservation-plus-patience + wrong-objection + receiver-restriction classes) | stage-3 wave-1: V-T4 rebalance (key trimmed) | stage-3 wave-1: V-T4 rebalance | blind-1 class sweep: bowl pinned AT room temperature before the claimed re-warming | blind-2 precision: key rephrased for the pinned equal-start temperature (r3 advisory) · mcq4
A student reasons, 'My bowl of oatmeal has cooled right down to room temperature. It could now re-warm itself from the room, since the room's energy total wouldn't change — conservation allows it.' Which reply is correct?
Conservation allows it, but that is not the only test — the second law never lets heat flow by itself into a bowl that is no cooler than the room. KEY
The student is right — whatever conservation allows will eventually happen if you are patient enough to wait for it, oatmeal included.
The student is wrong because re-warming the oatmeal would use up energy and shrink the total.
The student is wrong because a room's thermal energy can only move into colder rooms, never into objects.
THM-016 · medium · application · seq 21 · authored:U12-G1 stage 2 (fresh conceptual FRQ; instances disjoint from forms A/B and all placed seqs) · frq
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about.
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about. (a) A yo-yo spun down to a standstill leaves its string, its axle, and the player's fingertips warmed — by precisely the amount of motion energy the yo-yo lost, according to a careful audit. Name the law this illustrates and justify your answer. (b) A physics-fair exhibit chills a coin-sized wafer to a hair's breadth above the lowest possible temperature, and the placard explains that the last step can never be completed. Name the law this illustrates and justify your answer. (c) Two halves of laundry day: (i) a stack of folded towels and the linen shelf beneath them settle overnight until a probe shows one shared temperature; (ii) a smooth warming stone placed on the stack passes its warmth one way into the towels, never drawing it back. Assign each half its law, and state the deciding aspect for each.
Part a. A yo-yo spun down to a standstill leaves its string, its axle, and the player's fingertips warmed — by precisely the amount of motion energy the yo-yo lost, according to a careful audit. Name the law this illustrates and justify your answer.
Model: The first law of thermodynamics. The audit is an energy accounting: the warmth in the string, axle, and fingertips equals exactly the motion energy the yo-yo lost — the energy changed form but the total never changed, which is conservation of energy.
Part b. A physics-fair exhibit chills a coin-sized wafer to a hair's breadth above the lowest possible temperature, and the placard explains that the last step can never be completed. Name the law this illustrates and justify your answer.
Model: The third law of thermodynamics. The observation hinges on the unreachable floor: a real object can approach absolute zero ever more closely, but the last step to the floor can never be taken.
Part c. Two halves of laundry day: (i) a stack of folded towels and the linen shelf beneath them settle overnight until a probe shows one shared temperature; (ii) a smooth warming stone placed on the stack passes its warmth one way into the towels, never drawing it back. Assign each half its law, and state the deciding aspect for each.
Model: Half (i) is the zeroth law of thermodynamics: the towels and the shelf end at one shared temperature, so they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the stone's warmth flows one way into the cooler towels and never returns by itself — the deciding aspect is the one-way DIRECTION of the flow.
Full model answer. (a) The first law of thermodynamics. The audit is an energy accounting: the warmth in the string, axle, and fingertips equals exactly the motion energy the yo-yo lost — the energy changed form but the total never changed, which is conservation of energy. (b) The third law of thermodynamics. The observation hinges on the unreachable floor: a real object can approach absolute zero ever more closely, but the last step to the floor can never be taken. (c) Half (i) is the zeroth law of thermodynamics: the towels and the shelf end at one shared temperature, so they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the stone's warmth flows one way into the cooler towels and never returns by itself — the deciding aspect is the one-way DIRECTION of the flow.

Form D

THM-002 · easy · recall · seq 1 · authored:U12-G1 stage 2 (p5's every-particle-same-speed claim family reproduced fresh — p5 spared because 40 was a colliding value; fresh reading 52 °C) · mcq4
A student says: 'At 52 °C, every particle in a sample moves at exactly the same speed.' Which correction fixes the claim?
The reading gives an average — individual particles move at many different speeds around that average. KEY
No correction is needed — a single temperature means a single particle speed.
The claim is true for solids only, where the particles are locked together.
Temperature says nothing about particle motion, so no speed claim can be made.
THM-004 · easy · recall · seq 2 · authored:U12-G1 stage 2 (fresh direction-and-why read; cold-as-energy + balanced-flow classes) · mcq4
A freshly baked roll is set on a chilled ceramic platter. In which direction does energy flow, and why?
From the roll into the platter, because energy transfers from the hotter object to the colder one. KEY
From the platter into the roll, because chilled objects release their stored cold as energy.
In both directions equally, so neither object changes temperature.
In no direction, because a platter cannot absorb energy from food.
THM-008 · easy · recall · seq 3 · authored:U12-G1 stage 2 (fresh long-gap read; relay-through-middle + invented-flow + contact-required classes) | stage-3 wave-1: V-T7: 'and the waves deliver' (+1) = THM-008 spec grams | sol-1: immediacy cue added (bit-by-bit heating route excluded) · mcq4
A follow-spot light at the back of a hall warms the presenter's face on stage the instant it switches on, all the way across the audience. Why can the energy arrive from so far away, so quickly?
The beam is made of electromagnetic waves, which hand over their energy where they strike the skin. KEY
The lamp heats the hall bit by bit until the warmth finally reaches the stage.
A steady warm breeze blows from the lamp to the stage.
It cannot arrive from that far — stage lights only warm what they touch.
THM-015 · easy · recall · seq 4 · authored:U12-G1 stage 2 (fresh claim-fix; register wording 'falls to its minimum', never 'stops completely'; reachable-floor + stops-at-freezing classes) | stage-3 wave-1: V-T7: 'the claim is too' cross-form vs C#13 seed · mcq4
A lab-equipment brochure claims its newest chiller 'removes every last bit of particle motion from a sample.' Which correction fixes the claim?
Particle motion falls toward a minimum as absolute zero is approached, but real samples never reach it, so some motion always remains. KEY
No correction is needed — a good enough chiller really can bring particle motion to a complete stop.
The claim fails only because particle motion stops at the ordinary freezing point, long before any special chiller is needed.
The brochure is actually too modest — a strong chiller removes the particles themselves along with their motion.
THM-001 · medium · application · seq 5 · authored:U12-G1 stage 2 (fresh two-step chain mirroring the register's chained example; battery-assumed + reversed + skipped-current classes) | sol-1: battery-free stated; chemical-chain feedback grounded in the stem | sol-1/blind-3 HARD fix (r7 F2): stem now demands the complete chain, so the skipped-intermediate option is cleanly wrong · mcq4
Turning the hand crank of a battery-free emergency radio lights its small built-in lamp. Which chain lists every energy form in order, from the crank's effort to the light?
Kinetic energy → electrical energy → light energy KEY
Chemical energy → electrical energy → light energy
Light energy → electrical energy → kinetic energy
Kinetic energy → light energy
THM-003 · medium · application · seq 6 · authored:U12-G1 stage 2 (fresh one-factor comparison, temperature varying at fixed amount; amount-only + coolness-stores classes) · mcq4
Two identical trays hold equal amounts of damp sand. One tray has warmed to 47 °C in the sun and the other sits at 24 °C in the shade. Which statement is correct?
The 47 °C tray holds more thermal energy, because equal amounts make the warmer sample's total larger. KEY
Both trays hold the same thermal energy, because they hold the same amount of sand.
The 24 °C tray holds more thermal energy, because cooler samples store energy instead of releasing it.
The comparison is impossible without weighing the trays first.
THM-005 · medium · application · seq 7 · authored:U12-G1 stage 2 (fresh quoted transfer statement, R1 strict; key Heat; two-object cue) | sol-1 class sweep: 'stays thermal as it moves' boundary wording fixed · mcq4
'While the dishwasher ran, energy passed from its hot inner wall into the cold plates stacked inside.' Which quantity does this statement describe?
Heat KEY
Temperature
Thermal energy
An energy transformation
THM-006 · medium · application · seq 8 · authored:U12-G1 stage 2 (fresh contact-transfer account; MECH-HEAT-FLOW-HS verbatim in keyExplanation; migration + reversed + waves classes) | stage-3 wave-1: V-T4 rebalance | stage-3 wave-1b: V-T4 margin touch-up · mcq4
A metal cookie sheet, fresh from baking, warms the padded mitt gripping its edge. Which statement describes the energy transfer where the mitt touches the sheet?
The sheet's faster-moving particles collide with the mitt's slower-moving particles, passing energy into the mitt at the contact. KEY
The sheet's hot particles seep out of the metal, travel through the padding, and slowly gather inside the mitt's padding.
The mitt's particles collide with the sheet's and push energy into the metal, cooling the mitt.
The energy crosses to the mitt as waves, with the contact playing no part.
THM-007 · medium · application · seq 9 · authored:U12-G1 stage 2 (fresh gas loop account; AIR family slot A-U12G1-AIR; contact-route + flipped-density + waves-only classes) | stage-3 wave-1: V-T4 rebalance (key trimmed; also drops one seed-echo gram) | stage-3 wave-1: V-T4 rebalance | stage-3 wave-1b: V-T4 margin touch-up | sol-1: warmed AIR pinned (ridge-structure reading removed); too-slow overclaim fixed · mcq4
In a tall greenhouse, the air warms all the way up to the ridge from heating pipes laid along the floor. Which account is correct?
Air warmed at the pipes becomes less dense and rises toward the ridge while cooler, denser air sinks — the circulating air carries the energy up to the ridge. KEY
The energy travels up the glazing bars particle by particle, and that slow contact route through the frame is what finally warms the ridge itself.
Air warmed at the pipes becomes denser and is forced upward by the lighter cold air near the roof.
The ridge warms only by waves beamed straight up from the pipes, with the air standing still.
THM-009 · medium · application · seq 10 · authored:U12-G1 stage 2 (fresh liquid-loop scene, R1 physical clues; relay + waves + state-vs-route classes) · mcq4
In a tall fermentation vat, warmer brew keeps drifting upward through the middle while cooler brew descends along the walls, evening out the vat's temperature. Classify the transfer.
Convection KEY
Conduction
Radiation
Thermal equilibrium
THM-009 · medium · application · seq 11 · authored:U12-G1 stage 2 (fresh gap-crossing scene with the facing-side cue; contact + sideways-flow + transformation classes) | blind-1 HARD fix (r1 F2): 'no fan blows' did not exclude natural convection -> one-sided warming with cool back side is the excluding clue | sol-1: no-passing-stream clue added; convection feedback no longer overclaims | sol-2: convection feedback tied to the stem exclusion (both-faces generalization dropped) · mcq4
At a pizzeria, a baker's peel held near the oven's glowing brick wall warms only on the side facing the bricks — the side facing away stays cool — though the peel touches nothing hot and nothing warm streams past it. Classify the transfer warming the peel.
Radiation KEY
Conduction
Convection
An energy transformation
THM-010 · medium · application · seq 12 · authored:U12-G1 stage 2 (fresh surroundings-receiving read; container-position + reversed-flow + sealed-boundary classes) | stage-3 wave-1: V-T4 rebalance · mcq4
A rust-removal gel reacts on an old hinge sealed inside a plastic zip bag, and the bag's outside soon feels warm. Taking the reacting gel chemicals as the system, which statement is correct?
The bag is part of the surroundings, and its warming shows the surroundings receiving energy from the system. KEY
The bag is part of the system, because the reaction happens inside it.
The warm bag shows the system receiving energy from the surroundings.
Nothing outside the gel can warm up, because energy always stays locked inside a system's boundary.
THM-011 · medium · application · seq 13 · authored:U12-G1 stage 2 (fresh two-check classification with energy leaving; matter-crossing + energy-blocked + reaction-required classes) · mcq4
A factory-sealed jar of pickles sits in a cold pantry and slowly cools overnight. Classify the jar and its contents.
A closed system KEY
An open system
An isolated system
Not a system at all, because nothing inside is reacting
THM-012 · medium · application · seq 14 · authored:U12-G1 stage 2 (fresh D8 isolated-total read; one-item-tracking + outside-source + zero-at-equilibrium classes) | stage-3 wave-1: V-T4 rebalance · mcq4
A sealed, perfectly insulating cabinet holds a jug of warm gravy and a block of cold tofu. Treating the cabinet as an isolated system, what happens to the total energy inside as the contents trade energy?
The total stays constant — energy moves from the gravy to the tofu, while none enters or leaves the cabinet. KEY
The total falls, because the gravy's cooling steadily drains energy out through the cabinet's walls.
The total rises, because the tofu's warming pulls new energy into the cabinet.
The total falls to nothing once the two reach the same temperature.
THM-012 · medium · application · seq 15 · authored:U12-G1 stage 2 (fresh exact whole-number split; two named outputs + thermal remainder; four misconception classes carried) · numeric
A sewing machine converts 280 J of electrical energy. It sends 63 J into the needle's motion and gives off 9 J as sound. How much energy, in joules, becomes thermal energy? (Energy is conserved — every joule must be accounted for.) Give your answer as a whole number of joules.
Answer: 208 J KEY
also accepted: 208 J, 208.0
wrongValueDiagnostics
[
 {
  "value": 280,
  "misconception": "you gave the total converted energy instead of the thermal share — subtract the motion and sound from the 280 J",
  "feedback": "This answer is wrong — 280 J is everything the machine converted. Thermal = 280 − 63 − 9 = 208 J."
 },
 {
  "value": 72,
  "misconception": "you gave the motion plus sound instead of what remains — 63 + 9 = 72 J is the part already accounted for",
  "feedback": "This answer is wrong — 72 J is the motion and sound together. Thermal is the remainder: 280 − 72 = 208 J."
 },
 {
  "value": 352,
  "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 280 minus the 72 J of motion and sound",
  "feedback": "This answer is wrong — adding makes more leave than entered. 280 in = 280 out, so thermal = 208 J."
 },
 {
  "value": 217,
  "misconception": "you subtracted only the motion — the 9 J of sound must be accounted for too",
  "feedback": "This answer is wrong — 280 − 63 leaves the sound unaccounted. Subtract both: 280 − 63 − 9 = 208 J."
 }
]
feedback
{
 "keyExplanation": "Energy cannot be created or destroyed, so all 280 J must leave in some form. Motion and sound account for 63 J + 9 J = 72 J. The rest becomes thermal energy: 280 J − 72 J = 208 J.",
 "anticipatedWrong": [
  {
   "value": 280,
   "misconception": "you gave the total converted energy instead of the thermal share — subtract the motion and sound from the 280 J",
   "feedback": "This answer is wrong — 280 J is everything the machine converted. Thermal = 280 − 63 − 9 = 208 J."
  },
  {
   "value": 72,
   "misconception": "you gave the motion plus sound instead of what remains — 63 + 9 = 72 J is the part already accounted for",
   "feedback": "This answer is wrong — 72 J is the motion and sound together. Thermal is the remainder: 280 − 72 = 208 J."
  },
  {
   "value": 352,
   "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 280 minus the 72 J of motion and sound",
   "feedback": "This answer is wrong — adding makes more leave than entered. 280 in = 280 out, so thermal = 208 J."
  },
  {
   "value": 217,
   "misconception": "you subtracted only the motion — the 9 J of sound must be accounted for too",
   "feedback": "This answer is wrong — 280 − 63 leaves the sound unaccounted. Subtract both: 280 − 63 − 9 = 208 J."
  }
 ]
}
THM-013 · medium · application · seq 16 · authored:U12-G1 stage 2 (fresh shared-final-temperature read; still-flowing + equal-totals + never-flowed classes) · mcq4
By morning, a crate of oranges and the storeroom shelf beneath it show one shared reading on a checking thermometer. What does that shared reading mean?
They are in thermal equilibrium — heat stopped flowing between them once they reached one temperature. KEY
Heat is still flowing strongly between them, which is what keeps the readings matched.
The crate and the shelf now hold equal amounts of thermal energy.
No heat ever flowed between them, since they were destined to match overnight.
THM-014 · hard · transfer · seq 17 · authored:U12-G1 stage 2 (fresh cold-end-colder counterfactual; material-sets-direction + slow-uphill + sealed-joint classes) | stage-3 wave-1: V-T4 rebalance · mcq4
In an unheated hallway, a cold bronze door handle hangs on a slightly warmer door. Could the handle push its remaining warmth into the door and grow colder still, all by itself?
No — that would be heat flowing from the colder handle into the warmer door on its own, and heat never does that. KEY
Yes — metal fittings shed their warmth into anything they are attached to, whichever of the two is warmer.
Yes, slowly — given enough hours, the flow can run uphill in temperature.
No — because a handle and a door never exchange heat where they join.
THM-016 · hard · transfer · seq 18 · authored:U12-G1 stage 2 (fresh first-law accounting observation; energy-audit framing) · mcq4
A flight log for a toy drone accounts for the charge pack's entire lost store: the motion made, the sound given off, and the warmth left in the motors add back up to exactly that store. Which law does the accounting illustrate?
The first law of thermodynamics KEY
The second law of thermodynamics
The zeroth law of thermodynamics
The third law of thermodynamics
THM-016 · hard · transfer · seq 19 · authored:U12-G1 stage 2 (fresh one-way-direction observation; sensor framing keeps the hinge on DIRECTION) · mcq4
A mechanic's warm wrench is left overnight on a cold steel-topped bench. Sensors show heat moving only from the wrench into the bench top, hour after hour, never the reverse. Which law names that one-way rule?
The second law of thermodynamics KEY
The zeroth law of thermodynamics
The first law of thermodynamics
The third law of thermodynamics
THM-014 · hard · transfer · seq 20 · authored:U12-G1 stage 2 (fresh boundary argument; energy-memory + destroyed-on-dispersal + partial-reversal classes) | stage-3 wave-1: V-T4 rebalance | blind-1 class sweep: pot pinned AT kitchen temperature before the claimed return flow | blind-2 precision: key rephrased for the pinned equal-start temperature (r3 advisory) · mcq4
A student insists, 'My pot of polenta has finished cooling and now sits at the kitchen's temperature. The warmth it spread earlier is all still out there, so nothing forbids it flowing back to make the pot warm again.' Which reply is correct?
The energy is indeed still out there, but the second law forbids the return trip — heat never flows by itself into a pot that is no cooler than the kitchen. KEY
The student is right — energy that came out of an object keeps a standing claim on returning to that same object, whenever the kitchen allows it.
The student is wrong because the spread-out energy was destroyed as it dispersed.
The student is wrong only about the amount — a small portion of the warmth does flow back by itself.
THM-016 · medium · application · seq 21 · authored:U12-G1 stage 2 (fresh conceptual FRQ; instances disjoint from forms A-C and all placed seqs) · frq
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about.
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about. (a) An arcade's spiral coin funnel spins a donated coin around and around until it drops through the slot. An energy audit finds the funnel's rim and the coin warmed by just the amount of motion the coin gave up. Name the law this illustrates and justify your answer. (b) A quantum-computing lab holds its processors a whisker above the ultimate cold floor and reports, every year, that the floor itself can only be approached, never touched. Name the law this illustrates and justify your answer. (c) Two halves of a night in a storage room: (i) a bin of potatoes and the cool floor beneath it reach one shared temperature by morning, confirmed by a settling probe; (ii) a warm stack of tortillas set on the shelf cools one way toward the room, never rewarming itself from it. Assign each half its law, and state the deciding aspect for each.
Part a. An arcade's spiral coin funnel spins a donated coin around and around until it drops through the slot. An energy audit finds the funnel's rim and the coin warmed by just the amount of motion the coin gave up. Name the law this illustrates and justify your answer.
Model: The first law of thermodynamics. The audit is an energy accounting: the warmth in the rim and the coin equals just the motion the coin gave up — energy transformed from motion to warmth while the total stayed the same, which is conservation of energy.
Part b. A quantum-computing lab holds its processors a whisker above the ultimate cold floor and reports, every year, that the floor itself can only be approached, never touched. Name the law this illustrates and justify your answer.
Model: The third law of thermodynamics. The report is about the unreachable floor: absolute zero can be approached ever more closely but never touched by a real object.
Part c. Two halves of a night in a storage room: (i) a bin of potatoes and the cool floor beneath it reach one shared temperature by morning, confirmed by a settling probe; (ii) a warm stack of tortillas set on the shelf cools one way toward the room, never rewarming itself from it. Assign each half its law, and state the deciding aspect for each.
Model: Half (i) is the zeroth law of thermodynamics: the bin and the floor reach one shared temperature, so they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the tortillas' warmth flows one way into the cooler room and never returns by itself — the deciding aspect is the one-way DIRECTION of the flow.
Full model answer. (a) The first law of thermodynamics. The audit is an energy accounting: the warmth in the rim and the coin equals just the motion the coin gave up — energy transformed from motion to warmth while the total stayed the same, which is conservation of energy. (b) The third law of thermodynamics. The report is about the unreachable floor: absolute zero can be approached ever more closely but never touched by a real object. (c) Half (i) is the zeroth law of thermodynamics: the bin and the floor reach one shared temperature, so they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the tortillas' warmth flows one way into the cooler room and never returns by itself — the deciding aspect is the one-way DIRECTION of the flow.

Form E

THM-002 · easy · recall · seq 1 · authored:U12-G1 stage 2 (fresh warming read mirroring the cooling class; fresh instance + values) · mcq4
A tray of gelatin warms from 14 °C to 39 °C. What happened to its particles?
Their average kinetic energy increased — they now move faster on average. KEY
Their average kinetic energy stayed the same, because warming only adds particles.
Every particle now moves at exactly the new, higher speed.
The particles began moving — below room temperature they had been still.
THM-004 · easy · recall · seq 2 · authored:U12-G1 stage 2 (fresh direction read; amount-picks-direction + reversed-condition classes) · mcq4
A hot roasted chestnut is dropped into a bowl of cold rice. Which statement describes the energy flow?
Energy flows from the hot chestnut into the colder rice, because of the temperature difference. KEY
Coldness flows from the rice into the chestnut, cooling it down.
Energy flows from the rice into the chestnut, because the rice has far more particles to give energy from.
No energy flows, because the two foods are not at the same temperature yet.
THM-008 · easy · recall · seq 3 · authored:U12-G1 stage 2 (fresh from-the-side read; instant + sideways cues; gas-pours + floor-conduction + cold-escape classes) | blind-1 HARD fix (r1 F2): open port did not exclude sideways hot gas -> sealed glass viewing window + inner shutter; 'port' swept from every field | blind-1 style: gas distractor lengthened to rebalance V-T4 after the key rework · mcq4
A kiln's viewing window is a pane of thick glass that stays sealed shut. Standing a step to the SIDE of the window, a potter feels warmth on the apron the moment the kiln's inner shutter swings open. Which statement explains the warmth?
Electromagnetic waves from the glowing interior pass through the glass, spread outward in all directions, and deliver energy on arrival. KEY
Hot gas escapes around the frame of the viewing window, washes sideways through the workshop, and delivers its warmth to the apron on contact.
The kiln wall conducts the energy through the workshop floor into the potter's shoes.
Opening the shutter lets coldness escape from the workshop into the kiln, which feels like warmth.
THM-015 · easy · recall · seq 4 · authored:U12-G1 stage 2 (fresh approach read; stops-early + past-the-floor + no-link classes) · mcq4
A sample is cooled closer and closer to absolute zero. What happens to its particles' motion?
It falls toward its minimum — but the sample can never actually reach absolute zero. KEY
It stops completely as soon as the sample gets within one degree of absolute zero.
It keeps falling without limit, passing absolute zero into negative motion.
It stays unchanged, because cooling only affects a sample's amount, not its particles.
THM-001 · medium · application · seq 5 · authored:U12-G1 stage 2 (fresh device from the six-form roster; reversed + fuel-assumed + wrong-output classes) | blind-1 advisory: wall-outlet supply stated, battery reading removed · mcq4
An electric buzzer plugged into a wall outlet sounds for as long as its button is held down. Which energy transformation happens in the buzzer?
Electrical energy → sound energy KEY
Sound energy → electrical energy
Chemical energy → sound energy
Electrical energy → light energy
THM-003 · medium · application · seq 6 · authored:U12-G1 stage 2 (fresh both-factors-in-words comparison; amount-raises-average + zero-at-room classes) · mcq4
A restaurant's big tub of hummus and a small dish of the same hummus both sit at 21 °C. The tub holds twenty times as much. Which statement is correct?
The tub holds about twenty times the thermal energy, while the two temperatures are equal. KEY
The tub is at a higher temperature, because twenty times the hummus means twenty times the warmth.
The dish and the tub hold equal thermal energy, because temperature decides the total.
Neither holds thermal energy at room temperature.
THM-005 · medium · application · seq 7 · authored:U12-G1 stage 2 (fresh quoted statement, R1 strict; key Temperature; parallel to B with fresh instance/value) · mcq4
'This jar of tomato sauce is at 49 °C.' Which quantity does this statement describe?
Temperature KEY
Heat
Thermal energy
An energy transformation
THM-006 · medium · application · seq 8 · authored:U12-G1 stage 2 (fresh contact account; MECH-HEAT-FLOW-HS verbatim in keyExplanation; particle-swap + cold-passing + self-heating classes) | stage-3 wave-1: V-T4 rebalance · mcq4
Pinched between two warm fingers, the cold metal zipper pull of a parka quickly stops feeling cold. What happens, particle by particle, at the contact?
The fingers' faster-moving particles collide with the pull's slower-moving particles, so energy passes from the skin into the metal. KEY
The pull's cold particles trade places with the fingers' warm particles until the two particle populations fully match each other.
The pull's particles collide with the skin's and push coldness into the fingers.
Nothing passes between them — the pull warms itself up once it senses the grip.
THM-007 · medium · application · seq 9 · authored:U12-G1 stage 2 (fresh layering account; AIR family slot A-U12G1-AIR; contact-route + heat-floats + flipped-density classes) | stage-3 wave-1: V-T4 rebalance · mcq4
On the top bench of a sauna it feels far hotter than on the floor-level bench, though one heater serves the whole room. Which account explains the difference?
Air warmed at the heater becomes less dense and rises to collect near the ceiling, while cooler, denser air settles low — so the top bench sits in the warmest layer. KEY
The upper bench is closer to the ceiling, which conducts the heater's energy sideways along the boards.
Heat itself is lighter than air, so it floats to the top of the room on its own.
Warmed air becomes denser and drops toward the floor, so the heater must be aimed upward if the ceiling region is ever going to fill with warmth first.
THM-009 · medium · application · seq 10 · authored:U12-G1 stage 2 (fresh contact scene, R1 physical clues; gap + fluid + state-vs-route classes) · mcq4
Each sheet fed through a laminating machine warms exactly where it presses against the hot roller. Classify the transfer warming the sheet.
Conduction KEY
Radiation
Convection
Thermal equilibrium
THM-009 · medium · application · seq 11 · authored:U12-G1 stage 2 (fresh liquid-loop scene; E's 10/11 pair covers Conduction + Convection; relay + waves + transformation classes) | sol-1 class sweep: 'stays thermal as it moves' boundary wording fixed · mcq4
In a dye works, liquid above the vat's bottom heating coils keeps rising in a slow column while cooler dye sinks near the sides, warming the whole vat. Classify the transfer.
Convection KEY
Conduction
Radiation
An energy transformation
THM-010 · medium · application · seq 12 · authored:U12-G1 stage 2 (fresh surroundings-list pick mirroring the seed class; system-named + output-picked + far-away classes) | sol-1: examples-list framing (key need not be exhaustive) + system-mixed distractor · mcq4
Freshly stirred plaster in a mixing pouch sets and grows warm in a molder's hands. If you are studying the plaster's setting reaction, which list contains only examples of the surroundings?
The pouch, the molder's hands, and the workbench beneath them KEY
The reacting plaster mix itself
Only the warmth the reaction gives off
The setting plaster itself along with the pouch that holds it
THM-011 · medium · application · seq 13 · authored:U12-G1 stage 2 (fresh two-check classification with energy entering; matter-out + energy-ignored + no-surroundings classes) · mcq4
A slow-cooker simmers all afternoon with its lid clamped tight: nothing escapes, while the plugged-in base feeds energy in steadily. Classify the cooker and its contents.
A closed system KEY
An open system
An isolated system
A system with no surroundings, since the lid seals everything
THM-012 · medium · application · seq 14 · authored:U12-G1 stage 2 (fresh transformed-not-destroyed read on a motion instance; motion-vanishes + parked-energy + destroy-create classes) | stage-3 wave-1: V-T4 rebalance · mcq4
A student says, 'A spinning office chair that drifts to a stop shows energy simply vanishing.' Which correction fixes the claim?
The motion energy did not vanish — it was transformed into thermal energy in the chair's bearings and a little sound along the way. KEY
No correction is needed — motion energy is the one form of energy that simply disappears whenever the motion it powered comes to an end.
The chair stores the motion energy inside its seat, ready to spin again on its own.
The energy vanished here, but a matching amount appeared somewhere far away to keep the books even.
THM-012 · medium · application · seq 15 · authored:U12-G1 stage 2 (fresh exact whole-number split; two named outputs + thermal remainder; four misconception classes carried) · numeric
An electric scooter converts 540 J of electrical energy from its power pack during a short ride. It sends 210 J into motion and gives off 26 J as light from the headlamp. How much energy, in joules, becomes thermal energy? (Energy is conserved — every joule must be accounted for.) Give your answer as a whole number of joules.
Answer: 304 J KEY
also accepted: 304 J, 304.0
wrongValueDiagnostics
[
 {
  "value": 540,
  "misconception": "you gave the total converted energy instead of the thermal share — subtract the motion and light from the 540 J",
  "feedback": "This answer is wrong — 540 J is everything the scooter converted. Thermal = 540 − 210 − 26 = 304 J."
 },
 {
  "value": 236,
  "misconception": "you gave the motion plus light instead of what remains — 210 + 26 = 236 J is the part already accounted for",
  "feedback": "This answer is wrong — 236 J is the motion and light together. Thermal is the remainder: 540 − 236 = 304 J."
 },
 {
  "value": 776,
  "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 540 minus the 236 J of motion and light",
  "feedback": "This answer is wrong — adding makes more leave than entered. 540 in = 540 out, so thermal = 304 J."
 },
 {
  "value": 330,
  "misconception": "you subtracted only the motion — the 26 J of light must be accounted for too",
  "feedback": "This answer is wrong — 540 − 210 leaves the light unaccounted. Subtract both: 540 − 210 − 26 = 304 J."
 }
]
feedback
{
 "keyExplanation": "Energy cannot be created or destroyed, so all 540 J must leave in some form. Motion and light account for 210 J + 26 J = 236 J. The rest becomes thermal energy: 540 J − 236 J = 304 J.",
 "anticipatedWrong": [
  {
   "value": 540,
   "misconception": "you gave the total converted energy instead of the thermal share — subtract the motion and light from the 540 J",
   "feedback": "This answer is wrong — 540 J is everything the scooter converted. Thermal = 540 − 210 − 26 = 304 J."
  },
  {
   "value": 236,
   "misconception": "you gave the motion plus light instead of what remains — 210 + 26 = 236 J is the part already accounted for",
   "feedback": "This answer is wrong — 236 J is the motion and light together. Thermal is the remainder: 540 − 236 = 304 J."
  },
  {
   "value": 776,
   "misconception": "you added everything together — energy in must equal energy out, so the thermal share is 540 minus the 236 J of motion and light",
   "feedback": "This answer is wrong — adding makes more leave than entered. 540 in = 540 out, so thermal = 304 J."
  },
  {
   "value": 330,
   "misconception": "you subtracted only the motion — the 26 J of light must be accounted for too",
   "feedback": "This answer is wrong — 540 − 210 leaves the light unaccounted. Subtract both: 540 − 210 − 26 = 304 J."
  }
 ]
}
THM-013 · medium · application · seq 16 · authored:U12-G1 stage 2 (fresh in-between endpoint read, kept qualitative per the THM-035 fence; big-object-wins + material-block + swap classes) | stage-3 wave-1: V-T4 rebalance · mcq4
A warm trivet is set on a cool slate counter and both are left alone. Where will their temperatures end up?
At one shared value in between the two starting temperatures — the trivet cools while the slate beneath it warms, until the flow stops. KEY
Both end up sitting exactly at the slate's original temperature, because the bigger, cooler object always wins the exchange outright.
The trivet keeps its warmth, because stone cannot accept energy from metal.
They swap temperatures — the trivet ends at the slate's start, and the slate at the trivet's.
THM-014 · hard · transfer · seq 17 · authored:U12-G1 stage 2 (fresh within-object sorting counterfactual; self-sorting + temporary-sorting + between-objects-only classes) | stage-3 wave-1: V-T4 rebalance · mcq4
A pewter serving tray rests in a cool room, all of it at one temperature. Could one half of the tray spontaneously grow hotter while the other half grows colder?
No — that would need heat to gather itself and flow into the hotter half by itself, and heat never flows toward the hotter side on its own. KEY
Yes — the energy inside a single object is completely free to bunch itself up at either end whenever it happens to do so.
Yes, briefly — trays often develop hot ends before settling back to even.
No — because heat can only move between separate objects, never within one object.
THM-016 · hard · transfer · seq 18 · authored:U12-G1 stage 2 (fresh first-law observation, instances disjoint from the pendulum seed; same-seq parallel by design) | stage-3 wave-1: V-T7: 'careful measurement finds the' = THM-016 spec gram; 'shows' matches the same-seq seed lane (instance-free) · mcq4
A conference-desk spinning top slows and falls still. Careful measurement shows the felt mat and the top's tip warmed by exactly the energy the spin gave up. Which law does the measurement illustrate?
The first law of thermodynamics KEY
The zeroth law of thermodynamics
The second law of thermodynamics
The third law of thermodynamics
THM-016 · hard · transfer · seq 19 · authored:U12-G1 stage 2 (fresh zeroth-law shared-reading observation; instances disjoint from A and C) · mcq4
A tin of buttons and the craft drawer holding it are checked with one probe, which settles on the same value against each. Which law says the tin and the drawer are in thermal equilibrium with each other?
The zeroth law of thermodynamics KEY
The third law of thermodynamics
The second law of thermodynamics
The first law of thermodynamics
THM-014 · hard · transfer · seq 20 · authored:U12-G1 stage 2 (fresh boundary argument framed inside one object; special-case + wrong-objection + sealed-ends classes) | stage-3 wave-1: V-T4 rebalance (key trimmed) | stage-3 wave-1: V-T4 rebalance · mcq4
A student argues, 'Since energy is conserved, the cold end of an untouched crowbar could lend its warmth to the hot end just as easily as the other way around.' Which reply is correct?
Conservation permits both directions, but the second law does not — on its own, heat flows only from the hotter end toward the colder end. KEY
The student is right — inside one single solid object, the two directions of flow really are equally easy for heat to take.
The student is wrong because lending warmth uphill would destroy some energy on the way.
The student is wrong because a crowbar's two ends can never exchange heat at all.
THM-016 · medium · application · seq 21 · authored:U12-G1 stage 2 (fresh conceptual FRQ; (c) instances re-minted dominoes-case/games-shelf so form E's seq-19 tin-of-buttons surface is not telegraphed; instances disjoint from forms A-D and all placed seqs) · frq
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about.
Match each everyday observation to the law of thermodynamics it illustrates, and justify each match from what the observation is about. (a) After a bowling ball rolls the length of a lane and settles in the pit, an energy audit finds the lane boards, the ball's surface, and the pit padding warmed by just the amount of motion the ball gave up. Name the law this illustrates and justify your answer. (b) A specialty cooling-equipment maker advertises reaching within a millionth of a degree of the ultimate low, while its manual admits that the ultimate low itself is unreachable. Name the law this illustrates and justify your answer. (c) Two halves of an afternoon at a games table: (i) a case of dominoes and the games shelf it sits on settle until a probe shows one shared temperature for both; (ii) a still-warm glue gun, unplugged and set on that shelf, passes its warmth one way into the cooler case and never draws it back. Assign each half its law, and state the deciding aspect for each.
Part a. After a bowling ball rolls the length of a lane and settles in the pit, an energy audit finds the lane boards, the ball's surface, and the pit padding warmed by just the amount of motion the ball gave up. Name the law this illustrates and justify your answer.
Model: The first law of thermodynamics. The audit is an energy accounting: the warmth in the boards, the ball's surface, and the padding equals just the motion the ball gave up — the energy changed form while the total stayed the same, which is conservation of energy.
Part b. A specialty cooling-equipment maker advertises reaching within a millionth of a degree of the ultimate low, while its manual admits that the ultimate low itself is unreachable. Name the law this illustrates and justify your answer.
Model: The third law of thermodynamics. The manual describes the unreachable floor: a real device can approach absolute zero ever more closely, but the ultimate low can never actually be reached.
Part c. Two halves of an afternoon at a games table: (i) a case of dominoes and the games shelf it sits on settle until a probe shows one shared temperature for both; (ii) a still-warm glue gun, unplugged and set on that shelf, passes its warmth one way into the cooler case and never draws it back. Assign each half its law, and state the deciding aspect for each.
Model: Half (i) is the zeroth law of thermodynamics: the case and the shelf settle at one shared temperature, so they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the glue gun's warmth flows one way into the cooler case and never returns by itself — the deciding aspect is the one-way DIRECTION of the flow.
Full model answer. (a) The first law of thermodynamics. The audit is an energy accounting: the warmth in the boards, the ball's surface, and the padding equals just the motion the ball gave up — the energy changed form while the total stayed the same, which is conservation of energy. (b) The third law of thermodynamics. The manual describes the unreachable floor: a real device can approach absolute zero ever more closely, but the ultimate low can never actually be reached. (c) Half (i) is the zeroth law of thermodynamics: the case and the shelf settle at one shared temperature, so they are in thermal equilibrium — the deciding aspect is reaching the SAME temperature. Half (ii) is the second law of thermodynamics: the glue gun's warmth flows one way into the cooler case and never returns by itself — the deciding aspect is the one-way DIRECTION of the flow.

End of Topic Test: Exothermic and endothermic processes & Representing energy changes (u12-t2 · 5 forms × 21 items · 105 total)

David's notes for James:
full notes file
# u12-t2 — notes/queries from David's side (U12-G2)

1. FRQ ALLOCATION - frq_per_form = 1 (confirm the composition): the wave calc-heavy 2-3-FRQ directive does NOT apply to this gate. U12's quantitative territory (q = mc-Delta-T, calorimetry) is entirely OUTSIDE this scope: THM-017..024 are fact/explanation/representation/discrimination atoms under the unit's binding decisions D2/D4 - every energy statement is in WORDS (no kJ, no Delta-H, no signed q, no bond-energy numbers, which THM-019/020/021 extraNotes exclude as AP territory). No formula is ever substituted (5-line scaffold N/A) and no numeric-entry row can exist (V-T6 unarmed by design - zero numeric slots, recorded in the blueprint). Your seed file's frq_per_form=1 concurs. The single FRQ is the capstone THM-023 sketch production (your gate production seeds land on forms A+B; drawing-assessment policy per your 2026-07-31 answer), terminal at seq 21 per D6. D5: min(20, 6 x 8 lessons) = 20 objective rows, no scaling; your target_size=20 concurs. Mix 4 recall / 12 application / 4 transfer; 25 objective figure rows (seq 11-14 + 19) honor THM-022's R10 rule that diagrams are rendered, never prose-described.
2. PHOTOSYNTHESIS RESERVATION (blueprint ruling, confirm): photosynthesis appears in THREE of your seeds (pool 7 THM-019 bond-breaking, pool 18 THM-023 FRQ production = demo_curated[0], pool 21 THM-024 equation). The cross-form instance rule bans sharing it, and the FRQ stem STATES the process is endothermic - which would leak pool 21's key and cue pool 7 on any shared form. Ruling: the instance is reserved to the highest-value seed, the form-A capstone FRQ production; pools 7 and 21 were placed with must_freshen_instance (skills + foil designs kept, instances swapped). At stage 3 the FRQ prompt's science clause was additionally de-instanced (water/oxygen/carbon named substances out, glucose-building wording kept) because water+oxygen are own-lesson THM-023 materials; the endothermic-process framing and the drawing task are unchanged.
3. SEED FRESHENINGS UNDER THE STRICT SEED RULING (recorded content edits to your verbatim seed text, A-U12G2-3 - dispositions to confirm; every skill + foil design kept): A#1 'the air around it' -> 'the benchtop beneath it' (collided with THM-018 fluency text + own-lesson material); A#5 water -> broth (own-lesson THM-017 material + 6 cross-form pairs); A#8 'drifting hydrogen atoms pair up into H2 molecules' -> 'drifting single atoms pair up into two-atom molecules' (own-lesson THM-020 material + ASCII-formula notation); A#11 lead-in 'The energy diagram for a reaction is shown.' -> 'The energy diagram below describes one reaction.' (your lead-in is verbatim in a student-seen THM-022 fluency stem); A#21 FRQ prompt de-instanced per the photosynthesis note, instruction tail unified to the course's 'for this process' wording. Blueprint-level freshenings: pool 14's limestone kiln (student-seen in THM-023 WE2 + THM-024 WE2) -> generic unnamed decomposition; pool 22's 'Propane burns exothermically' (verbatim collision with the student-seen THM-021 fluency stem) -> ethane.
4. YOUR prod_seeds WERE NOT USED AS TEST ITEMS (confirm): both match THM-023 fluencyItems verbatim (pocket hand warmer, citric acid + baking soda) - student-seen in-lesson practice, so they are spares only per the standing rule, and their instances are banned from authored items. The gate FRQ productions come from pool 18/20 (= demo_curated 0/2) on forms A/B; forms C-E carry fresh authored productions of the same THM-023 drawing construct.
5. WHITELIST ADJUDICATION A-U12G2-1 (extra_task_idioms, confirm): 'Classify the reaction shown by the thermochemical equation' is THM-024's own recurring task question - verbatim in BOTH article worked examples, both fluency items, and the gate item (5 spec occurrences). The course asks classification in exactly these words on every parallel item, so the clause is task boilerplate, not instance content. The five seq-15 equations themselves (NH4Cl / H2O2 / C5H12 / CH3OH / Ag2O - all fresh, form-local) remain fully scanned.
6. WHITELIST ADJUDICATION A-U12G2-2 (extra_convention_phrases, confirm): the drawing-FRQ instruction block 'On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.' is THM-023's own mandated production-task boilerplate (verbatim in its fluency items and gate items; your two gate production seeds carry it, and the drawing task IS the assessed skill). The whitelist covers the instruction wording only; every scenario clause ahead of it is fresh, form-local, and fully scanned. 'Select Continue' is course delivery boilerplate (courseware, not paper) - flagged by a blind reviewer, dismissed as production convention.
7. BLIND-PACKET RENDERER GAP - PROMOTE TO _SHARED (A-U12G2-4, action item for the harness, no content impact): _shared/make_blind_packet.py has no fig_text family for figureType 'energy-diagram' / 'energy-diagram-panels', so blind round 1 rendered ONLY the figureSpec 'style' string for the 25 figure items (both reviewers correctly called seq 11-13/19 unanswerable = 20 spurious hard fails) AND the seq-14 style annotations leaked the drawing flaw they name. A gate-local renderer (_make_blind_packet_local.py) now renders the drawn fields verbatim (axes, levels, curve, gap; panels + sharedFeatures/sharedScale) and NEVER renders 'style' (same R23 class as the shared graduated-cylinder rule). U13/U14 gates with energy-diagram figures need the same family in _shared. Forms content was never changed by this fix.
8. SEQ-9 DE-DIRECTIONING (disclosure, blind round-1 catch): the five seq-9 stems originally stated the energy-flow direction, which answered the form's THM-019/020 recall rows. All five now say only which side's energy total is LARGER - knowing breaking=cost / forming=release is part of the tested inference. A same-class sweep also de-instanced the THM-021 dependence stems (seq 10): they now state ongoing absorption explicitly, closing a photochemical/activation loophole a rigorous reviewer raised (the light-source instance was replaced with a thermal supply on form C for the same reason).
9. BLIND-QC LEDGER (disclosure): round 1 (gpt-5.6-sol blind role + gemini, all 105 items x 2 reviewers) key picks 169/192 with 22 hard fails - 20 were the packet renderer defect above, 2 real (THM-021 literal-reading class, fixed); round 2 (fresh tags, 45 items = 20 patched + 25 figure rows under the fixed renderer) key picks 90/90, 4 rigorous-parse fails fixed in content (unheated oil bath stated; warming pad replaces sun lamp; seq-11 thermometer item now asks what the DIAGRAM PREDICTS; every seq-13 figureSpec gained the axis-labeling sharedFeatures line - class sweep); round 3 (8 items) 0 hard fails, key picks 16/16; post-sol re-blind (5 items) 0 fails, key picks 8/8. All 12 drawing-FRQ cold answers (5 forms x 2 reviewers + 2 post-sol) hand-graded MATCH with justifications (frq_verdicts.json). ~45 cross-item-cueing advisories dismissed with recorded rationale: an 8-lesson topic test with 21 slots necessarily co-seats recall and application rows of the same lesson family, and the blind packet's conventions block hands reviewers the taught rules; the actionable stem-leak subset (seq 9) was fixed instead.
10. SOL-QC LEDGER (disclosure): authoritative gpt-5.6-sol loops 1-3 went 5 -> 1 -> 0 FAILs, all content-fixed: the THM-021 dependence-inference FEEDBACK class (feedback argued net direction determines self-sustainment - re-anchored to each stem's stated net absorption; the loop-2 residual was the QB 3.9 all-fields trap, closed with a deterministic bank-wide scan); D#4 rekeyed onto its own THM-020 construct (was keyed on THM-019's breaking-requires skill); an invalid equal-energy counterfactual in E#3's feedback replaced; E#21's FRQ exclusivity claim softened to match THM-018's supply rule; a rubric-vocabulary minor ('activation-energy hump') swept from all five FRQ rubrics + graderDiagnostics (grader-facing only, D3 hygiene). Final ledger: 105 pass / 0 fail. Three accepted pass-with-minor distractor-quality notes recorded in solqc_report.md (B#7, B#15, D#8) - each distractor is unambiguously wrong and misconception-tagged; left as-is.
11. NOTA/AOTA (confirm none needed): absent from all 24 pool seeds - V-T5 clean at placement and as shipped. The 'Both diagrams' / 'Neither diagram' options in your THM-022 seeds are substantive two-panel claims, not none-of-the-above constructions (U01-G1 canon reading), and were kept.
12. BINDING INSTANCE RULE (course-wide, disclosure): zero uranium/plutonium/enrichment/reactor/weapons/dose framings anywhere in the gate - deterministic token scan at packaging over forms_final.json AND this export body (0 hits). Classroom-safe instances throughout (camping stoves, cold packs, bread dough, kilns, benchtop apparatus).
13. QC LEDGER (disclosure): deterministic validators 12/12 PASS exit 0 with the UNTOUCHED shared validator (no adjudication wrapper needed - the only gate_config entries are the two whitelist adjudications above + the spec pointer; single standing warn: A#3 'nitrogen' is taught elsewhere in scope - the stem states N2's bond strength inline, so the item is self-contained); stage-3 content patching ran FIRST (183 V-T7 collision lines -> 0 across two waves of instance freshening + stem rewrites, validator never weakened); blind = 3 rounds + post-sol re-blind, 0 open hard fails; sol authoritative loops 1-3 = 5 -> 1 -> 0 FAILs, subset raws verified to cover every requested item (no stale verdicts); 41+ machine-logged patch edits across 4 waves (_stage3_patches.py, _patch_blind1/2.py, _patch_sol1/2.py) plus the point fixes recorded in fix_log.md.

Form A

THM-017 · easy · recall · seq 1 · seed:U12-G2.pool[1] (THM-017 gateItems, James) - VERBATIM (field mapping only) · mcq4
Which observation shows that a process running in a flask is exothermic?
The flask and the benchtop beneath it warm up while the process runs. KEY
The flask and the benchtop beneath it cool down while the process runs.
The contents change color while the process runs.
Bubbles of gas escape from the contents while the process runs.
THM-018 · easy · recall · seq 2 · seed:U12-G2.pool[3] (THM-018 gateItems, James) - VERBATIM (field mapping only) · mcq4
Sherbet powder reacting with the moisture on your tongue makes your tongue feel cold. Which statement describes the energy flow?
The reacting sherbet absorbs energy from your tongue. KEY
The reacting sherbet releases energy to your tongue.
The sherbet passes coldness into your tongue.
No energy moves — the cold feeling is only a taste effect.
THM-019 · easy · recall · seq 3 · seed:U12-G2.pool[6] (THM-019 gateItems, James) - VERBATIM (field mapping only) · mcq4
Nitrogen molecules, N₂, hold two atoms together with one of the strongest bonds in chemistry. Which statement about the molecule and its two separated atoms is correct?
The bonded molecule sits at lower energy, so separating the atoms requires an energy input. KEY
The bonded molecule sits at higher energy, so separating the atoms requires an energy input.
The bonded molecule sits at lower energy, so separating the atoms releases energy.
The bonded molecule sits at higher energy, so separating the atoms releases energy.
THM-020 · easy · recall · seq 4 · seed:U12-G2.pool[9] (THM-020 gateItems, James) - VERBATIM (field mapping only) · mcq4
Which pairing of a bond process with its energy direction is correct?
Forming a bond — releases energy. KEY
Forming a bond — requires an energy input.
Breaking a bond — releases energy.
Breaking a bond — neither absorbs nor releases energy.
THM-017 · medium · application · seq 5 · seed:U12-G2.pool[0] (THM-017 gateItems, James) - VERBATIM (field mapping only) · mcq4
Butane burns in a camping stove under a pot of cold broth, and the broth steadily warms. In this exothermic process, which is the system, and which way does the energy flow?
The burning butane is the system, and energy flows out of it into the pot and broth. KEY
The broth is the system, and it releases its stored energy down into the burning butane.
The burning butane is the system, and it absorbs energy from the pot and broth above it.
Energy flows equally in both directions, so nothing changes overall.
THM-018 · medium · application · seq 6 · seed:U12-G2.pool[4] (THM-018 gateItems, James) - VERBATIM (field mapping only) · mcq4
While a reaction runs, the bench under the flask cools noticeably. Classify the process, and give the direction of energy flow.
Endothermic — energy flows from the surroundings into the system. KEY
Exothermic — energy flows from the system into the surroundings.
Endothermic — energy flows from the system into the surroundings.
Exothermic — energy flows from the surroundings into the system.
THM-019 · medium · application · seq 7 · seed:U12-G2.pool[8] (THM-019 gateItems, James) - VERBATIM (field mapping only) · mcq4
An inventor proposes a fuel that powers a car purely by breaking its molecules' bonds apart, with no new bonds formed. Why must the proposal fail?
Breaking bonds requires an energy input, so a process that only breaks bonds absorbs energy instead of supplying any. KEY
It cannot fail — most fuels release their energy exactly this way.
Bond breaking does release energy, but far too little of it to move something as heavy as a car.
Bond breaking involves no energy change either way, so the car would sit still rather than absorb anything.
THM-020 · medium · application · seq 8 · seed:U12-G2.pool[10] (THM-020 gateItems, James) - VERBATIM (field mapping only) · mcq4
In a gas cloud between the stars, drifting single atoms pair up into two-atom molecules, and astronomers detect energy being given out by the cloud exactly as the molecules form. Where does that energy come from?
It is released as the new bonds form. KEY
It is released as old bonds break.
The atoms create the energy at the moment they touch.
The cloud absorbs the energy from nearby starlight and re-emits it.
THM-021 · medium · application · seq 9 · seed:U12-G2.pool[12] (THM-021 gateItems, James) - VERBATIM (field mapping only) · mcq4
A fuel engineer compares two candidate reactions. In reaction 1, the energy involved in forming the products' bonds is larger than the energy involved in breaking the reactants' bonds. In reaction 2, it is the other way around. Which reaction could warm an engine, and why?
Reaction 1 — the surplus from bond forming is released to the surroundings. KEY
Reaction 2 — the extra bond breaking releases the most energy.
Both reactions — every reaction warms its surroundings.
Neither reaction — bond energies say nothing about warming.
THM-021 · medium · application · seq 10 · seed:U12-G2.pool[14] (THM-021 gateItems, James) - FRESHENED instance (limestone kiln -> generic unnamed decomposition): limestone/kiln is student-seen in THM-023 WE2 and THM-024 WE2 (SEED RULING, no freshness exemption); key + foil design kept verbatim · mcq4
A powdered solid decomposes into two simpler substances only while a burner keeps heating its crucible, soaking up the burner's heat for the whole change — take the burner away and the decomposition stops. Which comparison of the reaction's bond energies must hold?
Breaking the reactants' bonds requires more energy than forming the products' bonds releases. KEY
Forming the products' bonds releases more energy than breaking the reactants' bonds requires.
Breaking the reactants' bonds releases more energy than forming the products' bonds requires.
The two amounts are exactly equal, so the burner's energy is never used.
THM-022 · medium · application · seq 11 · seed:U12-G2.pool[15] (THM-022 gateItems, James) - VERBATIM (field mapping only) · mcq4
The energy diagram below describes one reaction. What happens to the temperature of the surroundings as this reaction runs?
FIGURE (energy-diagram · stimulus) — yAxisLabel: "energy" · xAxisLabel: "progress of the reaction" · levels: "flat reactants level on the left; flat products level on the right, clearly LOWER than the reactants level" · curve: "smooth unlabeled curve joining the levels, no hump" · style: "clean textbook energy diagram"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "energy",
  "xAxisLabel": "progress of the reaction",
  "levels": "flat reactants level on the left; flat products level on the right, clearly LOWER than the reactants level",
  "curve": "smooth unlabeled curve joining the levels, no hump",
  "style": "clean textbook energy diagram"
 }
}
They warm up. KEY
They cool down.
Their temperature stays exactly the same.
It cannot be told from an energy diagram.
THM-022 · medium · application · seq 12 · seed:U12-G2.pool[16] (THM-022 gateItems, James) - VERBATIM (field mapping only) · mcq4
Diagrams A and B show two exothermic reactions drawn on the same energy scale. Which reaction releases more energy?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level and flat products level with a LARGE vertical gap, products below reactants, smooth unlabeled joining cu… · sharedScale: true · style: "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level and flat products level with a LARGE vertical gap, products below reactants, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level and flat products level with a SMALL vertical gap, products below reactants, smooth unlabeled joining curve, no hump"
   }
  ],
  "sharedScale": true,
  "style": "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B"
 }
}
Reaction A KEY
Reaction B
Both release the same energy
It cannot be compared from the diagrams
THM-023 · medium · application · seq 13 · seed:U12-G2.pool[19] (THM-023 gateItems, James) - VERBATIM (field mapping only; = demo_curated 1, pool option order) · mcq4
Four panels labeled A to D each offer one attempt at the energy diagram of an EXOTHERMIC reaction. Which panel follows every drawing rule?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat labeled reactants level, flat labeled products level ABOVE it, one smooth joining curve, gap labeled 'energy absorbed'"}… · style: "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere" · sharedFeatures: "every panel is drawn with its vertical axis labeled 'energy'"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat labeled reactants level, flat labeled products level ABOVE it, one smooth joining curve, gap labeled 'energy absorbed'"
   },
   {
    "panel": "B",
    "description": "two labeled levels that SLOPE steadily upward instead of lying flat, joined end to end, gap labeled 'energy released'"
   },
   {
    "panel": "C",
    "description": "flat labeled reactants level, flat labeled products level BELOW it, one smooth joining curve, gap marked and labeled 'energy released'"
   },
   {
    "panel": "D",
    "description": "flat labeled reactants level, flat labeled products level BELOW it, one smooth joining curve, but the gap is labeled 'energy absorbed'"
   }
  ],
  "style": "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere",
  "sharedFeatures": "every panel is drawn with its vertical axis labeled 'energy'"
 }
}
Panel C KEY
Panel A
Panel B
Panel D
THM-023 · medium · application · seq 14 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
The figure shows one hand-drawn energy diagram for an EXOTHERMIC reaction, and it contains exactly one drawing error. What is the error?
FIGURE (energy-diagram · stimulus) — yAxisLabel: "energy" · xAxisLabel: "progress of the reaction" · levels: "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level" · curve: "smooth unlabeled curve joining the levels, no hump" · style: "clean textbook energy diagram drawn as a student's answer; axis and level labels present and correct; the only flaw is the gap label" · gap: "marked, but labeled 'energy absorbed'"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "energy",
  "xAxisLabel": "progress of the reaction",
  "levels": "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level",
  "curve": "smooth unlabeled curve joining the levels, no hump",
  "style": "clean textbook energy diagram drawn as a student's answer; axis and level labels present and correct; the only flaw is the gap label",
  "gap": "marked, but labeled 'energy absorbed'"
 }
}
The gap is labeled 'energy absorbed' — a drop from reactants to products should be labeled 'energy released'. KEY
The products level is on the wrong side of the diagram: it should sit above the reactants level.
The levels should slope downward rather than lie flat.
The vertical axis should be labeled 'progress of the reaction' instead of 'energy'.
THM-024 · medium · application · seq 15 · seed:U12-G2.pool[21] (THM-024 gateItems, James) - FRESHENED instance (photosynthesis equation -> NH₄Cl + energy → NH₃ + HCl): the photosynthesis instance is reserved to the form-A FRQ seed, whose stem states the classification and would leak this row's key on the same form; key (Endothermic) + foil design kept · mcq4
Classify the reaction shown by the thermochemical equation NH₄Cl + energy → NH₃ + HCl.
Endothermic KEY
Exothermic
Neither — a reaction that makes two products cannot absorb energy
It cannot be classified, because the equation shows no temperatures
THM-024 · medium · application · seq 16 · seed:U12-G2.pool[22] (THM-024 gateItems, James) - FRESHENED instance (propane -> ethane): 'Propane burns exothermically' collides verbatim with the student-seen THM-021 fluency stem (SEED RULING); foil design (wrong side / both sides / dropped term) kept verbatim · mcq4
Ethane fuel gas burns exothermically. Which thermochemical equation writes the energy term on the correct side?
2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O + energy KEY
2C₂H₆ + 7O₂ + energy → 4CO₂ + 6H₂O
2C₂H₆ + 7O₂ + energy → 4CO₂ + 6H₂O + energy
2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O
THM-018 · hard · transfer · seq 17 · seed:U12-G2.pool[5] (THM-018 gateItems, James) - VERBATIM (field mapping only) · mcq4
An endothermic reaction runs inside a sealed vacuum flask, which lets no energy in from outside. The thermometer in the mixture falls steadily while the reaction runs. Where is the reaction getting its energy?
From the mixture itself — draining its energy is why the mixture keeps cooling. KEY
From nowhere — an endothermic reaction can run without taking in any energy.
From the coldness that the reaction produces.
From the flask walls, which pass energy in from outside.
THM-021 · hard · transfer · seq 18 · seed:U12-G2.pool[13] (THM-021 gateItems, James) - VERBATIM (field mapping only) · mcq4
A student says a campfire's heat comes 'from the wood's bonds breaking open and letting their energy out.' Which correction fixes the claim?
Breaking bonds absorbs energy — the fire's heat is the surplus released as the products' new bonds form. KEY
No correction is needed — burning releases energy by breaking bonds open.
The heat comes from bond breaking and bond forming together, because both halves of the change release energy.
The heat comes from the wood drawing energy out of its cooler surroundings.
THM-022 · hard · transfer · seq 19 · seed:U12-G2.pool[17] (THM-022 gateItems, James) - VERBATIM (field mapping only) · mcq4
While a reaction runs in a flask, the flask grows cold to the touch. Diagrams A and B are shown. Which diagram matches the reaction?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level on the left, flat products level on the right sitting clearly BELOW it, smooth unlabeled joining curve, … · style: "two clean textbook energy diagrams side by side, boxes labeled A and B"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly BELOW it, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly ABOVE it, smooth unlabeled joining curve, no hump"
   }
  ],
  "style": "two clean textbook energy diagrams side by side, boxes labeled A and B"
 }
}
Diagram B KEY
Diagram A
Both diagrams
Neither diagram
THM-024 · hard · transfer · seq 20 · seed:U12-G2.pool[23] (THM-024 gateItems, James) - VERBATIM (field mapping only) · mcq4
A reaction's thermochemical equation writes its energy term on the reactant side. What happens to the temperature of the surroundings as the reaction runs?
They cool down. KEY
They warm up.
Their temperature stays the same.
They warm at first and then cool back.
THM-023 · medium · application · seq 21 · seed:U12-G2.pool[18] (THM-023 gateItems production, James; = demo_curated 0) - VERBATIM stem/model/checklist; checklist folded into 3 rubric criteria (40/35/25), drawing-assessment policy James 2026-07-31 + U01-G1 drawing-FRQ canon · frq
Photosynthesis is an endothermic process: a plant absorbs light energy the whole time it is building glucose molecules from simpler starting molecules. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Photosynthesis is an endothermic process: a plant absorbs light energy the whole time it is building glucose molecules from simpler starting molecules. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Part a. Photosynthesis is an endothermic process: a plant absorbs light energy the whole time it is building glucose molecules from simpler starting molecules. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Model: A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly HIGHER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy absorbed'.
Full model answer. A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly HIGHER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy absorbed'.

Form B

THM-017 · easy · recall · seq 1 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reaction runs in a corked test tube. Which observation would show that the process is exothermic?
The tube grows warm in the hand holding it while the reaction runs. KEY
The tube grows cold in the hand holding it while the reaction runs.
The mixture inside turns from clear to cloudy while the reaction runs.
A faint smell escapes from under the cork while the reaction runs.
THM-018 · easy · recall · seq 2 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Two powders stirred together in a paper cup react, and the cup quickly turns icy cold in your hand. Which statement describes the energy flow?
The reacting mixture absorbs energy from the cup and your hand. KEY
The reacting mixture releases energy into the cup and your hand.
The reacting mixture passes coldness out into the cup and your hand.
No energy moves — the powders simply feel cold by nature.
THM-019 · easy · recall · seq 3 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Which statement correctly compares a carbon monoxide molecule, CO, with its two atoms pulled apart?
The bonded molecule sits at lower energy, so pulling the atoms apart requires an energy input. KEY
The bonded molecule sits at higher energy, so pulling the atoms apart requires an energy input.
The bonded molecule sits at lower energy, so pulling the atoms apart releases energy.
The bonded molecule sits at higher energy, so pulling the atoms apart releases energy.
THM-020 · easy · recall · seq 4 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Which statement about what happens when a chemical bond forms is correct?
The atoms drop to a lower-energy state, and the energy difference is released. KEY
The atoms rise to a higher-energy state, absorbing the difference.
The energy difference is stored inside the new bond, waiting to be released when the bond breaks.
The atoms' energy does not change when the bond forms.
THM-017 · medium · application · seq 5 · seed:U12-G2.pool[2] (THM-017 gateItems, James) - VERBATIM (field mapping only) · mcq4
A student says an exothermic reaction 'keeps its released energy inside itself, which is why it feels hot.' Which correction fixes the claim?
The energy leaves the system — the reaction feels hot because released energy is entering your hand and the bench. KEY
Nothing needs correcting — an exothermic reaction really does keep every bit of its released energy locked inside itself.
The reaction feels hot because it is absorbing energy from your hand.
The reaction feels hot because it is creating new energy on the spot.
THM-018 · medium · application · seq 6 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
While two solutions react in a beaker, the metal stand supporting the beaker turns noticeably cold. Classify the process, and give the direction of energy flow.
Endothermic — the reacting mixture is absorbing energy from its surroundings. KEY
Exothermic — the reacting mixture is releasing energy to its surroundings.
Endothermic — the reacting mixture is releasing energy to its surroundings.
Exothermic — the reacting mixture is absorbing energy from its surroundings.
THM-019 · medium · application · seq 7 · seed:U12-G2.pool[7] (THM-019 gateItems, James) - FRESHENED instance (photosynthesis -> iodine-vapor photodissociation): photosynthesis is reserved to the form-A FRQ seed under the cross-form instance rule; skill + foil design kept (seed_placement note) · mcq4
In a spectroscopy demonstration, iodine molecules, I₂, in a sealed tube split into single iodine atoms only while a bright lamp shines into the tube. Why does the splitting stop as soon as the lamp is switched off?
Breaking the I–I bond requires a steady energy input, and the lamp's light supplies it. KEY
The lamp's light cools the tube until the bonds give up their energy.
The bonds break on their own, and the light only makes the atoms easier to see.
Splitting the molecules releases energy, which the light then carries out of the tube.
THM-020 · medium · application · seq 8 · seed:U12-G2.pool[11] (THM-020 gateItems, James) - VERBATIM (field mapping only) · mcq4
A student writes: 'Forming a bond needs an energy investment, because building anything takes work.' Which correction fixes the claim?
Bond forming is a drop to lower energy, so it releases energy rather than needing an investment. KEY
No change is needed — bond forming really does need an energy investment.
Bond forming releases energy for small molecules but needs an investment for large ones.
Bond forming leaves the energy of the atoms completely unchanged.
THM-021 · medium · application · seq 9 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A designer wants a reaction that will chill a drink can from the outside. Reaction 1: the energy involved in breaking its reactants' bonds outweighs the energy involved in forming its products' bonds. Reaction 2: the balance tips the opposite way. Which reaction suits the job, and why?
Reaction 1 — it runs at a shortfall and absorbs the difference from the can, cooling it. KEY
Reaction 2 — its surplus energy pours into the can and chills it.
Both reactions — any reacting mixture draws energy from its surroundings.
Neither reaction — comparing bond energies tells you nothing about how the temperature of anything changes.
THM-021 · medium · application · seq 10 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A mixture in a lidded cup begins reacting the moment it is stirred, and its temperature climbs and then stays high for many minutes with no outside heating. Which comparison of its bond energies must hold?
Forming the products' bonds releases more energy than breaking the reactants' bonds requires. KEY
Breaking the reactants' bonds requires more energy than forming the products' bonds releases.
Breaking the reactants' bonds releases the energy, and forming the products' bonds absorbs it.
The two amounts are exactly equal, so warmth appears without any surplus.
THM-022 · medium · application · seq 11 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
The energy diagram for a reaction is shown. What happens to the temperature of the surroundings while this reaction runs?
FIGURE (energy-diagram · stimulus) — yAxisLabel: "energy" · xAxisLabel: "progress of the reaction" · levels: "flat labeled reactants level on the left; flat labeled products level on the right, clearly HIGHER than the reactants level" · curve: "smooth unlabeled curve joining the levels, no hump" · style: "clean textbook energy diagram"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "energy",
  "xAxisLabel": "progress of the reaction",
  "levels": "flat labeled reactants level on the left; flat labeled products level on the right, clearly HIGHER than the reactants level",
  "curve": "smooth unlabeled curve joining the levels, no hump",
  "style": "clean textbook energy diagram"
 }
}
They cool down. KEY
They warm up.
Their temperature stays exactly the same.
It cannot be told from an energy diagram.
THM-022 · medium · application · seq 12 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Diagrams A and B show two endothermic reactions drawn on the same energy scale. Which reaction absorbs more energy?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level and flat products level with a SMALL vertical gap, products above reactants, smooth unlabeled joining cu… · style: "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B" · sharedScale: true
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level and flat products level with a SMALL vertical gap, products above reactants, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level and flat products level with a LARGE vertical gap, products above reactants, smooth unlabeled joining curve, no hump"
   }
  ],
  "style": "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B",
  "sharedScale": true
 }
}
Reaction B KEY
Reaction A
Both absorb the same energy
It cannot be compared from the diagrams
THM-023 · medium · application · seq 13 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Diagrams A to D give four attempts at the energy diagram of an ENDOTHERMIC reaction. Which one is drawn correctly?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat labeled reactants level, flat labeled products level BELOW it, one smooth joining curve, gap labeled 'energy absorbed'"}… · style: "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere" · sharedFeatures: "every panel is drawn with its vertical axis labeled 'energy'"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat labeled reactants level, flat labeled products level BELOW it, one smooth joining curve, gap labeled 'energy absorbed'"
   },
   {
    "panel": "B",
    "description": "flat labeled reactants level, flat labeled products level ABOVE it, one smooth joining curve, gap marked and labeled 'energy absorbed'"
   },
   {
    "panel": "C",
    "description": "two flat labeled levels drawn at exactly the same height, joined by a level line, no gap marked"
   },
   {
    "panel": "D",
    "description": "flat labeled reactants level, flat labeled products level ABOVE it, one smooth joining curve, but the gap is labeled 'energy released'"
   }
  ],
  "style": "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere",
  "sharedFeatures": "every panel is drawn with its vertical axis labeled 'energy'"
 }
}
Panel B KEY
Panel A
Panel C
Panel D
THM-023 · medium · application · seq 14 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
An energy diagram sketched for an ENDOTHERMIC reaction appears in the figure. It breaks exactly one drawing rule. What is wrong with the diagram?
FIGURE (energy-diagram · stimulus) — yAxisLabel: "energy" · xAxisLabel: "progress of the reaction" · levels: "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level" · curve: "smooth unlabeled curve joining the levels, no hump" · style: "clean textbook energy diagram drawn as a student's answer; axis and level labels present; the level placement is the flaw" · gap: "marked and labeled 'energy absorbed'"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "energy",
  "xAxisLabel": "progress of the reaction",
  "levels": "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level",
  "curve": "smooth unlabeled curve joining the levels, no hump",
  "style": "clean textbook energy diagram drawn as a student's answer; axis and level labels present; the level placement is the flaw",
  "gap": "marked and labeled 'energy absorbed'"
 }
}
The products level sits below the reactants level — an endothermic reaction's products end up higher. KEY
The gap label is wrong: an endothermic diagram's gap should read 'energy released'.
The curve joining the levels should carry its own arrow and label.
The reactants level should be drawn on the right, after the products.
THM-024 · medium · application · seq 15 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Classify the reaction shown by the thermochemical equation 2H₂O₂ → 2H₂O + O₂ + energy.
Exothermic KEY
Endothermic
Neither — the energy term cancels against the O₂
It cannot be classified, because the equation gives no temperatures
THM-024 · medium · application · seq 16 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Zinc carbonate decomposes endothermically when heated. Which thermochemical equation writes the energy term on the correct side?
ZnCO₃ + energy → ZnO + CO₂ KEY
ZnCO₃ → ZnO + CO₂ + energy
ZnCO₃ + energy → ZnO + CO₂ + energy
ZnCO₃ → ZnO + CO₂
THM-018 · hard · transfer · seq 17 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
An endothermic reaction runs inside a sealed vacuum flask whose walls let no measurable energy through from outside. A probe in the mixture shows its temperature falling steadily while the reaction runs. Where is the reaction getting its energy?
From the mixture itself — draining the mixture's own energy is why its temperature keeps falling. KEY
From nowhere — an endothermic reaction can run without taking energy in.
From the coldness the reaction produces as it runs.
From the flask walls, which let outside energy trickle in fast enough to feed it.
THM-021 · hard · transfer · seq 18 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A student says a struck match's burst of heat comes 'from the bonds in the match head cracking open and spilling their energy.' Which correction fixes the claim?
Breaking bonds absorbs energy — the match's heat is the surplus released as the products' new bonds form. KEY
No correction is needed — burning releases energy exactly by cracking bonds open.
The heat comes from both halves at once, because breaking and forming each release their own share of energy.
The heat comes from the match head collecting energy from its cooler surroundings.
THM-022 · hard · transfer · seq 19 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A sealed tube reacts inside an unheated oil bath, and from the moment the reaction starts the bath's temperature climbs steadily. Diagrams A and B are shown. Which diagram matches the reaction?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level on the left, flat products level on the right sitting clearly BELOW it, smooth unlabeled joining curve, … · style: "two clean textbook energy diagrams side by side, boxes labeled A and B"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly BELOW it, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly ABOVE it, smooth unlabeled joining curve, no hump"
   }
  ],
  "style": "two clean textbook energy diagrams side by side, boxes labeled A and B"
 }
}
Diagram A KEY
Diagram B
Both diagrams
Neither diagram
THM-024 · hard · transfer · seq 20 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reaction's thermochemical equation writes its energy term on the product side. What happens to the temperature of the surroundings as the reaction runs?
They warm up. KEY
They cool down.
Their temperature stays the same.
They warm briefly and then cool below where they started.
THM-023 · medium · application · seq 21 · seed:U12-G2.pool[20] (THM-023 gateItems production, James; = demo_curated 2) - VERBATIM stem/model/checklist; checklist folded into 3 rubric criteria (40/35/25), drawing-assessment policy James 2026-07-31 + U01-G1 drawing-FRQ canon · frq
Natural gas burning in a boiler is an exothermic process. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Natural gas burning in a boiler is an exothermic process. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Part a. Natural gas burning in a boiler is an exothermic process. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Model: A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly LOWER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy released'.
Full model answer. A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly LOWER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy released'.

Form C

THM-017 · easy · recall · seq 1 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Which observation tells a student that the reaction inside a sealed pouch is exothermic?
The metal block holding the pouch rises in temperature while the reaction runs. KEY
The metal block holding the pouch falls in temperature while the reaction runs.
The pouch puffs up as gas collects inside it.
The contents of the pouch slowly darken as the reaction runs.
THM-018 · easy · recall · seq 2 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A scoop of powder reacts with the liquid inside a glass jar, and the jar's walls turn cold. Which statement describes the energy flow?
The reacting contents absorb energy from the jar's walls. KEY
The reacting contents release energy into the jar's walls.
The reacting contents push coldness outward into the glass.
No energy moves between the contents and the jar.
THM-019 · easy · recall · seq 3 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Fluorine gas is made of F₂ molecules. Which statement compares one F₂ molecule with its two separated atoms?
The molecule is the lower-energy state, so separating the atoms needs an energy input. KEY
The molecule is the higher-energy state, so separating the atoms needs an energy input.
The molecule is the lower-energy state, so separating the atoms gives energy out.
The two states have equal energy, so moving between them neither costs nor supplies energy.
THM-020 · easy · recall · seq 4 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
When separated atoms come together and a bond forms between them, what happens to the energy difference between the separated state and the bonded state?
It leaves the atoms and is released to whatever is around them. KEY
It disappears as the bond forms.
It stays locked inside the bond until the bond is broken.
It is pulled in from the surroundings to hold the atoms together.
THM-017 · medium · application · seq 5 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A solid fuel tablet burns under a mess tin of soup on a camping table, and the soup steadily heats. In this exothermic process, which is the system, and which way does energy flow?
The burning fuel tablet is the system, and energy flows out of it into the tin and soup. KEY
The soup is the system, and it releases energy to the fuel tablet.
The burning fuel tablet is the system, and it absorbs energy from the tin and soup.
Energy circles between the tablet and the soup with no overall direction.
THM-018 · medium · application · seq 6 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A paste reacts in a crucible, and the tile under the crucible grows cold. Classify the process, and state which way the energy is moving.
Endothermic — energy is moving from the tile and the crucible into the reacting paste. KEY
Exothermic — energy is moving from the reacting paste into the tile and the crucible.
Endothermic — energy is moving from the reacting paste into the tile and the crucible.
Exothermic — energy is moving from the tile and the crucible into the reacting paste.
THM-019 · medium · application · seq 7 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
In an industrial cell, aluminum atoms are torn away from their bonded partners in the ore only while a huge electric current keeps flowing; the moment the current stops, production stops. Why?
Breaking the ore's aluminum bonds needs a steady energy input, and the current supplies it. KEY
The current cools the ore until its bonds fall apart on their own.
The bonds break by themselves, and the current only sweeps the freed metal away.
Breaking the bonds releases energy, and the current is needed to carry that energy off.
THM-020 · medium · application · seq 8 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
In a coating furnace, single silicon atoms land on a growing silicon film and bond to its surface; sensors record energy streaming out of the film exactly while it grows. Where does that energy come from?
Each new bond releases it — the atoms drop to the lower-energy bonded state. KEY
It is set free by old bonds breaking inside the film.
The landing atoms manufacture the energy at the moment of impact.
The film soaks the energy up from the furnace walls and re-emits it.
THM-021 · medium · application · seq 9 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
For one reaction, the energy involved in breaking the reactants' bonds is smaller than the energy involved in forming the products' bonds. Classify the reaction.
Exothermic KEY
Endothermic
Neither — the two amounts must always cancel exactly
It cannot be classified without a temperature measurement
THM-021 · medium · application · seq 10 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A pale gel reacts in its dish only while a gentle warming pad underneath keeps feeding it heat, drinking that heat in at every moment of the change; slide the dish off the pad and the reaction stops. Which comparison of the reaction's bond energies must hold?
Breaking the reactants' bonds requires more energy than forming the products' bonds releases. KEY
Forming the products' bonds releases more energy than breaking the reactants' bonds requires.
Breaking the reactants' bonds releases more energy than forming the products' bonds requires.
The two amounts are exactly equal, so the warming pad adds nothing the reaction uses.
THM-022 · medium · application · seq 11 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reaction has the energy diagram given in the figure. While the reaction runs, which reading does the energy diagram predict for a thermometer clipped to the outside of the reaction vessel?
FIGURE (energy-diagram · stimulus) — yAxisLabel: "energy" · xAxisLabel: "progress of the reaction" · levels: "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level" · curve: "smooth unlabeled curve joining the levels, no hump" · style: "clean textbook energy diagram"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "energy",
  "xAxisLabel": "progress of the reaction",
  "levels": "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level",
  "curve": "smooth unlabeled curve joining the levels, no hump",
  "style": "clean textbook energy diagram"
 }
}
A rising temperature. KEY
A falling temperature.
A perfectly steady temperature.
Nothing can be predicted from an energy diagram.
THM-022 · medium · application · seq 12 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Two exothermic reactions are drawn on one shared energy scale in diagrams A and B. Which reaction releases more energy?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level and flat products level with a SMALL vertical gap, products below reactants, smooth unlabeled joining cu… · style: "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B" · sharedScale: true
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level and flat products level with a SMALL vertical gap, products below reactants, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level and flat products level with a LARGE vertical gap, products below reactants, smooth unlabeled joining curve, no hump"
   }
  ],
  "style": "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B",
  "sharedScale": true
 }
}
Reaction B KEY
Reaction A
Both release the same energy
It cannot be compared from the diagrams
THM-023 · medium · application · seq 13 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Study panels A, B, C, and D — four tries at drawing an EXOTHERMIC reaction's energy diagram. Which try is free of drawing errors?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat labeled reactants level, flat labeled products level BELOW it, one smooth joining curve, but the gap is labeled 'energy … · style: "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere" · sharedFeatures: "every panel is drawn with its vertical axis labeled 'energy'"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat labeled reactants level, flat labeled products level BELOW it, one smooth joining curve, but the gap is labeled 'energy absorbed'"
   },
   {
    "panel": "B",
    "description": "flat labeled reactants level, flat labeled products level ABOVE it, one smooth joining curve, gap labeled 'energy released'"
   },
   {
    "panel": "C",
    "description": "two labeled levels that SLOPE steadily downward instead of lying flat, joined end to end, gap labeled 'energy released'"
   },
   {
    "panel": "D",
    "description": "flat labeled reactants level, flat labeled products level BELOW it, one smooth joining curve, gap marked and labeled 'energy released'"
   }
  ],
  "style": "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere",
  "sharedFeatures": "every panel is drawn with its vertical axis labeled 'energy'"
 }
}
Panel D KEY
Panel A
Panel B
Panel C
THM-023 · medium · application · seq 14 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Look at the drawn energy diagram of an EXOTHERMIC reaction. Exactly one thing about it is drawn incorrectly. What is it?
FIGURE (energy-diagram · stimulus) — yAxisLabel: "energy" · xAxisLabel: "progress of the reaction" · levels: "labeled reactants line on the left and labeled products line on the right, the products line ending clearly lower — but BOTH lines SLOPE steadily downward i… · curve: "one smooth unlabeled curve joining the two sloping lines, no hump" · gap: "marked and labeled 'energy released'" · style: "clean textbook energy diagram drawn as a student's answer; the sloping levels are the flaw"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "energy",
  "xAxisLabel": "progress of the reaction",
  "levels": "labeled reactants line on the left and labeled products line on the right, the products line ending clearly lower — but BOTH lines SLOPE steadily downward instead of lying flat",
  "curve": "one smooth unlabeled curve joining the two sloping lines, no hump",
  "gap": "marked and labeled 'energy released'",
  "style": "clean textbook energy diagram drawn as a student's answer; the sloping levels are the flaw"
 }
}
The levels slope — reactant and product energies must be drawn as flat levels. KEY
The gap should be labeled 'energy absorbed' for this case.
The products level should end higher than the reactants level.
The diagram needs a second curve joining the levels.
THM-024 · medium · application · seq 15 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Classify the reaction shown by the thermochemical equation 2C₄H₁₀ + 13O₂ → 8CO₂ + 10H₂O + energy.
Exothermic KEY
Endothermic
Neither — an equation with so many molecules cannot be classified
It cannot be classified without knowing what the substances are
THM-024 · medium · application · seq 16 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Octane in gasoline burns exothermically. Which thermochemical equation writes the energy term on the correct side?
2C₈H₁₈ + 25O₂ → 16CO₂ + 18H₂O + energy KEY
2C₈H₁₈ + 25O₂ + energy → 16CO₂ + 18H₂O
2C₈H₁₈ + 25O₂ + energy → 16CO₂ + 18H₂O + energy
2C₈H₁₈ + 25O₂ → 16CO₂ + 18H₂O
THM-018 · hard · transfer · seq 17 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reaction that absorbs energy runs inside a double-walled bottle that blocks transfer with the outside. The mixture inside grows steadily colder for as long as the reaction keeps going. What is supplying the reaction's energy?
The mixture's own energy — draining it is why the mixture keeps getting colder. KEY
Nothing — once sealed in, the reaction no longer needs an energy supply.
The chill it creates — the reaction runs on its own coldness.
The bottle's walls, which conduct plenty of energy inward.
THM-021 · hard · transfer · seq 18 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A student says a sparkler's shower of heat and light comes 'from bonds in its coating snapping apart and freeing their energy.' Which correction fixes the claim?
Snapping bonds apart absorbs energy — the shower is the surplus released as the products' new bonds form. KEY
No correction is needed — the coating's bonds really do free their energy by snapping.
The correction is that both snapping and forming free energy together.
The correction is that the sparkler pulls its energy in from the cool evening around it.
THM-022 · hard · transfer · seq 19 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
While a mixture reacts in a tall vessel, the dish supporting the vessel grows cold. Which of the two diagrams shown, A or B, matches the reaction?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level on the left, flat products level on the right sitting clearly ABOVE it, smooth unlabeled joining curve, … · style: "two clean textbook energy diagrams side by side, boxes labeled A and B"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly ABOVE it, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly BELOW it, smooth unlabeled joining curve, no hump"
   }
  ],
  "style": "two clean textbook energy diagrams side by side, boxes labeled A and B"
 }
}
Diagram A KEY
Diagram B
Both diagrams
Neither diagram
THM-024 · hard · transfer · seq 20 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
While a reaction runs, the tabletop beneath its flask grows warm. On which side of the reaction's thermochemical equation must the energy term be written?
On the product side. KEY
On the reactant side.
On both sides at once.
On neither side — temperature changes are never written into an equation.
THM-023 · medium · application · seq 21 · authored:U12-G2 stage 2 (fresh FRQ instance; THM-023 capstone production pattern — stem template, rubric split, and model-answer form mirror the pool 18/20 gate productions) · frq
Copper carbonate powder decomposing into copper oxide and a colorless gas in a heated test tube is an endothermic process. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Copper carbonate powder decomposing into copper oxide and a colorless gas in a heated test tube is an endothermic process. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Part a. Copper carbonate powder decomposing into copper oxide and a colorless gas in a heated test tube is an endothermic process. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Model: A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly HIGHER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy absorbed'.
Full model answer. A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly HIGHER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy absorbed'.

Form D

THM-017 · easy · recall · seq 1 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A mixture reacts inside a stoppered jar. Which observation shows the process is exothermic?
A thermometer taped to the outside of the jar climbs while the reaction runs. KEY
A thermometer taped to the outside of the jar drops while the reaction runs.
Fine solid grains settle out of the mixture while the reaction runs.
The jar's stopper lifts as gas builds up inside.
THM-018 · easy · recall · seq 2 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reacting paste sits in a plastic tray, and the tray beneath it goes cold. Which statement describes the energy flow?
The paste absorbs energy from the tray. KEY
The paste releases energy into the tray.
The paste leaks coldness down into the tray.
Nothing is transferred — the tray only seems cold next to the warm room.
THM-019 · easy · recall · seq 3 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Which statement about bonded atoms and the same atoms fully separated is correct?
The bonded atoms sit at lower energy, and separating them always requires an energy input. KEY
The bonded atoms sit at higher energy, and separating them always requires an energy input.
The bonded atoms sit at lower energy, and separating them releases the difference.
The bonded and separated states sit at the same energy, so separation is free.
THM-020 · easy · recall · seq 4 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Which option pairs a bond process with the correct energy direction?
Forming a bond — releases energy. KEY
Forming a bond — requires an energy input.
Forming a bond — neither absorbs nor releases energy.
Breaking a bond — releases energy.
THM-017 · medium · application · seq 5 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A student watches a reacting mixture warm its beaker and says the mixture must be 'soaking up heat from the room, which is why the glass feels warm.' Which correction fixes the claim?
The mixture is releasing energy — the warm glass shows energy flowing out of the system into the beaker and the bench. KEY
Nothing needs correcting — a warm beaker really does show the mixture absorbing energy from the room.
The mixture is creating fresh energy out of nothing as it reacts, warming everything nearby.
The warmth means the mixture has stopped exchanging energy with the beaker.
THM-018 · medium · application · seq 6 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A dish of reacting chemicals stands on a window sill, and the sill beneath it cools noticeably. Classify the process, with the direction of energy flow.
Endothermic — the reaction is taking energy in from the sill beneath it. KEY
Exothermic — the reaction is giving energy out to the sill beneath it.
Endothermic — the reaction is giving energy out to the sill beneath it.
Exothermic — the reaction is taking energy in from the sill beneath it.
THM-019 · medium · application · seq 7 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Inside a test chamber, an ultraviolet lamp splits molecules of a test gas into fragments — but only while the lamp is on. Why does switching the lamp off end the splitting?
Each bond that breaks needs an energy input, and the ultraviolet light is the only supply. KEY
The splitting releases energy, and the lamp is needed to carry that energy away.
The bonds would break on their own eventually; the lamp merely speeds this up.
The lamp merely holds the fragments apart once they split, adding no energy to the molecules themselves.
THM-020 · medium · application · seq 8 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
In a materials lab, loose atoms sprayed onto a plate bond into a solid coating, and the plate's sensor registers energy arriving the whole time the coating forms. Which statement explains the arriving energy?
Forming each new bond releases energy — the drop from separated to bonded leaves the atoms. KEY
Bonds in the spray break as the atoms land, letting their stored energy out.
The plate generates the energy itself as the arriving atoms strike and press against its surface.
The sensor is misreading pressure — bonding atoms into a solid leaves energy totally untouched.
THM-021 · medium · application · seq 9 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
An engineer needs a reaction to keep a self-heating meal pouch hot. Reaction 1: the energy involved in breaking the reactants' bonds is larger than the energy involved in forming the products' bonds. Reaction 2: the comparison is reversed. Which reaction should the engineer pick, and why?
Reaction 2 — its surplus from bond forming is released into the meal. KEY
Reaction 1 — the extra bond breaking pours out the most energy.
Either reaction — every reaction gives out energy while it runs.
Neither — a reaction can only warm itself, never anything around it.
THM-021 · medium · application · seq 10 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reaction runs in a dish on a hot plate that feeds it energy; lifted off the plate, the mixture grows colder and colder while the reaction continues. Which comparison must hold for this reaction?
Breaking the reactants' bonds requires more energy than forming the products' bonds releases. KEY
Forming the products' bonds releases more energy than breaking the reactants' bonds requires.
Breaking the reactants' bonds releases more energy than forming the products' bonds requires.
The two amounts are exactly equal, so the hot plate's energy goes unused.
THM-022 · medium · application · seq 11 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reaction has the energy diagram shown. While it runs, what will a thermometer standing in the liquid bath around the reaction flask read?
FIGURE (energy-diagram · stimulus) — yAxisLabel: "energy" · xAxisLabel: "progress of the reaction" · levels: "flat labeled reactants level on the left; flat labeled products level on the right, clearly HIGHER than the reactants level" · curve: "smooth unlabeled curve joining the levels, no hump" · style: "clean textbook energy diagram"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "energy",
  "xAxisLabel": "progress of the reaction",
  "levels": "flat labeled reactants level on the left; flat labeled products level on the right, clearly HIGHER than the reactants level",
  "curve": "smooth unlabeled curve joining the levels, no hump",
  "style": "clean textbook energy diagram"
 }
}
A falling temperature. KEY
A rising temperature.
A steady, unchanged temperature.
A reading that cannot be predicted from the diagram.
THM-022 · medium · application · seq 12 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
On a single shared energy scale, diagrams A and B show two reactions that both absorb energy. Which one absorbs more?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level and flat products level with a LARGE vertical gap, products above reactants, smooth unlabeled joining cu… · style: "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B" · sharedScale: true
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level and flat products level with a LARGE vertical gap, products above reactants, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level and flat products level with a SMALL vertical gap, products above reactants, smooth unlabeled joining curve, no hump"
   }
  ],
  "style": "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B",
  "sharedScale": true
 }
}
Reaction A KEY
Reaction B
They absorb equal amounts
The two cannot be compared
THM-023 · medium · application · seq 13 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
The figure holds four candidate energy diagrams, A to D, for an ENDOTHERMIC reaction. Which candidate is drawn correctly?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat labeled reactants level, flat labeled products level ABOVE it, one smooth joining curve, gap marked and labeled 'energy … · style: "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere" · sharedFeatures: "every panel is drawn with its vertical axis labeled 'energy'"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat labeled reactants level, flat labeled products level ABOVE it, one smooth joining curve, gap marked and labeled 'energy absorbed'"
   },
   {
    "panel": "B",
    "description": "two flat labeled levels drawn at exactly the same height, joined by a straight line, no gap marked"
   },
   {
    "panel": "C",
    "description": "flat labeled reactants level, flat labeled products level ABOVE it, one smooth joining curve, but the gap is labeled 'energy released'"
   },
   {
    "panel": "D",
    "description": "flat labeled reactants level, flat labeled products level BELOW it, one smooth joining curve, gap labeled 'energy absorbed'"
   }
  ],
  "style": "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere",
  "sharedFeatures": "every panel is drawn with its vertical axis labeled 'energy'"
 }
}
Panel A KEY
Panel B
Panel C
Panel D
THM-023 · medium · application · seq 14 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
The energy diagram drawn in the figure is meant to show an ENDOTHERMIC reaction, but it contains a single mistake. What is the mistake?
FIGURE (energy-diagram · stimulus) — yAxisLabel: "energy" · xAxisLabel: "progress of the reaction" · levels: "flat labeled reactants level on the left; flat labeled products level on the right, clearly HIGHER than the reactants level" · curve: "smooth unlabeled curve joining the levels, no hump" · style: "clean textbook energy diagram drawn as a student's answer; axis and level labels present; the missing gap mark is the flaw" · gap: "no gap marked or labeled anywhere"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "energy",
  "xAxisLabel": "progress of the reaction",
  "levels": "flat labeled reactants level on the left; flat labeled products level on the right, clearly HIGHER than the reactants level",
  "curve": "smooth unlabeled curve joining the levels, no hump",
  "style": "clean textbook energy diagram drawn as a student's answer; axis and level labels present; the missing gap mark is the flaw",
  "gap": "no gap marked or labeled anywhere"
 }
}
The energy gap between the two levels is not marked or labeled. KEY
The products level should sit below the reactants level for this case.
The levels are wrongly drawn flat — they should climb toward the products.
The single smooth curve is an error — the levels should not be joined at all.
THM-024 · medium · application · seq 15 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Classify the reaction shown by the thermochemical equation 2CH₃OH + 3O₂ → 2CO₂ + 4H₂O + energy.
Exothermic KEY
Endothermic
Neither — the energy term belongs to neither side
It cannot be classified, because no flame is mentioned
THM-024 · medium · application · seq 16 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Ethyne welding gas burns exothermically. Which thermochemical equation writes the energy term on the correct side?
2C₂H₂ + 5O₂ → 2H₂O + 4CO₂ + energy KEY
2C₂H₂ + 5O₂ + energy → 2H₂O + 4CO₂
2C₂H₂ + 5O₂ + energy → 2H₂O + 4CO₂ + energy
2C₂H₂ + 5O₂ → 2H₂O + 4CO₂
THM-018 · hard · transfer · seq 17 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
An endothermic reaction runs in a lidded ceramic pot that insulates it almost perfectly. The temperature of the reacting mixture drops and drops while the reaction runs. Where does the absorbed energy come from?
From the mixture itself — the reaction keeps drawing the mixture's own energy down. KEY
From nowhere — absorbing reactions only need energy when they start.
From the cold that collects inside the pot.
From the pot's ceramic walls, which pass energy through freely.
THM-021 · hard · transfer · seq 18 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
'A burning splint pours out heat because its bonds are breaking and emptying their energy,' writes a student. Which correction fixes the claim?
Breaking bonds takes energy in — the splint's heat is the surplus given out as the products' new bonds form. KEY
No correction is needed — bonds empty their energy whenever they break.
The heat comes from breaking and forming together, since each step gives out its own share of energy.
The heat comes from the splint soaking energy in from the flame around it.
THM-022 · hard · transfer · seq 19 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reaction runs in a beaker, and the tabletop under it becomes warm to the touch. Diagrams A and B are shown. Which diagram matches the reaction?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level on the left, flat products level on the right sitting clearly ABOVE it, smooth unlabeled joining curve, … · style: "two clean textbook energy diagrams side by side, boxes labeled A and B"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly ABOVE it, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly BELOW it, smooth unlabeled joining curve, no hump"
   }
  ],
  "style": "two clean textbook energy diagrams side by side, boxes labeled A and B"
 }
}
Diagram B KEY
Diagram A
Both diagrams
Neither diagram
THM-024 · hard · transfer · seq 20 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reaction's thermochemical equation shows the word 'energy' with the products. A beaker of this reacting mixture stands on a wooden board. What happens to the board's temperature?
It rises — the reaction releases energy into its surroundings. KEY
It falls — the reaction absorbs energy from the board.
It stays constant — the energy term only balances the equation's atoms.
It falls at first, then rises once the energy term changes sides.
THM-023 · medium · application · seq 21 · authored:U12-G2 stage 2 (fresh FRQ instance; THM-023 capstone production pattern — stem template, rubric split, and model-answer form mirror the pool 18/20 gate productions) · frq
Ethanol burning in a spirit burner is an exothermic process. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Ethanol burning in a spirit burner is an exothermic process. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Part a. Ethanol burning in a spirit burner is an exothermic process. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Model: A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly LOWER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy released'.
Full model answer. A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly LOWER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy released'.

Form E

THM-017 · easy · recall · seq 1 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Which observation is evidence that a reaction in an open dish is exothermic?
The rim of the dish becomes noticeably warm while the reaction runs. KEY
The rim of the dish becomes noticeably cool while the reaction runs.
A soft fizzing sound comes from the dish while the reaction runs.
The mixture froths up toward the rim of the dish.
THM-018 · easy · recall · seq 2 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
While a reaction runs in a flask, the clamp holding the flask turns cold. Which statement describes the energy flow?
The reacting mixture absorbs energy from the flask and the clamp. KEY
The reacting mixture releases energy to the flask and the clamp.
The reacting mixture sends coldness out through the glass into the clamp.
No energy moves — metal clamps always feel cold.
THM-019 · easy · recall · seq 3 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Bromine gas contains Br₂ molecules. Which statement compares a Br₂ molecule with its two separated atoms?
The molecule sits lower in energy, so splitting it into atoms costs an energy input. KEY
The molecule sits higher in energy, so splitting it into atoms costs an energy input.
The molecule sits lower in energy, so splitting it into atoms pays energy out.
The molecule and its separated atoms sit at the same energy, so the split involves no energy at all.
THM-020 · easy · recall · seq 4 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Which of these changes releases energy?
Two separate atoms joining into a bonded molecule. KEY
A bonded molecule being pulled apart into two separate atoms.
Both changes — joining and pulling apart each release energy.
Neither change — energy is only released when a substance burns.
THM-017 · medium · application · seq 5 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
In a class demonstration, a spoonful of powder reacts in a dish and the desktop around the dish grows warm. Identify the system in this exothermic process, and state the direction of the energy flow.
The reacting powder is the system, and it releases energy to the dish and the desktop. KEY
The desktop is the system, and it feeds energy into the reacting powder.
The reacting powder is the system, and it draws energy in from the desk and the dish.
Energy moves equally in both directions, so neither the powder nor the desk changes overall.
THM-018 · medium · application · seq 6 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A jar of reacting liquid rests on a cork mat, and the mat under it turns cold. Classify the process, and give the direction of the energy flow.
Endothermic — energy flows out of the mat and jar into the reacting liquid. KEY
Exothermic — energy flows out of the reacting liquid into the mat and jar.
Endothermic — energy flows out of the reacting liquid into the mat and jar.
Exothermic — energy flows out of the mat and jar into the reacting liquid.
THM-019 · medium · application · seq 7 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A student claims that molecules eventually fall apart on their own, 'because bonds wear out with age — no energy needed.' Which correction fixes the claim?
A bond stays intact until energy is supplied from outside — breaking one always costs an energy input. KEY
The claim is right as written — bonds really do loosen and split without any energy.
The claim only needs one fix: falling apart gives out energy instead of costing it.
Bonds can never be broken, however much energy is supplied.
THM-020 · medium · application · seq 8 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
As a new solid forms in a reacting mixture, every pair of atoms that bonds gives off a little energy. Which statement says where that energy comes from?
The atoms drop from the separated state to the lower bonded state, and the difference is released. KEY
It was stored inside each new bond beforehand and leaks out slowly afterwards.
It appears from nothing at the instant of bonding.
It is drawn out of the surroundings and immediately handed back.
THM-021 · medium · application · seq 9 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
In a certain reaction, the energy involved in forming the products' bonds is smaller than the energy involved in breaking the reactants' bonds. Classify the reaction.
Endothermic KEY
Exothermic
Neither — the difference is too small to matter either way
It cannot be classified from bond energies alone
THM-021 · medium · application · seq 10 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A mixture reacting in a small flask makes the flask's walls grow steadily warmer until the reaction ends. Which comparison of bond energies must hold?
Forming the products' bonds releases more energy than breaking the reactants' bonds requires. KEY
Breaking the reactants' bonds requires more energy than forming the products' bonds releases.
Breaking the reactants' bonds releases more energy than forming the products' bonds requires.
The two amounts are exactly equal, so the walls warm without any surplus.
THM-022 · medium · application · seq 11 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
The diagram shows the energy of a reaction across its course. What happens in the room around the reaction vessel while the reaction runs?
FIGURE (energy-diagram · stimulus) — yAxisLabel: "energy" · xAxisLabel: "progress of the reaction" · levels: "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level" · curve: "smooth unlabeled curve joining the levels, no hump" · style: "clean textbook energy diagram"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "energy",
  "xAxisLabel": "progress of the reaction",
  "levels": "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level",
  "curve": "smooth unlabeled curve joining the levels, no hump",
  "style": "clean textbook energy diagram"
 }
}
It warms. KEY
It cools.
It first cools, then warms back to where it started.
It is unaffected — energy diagrams say nothing about the room.
THM-022 · medium · application · seq 12 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Diagrams A and B show two exothermic reactions on the same energy scale. Which reaction releases LESS energy?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level and flat products level with a SMALL vertical gap, products below reactants, smooth unlabeled joining cu… · style: "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B" · sharedScale: true
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level and flat products level with a SMALL vertical gap, products below reactants, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level and flat products level with a LARGE vertical gap, products below reactants, smooth unlabeled joining curve, no hump"
   }
  ],
  "style": "two clean textbook energy diagrams side by side on one shared vertical scale, boxes labeled A and B",
  "sharedScale": true
 }
}
Reaction A KEY
Reaction B
They release equal amounts
The diagrams cannot settle it
THM-023 · medium · application · seq 13 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Panels A through D present four versions of an EXOTHERMIC reaction's energy diagram. Which version obeys every drawing convention?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "two labeled levels that SLOPE steadily downward instead of lying flat, joined end to end, gap labeled 'energy released'"}, {"… · style: "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere" · sharedFeatures: "every panel is drawn with its vertical axis labeled 'energy'"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "two labeled levels that SLOPE steadily downward instead of lying flat, joined end to end, gap labeled 'energy released'"
   },
   {
    "panel": "B",
    "description": "flat labeled reactants level, flat labeled products level BELOW it, one smooth joining curve, gap marked and labeled 'energy released'"
   },
   {
    "panel": "C",
    "description": "flat labeled reactants level, flat labeled products level ABOVE it, one smooth joining curve, gap labeled 'energy absorbed'"
   },
   {
    "panel": "D",
    "description": "two flat labeled levels drawn at exactly the same height, joined by a level line, no gap marked"
   }
  ],
  "style": "four clean textbook energy diagrams in one figure, boxes labeled A to D, no humps anywhere",
  "sharedFeatures": "every panel is drawn with its vertical axis labeled 'energy'"
 }
}
Panel B KEY
Panel A
Panel C
Panel D
THM-023 · medium · application · seq 14 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
In the figure, an EXOTHERMIC reaction's energy diagram has one flaw in how it is drawn. Identify the flaw.
FIGURE (energy-diagram · stimulus) — yAxisLabel: "(the vertical axis is drawn but carries NO label)" · xAxisLabel: "progress of the reaction" · levels: "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level" · curve: "smooth unlabeled curve joining the levels, no hump" · gap: "marked and labeled 'energy released'" · style: "clean textbook energy diagram drawn as a student's answer; the unlabeled vertical axis is the flaw"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram",
  "yAxisLabel": "(the vertical axis is drawn but carries NO label)",
  "xAxisLabel": "progress of the reaction",
  "levels": "flat labeled reactants level on the left; flat labeled products level on the right, clearly LOWER than the reactants level",
  "curve": "smooth unlabeled curve joining the levels, no hump",
  "gap": "marked and labeled 'energy released'",
  "style": "clean textbook energy diagram drawn as a student's answer; the unlabeled vertical axis is the flaw"
 }
}
The vertical axis is missing its 'energy' label. KEY
The gap label should read 'energy absorbed'.
The products level is on the wrong side of the diagram.
The smooth curve should be replaced by a straight vertical arrow between the levels.
THM-024 · medium · application · seq 15 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Classify the reaction shown by the thermochemical equation 2Ag₂O + energy → 4Ag + O₂.
Endothermic KEY
Exothermic
Neither — a decomposition has no energy direction
It cannot be classified from the equation alone
THM-024 · medium · application · seq 16 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
Propene fuel gas burns exothermically. Which thermochemical equation writes the energy term on the correct side?
2C₃H₆ + 9O₂ → 6CO₂ + 6H₂O + energy KEY
2C₃H₆ + 9O₂ + energy → 6CO₂ + 6H₂O
2C₃H₆ + 9O₂ + energy → 6CO₂ + 6H₂O + energy
2C₃H₆ + 9O₂ → 6CO₂ + 6H₂O
THM-018 · hard · transfer · seq 17 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reacting mixture sits sealed inside a foam shipping chest that supplies it nothing. The mixture's thermometer falls steadily while its endothermic reaction runs. What is the reaction's energy source?
The mixture itself — the reaction drains the mixture's own energy, which is why the reading keeps falling. KEY
It has none and needs none — endothermic reactions absorb no energy while sealed away.
The coldness building up inside the chest.
The foam walls, which soak up warmth outside and pass it inward.
THM-021 · hard · transfer · seq 18 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A student explains a kerosene lamp's warmth as 'the fuel's bonds breaking apart and releasing the energy they hold.' Which correction fixes the claim?
Breaking the fuel's bonds costs energy — the warmth is the surplus released as new bonds form. KEY
No correction is needed — fuels release their energy by their bonds breaking apart.
The warmth comes from both bond breaking and bond forming releasing energy side by side as the fuel burns.
The warmth comes from the lamp gathering up energy from the cool room and concentrating it.
THM-022 · hard · transfer · seq 19 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
A reacting pouch inside a lunchbox chills the box around it. Diagrams A and B are shown. Which diagram matches the reaction in the pouch?
FIGURE (energy-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "flat reactants level on the left, flat products level on the right sitting clearly BELOW it, smooth unlabeled joining curve, … · style: "two clean textbook energy diagrams side by side, boxes labeled A and B"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "energy-diagram-panels",
  "panels": [
   {
    "panel": "A",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly BELOW it, smooth unlabeled joining curve, no hump"
   },
   {
    "panel": "B",
    "description": "flat reactants level on the left, flat products level on the right sitting clearly ABOVE it, smooth unlabeled joining curve, no hump"
   }
  ],
  "style": "two clean textbook energy diagrams side by side, boxes labeled A and B"
 }
}
Diagram B KEY
Diagram A
Both diagrams
Neither diagram
THM-024 · hard · transfer · seq 20 · authored:U12-G2 stage 2 (fresh instance per blueprint case_target) · mcq4
While a reaction runs, its surroundings steadily cool. On which side of the reaction's thermochemical equation must its energy term sit?
On the reactant side. KEY
On the product side.
On whichever side has fewer substances.
On both sides, to keep the equation balanced.
THM-023 · medium · application · seq 21 · authored:U12-G2 stage 2 (fresh FRQ instance; THM-023 capstone production pattern — stem template, rubric split, and model-answer form mirror the pool 18/20 gate productions) · frq
Cooking an egg in a hot pan is an endothermic process: the egg's contents absorb energy from the pan the whole time they are changing. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Cooking an egg in a hot pan is an endothermic process: the egg's contents absorb energy from the pan the whole time they are changing. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Part a. Cooking an egg in a hot pan is an endothermic process: the egg's contents absorb energy from the pan the whole time they are changing. On paper, sketch the energy diagram for this process: label the axis, both levels, and the energy gap. Then select Continue to compare your sketch with the model answer.
Model: A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly HIGHER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy absorbed'.
Full model answer. A diagram with a vertical axis labeled 'energy'. A flat level labeled 'reactants' sits on the left, and a flat level labeled 'products' sits on the right, clearly HIGHER than the reactants level. One smooth curve joins the levels. The vertical gap between the levels is marked and labeled 'energy absorbed'.

End of Topic Test: Specific heat capacity and q = mcΔT & Calorimetry (u12-t3 · 5 forms × 22 items · 110 total)

David's notes for James:
full notes file
# u12-t3 — notes/queries from David's side (U12-G3)

1. FRQ ALLOCATION - frq_per_form = 2 (confirm the composition): the wave's calc-heavy 2-3-FRQ directive APPLIES - calorimetry is NAMED in QB-v2 sec.4's calculation-heavy list and this scope is the unit's calculation core (6 of 11 lessons quant; 12 of your 33 pool seeds numeric). Your seed file's frq_per_form=1 baseline was OVERRIDDEN per the wave brief (recorded adjudication). COUNT = 2, not 3 (one FRQ per production construct, U7-G2 precedent): FRQ1 (seq 21) = the THM-031 substituted-formula rearrangement production - (a) make the named unknown the subject of q = mc-Delta-T in symbols, (b) execute with the 5-line scaffold, (c) one-step in-scope interpretation; the subject ROTATES across forms (c/m/Delta-T). FRQ2 (seq 22, terminal capstone) = the THM-035 two-substance balance - (a) each substance's own temperature change, (b) the water's heat first, (c) the written balance 'heat lost = heat gained' EXPANDED with m x c x Delta-T before substitution (R15), then make-the-subject and solve. THM-034's measure-a-process routine is NOT a third construct (computationally one forward q on the water + a direction word): it keeps a numeric ENTRY row (seq 15) + a direction MCQ (seq 16) instead. D5: min(20, 6 x 11) = 20 objective rows, no scaling; your target_size=20 concurs.
2. WATER AS THE REGISTER-LOCKED WORKING SUBSTANCE (recorded adjudication, confirm): 'water' appears on 71 of 110 items and is excused by a recorded, slot-enumerated family enforced by the gate-local wrapper (the shared validator itself was never weakened). It is unavoidable by taught course design: THM-032/033/034/035 rule lines lock the part name 'measured mass of water' and the compute-the-water routine; THM-034's specNotes mandate the verbatim in-stem clause '(c of water = 4.18 J/(g.degC))' on every measure-the-process stem; THM-030/031's taught calculation runs on water; THM-035's final-T design keeps BOTH substances water so c divides out (metal+water final-T algebra excluded as AP territory). Substance exclusivity is preserved for every OTHER material (fresh scenario materials globally unique, enforced by the untouched shared scans); nine recorded instance-free carrier words ride the family windows.
3. COFFEE-CUP APPARATUS NAMES (recorded adjudication, confirm): 'coffee-cup calorimeter' (THM-032's title + hook) and 'insulated foam cup' (a part name THM-032's specNotes require verbatim) are excused on the 11 calorimetry slots that name the apparatus (seq 13/15/19/22 rows). Neither token is a sample substance anywhere in the gate.
4. TEN TAUGHT SPECIFIC-HEAT CONSTANTS (recorded adjudication, confirm): 4.18 / 2.44 / 1.97 / 0.897 / 0.84 / 0.449 / 0.385 / 0.128 / 0.235 / 0.790 J/(g.degC) are taught constants mandated in student-facing text by the specs ('all c values real', supplied in-stem for every calculation row) and printed in the taught THM-026 table, so the freshness scan's numeric-vs-spec and cross-form lanes fire on every legitimate use. Excused by a recorded token family over the 29 slots that carry them; every scenario value (masses, readings, energies) remains fully scanned and globally unique - a stage-3 machine assertion proves every non-family number string is absent from all 11 scope lessons' spec text and unique to ONE (form,seq) across the whole bank.
5. REFERENCE-FIGURE MATERIAL RELIEF ON THE TABLE-READ ROW (A6 class, U01-G3 density-table precedent; confirm): every seq-4 item on every form displays the canonical THM-026 'Specific heat capacities' data-table verbatim, and the taught comparison routine IS 'read the table' (your seeds p3/p4 say 'Using the table'). Material NAMES read off a table that is on screen for every student on every form carry no instance signal on those items, so the seven table materials get scoped relief on the five seq-4 slots ONLY; measured VALUES still scan in full. The seq-17 inverse-comparison rows are abstract (no figure), so NO relief applies there - they use fresh material words.
6. SIG-FIG SENTENCE = ANSWER-FORMAT CONVENTION, NOT STRICT PROPAGATION (recorded adjudication A-U12G3-6, confirm): the appended significant-figure sentence states the required ANSWER FORMAT (it matches the display's declared sigFigs) - your own seed canon does the same (e.g. p27's 4-sf answer from a 4.5-degree change) and QB 3.7's exact-division doctrine means values are CHOSEN to divide exactly. sol's strict-propagation objections were resolved IN CONTENT: the new instruction sentence 'Treat the given values as exact.' now sits on every numeric-entry stem and the seq-18 comparison stems (recorded convention phrase), over-precise acceptedAlternates were stripped bank-wide (real defects), and whole-joule gradingNotes were clarified. Trailing-zero 3-sf displays (41800 / 7900 / 190 class) carry integer:true + a gradingNote recording the sigFigs adjudication.
7. NUMERIC-CONTRACT SPLIT (recorded stage-2 adjudication, U12-G1 seq-15 precedent; confirm): proportional rows 6/7 and bookkeeping row 14 are EXACT whole-joule arithmetic by spec design (THM-027/028 base energies supplied as data; THM-033 whole-joule bookkeeping) -> integer:true + 'Give your answer in joules.' with NO sig-fig sentence (your seeds p6/p9/p26 carry sig_figs_sentence_appended=false and concur) and PLAIN-LINE explanations (no 5-line scaffold - no formula is substituted). Calculation rows 10/11/15 keep the sig-fig sentence + the 5-line scaffold in feedback; the display value IS the graded value; unit lives in answer.unit.
8. THM-029 QUANT LESSON CARRIES NO NUMERIC ROW (recorded adjudication, confirm): the Delta-T-from-two-readings subtraction is EMBEDDED as the opening scaffold line of every seq-10 and seq-15 numeric (THM-030 rule line 2 makes it the forward routine's opening move), so a standalone two-reading subtraction row would double-count that production. THM-029's two rows carry its distinctive constructs instead (symbols/units recall at seq 2; the kg-to-g trap + which-quantity-differs at seq 9); your p13 subtraction seed is the gate's one spare.
9. NOTA-PATTERN SEED DISTRACTOR REPLACED (opportunistic rule, confirm): your p14 (form B seq 9, which-RHS-quantity-differs) carried the close-NOTA fourth option 'None of them - all three right-hand quantities are the same'. Replaced with the misconception-keyed 'Both m and Delta-T differ, because the two blocks absorb different amounts of energy' (working backwards from the energy difference). At sol QC the item's named metals (copper/aluminum) also had to go - copper's 0.385 sits verbatim in THM-030's worked example - so the blocks are now two UNNAMED metals at fresh values (72.0 g, 15.5 to 46.5 degC); the which-differs construct and your replaced-distractor slot are intact. Recorded in seed_placement.json.
10. SEED FRESHENINGS UNDER THE STRICT SEED RULING (dispositions to confirm): 32 of your 33 pool seeds placed (demo_curated[0..2] = pool[30..32], dual refs; form A 20 cells incl. FRQ2 from p30, form B 10 incl. FRQ2 from p31, form C 2), 1 spare (p13). Colliding seed instances were freshened IN CONTENT, never excused: p6 (A#6) 18-to-38 window collided with THM-030's fluency spoon -> fresh window, then the whole value set reminted at stage 3 (310/930 g, 25916/77748 J) when 250 g / 20900 J proved spec-saturated; p9 (A#7) 15-degree readings collided with THM-030 WE / THM-028 WE0 / THM-035 fluency -> 230 g ethanol, 5612/28060 J, 10-vs-50 change pair kept; p11 (B#8) 'olive oil' would sit cross-seq against the seq-5 oil instance -> a flask of water (adjudicated lane), key logic unchanged; p19 (B#11) 8360 J + 200.0/20.0/30.0 saturate the corpus -> 240.0 g at 13.5 degC + 5016 J -> 18.5 degC, final-T construct kept; p30 (A#22 FRQ) revalued to 475.0 g bar 48.5->32.5 into 87.5 g water 24.5->32.5 with the COPPER 0.385 LANDING KEPT; p31 (B#22 FRQ) revalued to 555.0/185.0 g at 81.0/13.0 -> 64.0 degC with the 3-to-1 c-divides-out design kept; ~15 further seed value freshenings on form A are itemized in fix_log.md (every reminted value exact-division checked and corpus-clean).
11. WORDED OPERATOR TAGS ON THE SYMBOLIC REARRANGEMENT OPTIONS (recorded seed edit + gate convention, confirm): your p20 (A#12) and the fresh seq-12 items present four symbolic rearrangement forms as options; our shared duplicate-option normalizer strips division/multiplication signs, which makes bare symbolic forms collide as duplicate option texts. Each option now carries a neutral worded tag ('- the energy divided by the two knowns together', etc.) describing its own expression - no correctness cue, key logic and misconception space unchanged.
12. SEQ-18 REWORK (disclosure): stage 2 had cloned water-vs-copper two-product comparisons on every form, and copper is an own-lesson spec material of THM-030. Rebuilt with rotated partners at fresh exact values - A iron 700.0 g (11704 vs 11314.8 J), B granite 80.0 g (granite WINS 1200.8 vs 1003.2 J - the bigger-Delta-T-can-win case), C olive oil 105.0 g, D silver 145.0 g, E olive oil 165.0 g; the bigger-Delta-T-wins distractor is present everywhere and both c values are supplied in-stem.
13. BLIND-QC FIXES (disclosure): round 1 (gpt-5.6-sol blind role + gemini, all 110 items x 2 reviewers) scored 140/140 on the key-pick lane and 40 keyless numeric/FRQ slots per reviewer ALL graded match (three scientific-notation answers hand-verified equal to the keys); 4 hard fails, all the two-defensible idealization class -> fixed by stating the idealization ('leaks no heat', '(no heat leaks in or out, and the container itself soaks up none)') and replacing tied distractors. One round-2 catch was on MY fix: the A#16 replacement distractor was logically equivalent to the key (water-released = dissolving-absorbed) - rebuilt as the all-dissolving-is-exothermic misconception. A class sweep from a single reviewer catch: every form's seq-12 rearrangement subject now differs from its seq-21 FRQ subject (no within-form answer telegraphing). Rounds 3-4: 0 hard fails, 24/24 key picks.
14. SOL-QC FIXES (disclosure): authoritative gpt-5.6-sol loops 1-3 went 23 -> 2 -> 0 FAILs, all content-fixed: the seq-4 table caption stated the tested rule ('Lower value: the same energy warms the material further') - neutralized on every form; substitution-feedback leftovers after value remints (QB 3.9's recurrent class) swept (incl. D#22's model solve chain, whose stale coefficients coincidentally landed on the right answer); the A#22/C#22 FRQ model answers + rubrics now state the SYMBOLIC balance expansion before substituting (R15); idealization parentheticals unified; the sig-fig contract class resolved per the A-U12G3-6 note above. Final ledger: 110 pass / 0 fail (10 pass-with-minor notes recorded in solqc_report.md).
15. RECALL/PRODUCTION SAME-LESSON PAIRS (accepted class, disclosure): both round-4 blind reviewers flagged D#3 (THM-033 identity recall) as supplying the principle D#14 (THM-033 balance bookkeeping) uses - that pairing is the blueprint's own D6 arc (THM-033 holds 3 rows at the cap: identity recall, numeric bookkeeping, leak-accounting transfer), same for the seq-7/8 and seq-11/12 production+reasoning splits (instances disjoint). Recorded, no action.
16. BINDING INSTANCE RULE (course-wide, disclosure): zero fissile/weapons/dose framings; classroom-safe instances throughout (kettles, cooking pots, metal bars, dissolving solids, coffee-cup calorimeters). Re-swept at packaging with a deterministic token scan over forms_final.json AND this export body.
17. QC LEDGER (disclosure): deterministic validators 11/12 PASS as shipped (V-T6 numeric-realism PASSES with 30 live numeric slots) + gate-local adjudication wrapper VERDICT PASS exit 0 - V-T7's 2431 collision lines 100% covered by the three recorded slot-enumerated families + the A6 table relief + recorded convention phrases (0 uncovered; parity guard 2431/2431 MATCH; 9/9 wrapper negative probes); stage-3 content patching (51 seed-value freshenings + the seq-18 rework + gram kills) ran BEFORE any adjudication; blind = 4 rounds, 0 open hard fails, all FRQ/numeric cold answers graded match with justifications (frq_verdicts.json); sol authoritative loops 1-3 = 23 -> 2 -> 0 FAILs, subset raws verified to cover every requested item (no stale verdicts); 86 machine-logged patch ops across 5 waves (_patch_*_log.json) plus the point fixes recorded in fix_log.md.

Form A

THM-025 · easy · recall · seq 1 · seed:U12-G3.pool[0] (THM-025 gateItems, James) - VERBATIM (field mapping only) | blind-1 HARD fix: '1 J' was defensible as 0.897 rounded to 1 sf -> needs-the-mass misconception distractor · mcq4
Aluminum's specific heat capacity is 0.897 J/(g·°C). How much energy raises the temperature of 1 g of aluminum by 1 °C?
0.897 J KEY
4.18 J
Not enough information — the sample's total mass is missing.
8.97 J
THM-029 · easy · recall · seq 2 · authored:U12-G3 stage 2 (symbol meaning read — q; derived task idiom) · mcq4
In the heat equation q = mcΔT, what does q stand for, and in what unit is it measured?
The energy transferred as heat, measured in joules (J). KEY
The temperature change of the sample, measured in °C.
The specific heat capacity of the material, measured in J/(g·°C).
The mass of the sample, measured in grams (g).
THM-033 · easy · recall · seq 3 · seed:U12-G3.pool[24] (THM-033 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: 90/20 readings collide with spec text -> 82/23 (SEED RULING) | blind-1 HARD fix: leaks-no-heat idealization stated + loses-more distractor tied to the energy-vanish misconception · mcq4
An 82 °C stone is lowered into 23 °C water inside a sealed, insulated cooler that leaks no heat, and the two are left to exchange energy. Which statement is correct?
The stone loses exactly as much heat as the water gains. KEY
The water loses heat and the stone gains it.
The stone loses more heat than the water gains, because some heat always disappears during a transfer.
Both the stone and the water lose heat until each reaches 0 °C.
THM-026 · medium · application · seq 4 · seed:U12-G3.pool[4] (THM-026 gateItems, James) - VERBATIM (field mapping only) | sol-1: caption no longer states the tested rule (giveaway) | sol-1: pan no longer holds the water (thermal-coupling defect) — two separate equal-mass samples · mcq4
A cook warms an empty aluminum pan on one burner while an equal mass of water warms in a second container on another burner, and each happens to receive the same energy. Using the table, which shows the larger temperature change?
FIGURE (data-table · stimulus) — title: "Specific heat capacities" · columns: ["Material", "Specific heat capacity (J/(g·°C))"] · rows: [["water", "4.18"], ["ethanol", "2.44"], ["olive oil", "1.97"], ["aluminum", "0.897"], ["sand", "0.84"], ["iron", "0.449"], ["copper", "0.385"], ["lead", "0.… · caption: "Real specific heat capacities of common materials." · style: "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "data-table",
  "title": "Specific heat capacities",
  "columns": [
   "Material",
   "Specific heat capacity (J/(g·°C))"
  ],
  "rows": [
   [
    "water",
    "4.18"
   ],
   [
    "ethanol",
    "2.44"
   ],
   [
    "olive oil",
    "1.97"
   ],
   [
    "aluminum",
    "0.897"
   ],
   [
    "sand",
    "0.84"
   ],
   [
    "iron",
    "0.449"
   ],
   [
    "copper",
    "0.385"
   ],
   [
    "lead",
    "0.128"
   ]
  ],
  "caption": "Real specific heat capacities of common materials.",
  "style": "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
 }
}
The aluminum pan. KEY
The water.
Both change equally.
It cannot be predicted without knowing the stove's power.
THM-027 · medium · application · seq 5 · seed:U12-G3.pool[7] (THM-027 gateItems, James) - VERBATIM (field mapping only) · mcq4
Warming a full pot of soup takes three times the energy of warming a small bowl of the same soup through the same temperature change. What does that say about the masses?
The pot holds three times the bowl's mass. KEY
The pot holds nine times the bowl's mass.
The pot holds one third of the bowl's mass.
Nothing — energy needs do not depend on mass.
THM-027 · medium · application · seq 6 · seed:U12-G3.pool[6] (THM-027 gateItems, James) - FRESHENED (temperature window 18→38 °C re-minted to 46→66 °C: corpus collision with THM-030 fluency 18.0→38.0; masses + energies kept) | stage-3 freshen: 250/750 g + 20900/62700 J collide with spec text -> 310/930 g + 25916/77748 J (SEED RULING; x3 construct kept) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
Warming 310 g of water from 46 °C to 66 °C takes 25916 J. How much energy does warming 930 g of water from 46 °C to 66 °C take? Treat the given values as exact. Give your answer in joules.
Answer: 77748 J KEY
also accepted: 77,748 J, 77 748 J, 77748 J
wrongValueDiagnostics
[
 {
  "value": 25916,
  "misconception": "you kept the energy the same because the temperature change is the same — three times the mass needs three times the energy",
  "feedback": "This answer is wrong — 25916 J warms only the 310 g. Three times the grams need three times the shares: 3 × 25916 J = 77748 J."
 },
 {
  "value": 8638.67,
  "misconception": "you divided by three instead of multiplying — more mass needs more energy",
  "feedback": "This answer is wrong — dividing gives less energy for more water. Three times the mass needs three times the energy: 77748 J."
 }
]
feedback
{
 "keyExplanation": "Same material, same temperature change — only the mass differs. 930 g is three times 310 g. Three times the mass needs three times the energy: 3 × 25916 J = 77748 J.",
 "anticipatedWrong": [
  {
   "value": 25916,
   "misconception": "you kept the energy the same because the temperature change is the same — three times the mass needs three times the energy",
   "feedback": "This answer is wrong — 25916 J warms only the 310 g. Three times the grams need three times the shares: 3 × 25916 J = 77748 J."
  },
  {
   "value": 8638.67,
   "misconception": "you divided by three instead of multiplying — more mass needs more energy",
   "feedback": "This answer is wrong — dividing gives less energy for more water. Three times the mass needs three times the energy: 77748 J."
  }
 ]
}
THM-028 · medium · application · seq 7 · seed:U12-G3.pool[9] (THM-028 gateItems, James) - FRESHENED (windows 15→25/15→65 °C re-minted to 14→24/14→64 °C: 15.0/25.0 corpus collisions; mass + energies + the 10-vs-50 change pair kept) | stage-3 freshen: 200 g + 4880/24400 J collide with spec text -> 230 g + 5612/28060 J; 'g of ethanol from' spec gram reworded (SEED RULING; 10-vs-50 change pair kept) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
A 230 g sample of ethanol warms from 14 °C to 24 °C using 5612 J. How much energy does the same 230 g sample need to warm from 14 °C to 64 °C? Treat the given values as exact. Give your answer in joules.
Answer: 28060 J KEY
also accepted: 28,060 J, 28 060 J, 28060 J
wrongValueDiagnostics
[
 {
  "value": 14965.33,
  "misconception": "you scaled by the ratio of the final readings (64/24) — the energy follows the ratio of the CHANGES, not the finals",
  "feedback": "This answer is wrong — 64 and 24 are readings, not changes. The changes are 10 °C and 50 °C: five times the change, so 5 × 5612 J = 28060 J."
 },
 {
  "value": 5612,
  "misconception": "you kept the energy the same because the sample is the same — a bigger temperature change needs proportionally more energy",
  "feedback": "This answer is wrong — 5612 J pays for only a 10 °C change. A 50 °C change costs five shares: 28060 J."
 }
]
feedback
{
 "keyExplanation": "Same sample, so the mass and material are fixed — only the temperature CHANGE matters. The first change is 24 − 14 = 10 °C; the second is 64 − 14 = 50 °C — five times the change. Five times the change needs five times the energy: 5 × 5612 J = 28060 J.",
 "anticipatedWrong": [
  {
   "value": 14965.33,
   "misconception": "you scaled by the ratio of the final readings (64/24) — the energy follows the ratio of the CHANGES, not the finals",
   "feedback": "This answer is wrong — 64 and 24 are readings, not changes. The changes are 10 °C and 50 °C: five times the change, so 5 × 5612 J = 28060 J."
  },
  {
   "value": 5612,
   "misconception": "you kept the energy the same because the sample is the same — a bigger temperature change needs proportionally more energy",
   "feedback": "This answer is wrong — 5612 J pays for only a 10 °C change. A 50 °C change costs five shares: 28060 J."
  }
 ]
}
THM-028 · medium · application · seq 8 · seed:U12-G3.pool[10] (THM-028 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: 20/40/100 triple collides with spec text -> 19/39/99 (SEED RULING; x4 changes-ratio construct kept); 'of water is warmed' spec gram reworded | stage-3b: 39 shared with D#7 and 19 with E#8 -> 11->31 / 11->91 (x4 changes-ratio kept; 11 sits in the unscanned 0-12 band) | sol-1: distractor set re-minted for the 11->31/11->91 readings (the substituted feedbacks referenced stale arithmetic) · mcq4
The same kettle of water gets two warmings: on Monday from 11 °C to 31 °C, and on Tuesday from 11 °C to 91 °C. Tuesday's warming needs how many times Monday's energy?
Four times. KEY
About three times.
Sixteen times.
The same, because it is the same kettle of water.
THM-029 · medium · application · seq 9 · seed:U12-G3.pool[12] (THM-029 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: 0.250 kg option set collides with spec text -> 0.740 kg / 740 g (SEED RULING; kg->g trap kept); 'kg of water into a beaker' spec wording removed | stage-3b: 74.0 g option shared with D#22's 74.0 °C -> 0.940 kg / 940 g set · mcq4
A student measures out 0.940 kg of water and plans to use q = mcΔT. What value should the student substitute for m?
940 g KEY
0.940 g
94.0 g
9400 g
THM-030 · medium · application · seq 10 · seed:U12-G3.pool[15] (THM-030 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: 250.0 g + 20.0->60.0 collide with spec text -> 625.0 g + 41.0->57.0 (SEED RULING; q = 41800 J and the 3-sf integer contract kept) | stage-3b: 625.0 collides with THM-033 spec -> 800.0 g, 44.0->56.5 (q kept) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['41800.0'] · numeric
A kettle warms 800.0 g of water from 44.0 °C to 56.5 °C. How much energy does the water absorb, in J? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 3 significant figures.
Answer: 41800.0 J KEY
also accepted: 41,800 J, 41,800
wrongValueDiagnostics
[
 {
  "value": 188936.0,
  "misconception": "you used the final temperature instead of the temperature change — ΔT = 56.5 − 44.0 = 12.5 °C",
  "feedback": "This answer is wrong — 56.5 is a reading, not a change. ΔT = 12.5 °C, so q = 800.0 × 4.18 × 12.5 = 41,800 J."
 },
 {
  "value": 52.25,
  "misconception": "you left out the mass — all three quantities on the right multiply",
  "feedback": "This answer is wrong — 4.18 × 12.5 covers only one gram. Multiply by the 800.0 g as well: q = 41,800 J."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nm = 800.0 g\nc = 4.18 J/(g·°C)\nΔT = 56.5 − 44.0 = 12.5 °C\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 800.0 × 4.18 × 12.5\nq = 41,800 J\nWater's high specific heat capacity makes tens of thousands of joules a sensible size for warming a big kettle's worth of water through 12.5 °C.",
 "anticipatedWrong": [
  {
   "value": 188936.0,
   "misconception": "you used the final temperature instead of the temperature change — ΔT = 56.5 − 44.0 = 12.5 °C",
   "feedback": "This answer is wrong — 56.5 is a reading, not a change. ΔT = 12.5 °C, so q = 800.0 × 4.18 × 12.5 = 41,800 J."
  },
  {
   "value": 52.25,
   "misconception": "you left out the mass — all three quantities on the right multiply",
   "feedback": "This answer is wrong — 4.18 × 12.5 covers only one gram. Multiply by the 800.0 g as well: q = 41,800 J."
  }
 ]
}
THM-031 · medium · application · seq 11 · seed:U12-G3.pool[18] (THM-031 gateItems, James) - VERBATIM (field mapping only) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['0.1280', '.128'] · numeric
A 500.0 g fishing sinker absorbs 640 J of energy and warms by 10.0 °C. What is the metal's specific heat capacity, in J/(g·°C)? Treat the given values as exact. Give your answer to 3 significant figures.
Answer: 0.128 J/(g·°C) KEY
also accepted: 0.128 J/(g·°C)
wrongValueDiagnostics
[
 {
  "value": 1.28,
  "misconception": "you divided by the mass only — divide by both the mass and the temperature change",
  "feedback": "This answer is wrong — divide by m AND ΔT together: c = 640 ÷ (500.0 × 10.0) = 0.128 J/(g·°C)."
 },
 {
  "value": 64.0,
  "misconception": "you divided by the temperature change only — divide by both the mass and the temperature change",
  "feedback": "This answer is wrong — divide by m AND ΔT together: c = 640 ÷ (500.0 × 10.0) = 0.128 J/(g·°C)."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nq = 640 J\nm = 500.0 g\nΔT = 10.0 °C\nWrite down the equation:\nq = mcΔT\nMake c the subject:\nc = q ÷ (m × ΔT)\nSubstitute in the values, and calculate:\nc = 640 ÷ (500.0 × 10.0)\nc = 0.128 J/(g·°C)\nThat is the table value for lead — a very low specific heat capacity, which is why a small energy input warms the sinker so easily.",
 "anticipatedWrong": [
  {
   "value": 1.28,
   "misconception": "you divided by the mass only — divide by both the mass and the temperature change",
   "feedback": "This answer is wrong — divide by m AND ΔT together: c = 640 ÷ (500.0 × 10.0) = 0.128 J/(g·°C)."
  },
  {
   "value": 64.0,
   "misconception": "you divided by the temperature change only — divide by both the mass and the temperature change",
   "feedback": "This answer is wrong — divide by m AND ΔT together: c = 640 ÷ (500.0 × 10.0) = 0.128 J/(g·°C)."
  }
 ]
}
THM-031 · medium · application · seq 12 · seed:U12-G3.pool[20] (THM-031 gateItems, James) - FRESHENED (worded operator tags appended to the symbolic options: the shared normalizer strips ÷/×, making James's bare forms collide as duplicate option texts under V-T3 — recorded SEED-RULING edit, key logic + misconception space unchanged) · mcq4
A problem gives q, c, and ΔT and asks for the mass m. Which rearrangement of q = mcΔT is correct?
m = q ÷ (c × ΔT) — the energy divided by the two knowns together KEY
m = q × c × ΔT — the energy multiplied by the two knowns
m = (c × ΔT) ÷ q — the two knowns divided by the energy
m = q ÷ ΔT — the energy divided by the temperature change only
THM-032 · medium · application · seq 13 · seed:U12-G3.pool[21] (THM-032 gateItems, James) - VERBATIM (field mapping only) · mcq4
A student builds a calorimeter from a thin metal cup instead of an insulated foam cup, then runs an energy-releasing reaction in the water. What goes wrong with the measurement?
Energy escapes through the metal to the surroundings, so the water's temperature change reads too small. KEY
Energy builds up faster in the water, so the temperature change reads too large.
Nothing goes wrong, because the water still absorbs some of the energy.
The thermometer stops working inside a metal cup.
THM-033 · medium · application · seq 14 · seed:U12-G3.pool[26] (THM-033 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: 'iron block' seed material freed for the seq-18 comparison lane -> steel block (SEED RULING); container register aligned to 'well-insulated, sealed' (seq-14 wording lane, distinct from the seq-3 'sealed, insulated' lane) | blind-1: idealization parenthetical '(no heat leaks in or out)' added (reviewer idealization class) | sol-1: container declared non-absorbing (walls-absorption reading closed) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['4600.0'] · numeric
A hot steel block rests in cool water inside a well-insulated, sealed chest (no heat leaks in or out, and the container itself soaks up none) until both reach the same temperature. During the exchange the water gains 4600 J. How much heat did the steel block lose, in J? Treat the given values as exact. Give your answer in joules.
Answer: 4600.0 J KEY
also accepted: 4,600 J
wrongValueDiagnostics
[
 {
  "value": -4600,
  "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and 'lost' already carries the direction",
  "feedback": "This answer is wrong in form — give the size of the transfer: the steel block lost 4600 J."
 },
 {
  "value": 9200,
  "misconception": "you doubled the energy, counting it once leaving the block and once entering the water — it is the same 4600 J, transferred once",
  "feedback": "This answer is wrong — one transfer, counted from either end: the block lost exactly the 4600 J the water gained."
 }
]
feedback
{
 "keyExplanation": "The chest is insulated, so no energy escapes to anything else, and the heat lost by the hotter object equals the heat gained by the colder object. The water gained 4600 J, so the steel block lost exactly 4600 J — one transfer, counted from either end.",
 "anticipatedWrong": [
  {
   "value": -4600,
   "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and 'lost' already carries the direction",
   "feedback": "This answer is wrong in form — give the size of the transfer: the steel block lost 4600 J."
  },
  {
   "value": 9200,
   "misconception": "you doubled the energy, counting it once leaving the block and once entering the water — it is the same 4600 J, transferred once",
   "feedback": "This answer is wrong — one transfer, counted from either end: the block lost exactly the 4600 J the water gained."
  }
 ]
}
THM-034 · medium · application · seq 15 · seed:U12-G3.pool[27] (THM-034 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: 200.0 g + 20.0->24.5 collide with spec text -> 260.0 g + 21.2->26.2 (SEED RULING; wrong-m trap kept); spec-mirroring 'a solid dissolves in' wording replaced | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['5434.0'] · numeric
A 10.0 g scoop of a powdered solid is mixed into 260.0 g of water in a coffee-cup calorimeter, and the water warms from 21.2 °C to 26.2 °C. How much heat did the dissolving release, in J? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 4 significant figures.
Answer: 5434.0 J KEY
also accepted: 5,434 J, 5434 J
wrongValueDiagnostics
[
 {
  "value": 209,
  "misconception": "you used the solid's 10.0 g as m — the calorimeter reads the WATER, so the water's mass goes into q = mcΔT",
  "feedback": "This answer is wrong — the 10.0 g is the dissolving solid, not the absorber. Use the water's 260.0 g: q = 260.0 × 4.18 × 5.0 = 5,434 J."
 },
 {
  "value": 28474.16,
  "misconception": "you used the final temperature instead of the temperature change — ΔT = 26.2 − 21.2 = 5.0 °C",
  "feedback": "This answer is wrong — 26.2 is a reading, not a change. ΔT = 5.0 °C, so q = 5,434 J."
 },
 {
  "value": 1300,
  "misconception": "you left out c — every gram of water charges 4.18 J per degree",
  "feedback": "This answer is wrong — 260.0 × 5.0 skips the price per gram per degree. Multiply by 4.18: q = 5,434 J."
 }
]
feedback
{
 "keyExplanation": "The calorimeter measures the process through the WATER. For the water:\nm = 260.0 g (the water, not the 10.0 g solid)\nc = 4.18 J/(g·°C)\nΔT = 26.2 − 21.2 = 5.0 °C\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 260.0 × 4.18 × 5.0\nq = 5,434 J\nThe water warmed, so the dissolving RELEASED 5,434 J into it.",
 "anticipatedWrong": [
  {
   "value": 209,
   "misconception": "you used the solid's 10.0 g as m — the calorimeter reads the WATER, so the water's mass goes into q = mcΔT",
   "feedback": "This answer is wrong — the 10.0 g is the dissolving solid, not the absorber. Use the water's 260.0 g: q = 260.0 × 4.18 × 5.0 = 5,434 J."
  },
  {
   "value": 28474.16,
   "misconception": "you used the final temperature instead of the temperature change — ΔT = 26.2 − 21.2 = 5.0 °C",
   "feedback": "This answer is wrong — 26.2 is a reading, not a change. ΔT = 5.0 °C, so q = 5,434 J."
  },
  {
   "value": 1300,
   "misconception": "you left out c — every gram of water charges 4.18 J per degree",
   "feedback": "This answer is wrong — 260.0 × 5.0 skips the price per gram per degree. Multiply by 4.18: q = 5,434 J."
  }
 ]
}
THM-034 · medium · application · seq 16 · seed:U12-G3.pool[28] (THM-034 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: 21.0 collides with THM-034 spec text -> 18.5->12.5 (SEED RULING; falling-reading construct kept) | stage-3b: 12.5 collides with THM-029 spec -> 12.0 | stage-3b: 'c to 12.0 c' gram shared with C#15 -> 'down to 12.0' | blind-1: redundant exothermic distractor pair split (second now a flipped-attribution endothermic reading) | blind-2 HARD fix: round-1 replacement was logically equivalent to the key (water-released == dissolving-absorbed); now the all-dissolving-is-exothermic misconception · mcq4
A cold-pack salt dissolves in calorimeter water, and the thermometer reading sinks from 18.5 °C down to 12.0 °C. Which statement describes the energy flow?
The dissolving absorbed energy from the water, so the process is endothermic. KEY
The dissolving released energy into the water, so the process is exothermic.
The thermometer must be faulty — dissolving always releases energy, so a falling reading is impossible.
Some of the water's energy was destroyed as the salt dissolved.
THM-026 · hard · transfer · seq 17 · seed:U12-G3.pool[5] (THM-026 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: '30' collides with spec text of four lessons -> 32-vs-4 (SEED RULING; inverse-comparison construct kept) | sol-1: feedback factor corrected to eight times (32 vs 4) | sol-2: residual 'tenfold' leftover in D2 feedback -> eightfold · mcq4
Equal masses of two materials, X and Y, absorb the same energy. X warms by 32 °C while Y warms by 4 °C. What does this comparison say about their specific heat capacities?
X's specific heat capacity is lower than Y's. KEY
X's specific heat capacity is higher than Y's.
The two specific heat capacities are equal.
The comparison says nothing about their specific heat capacities.
THM-030 · hard · transfer · seq 18 · seed:U12-G3.pool[17] (THM-030 gateItems, James) - VERBATIM (field mapping only) | stage-3 rework: copper collides with THM-030's own spec text (own-lesson material + 'c of copper 0.385' verbatim WE clause) on every form -> iron comparison at fresh values (SEED RULING / rule-58 rework) | stage-3b: 150.0/2508 collide with THM-034/035 spec -> 700.0 g pair (11704 vs 11314.8 J) | sol-1: exactness sentence added · mcq4
Two 700.0 g samples sit side by side: one of water that warms by 4.0 °C, and one of iron that warms by 36.0 °C. Which sample absorbed more energy? (c of water = 4.18 J/(g·°C); c of iron = 0.449 J/(g·°C)) Treat the given values as exact.
The water — 11704 J compared with 11314.8 J. KEY
The iron, because its temperature change is nine times larger.
Both absorbed the same energy, because their masses are equal.
The iron — 11314.8 J is the larger of the two energies.
THM-033 · hard · transfer · seq 19 · seed:U12-G3.pool[25] (THM-033 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: '500' collides with THM-027 spec text -> gains 4870 J / missing 530 J (SEED RULING; leak-accounting construct kept) · mcq4
In an imperfectly insulated calorimeter, a metal block loses 5400 J while the water around it gains only 4870 J. What happened to the other 530 J?
It escaped through the imperfect insulation to the surroundings. KEY
It was destroyed as the block cooled.
It stayed stored in the block.
The numbers must be wrong, because heat lost always equals heat gained.
THM-035 · hard · transfer · seq 20 · seed:U12-G3.pool[32] (THM-035 gateItems, James) - VERBATIM (field mapping only; dual ref demo_curated[2]) | stage-3 freshen: 100.0/90.0/20.0/25.0 collide with spec text -> 110.0/86.0/16.0/20.5 (SEED RULING; equal-mass lands-near-water construct kept); spec-mirroring '100.0 g metal block' phrasing re-minted | stage-3b: '°C is lowered into' spec/cross-form gram -> 'goes into' | stage-3b: 'g metal block at' + 'metal's specific heat' spec grams (THM-035 wording) reworded | blind-1: insulated container stated · mcq4
A metal block of mass 110.0 g, at 86.0 °C, goes into 110.0 g of water at 16.0 °C in an insulated container, and the pair settles at just 20.5 °C — much nearer the water's start than the metal's. Why does the shared temperature settle so near the water's starting temperature?
The block's far lower specific heat capacity means its big drop supplies only a small rise in the water. KEY
The water gained less heat than the metal lost during the exchange inside the calorimeter.
The metal block is denser than water, so each of its degrees counts for less in the balance.
Heat flows out of hot metals more easily than it flows into water, so the metal's drop matters less.
THM-031 · medium · application · seq 21 · authored:U12-G3 stage 2 (fresh FRQ; c-subject production, granite-value landing) · frq
A 440.0 g block of an unknown solid absorbs 3476 J of energy and warms steadily by 10.0 °C.
A 440.0 g block of an unknown solid absorbs 3476 J of energy and warms steadily by 10.0 °C. (a) Rearrange q = mcΔT so that the specific heat capacity c stands alone on the left. Write the rearranged equation. (b) Using your rearranged equation, calculate the solid's specific heat capacity, in J/(g·°C). Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit. (c) In one sentence, state what your answer means for warming exactly one gram of this solid by exactly one degree Celsius.
Part a. Rearrange q = mcΔT so that the specific heat capacity c stands alone on the left. Write the rearranged equation.
Model: Start from q = mcΔT. Divide both sides by m × ΔT: c = q ÷ (m × ΔT)
Part b. Using your rearranged equation, calculate the solid's specific heat capacity, in J/(g·°C). Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit.
Model: Values: q = 3476 J m = 440.0 g ΔT = 10.0 °C q = mcΔT, rearranged: c = q ÷ (m × ΔT) c = 3476 ÷ (440.0 × 10.0) c = 0.790 J/(g·°C)
Part c. In one sentence, state what your answer means for warming exactly one gram of this solid by exactly one degree Celsius.
Model: Raising the temperature of 1 g of this solid by 1 °C takes 0.790 J.
Full model answer. (a) Start from q = mcΔT. Divide both sides by m × ΔT: c = q ÷ (m × ΔT) (b) Values: q = 3476 J m = 440.0 g ΔT = 10.0 °C q = mcΔT, rearranged: c = q ÷ (m × ΔT) c = 3476 ÷ (440.0 × 10.0) c = 0.790 J/(g·°C) (c) Raising the temperature of 1 g of this solid by 1 °C takes 0.790 J.
THM-035 · hard · transfer · seq 22 · seed:U12-G3.pool[30] = demo_curated[0] (THM-035 gateItems, James) - EXPANDED into the multi-part capstone FRQ (values + scaffold spine verbatim; parts and rubric authored at stage 2) | stage-3 freshen: 200.0/49.0/35.0/20.0/30.0 collide with spec text -> 475.0 g bar 48.5->32.5 into 70.0 g water 22.5->32.5 (SEED RULING; q = 2926 J, copper 0.385 landing and all three parts kept) | stage-3b: 70.0 collides with THM-035 spec -> water 87.5 g, 24.5->32.5 (q = 2926, c = 0.385 landing kept; metal 475.0 g at 48.5 unchanged) | sol-1: symbolic balance line added before substitution in model + rubric (R15; part-c wording demanded it) · frq
A 475.0 g metal bar at 48.5 °C is dropped into 87.5 g of water at 24.5 °C in a coffee-cup calorimeter, and the two settle at a shared 32.5 °C. (c of water = 4.18 J/(g·°C))
A 475.0 g metal bar at 48.5 °C is dropped into 87.5 g of water at 24.5 °C in a coffee-cup calorimeter, and the two settle at a shared 32.5 °C. (c of water = 4.18 J/(g·°C)) (a) Write down each substance's own temperature change: the water's rise and the bar's drop. (b) Calculate the heat gained by the water, in J, showing the equation and the substitution. (c) Using the balance 'heat lost by the metal = heat gained by the water', find the metal's specific heat capacity, in J/(g·°C), to 3 significant figures. Write the balance with the metal's mass × c × ΔT on one side before substituting, then rearrange for c.
Part a. Write down each substance's own temperature change: the water's rise and the bar's drop.
Model: Each substance has its own change: water: ΔT = 32.5 − 24.5 = 8.0 °C (a rise of 8.0 °C) metal: ΔT = 48.5 − 32.5 = 16.0 °C (a drop of 16.0 °C)
Part b. Calculate the heat gained by the water, in J, showing the equation and the substitution.
Model: Calculate the water's heat first: q = mcΔT q = 87.5 × 4.18 × 8.0 q = 2926 J gained by the water
Part c. Using the balance 'heat lost by the metal = heat gained by the water', find the metal's specific heat capacity, in J/(g·°C), to 3 significant figures. Write the balance with the metal's mass × c × ΔT on one side before substituting, then rearrange for c.
Model: Write down the balance — heat lost by the metal = heat gained by the water: mass × c × ΔT of the metal = q gained by the water 475.0 × c × 16.0 = 2926 Rearranged for c: c = 2926 ÷ (475.0 × 16.0) c = 0.385 J/(g·°C) That is the table value for copper — the balance just measured a real metal's specific heat capacity.
Full model answer. (a) Each substance has its own change: water: ΔT = 32.5 − 24.5 = 8.0 °C (a rise of 8.0 °C) metal: ΔT = 48.5 − 32.5 = 16.0 °C (a drop of 16.0 °C) (b) Calculate the water's heat first: q = mcΔT q = 87.5 × 4.18 × 8.0 q = 2926 J gained by the water (c) Write down the balance — heat lost by the metal = heat gained by the water: mass × c × ΔT of the metal = q gained by the water 475.0 × c × 16.0 = 2926 Rearranged for c: c = 2926 ÷ (475.0 × 16.0) c = 0.385 J/(g·°C) That is the table value for copper — the balance just measured a real metal's specific heat capacity.

Form B

THM-025 · easy · recall · seq 1 · seed:U12-G3.pool[1] (THM-025 gateItems, James) - VERBATIM (field mapping only) · mcq4
A handbook lists sand's specific heat capacity as 0.84 J/(g·°C). Which mass and temperature change does the 0.84 J refer to?
Warming 1 g of sand by 1 °C. KEY
Warming 1 g of sand to a final temperature of 1 °C.
Warming a whole sample of sand, of any size, by 1 °C.
Warming 1 g of sand by any number of degrees.
THM-029 · easy · recall · seq 2 · authored:U12-G3 stage 2 (ΔT definition read; derived task idiom) · mcq4
In q = mcΔT, ΔT stands for the temperature change. For a sample that warmed, how is ΔT calculated?
The final temperature minus the initial temperature. KEY
The initial temperature minus the final temperature.
The final temperature on its own — one reading is enough.
The final temperature divided by the initial temperature.
THM-033 · easy · recall · seq 3 · authored:U12-G3 stage 2 (balance identity read, insulated case) · mcq4
A hot glass marble sinks into cool water inside a sealed, insulated picnic box, and the two exchange energy until they match. Which statement is exactly true?
The heat lost by the marble equals the heat gained by the water, because no energy escapes. KEY
The marble loses slightly more heat than the water gains, because no transfer is ever perfect.
The water gains more heat than the marble loses, topped up by the box's walls.
The two amounts cannot be compared, because heat lost and heat gained are different kinds of energy.
THM-026 · medium · application · seq 4 · seed:U12-G3.pool[3] (THM-026 gateItems, James) - VERBATIM (field mapping only) | sol-1: caption no longer states the tested rule (giveaway) · mcq4
Using the table: samples of copper, aluminum, and water, all of equal mass, each absorb the same energy. Rank the samples by temperature change, largest first.
FIGURE (data-table · stimulus) — title: "Specific heat capacities" · columns: ["Material", "Specific heat capacity (J/(g·°C))"] · rows: [["water", "4.18"], ["ethanol", "2.44"], ["olive oil", "1.97"], ["aluminum", "0.897"], ["sand", "0.84"], ["iron", "0.449"], ["copper", "0.385"], ["lead", "0.… · caption: "Real specific heat capacities of common materials." · style: "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "data-table",
  "title": "Specific heat capacities",
  "columns": [
   "Material",
   "Specific heat capacity (J/(g·°C))"
  ],
  "rows": [
   [
    "water",
    "4.18"
   ],
   [
    "ethanol",
    "2.44"
   ],
   [
    "olive oil",
    "1.97"
   ],
   [
    "aluminum",
    "0.897"
   ],
   [
    "sand",
    "0.84"
   ],
   [
    "iron",
    "0.449"
   ],
   [
    "copper",
    "0.385"
   ],
   [
    "lead",
    "0.128"
   ]
  ],
  "caption": "Real specific heat capacities of common materials.",
  "style": "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
 }
}
Copper, then aluminum, then water. KEY
Water, then aluminum, then copper.
Aluminum, then copper, then water.
All three change by the same amount.
THM-027 · medium · application · seq 5 · seed:U12-G3.pool[8] (THM-027 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: 50/100 g + 20->40 collide with spec text -> 65/130 g + 34->54 (factor-2 construct kept) | sol-1: keyExplanation re-written (substitution had corrupted the change to '34 °C') · mcq4
Sample A is 65 g of olive oil warmed from 34 °C to 54 °C. Sample B is 130 g of olive oil warmed from 34 °C to 54 °C. Which sample needs more energy, and by what factor?
Sample B — twice as much. KEY
Sample B — four times as much.
Sample A — twice as much.
Both need the same energy.
THM-027 · medium · application · seq 6 · authored:U12-G3 stage 2 (proportional scaling, supplied real base energy; plain-line explanation per THM-027/028 specNotes — no scaffold, no formula substituted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
Warming 120 g of olive oil by 10 °C takes 2364 J. How much energy does warming 360 g of olive oil by 10 °C take? Treat the given values as exact. Give your answer in joules.
Answer: 7092 J KEY
also accepted: 7,092 J, 7 092 J, 7092 J
wrongValueDiagnostics
[
 {
  "value": 2364,
  "misconception": "you kept the energy the same because the temperature change is the same — three times the mass needs three times the energy",
  "feedback": "This answer is wrong — 2364 J warms only the 120 g. Three times the grams need three times the shares: 3 × 2364 J = 7092 J."
 },
 {
  "value": 788,
  "misconception": "you divided by three instead of multiplying — more mass needs more energy",
  "feedback": "This answer is wrong — dividing gives less energy for more oil. Three times the mass needs three times the energy: 7092 J."
 }
]
feedback
{
 "keyExplanation": "Same material, same temperature change — only the mass differs. 360 g is three times 120 g. Three times the mass needs three times the energy: 3 × 2364 J = 7092 J.",
 "anticipatedWrong": [
  {
   "value": 2364,
   "misconception": "you kept the energy the same because the temperature change is the same — three times the mass needs three times the energy",
   "feedback": "This answer is wrong — 2364 J warms only the 120 g. Three times the grams need three times the shares: 3 × 2364 J = 7092 J."
  },
  {
   "value": 788,
   "misconception": "you divided by three instead of multiplying — more mass needs more energy",
   "feedback": "This answer is wrong — dividing gives less energy for more oil. Three times the mass needs three times the energy: 7092 J."
  }
 ]
}
THM-028 · medium · application · seq 7 · authored:U12-G3 stage 2 (proportional scaling, supplied real base energy; plain-line explanation per THM-027/028 specNotes — no scaffold, no formula substituted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
Warming 135 g of water from 17 °C to 27 °C takes 5643 J. How much energy does warming the same 135 g of water from 17 °C to 57 °C take? Treat the given values as exact. Give your answer in joules.
Answer: 22572 J KEY
also accepted: 22,572 J, 22 572 J, 22572 J
wrongValueDiagnostics
[
 {
  "value": 11913,
  "misconception": "you scaled by the ratio of the final temperatures, 57 ÷ 27, instead of the ratio of the changes — the changes are 40 °C and 10 °C",
  "feedback": "This answer is wrong — 57 ÷ 27 compares readings, not changes. The changes are 10 °C and 40 °C, so the energy is 4 × 5643 J = 22572 J."
 },
 {
  "value": 5643,
  "misconception": "you kept the energy the same because it is the same sample — the temperature change quadrupled, so the energy quadruples",
  "feedback": "This answer is wrong — 5643 J covers only a 10 °C change. A 40 °C change on the same sample needs four times as much: 22572 J."
 }
]
feedback
{
 "keyExplanation": "Work with the CHANGES, not the final temperatures. First change: 27 − 17 = 10 °C. Second change: 57 − 17 = 40 °C — four times as large. Four times the change needs four times the energy: 4 × 5643 J = 22572 J.",
 "anticipatedWrong": [
  {
   "value": 11913,
   "misconception": "you scaled by the ratio of the final temperatures, 57 ÷ 27, instead of the ratio of the changes — the changes are 40 °C and 10 °C",
   "feedback": "This answer is wrong — 57 ÷ 27 compares readings, not changes. The changes are 10 °C and 40 °C, so the energy is 4 × 5643 J = 22572 J."
  },
  {
   "value": 5643,
   "misconception": "you kept the energy the same because it is the same sample — the temperature change quadrupled, so the energy quadruples",
   "feedback": "This answer is wrong — 5643 J covers only a 10 °C change. A 40 °C change on the same sample needs four times as much: 22572 J."
  }
 ]
}
THM-028 · medium · application · seq 8 · seed:U12-G3.pool[11] (THM-028 gateItems, James) - FRESHENED (material swap: 'olive oil' would collide cross-seq with the seq-5 oil instance — swapped to water per the recorded ledger decision; construct + key logic unchanged) | blind-1: same-water-both-times premise stated (mass no longer open) · mcq4
A flask of water needed twice as much energy for its second warming as for its first. The same water, untouched between warmings, filled the flask both times. What must be true?
The second temperature change was twice the first. KEY
The second final temperature was twice the first.
The flask held twice as much water the second time.
The water's specific heat capacity doubled between the warmings.
THM-029 · medium · application · seq 9 · seed:U12-G3.pool[14] (THM-029 gateItems, James) - VERBATIM + REPLACE_DISTRACTOR (close-NOTA 4th option replaced with a misconception-keyed distractor per ANSWERS #2; recorded for DAVID_REVIEW) | stage-3 freshen: copper/aluminum collide with other home seqs and 100.0 g/20.0->50.0 with spec text -> two unnamed metals, 75.0 g, 15.5->46.5 (SEED RULING; which-differs construct + replaced NOTA distractor kept) | stage-3b: 75.0 collides with THM-035 spec -> 72.0 g | sol-1: 75.0 g feedback leftovers -> 72.0 g · mcq4
Two 72.0 g blocks of two different metals sit on the same hot plate and warm together from 15.5 °C to 46.5 °C. In q = mcΔT, which quantity on the right-hand side differs between the two blocks?
c — the two metals have different specific heat capacities. KEY
m — the two blocks have different masses.
ΔT — the two blocks have different temperature changes.
Both m and ΔT differ, because the two blocks absorb different amounts of energy.
THM-030 · medium · application · seq 10 · seed:U12-G3.pool[16] (THM-030 gateItems, James) - VERBATIM (field mapping only) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['7900.0'] · numeric
A 2.00 kg slab of granite beside a campfire warms by 5.0 °C. How much energy does the granite absorb, in J? (c of granite = 0.790 J/(g·°C)) Treat the given values as exact. Give your answer to 3 significant figures.
Answer: 7900.0 J KEY
also accepted: 7,900 J
wrongValueDiagnostics
[
 {
  "value": 7.9,
  "misconception": "you substituted the mass in kilograms — m must be in grams, and 2.00 kg = 2000 g",
  "feedback": "This answer is wrong — one thousand times too small. Convert first: 2.00 kg = 2000 g, so q = 2000 × 0.790 × 5.0 = 7900 J."
 },
 {
  "value": 790.0,
  "misconception": "you converted 2.00 kg to 200 g — kilo- means one thousand, so 2.00 kg = 2000 g",
  "feedback": "This answer is wrong — ten times too small. 2.00 kg = 2000 g, so q = 2000 × 0.790 × 5.0 = 7900 J."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nm = 2.00 kg = 2000 g\nc = 0.790 J/(g·°C)\nΔT = 5.0 °C\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 2000 × 0.790 × 5.0\nq = 7900 J\nThe mass must go in as grams because c is joules per GRAM per degree — kilo- means one thousand, so 2.00 kg is 2000 g.",
 "anticipatedWrong": [
  {
   "value": 7.9,
   "misconception": "you substituted the mass in kilograms — m must be in grams, and 2.00 kg = 2000 g",
   "feedback": "This answer is wrong — one thousand times too small. Convert first: 2.00 kg = 2000 g, so q = 2000 × 0.790 × 5.0 = 7900 J."
  },
  {
   "value": 790.0,
   "misconception": "you converted 2.00 kg to 200 g — kilo- means one thousand, so 2.00 kg = 2000 g",
   "feedback": "This answer is wrong — ten times too small. 2.00 kg = 2000 g, so q = 2000 × 0.790 × 5.0 = 7900 J."
  }
 ]
}
THM-031 · medium · application · seq 11 · seed:U12-G3.pool[19] (THM-031 gateItems, James) - FRESHENED (final-T construct kept; values re-minted per corpus sweep; scene moved off the fluency 'sun' instance) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['18.50'] · numeric
A 240.0 g jug of water at 13.5 °C absorbs 5016 J of energy beside a radiator. What is the water's final temperature, in °C? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 3 significant figures.
Answer: 18.5 °C KEY
also accepted: 18.5 °C
wrongValueDiagnostics
[
 {
  "value": 5.0,
  "misconception": "you stopped at the temperature change — 5.0 °C is ΔT; add it to the initial temperature to get the final temperature",
  "feedback": "This answer is wrong — 5.0 °C is the CHANGE. Final temperature = 13.5 + 5.0 = 18.5 °C."
 },
 {
  "value": 34.4,
  "misconception": "you divided by the mass only, skipping the specific heat capacity, before adding to the initial temperature",
  "feedback": "This answer is wrong — divide by both m and c: ΔT = 5016 ÷ (240.0 × 4.18) = 5.0 °C, so the final temperature is 18.5 °C."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nq = 5016 J\nm = 240.0 g\nc = 4.18 J/(g·°C)\ninitial temperature = 13.5 °C\nWrite down the equation:\nq = mcΔT\nMake ΔT the subject:\nΔT = q ÷ (m × c)\nSubstitute in the values, and calculate:\nΔT = 5016 ÷ (240.0 × 4.18)\nΔT = 5.0 °C\nThe water warms by 5.0 °C, so its final temperature is 13.5 + 5.0 = 18.5 °C.",
 "anticipatedWrong": [
  {
   "value": 5.0,
   "misconception": "you stopped at the temperature change — 5.0 °C is ΔT; add it to the initial temperature to get the final temperature",
   "feedback": "This answer is wrong — 5.0 °C is the CHANGE. Final temperature = 13.5 + 5.0 = 18.5 °C."
  },
  {
   "value": 34.4,
   "misconception": "you divided by the mass only, skipping the specific heat capacity, before adding to the initial temperature",
   "feedback": "This answer is wrong — divide by both m and c: ΔT = 5016 ÷ (240.0 × 4.18) = 5.0 °C, so the final temperature is 18.5 °C."
  }
 ]
}
THM-031 · medium · application · seq 12 · authored:U12-G3 stage 2 (c-subject form pick) · mcq4
A problem gives q, m, and ΔT and asks for the specific heat capacity c. Which rearrangement of q = mcΔT is correct?
c = q ÷ (m × ΔT) — the energy divided by the two knowns together KEY
c = q × m × ΔT — the energy multiplied by the two knowns
c = (m × ΔT) ÷ q — the two knowns divided by the energy
c = q ÷ m — the energy divided by the mass only
THM-032 · medium · application · seq 13 · seed:U12-G3.pool[22] (THM-032 gateItems, James) - VERBATIM (field mapping only) | sol-1: thermometer-range distractor (not cleanly wrong) -> weight-check misconception; 'regardless' softened · mcq4
Before an experiment, a student carefully weighs the water that goes into the coffee-cup calorimeter. Why must the water's mass be known?
The same energy warms different masses of water by different amounts, so the reading needs the mass. KEY
Heavier water absorbs energy faster, so the mass sets how long the experiment takes to finish.
Heavier water presses harder on the cup, so the mass is needed to check the cup can bear the weight.
The cup only insulates properly when it is filled to the top with water.
THM-033 · medium · application · seq 14 · authored:U12-G3 stage 2 (heat lost = heat gained bookkeeping; plain-sentence explanation — identity, no formula) | stage-3 reword: spec-mirroring 'dropped into the water ... loses N J as it cools' construction replaced (THM-033 fluency wording); container register 'well-insulated, sealed' (seq-14 lane) | blind-1: idealization parenthetical '(no heat leaks in or out)' added (reviewer idealization class) | sol-1: container declared non-absorbing (walls-absorption reading closed) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['1730.0'] · numeric
A hot metal bolt sits in the water of a well-insulated, sealed canister (no heat leaks in or out, and the container itself soaks up none) and gives up 1730 J of heat while cooling. How much heat does the water gain, in J? Treat the given values as exact. Give your answer in joules.
Answer: 1730 J KEY
also accepted: 1,730 J
wrongValueDiagnostics
[
 {
  "value": -1730,
  "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and 'gain' already carries the direction",
  "feedback": "This answer is wrong in form — give the size of the transfer: the water gained 1730 J."
 },
 {
  "value": 3460,
  "misconception": "you doubled the energy, counting it once leaving the bolt and once entering the water — it is the same 1730 J, transferred once",
  "feedback": "This answer is wrong — one transfer, counted from either end: the water gained exactly the 1730 J the bolt lost."
 }
]
feedback
{
 "keyExplanation": "The canister is sealed and insulated, so no energy escapes to anything else. The heat lost by the hotter object equals the heat gained by the colder object: the bolt lost 1730 J, so the water gained 1730 J.",
 "anticipatedWrong": [
  {
   "value": -1730,
   "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and 'gain' already carries the direction",
   "feedback": "This answer is wrong in form — give the size of the transfer: the water gained 1730 J."
  },
  {
   "value": 3460,
   "misconception": "you doubled the energy, counting it once leaving the bolt and once entering the water — it is the same 1730 J, transferred once",
   "feedback": "This answer is wrong — one transfer, counted from either end: the water gained exactly the 1730 J the bolt lost."
  }
 ]
}
THM-034 · medium · application · seq 15 · seed:U12-G3.pool[29] (THM-034 gateItems, James) - VERBATIM (field mapping only) | stage-3 freshen: 500.0 g + 20.0->22.5 collide with spec text and the seq-11 sinker mass -> 360.0 g + 23.0->25.5 (SEED RULING; fizzing-tablet released-heat construct kept) | stage-3b: 23.0 collides with THM-034/035 spec -> 24.0->26.5 (q = 3762 kept) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['3762.0'] · numeric
A tablet dropped into 360.0 g of calorimeter water fizzes as it reacts, and the water warms from 24.0 °C to 26.5 °C. How much heat did the reaction release, in J? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 4 significant figures.
Answer: 3762.0 J KEY
also accepted: 3,762 J, 3762 J
wrongValueDiagnostics
[
 {
  "value": 39877.2,
  "misconception": "you used the final temperature instead of the temperature change — ΔT = 26.5 − 24.0 = 2.5 °C",
  "feedback": "This answer is wrong — 26.5 is a reading, not a change. ΔT = 2.5 °C, so q = 360.0 × 4.18 × 2.5 = 3,762 J."
 },
 {
  "value": 900,
  "misconception": "you left out c — every gram of water charges 4.18 J per degree",
  "feedback": "This answer is wrong — 360.0 × 2.5 skips the price per gram per degree. Multiply by 4.18: q = 3,762 J."
 }
]
feedback
{
 "keyExplanation": "The calorimeter measures the reaction through the WATER. For the water:\nm = 360.0 g\nc = 4.18 J/(g·°C)\nΔT = 26.5 − 24.0 = 2.5 °C\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 360.0 × 4.18 × 2.5\nq = 3,762 J\nThe water warmed, so the reaction RELEASED 3,762 J into it.",
 "anticipatedWrong": [
  {
   "value": 39877.2,
   "misconception": "you used the final temperature instead of the temperature change — ΔT = 26.5 − 24.0 = 2.5 °C",
   "feedback": "This answer is wrong — 26.5 is a reading, not a change. ΔT = 2.5 °C, so q = 360.0 × 4.18 × 2.5 = 3,762 J."
  },
  {
   "value": 900,
   "misconception": "you left out c — every gram of water charges 4.18 J per degree",
   "feedback": "This answer is wrong — 360.0 × 2.5 skips the price per gram per degree. Multiply by 4.18: q = 3,762 J."
  }
 ]
}
THM-034 · medium · application · seq 16 · authored:U12-G3 stage 2 (warming direction read) · mcq4
A scoop of bath salts dissolves in calorimeter water, and the thermometer climbs steadily. Which statement describes the energy flow?
The dissolving released energy into the water, so the process is exothermic. KEY
The dissolving absorbed energy from the water, so the process is endothermic.
The water released energy into the salts, so the process is endothermic.
Energy was created as the salts dissolved, which is what warmed the water.
THM-026 · hard · transfer · seq 17 · authored:U12-G3 stage 2 (inverse comparison, fourfold rise pair) · mcq4
Equal masses of two liquids, P and Q, each absorb the same energy. P warms by 28 °C while Q warms by 7 °C. Which comparison is correct?
P's specific heat capacity is lower than Q's. KEY
P's specific heat capacity is higher than Q's.
The two specific heat capacities are equal.
The comparison says nothing about their specific heat capacities.
THM-030 · hard · transfer · seq 18 · authored:U12-G3 stage 2 (two-product comparison; copper wins) | stage-3 rework: copper collides with THM-030's own spec text (own-lesson material + 'c of copper 0.385' verbatim WE clause) on every form -> granite comparison at fresh values (SEED RULING / rule-58 rework) | sol-1: exactness sentence added · mcq4
Two 80.0 g samples sit side by side: one of water that warms by 3.0 °C, and one of granite that warms by 19.0 °C. Which sample absorbed more energy? (c of water = 4.18 J/(g·°C); c of granite = 0.79 J/(g·°C)) Treat the given values as exact.
The granite — 1200.8 J compared with 1003.2 J. KEY
The water — its far higher specific heat capacity guarantees it absorbs more, whatever the changes.
Both absorbed the same energy, because their masses are equal.
The water — 1003.2 J is the larger of the two energies.
THM-033 · hard · transfer · seq 19 · authored:U12-G3 stage 2 (leak-accounting boundary) · mcq4
Inside a calorimeter with a cracked lid, a metal puck loses 6200 J while the water around it gains only 5745 J. What happened to the other 455 J?
It escaped through the cracked lid to the surroundings. KEY
It was destroyed as the puck cooled.
It stayed stored in the puck.
The readings must be wrong, because heat lost always equals heat gained.
THM-035 · hard · transfer · seq 20 · authored:U12-G3 stage 2 (both-water unequal-mass landing, qualitative) | blind-1: insulated tub stated · mcq4
A pot of hot water is poured into an insulated tub holding three times as much cool water, and the mixture settles at one shared temperature. Where does that shared temperature land?
Much closer to the cool water's starting temperature, because the larger mass carries more weight in the balance. KEY
Exactly halfway between the two starting temperatures, because both samples are water.
Much closer to the hot water's starting temperature, because heat leaves hot water faster than cool water takes it in.
At the cool water's exact starting temperature, because the cool water soaks up everything without warming at all.
THM-031 · medium · application · seq 21 · authored:U12-G3 stage 2 (fresh FRQ; m-subject production with back-substitution check) | stage-3 freshen: ethanol collides with its seq-7 home (cross-form substance exclusivity) and 'c of ethanol 2.44' with THM-030 spec text -> olive oil, 3152 J / 5.0 °C -> m = 320 g (m-subject construct + check-back part kept) | stage-3: modelAnswer re-set to the V-T9-safe FRQ scaffold phrasing (E#21 convention) · frq
A lab heater delivers exactly 3152 J to a sample of olive oil, and the oil must warm by exactly 5.0 °C. (c of olive oil = 1.97 J/(g·°C))
A lab heater delivers exactly 3152 J to a sample of olive oil, and the oil must warm by exactly 5.0 °C. (c of olive oil = 1.97 J/(g·°C)) (a) Rearrange q = mcΔT so that the mass m stands alone on the left. Write the rearranged equation. (b) Using your rearranged equation, calculate the mass of olive oil the heater can warm, in g. Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit. (c) Check your answer: substitute your mass back into q = mcΔT and show that it returns the 3152 J.
Part a. Rearrange q = mcΔT so that the mass m stands alone on the left. Write the rearranged equation.
Model: Start from q = mcΔT. Divide both sides by c × ΔT (typed: c x deltaT): m = q ÷ (c × ΔT)
Part b. Using your rearranged equation, calculate the mass of olive oil the heater can warm, in g. Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit.
Model: Values: q = 3152 J c = 1.97 J/(g·°C) ΔT = 5.0 °C q = mcΔT, rearranged: m = q ÷ (c × ΔT) m = 3152 ÷ (1.97 × 5.0) m = 3152 ÷ 9.85 m = 320 g
Part c. Check your answer: substitute your mass back into q = mcΔT and show that it returns the 3152 J.
Model: Check: q = mcΔT = 320 × 1.97 × 5.0 = 3152 J — the heater's energy is returned, so the mass is right.
Full model answer. (a) Start from q = mcΔT. Divide both sides by c × ΔT (typed: c x deltaT): m = q ÷ (c × ΔT) (b) Values: q = 3152 J c = 1.97 J/(g·°C) ΔT = 5.0 °C q = mcΔT, rearranged: m = q ÷ (c × ΔT) m = 3152 ÷ (1.97 × 5.0) m = 3152 ÷ 9.85 m = 320 g (c) Check: q = mcΔT = 320 × 1.97 × 5.0 = 3152 J — the heater's energy is returned, so the mass is right.
THM-035 · hard · transfer · seq 22 · seed:U12-G3.pool[31] = demo_curated[1] (THM-035 gateItems, James) - EXPANDED into the multi-part capstone FRQ (values + scaffold spine verbatim; substitute-then-solve deviation per THM-035 specNotes) | stage-3 freshen: 300.0/100.0/90.0/10.0 collide with spec text -> 375.0/125.0 g at 81.0/13.0 °C, T = 64.0 (SEED RULING; 3:1 both-water c-divides-out construct kept) | stage-3b: 125.0 collides with THM-031 spec -> 555.0/185.0 g (3:1 ratio, T = 64.0 unchanged) · frq
555.0 g of hot water at 81.0 °C is poured into 185.0 g of cool water at 13.0 °C in a calorimeter, and the mixture reaches one shared final temperature T. (c of water = 4.18 J/(g·°C))
555.0 g of hot water at 81.0 °C is poured into 185.0 g of cool water at 13.0 °C in a calorimeter, and the mixture reaches one shared final temperature T. (c of water = 4.18 J/(g·°C)) (a) Write each sample's temperature change in terms of T: the hot water's drop and the cool water's rise. (b) Write the balance 'heat lost by the hot water = heat gained by the cool water' with q = mcΔT on each side, and state why c divides out. (c) Solve for T step by step, to 3 significant figures, and finish with one sentence explaining why the answer lands so much nearer 81.0 °C than 13.0 °C.
Part a. Write each sample's temperature change in terms of T: the hot water's drop and the cool water's rise.
Model: Write down the values, and each sample's own change in terms of T: hot water: m = 555.0 g, starts at 81.0 °C, drop = 81.0 − T cool water: m = 185.0 g, starts at 13.0 °C, rise = T − 13.0
Part b. Write the balance 'heat lost by the hot water = heat gained by the cool water' with q = mcΔT on each side, and state why c divides out.
Model: Write down the balance — heat lost by the hot water = heat gained by the cool water: 555.0 × c × (81.0 − T) = 185.0 × c × (T − 13.0) Both samples are water, so the same c multiplies both sides and divides out.
Part c. Solve for T step by step, to 3 significant figures, and finish with one sentence explaining why the answer lands so much nearer 81.0 °C than 13.0 °C.
Model: Substitute and solve step by step: 555.0 × (81.0 − T) = 185.0 × (T − 13.0) 3 × (81.0 − T) = T − 13.0 243 − 3T = T − 13 256 = 4T T = 64.0 °C The shared temperature lands much nearer 81.0 °C than 13.0 °C because the hot sample holds three times the mass — the larger mass carries more weight in the balance.
Full model answer. (a) Write down the values, and each sample's own change in terms of T: hot water: m = 555.0 g, starts at 81.0 °C, drop = 81.0 − T cool water: m = 185.0 g, starts at 13.0 °C, rise = T − 13.0 (b) Write down the balance — heat lost by the hot water = heat gained by the cool water: 555.0 × c × (81.0 − T) = 185.0 × c × (T − 13.0) Both samples are water, so the same c multiplies both sides and divides out. (c) Substitute and solve step by step: 555.0 × (81.0 − T) = 185.0 × (T − 13.0) 3 × (81.0 − T) = T − 13.0 243 − 3T = T − 13 256 = 4T T = 64.0 °C The shared temperature lands much nearer 81.0 °C than 13.0 °C because the hot sample holds three times the mass — the larger mass carries more weight in the balance.

Form C

THM-025 · easy · recall · seq 1 · seed:U12-G3.pool[2] (THM-025 gateItems, James) - VERBATIM (field mapping only) · mcq4
About how much energy is one joule?
Roughly the energy of lifting an apple from the floor to a table. KEY
Roughly the energy needed to boil a full kettle of water.
Roughly the energy a phone battery stores when full.
Roughly the energy of a campfire burning for an evening.
THM-029 · easy · recall · seq 2 · authored:U12-G3 stage 2 (symbol meaning read — c; derived task idiom) · mcq4
In the heat equation q = mcΔT, what does c stand for?
The specific heat capacity of the material, in J/(g·°C). KEY
The temperature change of the sample, in °C.
A conversion constant that has the same value for every material.
The energy transferred as heat, in joules (J).
THM-033 · easy · recall · seq 3 · authored:U12-G3 stage 2 (validity-condition read) · mcq4
A lab manual states: 'the heat lost by the hotter object equals the heat gained by the colder object.' When does this balance hold exactly?
Only when no energy escapes to anything else. KEY
Whenever the two objects touch, insulated or not.
Only when the two objects have equal masses.
Only when the two objects are made of the same material.
THM-026 · medium · application · seq 4 · authored:U12-G3 stage 2 (pairwise table read; A6 reference figure) | sol-1: caption no longer states the tested rule (giveaway) · mcq4
Using the table: one sample of iron and one of olive oil, equal in mass, each absorb the same energy. Which sample's temperature rises more?
FIGURE (data-table · stimulus) — title: "Specific heat capacities" · columns: ["Material", "Specific heat capacity (J/(g·°C))"] · rows: [["water", "4.18"], ["ethanol", "2.44"], ["olive oil", "1.97"], ["aluminum", "0.897"], ["sand", "0.84"], ["iron", "0.449"], ["copper", "0.385"], ["lead", "0.… · caption: "Real specific heat capacities of common materials." · style: "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "data-table",
  "title": "Specific heat capacities",
  "columns": [
   "Material",
   "Specific heat capacity (J/(g·°C))"
  ],
  "rows": [
   [
    "water",
    "4.18"
   ],
   [
    "ethanol",
    "2.44"
   ],
   [
    "olive oil",
    "1.97"
   ],
   [
    "aluminum",
    "0.897"
   ],
   [
    "sand",
    "0.84"
   ],
   [
    "iron",
    "0.449"
   ],
   [
    "copper",
    "0.385"
   ],
   [
    "lead",
    "0.128"
   ]
  ],
  "caption": "Real specific heat capacities of common materials.",
  "style": "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
 }
}
The iron. KEY
The olive oil.
Both rise by the same amount.
It cannot be predicted without knowing how many joules were absorbed.
THM-027 · medium · application · seq 5 · authored:U12-G3 stage 2 (inverse mass-factor read) · mcq4
Warming the water for a full teapot takes four times the energy of warming the water for one mug, both through the same temperature change. What does that say about the masses of water?
The teapot holds four times the mug's mass. KEY
The teapot holds sixteen times the mug's mass.
The teapot holds one quarter of the mug's mass.
Nothing — with the same temperature change, the two energies should have been equal.
THM-027 · medium · application · seq 6 · authored:U12-G3 stage 2 (proportional scaling, supplied real base energy; plain-line explanation per THM-027/028 specNotes — no scaffold, no formula substituted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
Warming 580 g of water by 5 °C takes 12122 J. How much energy does warming 1160 g of water by 5 °C take? Treat the given values as exact. Give your answer in joules.
Answer: 24244 J KEY
also accepted: 24,244 J, 24 244 J, 24244 J
wrongValueDiagnostics
[
 {
  "value": 12122,
  "misconception": "you kept the energy the same because the temperature change is the same — twice the mass needs twice the energy",
  "feedback": "This answer is wrong — 12122 J warms only the 580 g. Twice the grams need twice the shares: 2 × 12122 J = 24244 J."
 },
 {
  "value": 6061,
  "misconception": "you divided by two instead of multiplying — more mass needs more energy",
  "feedback": "This answer is wrong — dividing gives less energy for more water. Twice the mass needs twice the energy: 24244 J."
 }
]
feedback
{
 "keyExplanation": "Same material, same temperature change — only the mass differs. 1160 g is twice 580 g. Twice the mass needs twice the energy: 2 × 12122 J = 24244 J.",
 "anticipatedWrong": [
  {
   "value": 12122,
   "misconception": "you kept the energy the same because the temperature change is the same — twice the mass needs twice the energy",
   "feedback": "This answer is wrong — 12122 J warms only the 580 g. Twice the grams need twice the shares: 2 × 12122 J = 24244 J."
  },
  {
   "value": 6061,
   "misconception": "you divided by two instead of multiplying — more mass needs more energy",
   "feedback": "This answer is wrong — dividing gives less energy for more water. Twice the mass needs twice the energy: 24244 J."
  }
 ]
}
THM-028 · medium · application · seq 7 · authored:U12-G3 stage 2 (proportional scaling, supplied real base energy; plain-line explanation per THM-027/028 specNotes — no scaffold, no formula substituted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
Warming 175 g of ethanol by 4 °C takes 1708 J. How much energy does warming the same 175 g of ethanol by 12 °C take? Treat the given values as exact. Give your answer in joules.
Answer: 5124 J KEY
also accepted: 5,124 J, 5 124 J, 5124 J
wrongValueDiagnostics
[
 {
  "value": 1708,
  "misconception": "you kept the energy the same because it is the same sample — three times the change needs three times the energy",
  "feedback": "This answer is wrong — 1708 J covers only a 4 °C change. A 12 °C change on the same sample needs 3 × 1708 J = 5124 J."
 },
 {
  "value": 569,
  "misconception": "you divided by three instead of multiplying — a bigger change needs more energy",
  "feedback": "This answer is wrong — dividing gives less energy for a bigger change. Three times the change needs three times the energy: 5124 J."
 }
]
feedback
{
 "keyExplanation": "Same material, same mass — only the temperature change differs. 12 °C is three times 4 °C, and three times the change needs three times the energy: 3 × 1708 J = 5124 J.",
 "anticipatedWrong": [
  {
   "value": 1708,
   "misconception": "you kept the energy the same because it is the same sample — three times the change needs three times the energy",
   "feedback": "This answer is wrong — 1708 J covers only a 4 °C change. A 12 °C change on the same sample needs 3 × 1708 J = 5124 J."
  },
  {
   "value": 569,
   "misconception": "you divided by three instead of multiplying — a bigger change needs more energy",
   "feedback": "This answer is wrong — dividing gives less energy for a bigger change. Three times the change needs three times the energy: 5124 J."
  }
 ]
}
THM-028 · medium · application · seq 8 · authored:U12-G3 stage 2 (doubling factor read, small free values) · mcq4
The same bowl of water is warmed once by 6 °C and later by 12 °C. How do the two energy needs compare?
The second warming needs twice the energy of the first. KEY
The second warming needs four times the energy.
Both warmings need the same energy, because it is the same bowl of water.
The second warming needs half the energy, because the water is already used to warming.
THM-029 · medium · application · seq 9 · authored:U12-G3 stage 2 (kg->g substitution trap, MPM-029 retrieval) | sol-1: 4.80 g feedback now names the x10-instead-of-x1000 error · mcq4
A student weighs 0.480 kg of water for a calorimetry practice run and reaches for q = mcΔT. What value should the student substitute for m?
480 g KEY
0.480 g
48.0 g
4.80 g
THM-030 · medium · application · seq 10 · authored:U12-G3 stage 2 (forward q, warming water; values minted fresh) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['7106.0'] · numeric
A saucepan holds 170.0 g of water that warms from 31.0 °C to 41.0 °C on a stove. How much energy does the water absorb, in J? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 4 significant figures.
Answer: 7106.0 J KEY
also accepted: 7,106 J
wrongValueDiagnostics
[
 {
  "value": 29134.6,
  "misconception": "you used the final temperature instead of the temperature change — ΔT = 41.0 − 31.0 = 10.0 °C",
  "feedback": "This answer is wrong — 41.0 is a reading, not a change. ΔT = 41.0 − 31.0 = 10.0 °C, giving q = 7106 J."
 },
 {
  "value": 41.8,
  "misconception": "you left out the mass — all three quantities on the right multiply",
  "feedback": "This answer is wrong — 4.18 × 10.0 covers only one gram. Multiply by the 170.0 g as well: q = 7106 J."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nm = 170.0 g\nc = 4.18 J/(g·°C)\nΔT = 41.0 − 31.0 = 10.0 °C\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 170.0 × 4.18 × 10.0\nq = 7106 J",
 "anticipatedWrong": [
  {
   "value": 29134.6,
   "misconception": "you used the final temperature instead of the temperature change — ΔT = 41.0 − 31.0 = 10.0 °C",
   "feedback": "This answer is wrong — 41.0 is a reading, not a change. ΔT = 41.0 − 31.0 = 10.0 °C, giving q = 7106 J."
  },
  {
   "value": 41.8,
   "misconception": "you left out the mass — all three quantities on the right multiply",
   "feedback": "This answer is wrong — 4.18 × 10.0 covers only one gram. Multiply by the 170.0 g as well: q = 7106 J."
  }
 ]
}
THM-031 · medium · application · seq 11 · authored:U12-G3 stage 2 (m-subject solve) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['190.0'] | sol-2: the two wrong-value feedbacks now name their DISTINCT errors (missing-c vs missing-dT) · numeric
How many grams of water can 3971 J of energy warm by 5.0 °C? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 3 significant figures.
Answer: 190.0 g KEY
also accepted: 190 g
wrongValueDiagnostics
[
 {
  "value": 794.2,
  "misconception": "you left out c and divided the energy by the temperature change alone — every gram of water charges 4.18 J per degree",
  "feedback": "This answer is wrong — 3971 ÷ 5.0 skips the price per gram per degree. Divide by c × ΔT: m = 3971 ÷ (4.18 × 5.0) = 190 g."
 },
 {
  "value": 950.0,
  "misconception": "you left out the temperature change and divided the energy by c alone — the 5.0 °C change multiplies c in the divisor",
  "feedback": "This answer is wrong — 3971 ÷ 4.18 covers only one degree of warming. Divide by c × ΔT: m = 3971 ÷ (4.18 × 5.0) = 190 g."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nq = 3971 J\nc = 4.18 J/(g·°C)\nΔT = 5.0 °C\nWrite down the equation:\nq = mcΔT\nMake m the subject:\nm = q ÷ (c × ΔT)\nSubstitute in the values, and calculate:\nm = 3971 ÷ (4.18 × 5.0)\nm = 190 g",
 "anticipatedWrong": [
  {
   "value": 794.2,
   "misconception": "you left out c and divided the energy by the temperature change alone — every gram of water charges 4.18 J per degree",
   "feedback": "This answer is wrong — 3971 ÷ 5.0 skips the price per gram per degree. Divide by c × ΔT: m = 3971 ÷ (4.18 × 5.0) = 190 g."
  },
  {
   "value": 950.0,
   "misconception": "you left out the temperature change and divided the energy by c alone — the 5.0 °C change multiplies c in the divisor",
   "feedback": "This answer is wrong — 3971 ÷ 4.18 covers only one degree of warming. Divide by c × ΔT: m = 3971 ÷ (4.18 × 5.0) = 190 g."
  }
 ]
}
THM-031 · medium · application · seq 12 · authored:U12-G3 stage 2 (ΔT-subject form pick) | blind-1 class sweep: swapped with D#12 — the dT-subject form previewed C#21(a)'s requested rearrangement (cross-item cue); now the make-c-the-subject move variant (C#21 asks dT) · mcq4
To make c the subject of q = mcΔT, what must be done to both sides of the equation?
Divide both sides by m × ΔT. KEY
Multiply both sides by m × ΔT.
Divide both sides by q.
Subtract m × ΔT from both sides.
THM-032 · medium · application · seq 13 · seed:U12-G3.pool[23] (THM-032 gateItems, James) - VERBATIM (field mapping only) · mcq4
A sealed hand-warmer pouch that releases energy is dropped into the water of a coffee-cup calorimeter. What does the thermometer show over the next few minutes?
The reading rises, because the water absorbs the energy the pouch releases. KEY
The reading falls, because the pouch takes up room in the water.
The reading stays constant, because the insulated cup blocks all energy flow.
The reading rises and then falls back to the starting temperature.
THM-033 · medium · application · seq 14 · authored:U12-G3 stage 2 (heat lost = heat gained bookkeeping; plain-sentence explanation — identity, no formula) | stage-3 reword: 'sealed, insulated cooler box' shared the seq-3 container gram -> 'well-insulated, sealed storage box' (seq-14 wording lane) | blind-1: idealization parenthetical '(no heat leaks in or out)' added (reviewer idealization class) | sol-1: container declared non-absorbing (walls-absorption reading closed) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['2840.0'] · numeric
Inside a well-insulated, sealed storage box (no heat leaks in or out, and the container itself soaks up none), a warm brick rests in cool water until the two match. During the exchange the brick loses 2840 J. How much heat does the water gain, in J? Treat the given values as exact. Give your answer in joules.
Answer: 2840 J KEY
also accepted: 2,840 J
wrongValueDiagnostics
[
 {
  "value": -2840,
  "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and the words carry the direction",
  "feedback": "This answer is wrong in form — give the size of the transfer: the water gained 2840 J."
 },
 {
  "value": 1420,
  "misconception": "you split the transfer in half between the brick and the water — the whole 2840 J moves into the water",
  "feedback": "This answer is wrong — nothing is split. Inside the insulated box the water gains everything the brick loses: 2840 J."
 }
]
feedback
{
 "keyExplanation": "The storage box is sealed and insulated, so the transferred energy has nowhere else to go. Heat lost equals heat gained: the brick lost 2840 J, so the water gained exactly 2840 J.",
 "anticipatedWrong": [
  {
   "value": -2840,
   "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and the words carry the direction",
   "feedback": "This answer is wrong in form — give the size of the transfer: the water gained 2840 J."
  },
  {
   "value": 1420,
   "misconception": "you split the transfer in half between the brick and the water — the whole 2840 J moves into the water",
   "feedback": "This answer is wrong — nothing is split. Inside the insulated box the water gains everything the brick loses: 2840 J."
  }
 ]
}
THM-034 · medium · application · seq 15 · authored:U12-G3 stage 2 (cooling case: water supplies, process absorbs; wrong-m trap planted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['1881.0'] · numeric
6.0 g of a crystalline solid stirs into 180.0 g of water in a coffee-cup calorimeter, and the water cools from 14.5 °C to 12.0 °C. How much heat did the dissolving absorb, in J? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 4 significant figures.
Answer: 1881.0 J KEY
also accepted: 1,881 J
wrongValueDiagnostics
[
 {
  "value": 62.7,
  "misconception": "you used the solid's mass instead of the water's — the equation is run on the WATER, the substance whose temperature was measured",
  "feedback": "This answer is wrong — the 6.0 g of solid is the trap. Use the water's 180.0 g: q = 180.0 × 4.18 × 2.5 = 1881 J absorbed."
 },
 {
  "value": 9028.8,
  "misconception": "you used a single reading instead of the temperature change — ΔT is the size of the drop, 14.5 − 12.0 = 2.5 °C",
  "feedback": "This answer is wrong — 12.0 is a reading, not a change. The drop is 2.5 °C, so q = 1881 J absorbed."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question — for the water:\nm = 180.0 g\nc = 4.18 J/(g·°C)\nΔT = 14.5 − 12.0 = 2.5 °C (a drop of 2.5 °C)\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 180.0 × 4.18 × 2.5\nq = 1881 J — absorbed, because the water cooled. The solid's 6.0 g never enters the calculation — the water is the substance measured.",
 "anticipatedWrong": [
  {
   "value": 62.7,
   "misconception": "you used the solid's mass instead of the water's — the equation is run on the WATER, the substance whose temperature was measured",
   "feedback": "This answer is wrong — the 6.0 g of solid is the trap. Use the water's 180.0 g: q = 180.0 × 4.18 × 2.5 = 1881 J absorbed."
  },
  {
   "value": 9028.8,
   "misconception": "you used a single reading instead of the temperature change — ΔT is the size of the drop, 14.5 − 12.0 = 2.5 °C",
   "feedback": "This answer is wrong — 12.0 is a reading, not a change. The drop is 2.5 °C, so q = 1881 J absorbed."
  }
 ]
}
THM-034 · medium · application · seq 16 · authored:U12-G3 stage 2 (cooling direction read) · mcq4
A reacting mixture rests in calorimeter water, and the thermometer falls steadily while the reaction runs. Which statement is correct?
The water supplied energy to the reaction, so the reaction is endothermic. KEY
The reaction released energy into the water, so the reaction is exothermic.
The water absorbed energy from the reaction, so the reaction is exothermic.
Some of the water's energy was destroyed as the reaction ran.
THM-026 · hard · transfer · seq 17 · authored:U12-G3 stage 2 (inverse comparison, equal-rise edge case) · mcq4
Equal masses of two materials absorb the same energy, and both warm by exactly 9 °C. A student concludes the two specific heat capacities must be equal. Is the student right?
Yes — with mass and energy held equal, equal temperature changes mean equal specific heat capacities. KEY
No — two different materials can never share a specific heat capacity.
No — temperature changes on their own say nothing at all about the two specific heat capacities.
Yes, but only if both materials are liquids.
THM-030 · hard · transfer · seq 18 · authored:U12-G3 stage 2 (two-product comparison; water wins) | stage-3 rework: copper collides with THM-030's own spec text (own-lesson material + 'c of copper 0.385' verbatim WE clause) on every form -> olive oil comparison at fresh values (SEED RULING / rule-58 rework) | sol-1: exactness sentence added · mcq4
Two 105.0 g samples sit side by side: one of water that warms by 9.0 °C, and one of olive oil that warms by 14.0 °C. Which sample absorbed more energy? (c of water = 4.18 J/(g·°C); c of olive oil = 1.97 J/(g·°C)) Treat the given values as exact.
The water — 3950.1 J compared with 2895.9 J. KEY
The olive oil, because its temperature change is larger.
Both absorbed the same energy, because their masses are equal.
The olive oil — 2895.9 J is the larger of the two energies.
THM-033 · hard · transfer · seq 19 · authored:U12-G3 stage 2 (impossible-gain diagnosis) · mcq4
A lab report claims that inside a leaky, uninsulated tub of water, a hot casting lost 3600 J while the water gained 3900 J. Why must the report be wrong?
In a leaky setup the water should gain LESS than the casting lost, never more — extra energy cannot appear from nowhere. KEY
Nothing is wrong — a large enough mass of water can gain more heat than the object lost.
The two numbers should instead match exactly, because heat lost always equals heat gained in every setup.
The report is wrong because the water's gain should always be exactly half the casting's loss.
THM-035 · hard · transfer · seq 20 · authored:U12-G3 stage 2 (which-ΔT-larger reasoning) | blind-1: near-duplicate both-equal distractor replaced with the inverted-c misconception | blind-2: key trimmed ('far below'/'much further' overgeneralization + longest-option cue) · mcq4
A hot metal ingot is lowered into an equal mass of cool water in a calorimeter, and the pair settles at one shared temperature. Which substance's temperature CHANGES more, and why?
The metal's — its lower specific heat capacity means the same exchanged energy moves its temperature further. KEY
The water's — it received every joule the metal lost, so its temperature must move further.
Both temperatures change equally, because the heat lost by the metal exactly equals the heat gained by the water.
The water's — its higher specific heat capacity means each joule moves its temperature further.
THM-031 · medium · application · seq 21 · authored:U12-G3 stage 2 (fresh FRQ; ΔT-subject production + one-step final-T extension, the lesson's own gate class) · frq
A 130.0 g cup of water at 27.5 °C sits near a bread oven and absorbs 2717 J of energy. (c of water = 4.18 J/(g·°C))
A 130.0 g cup of water at 27.5 °C sits near a bread oven and absorbs 2717 J of energy. (c of water = 4.18 J/(g·°C)) (a) Rearrange q = mcΔT so that the temperature change ΔT stands alone on the left. Write the rearranged equation. (b) Using your rearranged equation, calculate ΔT, in °C. Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit. (c) Find the water's final temperature, and state in one sentence why this last step is an addition rather than another rearrangement.
Part a. Rearrange q = mcΔT so that the temperature change ΔT stands alone on the left. Write the rearranged equation.
Model: Start from q = mcΔT. Divide both sides by m × c: ΔT = q ÷ (m × c)
Part b. Using your rearranged equation, calculate ΔT, in °C. Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit.
Model: Values: q = 2717 J m = 130.0 g c = 4.18 J/(g·°C) q = mcΔT, rearranged: ΔT = q ÷ (m × c) ΔT = 2717 ÷ (130.0 × 4.18) ΔT = 5.0 °C
Part c. Find the water's final temperature, and state in one sentence why this last step is an addition rather than another rearrangement.
Model: Final temperature = 27.5 + 5.0 = 32.5 °C. ΔT is a change, not a reading — so the final temperature comes from adding the change to the starting reading, which is arithmetic on top of the answer, not another rearrangement of q = mcΔT.
Full model answer. (a) Start from q = mcΔT. Divide both sides by m × c: ΔT = q ÷ (m × c) (b) Values: q = 2717 J m = 130.0 g c = 4.18 J/(g·°C) q = mcΔT, rearranged: ΔT = q ÷ (m × c) ΔT = 2717 ÷ (130.0 × 4.18) ΔT = 5.0 °C (c) Final temperature = 27.5 + 5.0 = 32.5 °C. ΔT is a change, not a reading — so the final temperature comes from adding the change to the starting reading, which is arithmetic on top of the answer, not another rearrangement of q = mcΔT.
THM-035 · hard · transfer · seq 22 · authored:U12-G3 stage 2 (fresh capstone FRQ; unknown-c variant, copper-value landing; values minted fresh) | stage-3b: '°C is lowered into' spec gram -> 'is placed into' | sol-1: symbolic balance line added before substitution in model + rubric (R15; part-c wording demanded it) · frq
A 950.0 g metal bar at 44.5 °C is placed into 140.0 g of water at 31.5 °C in a coffee-cup calorimeter, and the two settle at a shared 36.5 °C. (c of water = 4.18 J/(g·°C))
A 950.0 g metal bar at 44.5 °C is placed into 140.0 g of water at 31.5 °C in a coffee-cup calorimeter, and the two settle at a shared 36.5 °C. (c of water = 4.18 J/(g·°C)) (a) Write down each substance's own temperature change: the water's rise and the bar's drop. (b) Calculate the heat gained by the water, in J, showing the equation and the substitution. (c) Using the balance 'heat lost by the metal = heat gained by the water', find the metal's specific heat capacity, in J/(g·°C), to 3 significant figures. Write the balance with the metal's mass × c × ΔT on one side before substituting, then rearrange for c.
Part a. Write down each substance's own temperature change: the water's rise and the bar's drop.
Model: Each substance has its own change: water: ΔT = 36.5 − 31.5 = 5.0 °C (a rise of 5.0 °C) metal: ΔT = 44.5 − 36.5 = 8.0 °C (a drop of 8.0 °C)
Part b. Calculate the heat gained by the water, in J, showing the equation and the substitution.
Model: Calculate the water's heat first: q = mcΔT q = 140.0 × 4.18 × 5.0 q = 2926 J gained by the water
Part c. Using the balance 'heat lost by the metal = heat gained by the water', find the metal's specific heat capacity, in J/(g·°C), to 3 significant figures. Write the balance with the metal's mass × c × ΔT on one side before substituting, then rearrange for c.
Model: Write down the balance — heat lost by the metal = heat gained by the water: mass × c × ΔT of the metal = q gained by the water 950.0 × c × 8.0 = 2926 Rearranged for c: c = 2926 ÷ (950.0 × 8.0) c = 0.385 J/(g·°C) That is the table value for copper — the balance just measured a real metal's specific heat capacity.
Full model answer. (a) Each substance has its own change: water: ΔT = 36.5 − 31.5 = 5.0 °C (a rise of 5.0 °C) metal: ΔT = 44.5 − 36.5 = 8.0 °C (a drop of 8.0 °C) (b) Calculate the water's heat first: q = mcΔT q = 140.0 × 4.18 × 5.0 q = 2926 J gained by the water (c) Write down the balance — heat lost by the metal = heat gained by the water: mass × c × ΔT of the metal = q gained by the water 950.0 × c × 8.0 = 2926 Rearranged for c: c = 2926 ÷ (950.0 × 8.0) c = 0.385 J/(g·°C) That is the table value for copper — the balance just measured a real metal's specific heat capacity.

Form D

THM-025 · easy · recall · seq 1 · authored:U12-G3 stage 2 (definitional meaning read; 1.97 = canonical olive-oil value on an unnamed liquid, taught-constant lane) · mcq4
A data sheet lists a cooking liquid's specific heat capacity as 1.97 J/(g·°C). Exactly what does the 1.97 J pay for?
Raising the temperature of 1 g of the liquid by 1 °C. KEY
Bringing 1 g of the liquid to a final temperature of 1 °C.
Raising the temperature of any amount of the liquid by 1 °C.
Raising the temperature of 1 g of the liquid by any number of degrees.
THM-029 · easy · recall · seq 2 · authored:U12-G3 stage 2 (unit identification — R11 bare unit labels) · mcq4
Which unit belongs to the specific heat capacity c in q = mcΔT?
J/(g·°C) KEY
J
°C
g
THM-033 · easy · recall · seq 3 · authored:U12-G3 stage 2 (balance identity read, joule-for-joule wording) | sol-1: box declared non-absorbing; hoarder-distractor feedback realigned · mcq4
A warmed clay ball rests in cool water inside a sealed, insulated box that leaks no heat and absorbs none itself, until the two match. Which statement is exactly true?
Every joule the clay ball loses ends up in the water. KEY
The ball keeps most of its heat, because solids hold their energy tightly.
The ball and the water each lose energy until both cool to the box's own temperature.
The ball's heat is destroyed as it cools.
THM-026 · medium · application · seq 4 · authored:U12-G3 stage 2 (three-way rank off the table; A6 reference figure) | sol-1: caption no longer states the tested rule (giveaway) · mcq4
Using the table: samples of lead, sand, and ethanol, all of equal mass, each absorb the same energy. Rank the samples by temperature change, largest first.
FIGURE (data-table · stimulus) — title: "Specific heat capacities" · columns: ["Material", "Specific heat capacity (J/(g·°C))"] · rows: [["water", "4.18"], ["ethanol", "2.44"], ["olive oil", "1.97"], ["aluminum", "0.897"], ["sand", "0.84"], ["iron", "0.449"], ["copper", "0.385"], ["lead", "0.… · caption: "Real specific heat capacities of common materials." · style: "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "data-table",
  "title": "Specific heat capacities",
  "columns": [
   "Material",
   "Specific heat capacity (J/(g·°C))"
  ],
  "rows": [
   [
    "water",
    "4.18"
   ],
   [
    "ethanol",
    "2.44"
   ],
   [
    "olive oil",
    "1.97"
   ],
   [
    "aluminum",
    "0.897"
   ],
   [
    "sand",
    "0.84"
   ],
   [
    "iron",
    "0.449"
   ],
   [
    "copper",
    "0.385"
   ],
   [
    "lead",
    "0.128"
   ]
  ],
  "caption": "Real specific heat capacities of common materials.",
  "style": "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
 }
}
Lead, then sand, then ethanol. KEY
Ethanol, then sand, then lead.
Sand, then lead, then ethanol.
All three change by the same amount.
THM-027 · medium · application · seq 5 · authored:U12-G3 stage 2 (same-change-same-energy trap correction) · mcq4
Two pans of the same broth are warmed through the same temperature change: a small pan, and one holding five times as much. A student claims the two pans need equal energy 'because the temperature change is the same.' Which correction fixes the claim?
The larger pan needs five times the energy — with the change fixed, energy scales with the mass. KEY
No correction is needed — equal temperature changes always mean equal energy needs.
The larger pan needs twenty-five times the energy, because mass and change multiply together.
The larger pan needs more energy only if it is warmed more quickly than the small one.
THM-027 · medium · application · seq 6 · authored:U12-G3 stage 2 (proportional scaling, supplied real base energy; plain-line explanation per THM-027/028 specNotes — no scaffold, no formula substituted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
Warming 220 g of silver beads by 10 °C takes 517 J. How much energy does warming 660 g of the same beads by 10 °C take? Treat the given values as exact. Give your answer in joules.
Answer: 1551 J KEY
also accepted: 1,551 J, 1 551 J, 1551 J
wrongValueDiagnostics
[
 {
  "value": 517,
  "misconception": "you kept the energy the same because the temperature change is the same — three times the mass needs three times the energy",
  "feedback": "This answer is wrong — 517 J warms only the 220 g. Three times the grams need three times the shares: 3 × 517 J = 1551 J."
 },
 {
  "value": 172,
  "misconception": "you divided by three instead of multiplying — more mass needs more energy",
  "feedback": "This answer is wrong — dividing gives less energy for more beads. Three times the mass needs three times the energy: 1551 J."
 }
]
feedback
{
 "keyExplanation": "Same material, same temperature change — only the mass differs. 660 g is three times 220 g. Three times the mass needs three times the energy: 3 × 517 J = 1551 J.",
 "anticipatedWrong": [
  {
   "value": 517,
   "misconception": "you kept the energy the same because the temperature change is the same — three times the mass needs three times the energy",
   "feedback": "This answer is wrong — 517 J warms only the 220 g. Three times the grams need three times the shares: 3 × 517 J = 1551 J."
  },
  {
   "value": 172,
   "misconception": "you divided by three instead of multiplying — more mass needs more energy",
   "feedback": "This answer is wrong — dividing gives less energy for more beads. Three times the mass needs three times the energy: 1551 J."
  }
 ]
}
THM-028 · medium · application · seq 7 · authored:U12-G3 stage 2 (proportional scaling, supplied real base energy; plain-line explanation per THM-027/028 specNotes — no scaffold, no formula substituted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
Warming 115 g of water from 29 °C to 39 °C takes 4807 J. How much energy does warming the same 115 g of water from 29 °C to 79 °C take? Treat the given values as exact. Give your answer in joules.
Answer: 24035 J KEY
also accepted: 24,035 J, 24 035 J, 24035 J
wrongValueDiagnostics
[
 {
  "value": 9737,
  "misconception": "you scaled by the ratio of the final temperatures, 79 ÷ 39, instead of the ratio of the changes — the changes are 50 °C and 10 °C",
  "feedback": "This answer is wrong — 79 ÷ 39 compares readings, not changes. The changes are 10 °C and 50 °C, so the energy is 5 × 4807 J = 24035 J."
 },
 {
  "value": 4807,
  "misconception": "you kept the energy the same because it is the same sample — the change is five times larger, so the energy is too",
  "feedback": "This answer is wrong — 4807 J covers only a 10 °C change. A 50 °C change on the same sample needs 5 × 4807 J = 24035 J."
 }
]
feedback
{
 "keyExplanation": "Work with the CHANGES, not the final temperatures. First change: 39 − 29 = 10 °C. Second change: 79 − 29 = 50 °C — five times as large. Five times the change needs five times the energy: 5 × 4807 J = 24035 J.",
 "anticipatedWrong": [
  {
   "value": 9737,
   "misconception": "you scaled by the ratio of the final temperatures, 79 ÷ 39, instead of the ratio of the changes — the changes are 50 °C and 10 °C",
   "feedback": "This answer is wrong — 79 ÷ 39 compares readings, not changes. The changes are 10 °C and 50 °C, so the energy is 5 × 4807 J = 24035 J."
  },
  {
   "value": 4807,
   "misconception": "you kept the energy the same because it is the same sample — the change is five times larger, so the energy is too",
   "feedback": "This answer is wrong — 4807 J covers only a 10 °C change. A 50 °C change on the same sample needs 5 × 4807 J = 24035 J."
  }
 ]
}
THM-028 · medium · application · seq 8 · authored:U12-G3 stage 2 (equal-changes guard) · mcq4
The same jug of water is warmed once from 47.0 °C to 52.0 °C, and on another day from 84.0 °C to 89.0 °C. How do the two energy needs compare?
They are equal — both warmings are 5.0 °C changes on the same sample. KEY
The second needs more energy, because the water is already hotter to begin with.
The second needs almost twice the energy, because the readings are nearly twice as large.
The first needs more energy, because cooler water resists warming.
THM-029 · medium · application · seq 9 · authored:U12-G3 stage 2 (kg->g substitution trap, MPM-029 retrieval) · mcq4
A recipe measures 0.620 kg of water into a pot, and a student wants to use q = mcΔT on the warming. What value goes in for m?
620 g KEY
0.620 g
62.0 g
6.20 g
THM-030 · medium · application · seq 10 · authored:U12-G3 stage 2 (forward q, low-c metal; real lead value supplied in-stem) | stage-3b: 'warms by 10.0 °C' gram shared with A#11 -> 'heats up by 10.0 °C' | stage-3b: 'lead' material word carries the instance cross-lane (table row + '0.128 j g c' spec gram) -> unnamed metal counterweight, c supplied in-stem (value 0.128 = TC-CVALUES lane) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['288.0'] · numeric
A 225.0 g metal counterweight lying in sunshine heats up by 10.0 °C. How much energy does the counterweight absorb, in J? (c of the metal = 0.128 J/(g·°C)) Treat the given values as exact. Give your answer to 3 significant figures.
Answer: 288.0 J KEY
also accepted: 288 J
wrongValueDiagnostics
[
 {
  "value": 2880,
  "misconception": "you slipped the decimal in c — metal's value is 0.128 J/(g·°C), not 1.28",
  "feedback": "This answer is wrong — ten times too large. With c = 0.128, q = 225.0 × 0.128 × 10.0 = 288 J."
 },
 {
  "value": 1.28,
  "misconception": "you left out the mass — all three quantities on the right multiply",
  "feedback": "This answer is wrong — 0.128 × 10.0 covers only one gram. Multiply by the 225.0 g as well: q = 288 J."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nm = 225.0 g\nc = 0.128 J/(g·°C)\nΔT = 10.0 °C\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 225.0 × 0.128 × 10.0\nq = 288 J\nLead's very low specific heat capacity is why so little energy warms the whole counterweight.",
 "anticipatedWrong": [
  {
   "value": 2880,
   "misconception": "you slipped the decimal in c — metal's value is 0.128 J/(g·°C), not 1.28",
   "feedback": "This answer is wrong — ten times too large. With c = 0.128, q = 225.0 × 0.128 × 10.0 = 288 J."
  },
  {
   "value": 1.28,
   "misconception": "you left out the mass — all three quantities on the right multiply",
   "feedback": "This answer is wrong — 0.128 × 10.0 covers only one gram. Multiply by the 225.0 g as well: q = 288 J."
  }
 ]
}
THM-031 · medium · application · seq 11 · authored:U12-G3 stage 2 (c-subject solve, silver landing) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['0.2350', '.235'] · numeric
A 160.0 g metal bracket absorbs 376 J of energy and warms by 10.0 °C. What is the metal's specific heat capacity, in J/(g·°C)? Treat the given values as exact. Give your answer to 3 significant figures.
Answer: 0.235 J/(g·°C) KEY
also accepted: 0.235 J/(g·°C)
wrongValueDiagnostics
[
 {
  "value": 2.35,
  "misconception": "you divided by the mass only — divide by both the mass and the temperature change",
  "feedback": "This answer is wrong — divide by m AND ΔT together: c = 376 ÷ (160.0 × 10.0) = 0.235 J/(g·°C)."
 },
 {
  "value": 37.6,
  "misconception": "you divided by the temperature change only — divide by both the mass and the temperature change",
  "feedback": "This answer is wrong — divide by m AND ΔT together: c = 376 ÷ (160.0 × 10.0) = 0.235 J/(g·°C)."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nq = 376 J\nm = 160.0 g\nΔT = 10.0 °C\nWrite down the equation:\nq = mcΔT\nMake c the subject:\nc = q ÷ (m × ΔT)\nSubstitute in the values, and calculate:\nc = 376 ÷ (160.0 × 10.0)\nc = 0.235 J/(g·°C)\nThat is the table value for silver — the calculation just identified a real metal's specific heat capacity.",
 "anticipatedWrong": [
  {
   "value": 2.35,
   "misconception": "you divided by the mass only — divide by both the mass and the temperature change",
   "feedback": "This answer is wrong — divide by m AND ΔT together: c = 376 ÷ (160.0 × 10.0) = 0.235 J/(g·°C)."
  },
  {
   "value": 37.6,
   "misconception": "you divided by the temperature change only — divide by both the mass and the temperature change",
   "feedback": "This answer is wrong — divide by m AND ΔT together: c = 376 ÷ (160.0 × 10.0) = 0.235 J/(g·°C)."
  }
 ]
}
THM-031 · medium · application · seq 12 · authored:U12-G3 stage 2 (which-move variant) | blind-1 class sweep: swapped with C#12 — the c-move variant previewed D#21(a)'s c rearrangement; now the dT-subject form (D#21 asks c) · mcq4
A problem gives q, m, and c and asks for the temperature change ΔT. Which rearrangement of q = mcΔT is correct?
ΔT = q ÷ (m × c) — the energy divided by the two knowns together KEY
ΔT = q × m × c — the energy multiplied by the two knowns
ΔT = (m × c) ÷ q — the two knowns divided by the energy
ΔT = q ÷ c — the energy divided by the specific heat capacity only
THM-032 · medium · application · seq 13 · authored:U12-G3 stage 2 (missing-lid consequence) | blind-1: 'runs an energy-releasing dissolving' wording cleaned | blind-2: absolute-claim distractor wording softened · mcq4
A student dissolves an energy-releasing powder in a coffee-cup calorimeter but forgets to put the lid on. What happens to the measurement?
Some energy escapes through the open top, so the water's temperature change — and the measured energy — reads too small. KEY
The water's temperature change reads too large, because the open top lets extra warmth in from the room.
Nothing changes, because the foam cup on its own provides all the insulation the measurement needs.
The thermometer stops reading correctly without the lid to hold it.
THM-033 · medium · application · seq 14 · authored:U12-G3 stage 2 (heat lost = heat gained bookkeeping; plain-sentence explanation — identity, no formula) | stage-3 reword: container register 'well-insulated, sealed' (seq-14 lane) | blind-1: idealization parenthetical '(no heat leaks in or out)' added (reviewer idealization class) | sol-1: container declared non-absorbing (walls-absorption reading closed) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['3190.0'] · numeric
A heated brass weight sits in cool water inside a well-insulated, sealed carrier (no heat leaks in or out, and the container itself soaks up none) until both match. The water gains 3190 J during the exchange. How much heat did the brass weight lose, in J? Treat the given values as exact. Give your answer in joules.
Answer: 3190 J KEY
also accepted: 3,190 J
wrongValueDiagnostics
[
 {
  "value": -3190,
  "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and 'lost' already carries the direction",
  "feedback": "This answer is wrong in form — give the size of the transfer: the weight lost 3190 J."
 },
 {
  "value": 6380,
  "misconception": "you doubled the energy, counting it once leaving the weight and once entering the water — it is the same 3190 J, transferred once",
  "feedback": "This answer is wrong — one transfer, counted from either end: the weight lost exactly the 3190 J the water gained."
 }
]
feedback
{
 "keyExplanation": "The carrier is sealed and insulated, so no energy escapes and none appears from anywhere else. Heat lost equals heat gained, so the weight lost exactly what the water gained: 3190 J.",
 "anticipatedWrong": [
  {
   "value": -3190,
   "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and 'lost' already carries the direction",
   "feedback": "This answer is wrong in form — give the size of the transfer: the weight lost 3190 J."
  },
  {
   "value": 6380,
   "misconception": "you doubled the energy, counting it once leaving the weight and once entering the water — it is the same 3190 J, transferred once",
   "feedback": "This answer is wrong — one transfer, counted from either end: the weight lost exactly the 3190 J the water gained."
  }
 ]
}
THM-034 · medium · application · seq 15 · authored:U12-G3 stage 2 (reaction release measured via the water; wrong-m trap planted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['3553.0'] · numeric
An 8.5 g effervescent capsule fizzes in 85.0 g of calorimeter water, and the water warms from 33.5 °C to 43.5 °C. How much heat did the reaction release, in J? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 4 significant figures.
Answer: 3553.0 J KEY
also accepted: 3,553 J
wrongValueDiagnostics
[
 {
  "value": 355.3,
  "misconception": "you used the capsule's mass instead of the water's — the equation is run on the WATER, the substance whose temperature was measured",
  "feedback": "This answer is wrong — the 8.5 g capsule is the trap. Use the water's 85.0 g: q = 85.0 × 4.18 × 10.0 = 3553 J released."
 },
 {
  "value": 15455.6,
  "misconception": "you used the final temperature instead of the temperature change — ΔT = 43.5 − 33.5 = 10.0 °C",
  "feedback": "This answer is wrong — 43.5 is a reading, not a change. ΔT = 10.0 °C, so q = 3553 J released."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question — for the water:\nm = 85.0 g\nc = 4.18 J/(g·°C)\nΔT = 43.5 − 33.5 = 10.0 °C\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 85.0 × 4.18 × 10.0\nq = 3553 J — released, because the water warmed. The capsule's 8.5 g never enters the calculation.",
 "anticipatedWrong": [
  {
   "value": 355.3,
   "misconception": "you used the capsule's mass instead of the water's — the equation is run on the WATER, the substance whose temperature was measured",
   "feedback": "This answer is wrong — the 8.5 g capsule is the trap. Use the water's 85.0 g: q = 85.0 × 4.18 × 10.0 = 3553 J released."
  },
  {
   "value": 15455.6,
   "misconception": "you used the final temperature instead of the temperature change — ΔT = 43.5 − 33.5 = 10.0 °C",
   "feedback": "This answer is wrong — 43.5 is a reading, not a change. ΔT = 10.0 °C, so q = 3553 J released."
  }
 ]
}
THM-034 · medium · application · seq 16 · authored:U12-G3 stage 2 (flow-direction read) · mcq4
A pellet dissolves in calorimeter water, and the reading climbs from room temperature to noticeably warmer. In which direction did the energy flow?
From the dissolving process into the water — the process released energy, so it is exothermic. KEY
From the water into the dissolving process — the process absorbed energy, so it is endothermic.
No energy moved — dissolving always warms water on its own, without any transfer.
From the thermometer into the water, which is why the reading climbed.
THM-026 · hard · transfer · seq 17 · authored:U12-G3 stage 2 (inverse comparison, factor read) · mcq4
Equal masses of two materials, R and S, absorb the same energy. R's temperature change is four times S's. Which statement is correct?
R's specific heat capacity is about one quarter of S's — the larger change marks the lower value. KEY
R's specific heat capacity is about four times S's — the larger change marks the higher value.
R's specific heat capacity equals S's, because the two energy inputs match.
The factor says nothing about the two specific heat capacities.
THM-030 · hard · transfer · seq 18 · authored:U12-G3 stage 2 (two-product comparison; copper wins, mechanism distractor) | stage-3 rework: copper collides with THM-030's own spec text (own-lesson material + 'c of copper 0.385' verbatim WE clause) on every form -> silver comparison at fresh values (SEED RULING / rule-58 rework) | sol-1: exactness sentence added · mcq4
Two 145.0 g samples sit side by side: one of water that warms by 7.0 °C, and one of silver that warms by 88.0 °C. Which sample absorbed more energy? (c of water = 4.18 J/(g·°C); c of silver = 0.235 J/(g·°C)) Treat the given values as exact.
The water — 4242.7 J compared with 2998.6 J. KEY
The silver, because its temperature change is larger.
Both absorbed the same energy, because their masses are equal.
The silver — 2998.6 J is the larger of the two energies.
THM-033 · hard · transfer · seq 19 · authored:U12-G3 stage 2 (uninsulated expectation check) | blind-1 HARD fix: room-temperature water stated (closes the colder-than-room reading); gains-more distractor made a conservation violation · mcq4
A hot machine part cools in an open, uninsulated basin of room-temperature water. A student expects the water to gain exactly the heat the part loses. What actually happens?
The water gains less than the part loses, because some energy escapes to the basin and the surrounding room. KEY
The water gains exactly what the part loses — the balance holds in every setup, insulated or not.
The water gains more than the part loses, because open water automatically pulls in extra heat from everything nearby.
No energy reaches the water at all, because transfers need insulation to work.
THM-035 · hard · transfer · seq 20 · authored:U12-G3 stage 2 (halfway-prediction diagnosis) · mcq4
A hot block of a low-specific-heat metal is dropped into an equal mass of cool water. A student predicts the shared temperature will sit exactly halfway between the two starts. Why is the prediction wrong?
Halfway would need equal specific heat capacities — the metal's far lower value means its big drop lifts the water only a little. KEY
It fails because the water gains less heat than the metal loses inside the calorimeter.
It fails because the denser metal counts for more than the water in the balance.
It is not wrong — samples of equal mass always settle exactly halfway between their starting temperatures, whatever the materials.
THM-031 · medium · application · seq 21 · authored:U12-G3 stage 2 (fresh FRQ; c-subject production, iron-value landing) · frq
A 900.0 g metal doorstop absorbs 4041 J of energy and warms steadily by 10.0 °C.
A 900.0 g metal doorstop absorbs 4041 J of energy and warms steadily by 10.0 °C. (a) Rearrange q = mcΔT so that the specific heat capacity c stands alone on the left. Write the rearranged equation. (b) Using your rearranged equation, calculate the metal's specific heat capacity, in J/(g·°C). Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit. (c) In one sentence, state what your answer means for warming exactly one gram of this metal by exactly one degree Celsius.
Part a. Rearrange q = mcΔT so that the specific heat capacity c stands alone on the left. Write the rearranged equation.
Model: Start from q = mcΔT. Divide both sides by m × ΔT: c = q ÷ (m × ΔT)
Part b. Using your rearranged equation, calculate the metal's specific heat capacity, in J/(g·°C). Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit.
Model: Values: q = 4041 J m = 900.0 g ΔT = 10.0 °C q = mcΔT, rearranged: c = q ÷ (m × ΔT) c = 4041 ÷ (900.0 × 10.0) c = 0.449 J/(g·°C)
Part c. In one sentence, state what your answer means for warming exactly one gram of this metal by exactly one degree Celsius.
Model: Raising the temperature of 1 g of this metal by 1 °C takes 0.449 J.
Full model answer. (a) Start from q = mcΔT. Divide both sides by m × ΔT: c = q ÷ (m × ΔT) (b) Values: q = 4041 J m = 900.0 g ΔT = 10.0 °C q = mcΔT, rearranged: c = q ÷ (m × ΔT) c = 4041 ÷ (900.0 × 10.0) c = 0.449 J/(g·°C) (c) Raising the temperature of 1 g of this metal by 1 °C takes 0.449 J.
THM-035 · hard · transfer · seq 22 · authored:U12-G3 stage 2 (fresh capstone FRQ; water-into-water final-T variant; values minted fresh) | stage-3 freshen: 140.0 g shared with C#22's cool-water mass -> 465.0/155.0 g (same 3:1 ratio, T = 58.5 unchanged) | sol-1: model solve chain re-derived for 465.0/155.0 (stale 420/140 expansion coefficients removed) · frq
465.0 g of hot water at 74.0 °C is poured into 155.0 g of cool water at 12.0 °C in a calorimeter, and the mixture reaches one shared final temperature T. (c of water = 4.18 J/(g·°C))
465.0 g of hot water at 74.0 °C is poured into 155.0 g of cool water at 12.0 °C in a calorimeter, and the mixture reaches one shared final temperature T. (c of water = 4.18 J/(g·°C)) (a) Write each sample's temperature change in terms of T: the hot water's drop and the cool water's rise. (b) Write the balance 'heat lost by the hot water = heat gained by the cool water' with q = mcΔT on each side, and state why c divides out. (c) Solve for T step by step, to 3 significant figures, and finish with one sentence explaining why the answer lands so much nearer 74.0 °C than 12.0 °C.
Part a. Write each sample's temperature change in terms of T: the hot water's drop and the cool water's rise.
Model: Write down the values, and each sample's own change in terms of T: hot water: m = 465.0 g, starts at 74.0 °C, drop = 74.0 − T cool water: m = 155.0 g, starts at 12.0 °C, rise = T − 12.0
Part b. Write the balance 'heat lost by the hot water = heat gained by the cool water' with q = mcΔT on each side, and state why c divides out.
Model: Write down the balance — heat lost by the hot water = heat gained by the cool water: 465.0 × c × (74.0 − T) = 155.0 × c × (T − 12.0) Both samples are water, so the same c multiplies both sides and divides out.
Part c. Solve for T step by step, to 3 significant figures, and finish with one sentence explaining why the answer lands so much nearer 74.0 °C than 12.0 °C.
Model: Substitute and solve step by step: 465.0 × (74.0 − T) = 155.0 × (T − 12.0) 3 × (74.0 − T) = T − 12.0 222 − 3T = T − 12 234 = 4T T = 58.5 °C The shared temperature lands much nearer 74.0 °C than 12.0 °C because the hot sample holds three times the mass — the larger mass carries more weight in the balance.
Full model answer. (a) Write down the values, and each sample's own change in terms of T: hot water: m = 465.0 g, starts at 74.0 °C, drop = 74.0 − T cool water: m = 155.0 g, starts at 12.0 °C, rise = T − 12.0 (b) Write down the balance — heat lost by the hot water = heat gained by the cool water: 465.0 × c × (74.0 − T) = 155.0 × c × (T − 12.0) Both samples are water, so the same c multiplies both sides and divides out. (c) Substitute and solve step by step: 465.0 × (74.0 − T) = 155.0 × (T − 12.0) 3 × (74.0 − T) = T − 12.0 222 − 3T = T − 12 234 = 4T T = 58.5 °C The shared temperature lands much nearer 74.0 °C than 12.0 °C because the hot sample holds three times the mass — the larger mass carries more weight in the balance.

Form E

THM-025 · easy · recall · seq 1 · authored:U12-G3 stage 2 (joule-size anchor, rule-line instance; fresh oversize distractor set) | blind-1: 'Small —' answer-prefix tell removed from the key · mcq4
Roughly how large is one joule of energy?
About the energy of lifting an apple from the floor to a table. KEY
About the energy a phone battery stores when full.
About the energy needed to warm a whole bath of water.
About the energy a space heater delivers over an evening.
THM-029 · easy · recall · seq 2 · authored:U12-G3 stage 2 (symbol meaning read — m + unit discipline) · mcq4
In the heat equation q = mcΔT, what does m stand for, and in what unit must it be substituted?
The mass of the sample, in grams (g). KEY
The mass of the sample, in kilograms (kg).
The material's specific heat capacity, in J/(g·°C).
The temperature change of the sample, in °C.
THM-033 · easy · recall · seq 3 · authored:U12-G3 stage 2 (balance identity read, one-transfer framing) · mcq4
A heated coin is sealed with cool water in an insulated lunch jar until the two match. Which statement is exactly true?
The heat the coin loses equals the heat the water gains, joule for joule. KEY
Some of the coin's heat disappears, because the water cannot absorb energy as fast as the coin sheds it.
The water gains only half of what the coin loses; the other half stays stored in the metal.
The coin and the water both gain heat drawn in from the jar's walls.
THM-026 · medium · application · seq 4 · authored:U12-G3 stage 2 (inverted smaller-change read; A6 reference figure) | sol-1: caption no longer states the tested rule (giveaway) · mcq4
Using the table: one sample of ethanol and one of copper, equal in mass, each absorb the same energy. Which sample ends up with the SMALLER temperature change?
FIGURE (data-table · stimulus) — title: "Specific heat capacities" · columns: ["Material", "Specific heat capacity (J/(g·°C))"] · rows: [["water", "4.18"], ["ethanol", "2.44"], ["olive oil", "1.97"], ["aluminum", "0.897"], ["sand", "0.84"], ["iron", "0.449"], ["copper", "0.385"], ["lead", "0.… · caption: "Real specific heat capacities of common materials." · style: "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
raw spec
{
 "figureRequired": true,
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "data-table",
  "title": "Specific heat capacities",
  "columns": [
   "Material",
   "Specific heat capacity (J/(g·°C))"
  ],
  "rows": [
   [
    "water",
    "4.18"
   ],
   [
    "ethanol",
    "2.44"
   ],
   [
    "olive oil",
    "1.97"
   ],
   [
    "aluminum",
    "0.897"
   ],
   [
    "sand",
    "0.84"
   ],
   [
    "iron",
    "0.449"
   ],
   [
    "copper",
    "0.385"
   ],
   [
    "lead",
    "0.128"
   ]
  ],
  "caption": "Real specific heat capacities of common materials.",
  "style": "clean reference table — the THM-026 lesson figure verbatim; on screen for every student"
 }
}
The ethanol. KEY
The copper.
Both end up with the same change.
It cannot be told from specific heat capacities alone.
THM-027 · medium · application · seq 5 · authored:U12-G3 stage 2 (halving factor read) · mcq4
Warming a half-full bottle of the same juice through the same temperature change takes how much energy compared with warming the full bottle?
Half as much — with the change fixed, energy scales with the mass. KEY
The same amount — the temperature change sets the energy, not the amount.
One quarter as much.
Twice as much — smaller amounts heat less efficiently.
THM-027 · medium · application · seq 6 · authored:U12-G3 stage 2 (proportional scaling, supplied real base energy; plain-line explanation per THM-027/028 specNotes — no scaffold, no formula substituted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
Warming 280 g of olive oil by 5 °C takes 2758 J. How much energy does warming 560 g of olive oil by 5 °C take? Treat the given values as exact. Give your answer in joules.
Answer: 5516 J KEY
also accepted: 5,516 J, 5 516 J, 5516 J
wrongValueDiagnostics
[
 {
  "value": 2758,
  "misconception": "you kept the energy the same because the temperature change is the same — twice the mass needs twice the energy",
  "feedback": "This answer is wrong — 2758 J warms only the 280 g. Twice the grams need twice the shares: 2 × 2758 J = 5516 J."
 },
 {
  "value": 11032,
  "misconception": "you multiplied by four instead of two — doubling the mass doubles the energy, nothing more",
  "feedback": "This answer is wrong — 11032 J is a quadrupling. Twice the mass needs exactly twice the energy: 5516 J."
 }
]
feedback
{
 "keyExplanation": "Same material, same temperature change — only the mass differs. 560 g is twice 280 g. Twice the mass needs twice the energy: 2 × 2758 J = 5516 J.",
 "anticipatedWrong": [
  {
   "value": 2758,
   "misconception": "you kept the energy the same because the temperature change is the same — twice the mass needs twice the energy",
   "feedback": "This answer is wrong — 2758 J warms only the 280 g. Twice the grams need twice the shares: 2 × 2758 J = 5516 J."
  },
  {
   "value": 11032,
   "misconception": "you multiplied by four instead of two — doubling the mass doubles the energy, nothing more",
   "feedback": "This answer is wrong — 11032 J is a quadrupling. Twice the mass needs exactly twice the energy: 5516 J."
  }
 ]
}
THM-028 · medium · application · seq 7 · authored:U12-G3 stage 2 (proportional scaling, supplied real base energy; plain-line explanation per THM-027/028 specNotes — no scaffold, no formula substituted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) · numeric
Warming 155 g of water from 6 °C to 16 °C takes 6479 J. How much energy does warming the same 155 g of water from 6 °C to 36 °C take? Treat the given values as exact. Give your answer in joules.
Answer: 19437 J KEY
also accepted: 19,437 J, 19 437 J, 19437 J
wrongValueDiagnostics
[
 {
  "value": 14578,
  "misconception": "you scaled by the ratio of the final temperatures, 36 ÷ 16, instead of the ratio of the changes — the changes are 30 °C and 10 °C",
  "feedback": "This answer is wrong — 36 ÷ 16 compares readings, not changes. The changes are 10 °C and 30 °C, so the energy is 3 × 6479 J = 19437 J."
 },
 {
  "value": 6479,
  "misconception": "you kept the energy the same because it is the same sample — three times the change needs three times the energy",
  "feedback": "This answer is wrong — 6479 J covers only a 10 °C change. A 30 °C change on the same sample needs 3 × 6479 J = 19437 J."
 }
]
feedback
{
 "keyExplanation": "Work with the CHANGES, not the final temperatures. First change: 16 − 6 = 10 °C. Second change: 36 − 6 = 30 °C — three times as large. Three times the change needs three times the energy: 3 × 6479 J = 19437 J.",
 "anticipatedWrong": [
  {
   "value": 14578,
   "misconception": "you scaled by the ratio of the final temperatures, 36 ÷ 16, instead of the ratio of the changes — the changes are 30 °C and 10 °C",
   "feedback": "This answer is wrong — 36 ÷ 16 compares readings, not changes. The changes are 10 °C and 30 °C, so the energy is 3 × 6479 J = 19437 J."
  },
  {
   "value": 6479,
   "misconception": "you kept the energy the same because it is the same sample — three times the change needs three times the energy",
   "feedback": "This answer is wrong — 6479 J covers only a 10 °C change. A 30 °C change on the same sample needs 3 × 6479 J = 19437 J."
  }
 ]
}
THM-028 · medium · application · seq 8 · authored:U12-G3 stage 2 (finals-ratio trap, x5) · mcq4
The same tub of water is warmed once from 7 °C to 19 °C, and once from 7 °C to 67 °C. The second warming needs how many times the first warming's energy?
Five times. KEY
About three and a half times.
Nearly ten times.
The same, because it is the same tub of water.
THM-029 · medium · application · seq 9 · authored:U12-G3 stage 2 (which-quantity-differs, ΔT variant) · mcq4
One pan of water is warmed twice: first through a small temperature change, later through a much larger one. In q = mcΔT applied to each warming, which right-hand quantity differs between the two?
ΔT — the two warmings have different temperature changes. KEY
m — the second warming must use more water.
c — water's specific heat capacity rises as it gets hotter.
m and c both differ, because hotter water is lighter and easier to warm.
THM-030 · medium · application · seq 10 · authored:U12-G3 stage 2 (forward q, cooling case; ΔT = higher minus lower, direction word per D2) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['7315.0'] · numeric
A 350.0 g pot of water cools from 68.0 °C to 63.0 °C as it stands. How much energy does the water release, in J? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 4 significant figures.
Answer: 7315.0 J KEY
also accepted: 7,315 J
wrongValueDiagnostics
[
 {
  "value": -7315,
  "misconception": "you reported a negative value — q is a magnitude here, and the word 'released' carries the direction",
  "feedback": "This answer is wrong in form — give the size of the transfer, 7315 J, with the direction carried by 'released'."
 },
 {
  "value": 99484,
  "misconception": "you used a single reading instead of the temperature change — ΔT is the size of the drop, 68.0 − 63.0 = 5.0 °C",
  "feedback": "This answer is wrong — 68.0 is a reading, not a change. The drop is 5.0 °C, so q = 350.0 × 4.18 × 5.0 = 7315 J released."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nm = 350.0 g\nc = 4.18 J/(g·°C)\nΔT = 68.0 − 63.0 = 5.0 °C (a drop of 5.0 °C)\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 350.0 × 4.18 × 5.0\nq = 7315 J — released, because the water cooled",
 "anticipatedWrong": [
  {
   "value": -7315,
   "misconception": "you reported a negative value — q is a magnitude here, and the word 'released' carries the direction",
   "feedback": "This answer is wrong in form — give the size of the transfer, 7315 J, with the direction carried by 'released'."
  },
  {
   "value": 99484,
   "misconception": "you used a single reading instead of the temperature change — ΔT is the size of the drop, 68.0 − 63.0 = 5.0 °C",
   "feedback": "This answer is wrong — 68.0 is a reading, not a change. The drop is 5.0 °C, so q = 350.0 × 4.18 × 5.0 = 7315 J released."
  }
 ]
}
THM-031 · medium · application · seq 11 · authored:U12-G3 stage 2 (ΔT-subject solve) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['5', '5.00'] · numeric
A 380.0 g basin of water absorbs 7942 J of energy from a heat lamp. By how many degrees Celsius does the water warm? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 2 significant figures.
Answer: 5.0 °C KEY
also accepted: 5.0 °C
wrongValueDiagnostics
[
 {
  "value": 20.9,
  "misconception": "you divided by the mass only and dropped the specific heat capacity — divide by both",
  "feedback": "This answer is wrong — divide by m AND c together: ΔT = 7942 ÷ (380.0 × 4.18) = 5.0 °C."
 },
 {
  "value": 1900.0,
  "misconception": "you divided by the specific heat capacity only and dropped the mass — divide by both",
  "feedback": "This answer is wrong — divide by m AND c together: ΔT = 7942 ÷ (380.0 × 4.18) = 5.0 °C."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question:\nq = 7942 J\nm = 380.0 g\nc = 4.18 J/(g·°C)\nWrite down the equation:\nq = mcΔT\nMake ΔT the subject:\nΔT = q ÷ (m × c)\nSubstitute in the values, and calculate:\nΔT = 7942 ÷ (380.0 × 4.18)\nΔT = 5.0 °C",
 "anticipatedWrong": [
  {
   "value": 20.9,
   "misconception": "you divided by the mass only and dropped the specific heat capacity — divide by both",
   "feedback": "This answer is wrong — divide by m AND c together: ΔT = 7942 ÷ (380.0 × 4.18) = 5.0 °C."
  },
  {
   "value": 1900.0,
   "misconception": "you divided by the specific heat capacity only and dropped the mass — divide by both",
   "feedback": "This answer is wrong — divide by m AND c together: ΔT = 7942 ÷ (380.0 × 4.18) = 5.0 °C."
  }
 ]
}
THM-031 · medium · application · seq 12 · authored:U12-G3 stage 2 (m-subject form pick, alternate distractor space) | blind-1 class sweep: m-subject form previewed E#21(a)'s m rearrangement; rotated to the c-subject form | sol-1: distractor feedback target-variable leftover (mass -> specific heat capacity) · mcq4
Which rearrangement of q = mcΔT gives the specific heat capacity c?
c = q ÷ (m × ΔT) — the energy divided by the two knowns together KEY
c = (m × ΔT) ÷ q — the two knowns divided by the energy
c = q − (m × ΔT) — the two knowns subtracted from the energy
c = m × ΔT — the two knowns multiplied, with the energy dropped
THM-032 · medium · application · seq 13 · authored:U12-G3 stage 2 (part-job identification, reasoned distractors) · mcq4
In a coffee-cup calorimeter, which part has the job of recording the water's temperature change?
The thermometer, inserted through the lid into the water. KEY
The insulated foam cup — its walls sense the warmth passing through them.
The measured mass of water — it displays its own temperature on its surface.
The lid — it reads the temperature of the space under the lid trapped inside the cup.
THM-033 · medium · application · seq 14 · authored:U12-G3 stage 2 (heat lost = heat gained bookkeeping; plain-sentence explanation — identity, no formula) | stage-3 reword: spec-mirroring 'loses N J as it cools' construction replaced; container register 'well-insulated, sealed' (seq-14 lane) | blind-1: idealization parenthetical '(no heat leaks in or out)' added (reviewer idealization class) | sol-1: container declared non-absorbing (walls-absorption reading closed) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['2465.0'] · numeric
Inside a well-insulated, sealed crate (no heat leaks in or out, and the container itself soaks up none), a warm metal clamp rests in cool water until the two match. The clamp gives up 2465 J while cooling. How much heat does the water gain, in J? Treat the given values as exact. Give your answer in joules.
Answer: 2465 J KEY
also accepted: 2,465 J
wrongValueDiagnostics
[
 {
  "value": -2465,
  "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and 'gain' already carries the direction",
  "feedback": "This answer is wrong in form — give the size of the transfer: the water gained 2465 J."
 },
 {
  "value": 4930,
  "misconception": "you doubled the energy, counting it once leaving the clamp and once entering the water — it is the same 2465 J, transferred once",
  "feedback": "This answer is wrong — one transfer, counted from either end: the water gained exactly the 2465 J the clamp lost."
 }
]
feedback
{
 "keyExplanation": "The crate is sealed and insulated, so the transferred energy has nowhere else to go. The heat lost by the hotter object equals the heat gained by the colder object: 2465 J out of the clamp means 2465 J into the water.",
 "anticipatedWrong": [
  {
   "value": -2465,
   "misconception": "you reported a negative value — heat lost and heat gained are magnitudes here, and 'gain' already carries the direction",
   "feedback": "This answer is wrong in form — give the size of the transfer: the water gained 2465 J."
  },
  {
   "value": 4930,
   "misconception": "you doubled the energy, counting it once leaving the clamp and once entering the water — it is the same 2465 J, transferred once",
   "feedback": "This answer is wrong — one transfer, counted from either end: the water gained exactly the 2465 J the clamp lost."
  }
 ]
}
THM-034 · medium · application · seq 15 · authored:U12-G3 stage 2 (dissolving release measured via the water; wrong-m trap planted) | sol-1: exactness sentence added (QB 3.7 exact-division doctrine; closes the strict-propagation objection) | sol-1: over-precise alternates dropped ['4389.0'] · numeric
9.0 g of a solid stirs into 210.0 g of water in a coffee-cup calorimeter, and the water warms from 11.5 °C to 16.5 °C. How much heat did the dissolving release, in J? (c of water = 4.18 J/(g·°C)) Treat the given values as exact. Give your answer to 4 significant figures.
Answer: 4389.0 J KEY
also accepted: 4,389 J
wrongValueDiagnostics
[
 {
  "value": 188.1,
  "misconception": "you used the solid's mass instead of the water's — the equation is run on the WATER, the substance whose temperature was measured",
  "feedback": "This answer is wrong — the 9.0 g of solid is the trap. Use the water's 210.0 g: q = 210.0 × 4.18 × 5.0 = 4389 J released."
 },
 {
  "value": 14483.7,
  "misconception": "you used the final temperature instead of the temperature change — ΔT = 16.5 − 11.5 = 5.0 °C",
  "feedback": "This answer is wrong — 16.5 is a reading, not a change. ΔT = 5.0 °C, so q = 4389 J released."
 }
]
feedback
{
 "keyExplanation": "Write down the values in the question — for the water:\nm = 210.0 g\nc = 4.18 J/(g·°C)\nΔT = 16.5 − 11.5 = 5.0 °C\nWrite down the equation:\nq = mcΔT\nSubstitute in the values, and calculate:\nq = 210.0 × 4.18 × 5.0\nq = 4389 J — released, because the water warmed. The solid's 9.0 g never enters the calculation.",
 "anticipatedWrong": [
  {
   "value": 188.1,
   "misconception": "you used the solid's mass instead of the water's — the equation is run on the WATER, the substance whose temperature was measured",
   "feedback": "This answer is wrong — the 9.0 g of solid is the trap. Use the water's 210.0 g: q = 210.0 × 4.18 × 5.0 = 4389 J released."
  },
  {
   "value": 14483.7,
   "misconception": "you used the final temperature instead of the temperature change — ΔT = 16.5 − 11.5 = 5.0 °C",
   "feedback": "This answer is wrong — 16.5 is a reading, not a change. ΔT = 5.0 °C, so q = 4389 J released."
  }
 ]
}
THM-034 · medium · application · seq 16 · authored:U12-G3 stage 2 (label + reason read) · mcq4
During a calorimeter run, the water's temperature falls while a powder dissolves in it. Which label fits the dissolving, and why?
Endothermic — the dissolving absorbed energy that the water supplied. KEY
Exothermic — the dissolving released energy into the water.
Exothermic — a falling reading always means energy has been released somewhere.
Neither — a temperature change says nothing about the direction of energy flow.
THM-026 · hard · transfer · seq 17 · authored:U12-G3 stage 2 (inverse comparison, threefold rise pair) · mcq4
Equal masses of two solids absorb the same energy: solid G warms by 33 °C and solid H warms by 11 °C. Which statement is correct?
G's specific heat capacity is about a third of H's. KEY
G's specific heat capacity is about three times H's.
G and H share one specific heat capacity, because the energy inputs were the same.
H must be a metal and G a nonmetal.
THM-030 · hard · transfer · seq 18 · authored:U12-G3 stage 2 (two-product comparison; water wins) | stage-3 rework: copper collides with THM-030's own spec text (own-lesson material + 'c of copper 0.385' verbatim WE clause) on every form -> olive oil comparison at fresh values (SEED RULING / rule-58 rework) | sol-1: exactness sentence added · mcq4
Two 165.0 g samples sit side by side: one of water that warms by 8.0 °C, and one of olive oil that warms by 12.0 °C. Which sample absorbed more energy? (c of water = 4.18 J/(g·°C); c of olive oil = 1.97 J/(g·°C)) Treat the given values as exact.
The water — 5517.6 J compared with 3900.6 J. KEY
The olive oil, because its temperature change is larger.
Both absorbed the same energy, because their masses are equal.
The olive oil — 3900.6 J is the larger of the two energies.
THM-033 · hard · transfer · seq 19 · authored:U12-G3 stage 2 (exact-equality license read) | blind-1 HARD fix: the leak-free premise now states 'nothing absorbed anywhere else', closing the apparatus-absorption reading of the slightly-less distractor | blind-2: premise restated as closed loss PATHS (surroundings/cup/lid/thermometer) so the exact-equality inference is still the student's step · mcq4
A sealed, insulated calorimeter is advertised as perfectly leak-free: no heat can escape to the surroundings, and none soaks into the cup, lid, or thermometer. If the advertisement were exactly true and a hot sample inside lost 5150 J, how much heat would the water gain, and why?
Exactly 5150 J — with no escape route, conservation forces the two totals to match. KEY
Slightly less than 5150 J, because a little heat always vanishes in any transfer.
Slightly more than 5150 J, because the water also draws some warmth out of the foam cup.
There is no way to tell without knowing the masses and the materials.
THM-035 · hard · transfer · seq 20 · authored:U12-G3 stage 2 (small-metal-large-water landing) · mcq4
A small, very hot chunk of metal is dropped into a calorimeter holding many times its mass of cool water, and the shared temperature ends barely above the water's start. Which account is correct?
The water's huge mass and high specific heat capacity mean the metal's whole loss lifts the water's temperature only slightly. KEY
Most of the metal's heat was destroyed before it could reach the water.
The balance broke — the water must have gained far less than the metal lost.
The exchange must have stopped early, leaving the small metal chunk permanently hotter than the water around it.
THM-031 · medium · application · seq 21 · authored:U12-G3 stage 2 (fresh FRQ; m-subject production with back-substitution check) · frq
A hot plate delivers 10868 J to a sample of water, warming it by exactly 8.0 °C. (c of water = 4.18 J/(g·°C))
A hot plate delivers 10868 J to a sample of water, warming it by exactly 8.0 °C. (c of water = 4.18 J/(g·°C)) (a) Rearrange q = mcΔT so that the mass m stands alone on the left. Write the rearranged equation. (b) Using your rearranged equation, calculate the mass of water, in g. Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit. (c) Check your answer: substitute your mass back into q = mcΔT and show that it returns the 10868 J.
Part a. Rearrange q = mcΔT so that the mass m stands alone on the left. Write the rearranged equation.
Model: Start from q = mcΔT. Divide both sides by c × ΔT: m = q ÷ (c × ΔT)
Part b. Using your rearranged equation, calculate the mass of water, in g. Show every step: the values from the question, the rearranged equation, the substitution, and the result with its unit.
Model: Values: q = 10868 J c = 4.18 J/(g·°C) ΔT = 8.0 °C q = mcΔT, rearranged: m = q ÷ (c × ΔT) m = 10868 ÷ (4.18 × 8.0) m = 325 g
Part c. Check your answer: substitute your mass back into q = mcΔT and show that it returns the 10868 J.
Model: Check: q = mcΔT = 325 × 4.18 × 8.0 = 10868 J — the hot plate's energy is returned, so the mass is right.
Full model answer. (a) Start from q = mcΔT. Divide both sides by c × ΔT: m = q ÷ (c × ΔT) (b) Values: q = 10868 J c = 4.18 J/(g·°C) ΔT = 8.0 °C q = mcΔT, rearranged: m = q ÷ (c × ΔT) m = 10868 ÷ (4.18 × 8.0) m = 325 g (c) Check: q = mcΔT = 325 × 4.18 × 8.0 = 10868 J — the hot plate's energy is returned, so the mass is right.
THM-035 · hard · transfer · seq 22 · authored:U12-G3 stage 2 (fresh capstone FRQ; water-into-water final-T variant, 2:1 mass ratio; values minted fresh) · frq
390.0 g of hot water at 71.0 °C is poured into 195.0 g of cool water at 11.0 °C in a calorimeter, and the mixture reaches one shared final temperature T. (c of water = 4.18 J/(g·°C))
390.0 g of hot water at 71.0 °C is poured into 195.0 g of cool water at 11.0 °C in a calorimeter, and the mixture reaches one shared final temperature T. (c of water = 4.18 J/(g·°C)) (a) Write each sample's temperature change in terms of T: the hot water's drop and the cool water's rise. (b) Write the balance 'heat lost by the hot water = heat gained by the cool water' with q = mcΔT on each side, and state why c divides out. (c) Solve for T step by step, to 3 significant figures, and finish with one sentence explaining where the answer lands between the two starting temperatures, and why.
Part a. Write each sample's temperature change in terms of T: the hot water's drop and the cool water's rise.
Model: Each sample has its own change, written with the unknown shared temperature T: hot water: ΔT = 71.0 − T (a drop) cool water: ΔT = T − 11.0 (a rise)
Part b. Write the balance 'heat lost by the hot water = heat gained by the cool water' with q = mcΔT on each side, and state why c divides out.
Model: Write down the balance — heat lost by the hot water = heat gained by the cool water: 390.0 × c × (71.0 − T) = 195.0 × c × (T − 11.0) Both substances are water, so c = 4.18 J/(g·°C) multiplies both sides and divides out: 390.0 × (71.0 − T) = 195.0 × (T − 11.0)
Part c. Solve for T step by step, to 3 significant figures, and finish with one sentence explaining where the answer lands between the two starting temperatures, and why.
Model: Solve step by step: 27,690 − 390T = 195T − 2,145 29,835 = 585T T = 51.0 °C The hot water drops 20.0 °C while the cool water rises 40.0 °C: with twice the mass, the hot water's side moves half as far, so the shared temperature lands twice as close to 71.0 °C as to 11.0 °C.
Full model answer. (a) Each sample has its own change, written with the unknown shared temperature T: hot water: ΔT = 71.0 − T (a drop) cool water: ΔT = T − 11.0 (a rise) (b) Write down the balance — heat lost by the hot water = heat gained by the cool water: 390.0 × c × (71.0 − T) = 195.0 × c × (T − 11.0) Both substances are water, so c = 4.18 J/(g·°C) multiplies both sides and divides out: 390.0 × (71.0 − T) = 195.0 × (T − 11.0) (c) Solve step by step: 27,690 − 390T = 195T − 2,145 29,835 = 585T T = 51.0 °C The hot water drops 20.0 °C while the cool water rises 40.0 °C: with twice the mass, the hot water's side moves half as far, so the shared temperature lands twice as close to 71.0 °C as to 11.0 °C.

End of Topic Test: Heating and cooling curves (u12-t4 · 5 forms × 21 items · 105 total)

David's notes for James:
full notes file
# u12-t4 — notes/queries from David's side (U12-G4)

1. COMPOSITION - 1 FRQ PER FORM, calc-heavy split predicate NOT MET (confirm): zero quant lessons in scope (no THM-036..040 lesson carries a displayEquation or atomKind 'quant'); the unit's calculation content (q = mc-delta-T, calorimetry) lives in Topics 7-8 (gates U12-G2/G3), and phase-change heat arithmetic is an explicit COURSE EXCLUSION (your THM-036/037/038 extraNotes: never compute heat amounts from curve segments). The scope's only numeric routine is GRAPH READING, so a calculation FRQ would have nothing to assess and the 5-line scaffold is barred everywhere (no formula is ever substituted). The FRQ slot goes to the terminal capstone production: THM-039 curve construction as a TYPED 3-part PLAN - (a) axes + starting state, (b) ordered pieces with plateau placement and phase-change names, (c) the range check (which phase-change temperatures produce a plateau in the drawn window and why; your rule line 9). Rubric 20/50/30 = 100. Case rotation: A heating/boiling-off-range-above (seed p9 structure), B heating full five-piece, C COOLING plan per D9 (seed p10 structure; freezing off-range-below; axes 'energy removed'), D heating five-piece with sub-zero melting plateau, E starts liquid / melting-off-range-below. Composition 20 objective + 1 FRQ = 21 items/form, 105 items over 5 forms; D5 evaluated and NOT triggered (min(20, 6 x 5) = 20; your target_size=20 concurs).
2. ALLOCATION OVER-GUIDELINE (confirm; recorded adjudication): 21 items over 5 lessons = 4 rows/lesson average, above the 2-3-per-lesson guidance (U7-G3/U10-G3 precedents). THM-037 carries FIVE rows (seq 8/9/10/11/18) because it is the scope's multi-case reading lesson with five distinct taught surfaces (heating plateau-id / numeric temperature read / state-in-region / cooling-curve read per D9 / mixture-on-plateau transfer); THM-036/THM-038/THM-040 carry 4; capstone THM-039 carries 3 objective + the FRQ.
3. NUMERIC CONTRACT (disclosure): one numeric ENTRY row per form (seq 9, your gate's only live numeric seed - THM-037 graph read). The answer is the plateau temperature read off the drawn curve: integer values (357 mercury A-verbatim seed, 63 palmitic acid, 216 anthracene, 44 lauric acid, 1587 antimony), tolerance carried from the seed's grid-read contract (8/4/8/4/20 = half a gridline), acceptedAlternates carry the .0 variant, sigFigs = digit count as display metadata with precisionAssessed=false + a gradingNote (sig-fig formatting is not the assessed skill; the read is - U01-G2 precedent), wrongValueDiagnostics carry the wrong-plateau and curve-top misreads. Stems are value-free (the read IS the task); every figure prints dashed guides to labeled axis values. No formula anywhere, so no scaffold (plain-sentence explanation).
4. ONE-CELL INSTANCE LEDGER + COMPUTED BARRED SET (disclosure - and why this gate needs NO whitelist relief): before authoring we computed the 35-value barred number set from your THM-036..040 spec text with the validator's own loader (0..12 ignored) and built a home-cell ledger where every substance token and every text-visible number lives in exactly ONE (form,seq) cell across the whole gate. Consequences honored: water's 0/100 never appear as data in any scanned text field (water-default distractor panels describe the drawn 0/100 plateaus inside figure payloads only, or use the ignored constant 0); zinc/pentane and friends whose real data collide with spec text sit ONLY on figure-value rows where stems reference plateaus positionally ('the first flat segment'). Result: zero taught-constant adjudications, zero validator relief - the freshness scan passes clean with no whitelist families. One recorded within-form note: '30' appears twice inside form A (gallium's 30 degC hold at seq 13; panel window -30 at seq 14) - within-form reuse is outside the cross-form exclusivity scan.
5. SEED FRESHENINGS UNDER THE STRICT SEED RULING (11 of 15 placed seeds carried must_freshen_instance; validator never weakened; skill/case-shape/misconception sets preserved): p0 steam-burn ('100 degC' barred + 'water' own-lesson -> 'a splash of the boiling liquid it rose from, both at the same temperature'; steam kept); p2 citrus growers (water -> 'a fine mist'); p3 tin cooling read (tin own-scope + 232 barred -> bismuth crucible, 271 drawn on the figure only); p5 mixture-on-plateau (mercury -> stearic acid: mercury's home is the seq-9 numeric cell, keeping it at seq 18 would telegraph the numeric answer within form A); p6 stronger-burner rate transfer (water/pot/100 barred -> 1-hexanol over a lab burner); p11 panel item (window endpoint 80 is a barred spec number -> -30..85); p12 flatness verdict (mercury -> octane); p13 slopes verdict (ethanol corpus-barred -> 1-octanol); p14 cooling water-default verdict (benzene 5.5/80 barred -> dodecane); p9 FRQ (lead's 327 barred -> aluminum 660/2470); p10 FRQ (benzene -> 1-heptanol, freezing off-range-below added). Placed VERBATIM: p1 (A#5), p7 (A#13 gallium), p8 (A#2); p4 (A#9 mercury numeric) is verbatim except the stem opener ('The figure shows the' is a corpus gram).
6. prod_seeds RULING (confirm): your two prod_seeds entries are byte-identical to THM-039's IN-LESSON fluency productions (naphthalene 20-250; ethanol -130..100) - student-seen items are SPARES ONLY, never test items (also: naphthalene's 80/218 and ethanol's -114/78/-130/100 are all barred spec numbers). The FRQ is seeded from the lesson's GATE prods instead (pool p9 = demo_curated[0] -> form A; pool p10 = demo_curated[1] -> form C, the D9 cooling plan). demo_curated[2] = pool[11] (dual-cited on the seq-14 placement).
7. DECOMPOSITION-REALISM SWAPS at authoritative QC (confirm; gate_config + ledger updated, stage-1 invariants re-PASS): sol failed three windows on real-chemistry grounds and we agreed - C#16 glycerol (boils ~290 degC WITH decomposition) -> hexadecane (18/287, clean 1-atm behavior); E#18 urea (decomposes at its ~133 degC melt) -> benzophenone (melts cleanly at 48 degC); A#18 stearic acid window truncated to the melting region (the 361 degC boiling plateau + gas segment removed - it decomposes near its boil). Also C#8 propanol -> 1-propanol (isomer ambiguity; the plotted -126/97 are 1-propanol's).
8. UNDRAWABLE-TRACE SWEEP at blind review (disclosure): reviewers caught narrated curve shapes that could not be drawn as described; we swept every figure/panel narration deterministically (flat-sequence vs rise/fall verbs) and fixed all 9 hits (seq-20 falling-middle family recast as a drawable dip-then-climb defect; seq-14 panel-D plateau order; seq-15 swapped-order cooling panels recast as a drawable freezing-only misconception rendition). Sweep re-run post-patch: 0 hits.
9. COURSE-MODEL-VS-NUANCE FLAGS (recorded-accepted at blind review; your call if any should flip): C#6 fog forming over a pond keeping the shoreline milder (microclimate simplification), E#7 molten sugar candy hardening framed as freezing (real candy also crystallizes), D#18 sulfur (allotrope subtleties near its melt), C#13 molten tungsten in a filament works (exotic but physical), B#19 impurity caveat on exactly-flat plateaus. The course-local idealized phase-change model is AUTHORITY (flat plateau = pure-substance phase change; the three-check routine), so these stand as taught.
10. MATERIAL-NAME BUDGET (disclosure): gate_config extra_materials lists 41 fresh instance tokens this gate uses (heptane, menthol, bismuth, hexadecane, benzophenone, ...) - DETECTION-STRENGTHENING ONLY (each occupies exactly one home cell; the scans now see these words). Anion tokens (chloride/bromide/fluoride/iodide) are deliberately NOT added: they are shared chemistry vocabulary across distinct salt instances (lithium chloride 16B vs table salt 17D vs calcium fluoride 21B); the cation/organic token is each instance's scanned marker. Confirm.
11. SOL STANDING MINOR (recorded-accepted): A#19's drifting plateau could equally be framed as a heights failure; sol's own note confirms the keyed verdict and the cited flatness failure remain uniquely correct, and the keyExplanation no longer claims the heights check passes. Kept as authored.
12. SCHEMA GAP carried from U2-G5/U4-G1 packaging (still open): our forms_final.json also records a structured modelAnswerFigureSpec per FRQ (the correct curve for each form's plan, deterministic figureSpec shape - kept INSIDE the frq object so blind packets cannot leak it); the section-6 schema has no field for it and the exporter does not carry it. The typed model answers are complete without it; say the word if you want the specs delivered and we will extend the schema together.
13. NOTA/AOTA: zero literal hits in your 15-seed pool and 2 prods; zero replace_distractor flags; none authored.
14. BINDING INSTANCE RULE (course-wide): zero fissile/weapons/dose framings; classroom-safe instance set throughout (foundry/lab/kitchen/jewelry-studio framings). Pool scanned clean at stage 1; re-swept at packaging over forms_final + this export body - zero hits.
15. STAGE-3 PACKAGING-AUDIT DISCLOSURE (no action needed): six per-row working files (rows 03/04/06/07/12/17) were found to be unfaithful pre-fix-wave drafts from a parallel packaging pass; the validated FORMS were always the canon (the 12/12 validator ran on the forms) and the row files were repaired byte-faithfully FROM the forms, then re-audited 21 rows x 5 forms byte-identical. This export was built from forms_final.json, which is byte-identical to the validated form_A..E.json and forms_v1.json (re-verified at packaging).

Form A

THM-036 · easy · recall · seq 1 · authored fresh (stage 2); fluency[0] pairing family, stem reworded (corpus) · mcq4
Which phase change is matched with its correct energy direction?
Vaporization — absorbs energy KEY
Melting — releases energy
Condensation — absorbs energy
Freezing — absorbs energy
THM-038 · easy · recall · seq 2 · seed:U12-G4 pool[8] VERBATIM · mcq4
Along which parts of a heating curve does the added energy go into speeding the particles up?
Along the sloped segments only. KEY
Along the plateaus only.
Along the sloped segments and the plateaus equally.
Nowhere — added energy never changes particle speed.
THM-039 · easy · recall · seq 3 · authored fresh (stage 2); rule-line recall rotation · mcq4
To sketch a substance's heating curve, which two pieces of data do you need?
Its melting temperature and its boiling temperature. KEY
Its mass and its volume.
Its starting temperature and its mass.
The exact amount of energy each segment will absorb.
THM-040 · easy · recall · seq 4 · authored fresh (stage 2); rule-line recall rotation · mcq4
Which set names the three checks used to evaluate someone else's heating curve?
Plateau heights, plateau flatness, and the slopes of the segments. KEY
Plateau heights, plateau lengths, and the slopes of the segments.
Plateau flatness, the slopes of the segments, and the steepness of each rising segment.
Plateau heights, plateau flatness, and the temperature at which the curve begins.
THM-036 · medium · application · seq 5 · seed:U12-G4 pool[1] VERBATIM · mcq4
Which list contains ONLY energy-absorbing phase changes?
Melting and vaporization KEY
Melting and condensation
Freezing and vaporization
Freezing and condensation
THM-036 · medium · application · seq 6 · seed:U12-G4 pool[0] — instance freshened (barred '100 °C' and own-lesson 'water' removed; physics unchanged) · mcq4
A jet of steam scalds far worse than a splash of an equal mass of the boiling liquid it rose from, even though both arrive at the same temperature. What explains the difference?
The steam condenses on the skin, and condensation releases energy into the skin on top of the hot liquid's warmth. KEY
The steam is actually much hotter than the boiling liquid, despite the matching readings.
The steam absorbs energy from the skin as it condenses, which damages the skin more deeply.
The steam gives up extra energy by expanding as it spreads across the skin, and spreading gases release energy.
THM-036 · medium · application · seq 7 · seed:U12-G4 pool[2] — instance freshened (own-lesson 'water'/'air' removed; mist framing) · mcq4
Before a night of frost, citrus growers spray a fine mist over their trees. As the mist freezes on the branches, the fruit is protected from the worst of the cold. How does the freezing mist help?
Freezing releases energy, and that released energy keeps the branches and fruit warmer. KEY
Freezing absorbs the cold out of the night.
The frozen coating absorbs energy from the fruit and stores it.
The protection comes from the warmth the spray carried out of the nozzle, which lasts until dawn.
THM-037 · medium · application · seq 8 · authored fresh (stage 2); THM-037 fluency[0] family, fresh substance/curve · mcq4
The figure presents heptane's heating curve. What is happening along the second flat segment?
FIGURE (heating-curve · stimulus) — substance: "heptane" · xAxis: "energy added" · yAxis: "temperature (°C), −120 to 130, gridlines every 25" · plateaus: [{"temp": -91}, {"temp": 98}] · range: "curve runs from −110 °C to 120 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −120 to 130, gridlines every 25; the trace ris…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "heptane",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −120 to 130, gridlines every 25",
  "plateaus": [
   {
    "temp": -91
   },
   {
    "temp": 98
   }
  ],
  "range": "curve runs from −110 °C to 120 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −120 to 130, gridlines every 25; the trace rises from −110 °C, holds exactly flat at -91 °C, rises, holds exactly flat at 98 °C, then rises to 120 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
The liquid is boiling — turning to gas. KEY
The liquid is warming toward its boiling temperature.
The solid is melting.
The gas is warming.
THM-037 · medium · application · seq 9 · seed:U12-G4 pool[4] (the gate's numeric seed) — stem opener reworded ('The figure shows the' is a corpus gram); answer contract carried verbatim · numeric
The figure gives mercury's heating curve. Read mercury's boiling temperature from the curve, in °C.
FIGURE (heating-curve · stimulus) — substance: "mercury" · xAxis: "energy added" · yAxis: "temperature (°C), −60 to 400, gridlines every 60" · plateaus: [{"temp": -39}, {"temp": 357}] · range: "curve runs from −55 °C to 390 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −60 to 400, gridlines every 60; the trace rise…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "mercury",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −60 to 400, gridlines every 60",
  "plateaus": [
   {
    "temp": -39
   },
   {
    "temp": 357
   }
  ],
  "range": "curve runs from −55 °C to 390 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −60 to 400, gridlines every 60; the trace rises from −55 °C, holds exactly flat at -39 °C, rises, holds exactly flat at 357 °C, then rises to 390 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Answer: 357.0 °C KEY
also accepted: 357.0
wrongValueDiagnostics
[
 {
  "value": -39.0,
  "misconception": "you read the first plateau — that is the melting temperature; boiling is the SECOND plateau, the higher one",
  "feedback": "This answer is wrong — you read the first plateau — that is the melting temperature; boiling is the SECOND plateau, the higher one."
 },
 {
  "value": 390.0,
  "misconception": "you read the top of the curve instead of a plateau — the boiling temperature is the height where the curve flattens the second time",
  "feedback": "This answer is wrong — you read the top of the curve instead of a plateau — the boiling temperature is the height where the curve flattens the second time."
 }
]
feedback
{
 "keyExplanation": "Find the second flat plateau — its height is the boiling temperature. The plateau sits at 357 °C, so mercury boils at 357 °C. The other plateau is the melting temperature."
}
THM-037 · medium · application · seq 10 · authored fresh (stage 2); THM-037 fluency[2] family, fresh substance + fresh region wording · mcq4
In the figure, pentane's heating curve carries a small arrow on its middle sloped stretch, between the first plateau and the second. What state is the pentane in along the arrowed stretch?
FIGURE (heating-curve · stimulus) — substance: "pentane" · xAxis: "energy added" · yAxis: "temperature (°C), −160 to 70, gridlines every 25" · plateaus: [{"temp": -130}, {"temp": 36}] · range: "curve runs from −152 °C to 61 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −160 to 70, gridlines every 25; the trace rise…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "pentane",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −160 to 70, gridlines every 25",
  "plateaus": [
   {
    "temp": -130
   },
   {
    "temp": 36
   }
  ],
  "range": "curve runs from −152 °C to 61 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −160 to 70, gridlines every 25; the trace rises from −152 °C, holds exactly flat at -130 °C, rises, holds exactly flat at 36 °C, then rises to 61 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis; a small arrow marks the middle sloped stretch, between the first plateau and the second"
 }
}
Liquid KEY
Solid
Gas
A mixture of solid and liquid
THM-037 · medium · application · seq 11 · seed:U12-G4 pool[3] — instance freshened (tin is an own-scope taught material and 232 is a barred spec number -> bismuth; stem made positional; key/distractor classes carried) · mcq4
A crucible of molten bismuth is left to lose energy in a metals workshop. The figure tracks its cooling curve: the trace falls, levels out once, then falls again. What is happening along the level stretch?
FIGURE (heating-curve · stimulus) — substance: "bismuth" · xAxis: "energy removed" · yAxis: "temperature (°C), 100 to 400, gridlines every 50" · plateaus: [{"temp": 271}] · range: "curve descends from 360 °C to 140 °C" · style: "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 100 to 400, gridlines every 50; the trace fa…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "bismuth",
  "xAxis": "energy removed",
  "yAxis": "temperature (°C), 100 to 400, gridlines every 50",
  "plateaus": [
   {
    "temp": 271
   }
  ],
  "range": "curve descends from 360 °C to 140 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 100 to 400, gridlines every 50; the trace falls from 360 °C, holds exactly flat at 271 °C, then falls to 140 °C; a dashed guide ties the flat stretch to its labeled value on the temperature axis"
 }
}
The liquid bismuth is freezing into solid bismuth. KEY
The liquid bismuth is boiling.
Gaseous bismuth is condensing into liquid bismuth there.
The solid bismuth is melting.
THM-038 · medium · application · seq 12 · authored fresh (stage 2); THM-038 fluency[0] family, fresh instance · mcq4
A beaker of cyclohexane boils briskly over a lab burner. Energy keeps arriving, yet the thermometer's reading stays put while the liquid boils away. Why?
Because during a phase change the added energy goes into pulling particles away from their neighbors and rearranging them, not into speeding them up. KEY
It stops absorbing energy from the heater while the boiling is underway, and only begins absorbing again once every drop of the liquid has become gas.
A thermometer is unable to give an accurate reading while bubbles of vapor keep forming and collapsing around its bulb inside the liquid.
The energy added during the boiling is destroyed at the moment the liquid turns to gas, so there is nothing left over to raise the reading.
THM-038 · medium · application · seq 13 · seed:U12-G4 pool[7] VERBATIM · mcq4
Molten gallium from a classroom demonstration is left to cool, and its temperature holds at 30 °C while it solidifies, even though the room keeps drawing energy out of it. Why does the temperature hold?
Particles settling back beside their neighbors release energy, and that release replaces what the room removes until the freezing finishes. KEY
The room stops removing energy from the gallium once the freezing starts, so its temperature cannot change until the freezing ends.
The solid gallium forming around the remaining liquid insulates it, blocking any more energy from leaving.
The particles keep moving at the same speed because nothing in a phase change can ever slow particles down.
THM-039 · medium · application · seq 14 · seed:U12-G4 pool[11] (= demo_curated[2], dual ref) — window endpoint freshened (80 is a barred spec number -> 85); water-default panel recast to the melting plateau; stem template reworded (the fluency panel-stem grams are corpus) · mcq4
A pure substance has a melting temperature of -7 °C and a boiling temperature of 59 °C. Panels A through D each graph a curve for it over the window from -30 °C to 85 °C. Which panel shows a correct heating curve?
FIGURE (heating-curve-panels · image-options) — kind: "heating" · panels: [{"panel": "A", "description": "rises, holds flat at 59 °C only, rises — no flat stretch at −7 °C"}, {"panel": "B", "description": "rises, holds exactly flat… · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose bes…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "heating",
  "panels": [
   {
    "panel": "A",
    "description": "rises, holds flat at 59 °C only, rises — no flat stretch at −7 °C"
   },
   {
    "panel": "B",
    "description": "rises, holds exactly flat at −7 °C, rises, holds exactly flat at 59 °C, rises"
   },
   {
    "panel": "C",
    "description": "rises, holds flat at 0 °C, rises, holds flat at 59 °C, rises"
   },
   {
    "panel": "D",
    "description": "falls, holds flat at 59 °C, falls, holds flat at −7 °C, falls — a descending trace"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: rises, holds flat at 59 °C only, rises — no flat stretch at −7 °C; Panel B: rises, holds exactly flat at −7 °C, rises, holds exactly flat at 59 °C, rises; Panel C: rises, holds flat at 0 °C, rises, holds flat at 59 °C, rises; Panel D: falls, holds flat at 59 °C, falls, holds flat at −7 °C, falls — a descending trace"
 }
}
Panel B KEY
Panel A
Panel C
Panel D
THM-039 · medium · application · seq 15 · authored fresh (stage 2); cooling-panel family (D9), gate p10 construction routine as MCQ surface · mcq4
A pure substance boils at 81 °C and melts at -23 °C. In the figure, four panels labeled A, B, C, and D each graph a curve recorded as a gas sample of the substance loses energy, from 104 °C down to -44 °C. Which panel shows a correct cooling curve?
FIGURE (heating-curve-panels · image-options) — kind: "cooling" · panels: [{"panel": "A", "description": "rises, holds flat at −23 °C, rises, holds flat at 81 °C, rises"}, {"panel": "B", "description": "falls, holds exactly flat at… · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose b…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "cooling",
  "panels": [
   {
    "panel": "A",
    "description": "rises, holds flat at −23 °C, rises, holds flat at 81 °C, rises"
   },
   {
    "panel": "B",
    "description": "falls, holds exactly flat at −23 °C, falls — its only flat stretch; no flat stretch at 81 °C"
   },
   {
    "panel": "C",
    "description": "falls, holds exactly flat at 81 °C, falls, holds exactly flat at −23 °C, falls"
   },
   {
    "panel": "D",
    "description": "falls, holds flat at 100 °C, falls, holds flat at 0 °C, falls"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: rises, holds flat at −23 °C, rises, holds flat at 81 °C, rises; Panel B: falls, holds exactly flat at −23 °C, falls — its only flat stretch; no flat stretch at 81 °C; Panel C: falls, holds exactly flat at 81 °C, falls, holds exactly flat at −23 °C, falls; Panel D: falls, holds flat at 100 °C, falls, holds flat at 0 °C, falls"
 }
}
Panel C KEY
Panel A
Panel B
Panel D
THM-040 · medium · application · seq 16 · authored fresh (stage 2); THM-040 fluency[2] correct-verdict class, fresh instance · mcq4
Gold melts at 1064 °C and boils at 2856 °C. In the figure, a heating curve recorded for gold runs from 800 °C to 3100 °C. Check the curve against the data. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "gold" · xAxis: "energy added" · yAxis: "temperature (°C), 600 to 3300, gridlines every 300" · plateaus: [{"temp": 1064}, {"temp": 2856}] · range: "curve runs from 800 °C to 3100 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 600 to 3300, gridlines every 300; the trace ri…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "gold",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 600 to 3300, gridlines every 300",
  "plateaus": [
   {
    "temp": 1064
   },
   {
    "temp": 2856
   }
  ],
  "range": "curve runs from 800 °C to 3100 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 600 to 3300, gridlines every 300; the trace rises from 800 °C, holds exactly flat at 1064 °C, rises, holds exactly flat at 2856 °C, then rises to 3100 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Correct — flat plateaus at 1064 °C and 2856 °C, rising segments everywhere else. KEY
Flawed — the first plateau should sit at 0 °C.
Flawed — the plateaus should slope gently upward instead of lying flat.
Flawed — a correct curve needs a third plateau between the two.
THM-038 · hard · transfer · seq 17 · seed:U12-G4 pool[6] — instance freshened (own-lesson 'water' + barred '100 °C' -> 1-hexanol, reading value unstated); the R8-exception rate-transfer structure and all four option classes carried · mcq4
A flask of 1-hexanol boils steadily over a lab burner, its thermometer holding one reading. The energy flowing in each second is then doubled — yet the reading does not move. What does the extra energy do?
It pulls particles away from their neighbors faster, so the liquid boils away sooner — at the same steady reading. KEY
It raises the liquid's temperature while it boils.
It is turned away at the surface, because a liquid that is already boiling can only ever absorb energy at one fixed, unchangeable rate.
It tears the liquid molecules apart into new substances instead of boiling them.
THM-037 · hard · transfer · seq 18 · seed:U12-G4 pool[5] — instance freshened (mercury's home is the seq-9 numeric row; keeping it here would telegraph that answer within form A) -> stearic acid; stem made positional (no plateau values in text) · mcq4
In the figure, a dashed guide marks a point partway along the flat segment of stearic acid's heating curve. Which statement describes the sample at the marked point?
FIGURE (heating-curve · stimulus) — substance: "stearic acid" · xAxis: "energy added" · yAxis: "temperature (°C), 0 to 200, gridlines every 25" · plateaus: [{"temp": 69}] · range: "curve runs from 30 °C to 150 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 200, gridlines every 25; the trace rises …
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "stearic acid",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 0 to 200, gridlines every 25",
  "plateaus": [
   {
    "temp": 69
   }
  ],
  "range": "curve runs from 30 °C to 150 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 200, gridlines every 25; the trace rises from 30 °C, holds exactly flat at 69 °C, then rises to 150 °C; dashed guides tie the flat stretch to its labeled value on the temperature axis; a dashed guide drops from a point partway along the flat segment"
 }
}
A mixture of solid and liquid stearic acid, with melting underway. KEY
Entirely solid stearic acid, warming toward its melting temperature.
Entirely liquid stearic acid, warming toward its boiling temperature.
A mixture of liquid and gaseous stearic acid.
THM-040 · hard · transfer · seq 19 · seed:U12-G4 pool[12] — instance freshened (mercury's home is the seq-9 numeric cell -> octane); drift narrated in stem per the seed's own pattern and drawn in the figure; option classes carried · mcq4
Octane melts at -57 °C and boils at 126 °C. In the figure, octane's heating curve matches the data everywhere except one feature: its first plateau is drawn drifting gently upward before the curve climbs on. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "octane" · xAxis: "energy added" · yAxis: "temperature (°C), −90 to 160, gridlines every 25" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −90 to 160, gridlines every 25; the trace rise…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "octane",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −90 to 160, gridlines every 25",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −90 to 160, gridlines every 25; the trace rises from −80 °C, then a near-flat stretch drifts gently upward from −57 °C to −45 °C, then the trace rises, holds exactly flat at 126 °C, and rises to 150 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the melting plateau must be exactly flat, because the temperature holds during a phase change. KEY
Correct — a small upward drift on a plateau is within normal drawing tolerance, so no check fails.
Flawed — the boiling plateau should also drift upward, to match the other one.
Flawed — the melting plateau belongs at 0 °C, not below zero.
THM-040 · hard · transfer · seq 20 · seed:U12-G4 pool[13] — instance freshened (ethanol's −114/78 are barred spec numbers -> 1-octanol); falling-middle-segment structure and option classes carried · mcq4
1-octanol melts at -16 °C and boils at 195 °C. In the figure, a classmate has drawn 1-octanol's heating curve: both plateaus sit exactly flat at the right heights, but the stretch between them first dips downward before climbing to the second plateau as energy is added. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "1-octanol" · xAxis: "energy added" · yAxis: "temperature (°C), −40 to 230, gridlines every 30" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −40 to 230, gridlines every 30; the trace rise…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "1-octanol",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −40 to 230, gridlines every 30",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −40 to 230, gridlines every 30; the trace rises from −30 °C, holds exactly flat at −16 °C, then dips below that height before climbing to hold exactly flat at 195 °C, then rises to 220 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the stretch between the plateaus must rise the whole way, because the liquid warms as energy is added. KEY
Correct — the plateau heights match the data, and heights are the only check.
Flawed — the middle stretch should be exactly flat, making one long plateau between the two temperatures.
Flawed — the melting plateau belongs at 0 °C.
THM-039 · medium · application · seq 21 · seed:U12-G4 pool[9] (= demo_curated[0], dual ref) — lead -> aluminum (327 is a barred spec number); off-range-boiling structure and checklist observables carried into the rubric; converted to the typed 3-part plan (V-T12) · frq
Aluminum melts at 660 °C and boils at 2470 °C. A worksheet asks for aluminum's heating curve, drawn across the window 425 °C to 925 °C. Do not draw it. Instead, type the plan for the curve:
Aluminum melts at 660 °C and boils at 2470 °C. A worksheet asks for aluminum's heating curve, drawn across the window 425 °C to 925 °C. Do not draw it. Instead, type the plan for the curve: (a) Give the label for each axis, and name the state of the aluminum at 425 °C. (b) List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there. (c) For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Part a. Give the label for each axis, and name the state of the aluminum at 425 °C.
Model: Vertical axis: temperature (°C). Horizontal axis: energy added. At 425 °C aluminum is a solid, because 425 °C is below its 660 °C melting temperature.
Part b. List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there.
Model: In order: a rising sloped piece from 425 °C to 660 °C — the solid warming; a plateau exactly flat at 660 °C — melting; a rising sloped piece from 660 °C to 925 °C — the liquid warming. That is the whole curve for this window.
Part c. For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Model: The melting plateau appears, because 660 °C lies inside the 425–925 °C window. The boiling plateau does not appear, because aluminum boils at 2470 °C, far above the top of the window — if a phase-change temperature lies outside the drawn range, its plateau simply does not appear.
Full model answer. (a) Vertical axis: temperature (°C). Horizontal axis: energy added. At 425 °C aluminum is a solid, because 425 °C is below its 660 °C melting temperature. (b) In order: a rising sloped piece from 425 °C to 660 °C — the solid warming; a plateau exactly flat at 660 °C — melting; a rising sloped piece from 660 °C to 925 °C — the liquid warming. That is the whole curve for this window. (c) The melting plateau appears, because 660 °C lies inside the 425–925 °C window. The boiling plateau does not appear, because aluminum boils at 2470 °C, far above the top of the window — if a phase-change temperature lies outside the drawn range, its plateau simply does not appear.

Form B

THM-036 · easy · recall · seq 1 · authored fresh (stage 2); fluency[0] pairing family, stem reworded (corpus) · mcq4
Pick the option that pairs a phase change with the energy direction it actually has.
Freezing — releases energy KEY
Vaporization — releases energy
Melting — releases energy
Condensation — absorbs energy
THM-038 · easy · recall · seq 2 · authored fresh (stage 2); fluency[1] family, reworded · mcq4
On a heating curve's melting plateau, what is the incoming energy used for?
Pulling particles away from their neighbors and rearranging them. KEY
Making the particles move faster on average.
Warming only the liquid part of the sample.
Nothing — it passes straight through and out to the surroundings.
THM-039 · easy · recall · seq 3 · authored fresh (stage 2); rule-line recall rotation · mcq4
Which labels belong on the two axes of a heating curve?
Temperature (°C) on the vertical axis and energy added on the horizontal axis. KEY
Temperature (°C) on the vertical axis and time on the horizontal axis.
Energy added on the vertical axis and temperature (°C) on the horizontal axis.
Mass on the vertical axis and temperature (°C) on the horizontal axis.
THM-040 · easy · recall · seq 4 · authored fresh (stage 2); rule-line recall rotation · mcq4
What does the flatness check demand of every plateau?
Each plateau must be exactly flat, because the temperature holds during a phase change. KEY
Each plateau may drift a little, as long as it drifts upward.
Each plateau must slope slightly upward to show that energy still flows into the sample.
Each plateau must be exactly as long as the segments around it.
THM-036 · medium · application · seq 5 · authored fresh (stage 2); pool[1] family, releasing direction · mcq4
Which list contains ONLY energy-releasing phase changes?
Freezing and condensation KEY
Freezing and vaporization
Melting and condensation
Melting and vaporization
THM-036 · medium · application · seq 6 · authored fresh (stage 2); condensation-release scene · mcq4
On a clear night, dew forms on a lawn, and careful measurement shows the grass surface cools more slowly while the dew is forming. Why?
Condensation releases energy, and that release slows the surface's cooling. KEY
The dew absorbs the surface's coldness into its droplets.
The dew absorbs energy from the grass, storing it for the morning.
The droplets act as tiny blankets that trap the day's warmth.
THM-036 · medium · application · seq 7 · authored fresh (stage 2); freezing-release scene · mcq4
A shallow pond's surface is freezing over on a still night. Even while the frozen film is still paper-thin, the layers beneath it cool far more slowly than they did before freezing began. What does the freezing surface contribute?
Freezing releases energy, and that release slows the cooling of everything beneath it. KEY
The frozen surface absorbs the night's cold before it can sink.
The freezing layer absorbs energy out of the depths below as its surface hardens.
Nothing — a surface freezing over moves no energy at all.
THM-037 · medium · application · seq 8 · authored fresh (stage 2); melting-plateau rotation · mcq4
The figure presents menthol's heating curve. What is happening along the first flat segment?
FIGURE (heating-curve · stimulus) — substance: "menthol" · xAxis: "energy added" · yAxis: "temperature (°C), 0 to 240 by 30" · plateaus: [{"temp": 36}, {"temp": 212}] · range: "curve runs from 14 °C to 236 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 240 by 30; the trace rises from 14 °C, ho…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "menthol",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 0 to 240 by 30",
  "plateaus": [
   {
    "temp": 36
   },
   {
    "temp": 212
   }
  ],
  "range": "curve runs from 14 °C to 236 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 240 by 30; the trace rises from 14 °C, holds exactly flat at 36 °C, rises, holds exactly flat at 212 °C, then rises to 236 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
The solid is melting. KEY
The solid is warming toward its melting temperature.
The liquid is boiling — turning to gas.
The gas is condensing.
THM-037 · medium · application · seq 9 · authored fresh (stage 2) · numeric
The figure gives palmitic acid's heating curve. Read palmitic acid's melting temperature from the curve, in °C.
FIGURE (heating-curve · stimulus) — substance: "palmitic acid" · xAxis: "energy added" · yAxis: "temperature (°C), 0 to 400, gridlines every 50" · plateaus: [{"temp": 63}, {"temp": 351}] · range: "curve runs from 25 °C to 380 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 400, gridlines every 50; the trace rises …
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "palmitic acid",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 0 to 400, gridlines every 50",
  "plateaus": [
   {
    "temp": 63
   },
   {
    "temp": 351
   }
  ],
  "range": "curve runs from 25 °C to 380 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 400, gridlines every 50; the trace rises from 25 °C, holds exactly flat at 63 °C, rises, holds exactly flat at 351 °C, then rises to 380 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Answer: 63.0 °C KEY
also accepted: 63.0
wrongValueDiagnostics
[
 {
  "value": 351.0,
  "misconception": "you read the second plateau — that is the boiling temperature; melting is the FIRST plateau, the lower one",
  "feedback": "This answer is wrong — you read the second plateau — that is the boiling temperature; melting is the FIRST plateau, the lower one."
 },
 {
  "value": 25.0,
  "misconception": "you read the start of the curve instead of a plateau — the melting temperature is the height where the curve first flattens",
  "feedback": "This answer is wrong — you read the start of the curve instead of a plateau — the melting temperature is the height where the curve first flattens."
 }
]
feedback
{
 "keyExplanation": "Find the first flat plateau — its height is the melting temperature. The plateau sits at 63 °C, so palmitic acid melts at 63 °C. The other plateau is the boiling temperature."
}
THM-037 · medium · application · seq 10 · authored fresh (stage 2) · mcq4
In the figure, zinc's heating curve carries a small arrow on its final rising stretch, above the second plateau. What state is the zinc in along the arrowed stretch?
FIGURE (heating-curve · stimulus) — substance: "zinc" · xAxis: "energy added" · yAxis: "temperature (°C), 300 to 1000, gridlines every 100" · plateaus: [{"temp": 420}, {"temp": 907}] · range: "curve runs from 340 °C to 980 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 300 to 1000, gridlines every 100; the trace ri…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "zinc",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 300 to 1000, gridlines every 100",
  "plateaus": [
   {
    "temp": 420
   },
   {
    "temp": 907
   }
  ],
  "range": "curve runs from 340 °C to 980 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 300 to 1000, gridlines every 100; the trace rises from 340 °C, holds exactly flat at 420 °C, rises, holds exactly flat at 907 °C, then rises to 980 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis; a small arrow marks the final rising stretch, above the second plateau"
 }
}
Gas KEY
Liquid
Solid
A mixture of liquid and gas
THM-037 · medium · application · seq 11 · authored fresh (stage 2); pool[3] class, fresh instance · mcq4
A small ladle of molten nickel is set aside to lose energy in a materials lab. The figure tracks its cooling curve: the trace falls, levels out once, then falls again. What is happening along the level stretch?
FIGURE (heating-curve · stimulus) — substance: "nickel" · xAxis: "energy removed" · yAxis: "temperature (°C), 1100 to 1800, gridlines every 100" · plateaus: [{"temp": 1455}] · range: "curve descends from 1720 °C to 1180 °C" · style: "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 1100 to 1800, gridlines every 100; the trace…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "nickel",
  "xAxis": "energy removed",
  "yAxis": "temperature (°C), 1100 to 1800, gridlines every 100",
  "plateaus": [
   {
    "temp": 1455
   }
  ],
  "range": "curve descends from 1720 °C to 1180 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 1100 to 1800, gridlines every 100; the trace falls from 1720 °C, holds exactly flat at 1455 °C, then falls to 1180 °C; a dashed guide ties the flat stretch to its labeled value on the temperature axis"
 }
}
The liquid nickel is freezing into solid nickel. KEY
The liquid nickel is boiling.
Gaseous nickel is condensing into liquid nickel there.
The solid nickel is melting.
THM-038 · medium · application · seq 12 · authored fresh (stage 2) · mcq4
A dish of isopropyl alcohol boils gently on a warm heater block. Energy keeps arriving, yet the thermometer's reading stays put while the liquid boils away. Why?
Because during a phase change the added energy goes into pulling particles away from their neighbors and rearranging them, not into speeding them up. KEY
A thermometer is unable to give an accurate reading while bubbles of vapor keep forming and collapsing around its bulb inside the liquid.
The extra energy passes straight through the liquid and out into the surroundings exactly as fast as the heater can supply it.
It stops absorbing energy from the heater while the boiling is underway, and only begins absorbing again once every drop of the liquid has become gas.
THM-038 · medium · application · seq 13 · authored fresh (stage 2); pool[7] class, fresh instance · mcq4
In a jewelry studio, a bead of molten platinum cools after the torch is switched off. Its temperature holds steady while the metal solidifies, even though the surroundings keep drawing energy from it. Why does the temperature hold?
Particles settling back beside their neighbors release energy, and that release replaces what is being removed until the freezing finishes. KEY
The surroundings stop removing energy from the metal the moment freezing begins, so its temperature cannot change until the freezing has finished.
The layer of solid forming around the remaining liquid acts as insulation, blocking any more energy from escaping to the surroundings.
The particles keep moving at exactly the same speed, because nothing that happens during a phase change can ever slow particles down.
THM-039 · medium · application · seq 14 · authored fresh (stage 2); pool[11]/fluency[0] family, fresh data + defect rotation · mcq4
A pure substance has a melting temperature of -36 °C and a boiling temperature of 154 °C. Panels A through D each graph a curve for it over the window from -70 °C to 180 °C. Which panel shows a correct heating curve?
FIGURE (heating-curve-panels · image-options) — kind: "heating" · panels: [{"panel": "A", "description": "one straight rising line with no flat stretches"}, {"panel": "B", "description": "rises, holds flat at 154 °C, falls, holds f… · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose bes…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "heating",
  "panels": [
   {
    "panel": "A",
    "description": "one straight rising line with no flat stretches"
   },
   {
    "panel": "B",
    "description": "rises, holds flat at 154 °C, falls, holds flat at −36 °C, rises"
   },
   {
    "panel": "C",
    "description": "rises, holds exactly flat at −36 °C, rises, holds exactly flat at 154 °C, rises"
   },
   {
    "panel": "D",
    "description": "rises, then a near-flat stretch drifting from −36 °C up to −20 °C, rises, then a near-flat stretch drifting from 154 °C up to 170 °C, rises"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: one straight rising line with no flat stretches; Panel B: rises, holds flat at 154 °C, falls, holds flat at −36 °C, rises; Panel C: rises, holds exactly flat at −36 °C, rises, holds exactly flat at 154 °C, rises; Panel D: rises, then a near-flat stretch drifting from −36 °C up to −20 °C, rises, then a near-flat stretch drifting from 154 °C up to 170 °C, rises"
 }
}
Panel C KEY
Panel A
Panel B
Panel D
THM-039 · medium · application · seq 15 · authored fresh (stage 2) · mcq4
A pure substance boils at 208 °C and melts at 19 °C. In the figure, four panels labeled A, B, C, and D each graph a curve recorded as a gas sample of the substance loses energy, from 230 °C down to -12 °C. Which panel shows a correct cooling curve?
FIGURE (heating-curve-panels · image-options) — kind: "cooling" · panels: [{"panel": "A", "description": "falls, holds exactly flat at 208 °C, falls, holds exactly flat at 19 °C, falls"}, {"panel": "B", "description": "rises, holds… · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose b…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "cooling",
  "panels": [
   {
    "panel": "A",
    "description": "falls, holds exactly flat at 208 °C, falls, holds exactly flat at 19 °C, falls"
   },
   {
    "panel": "B",
    "description": "rises, holds flat at 19 °C, rises, holds flat at 208 °C, rises"
   },
   {
    "panel": "C",
    "description": "falls, holds flat at 100 °C, falls, holds flat at 0 °C, falls"
   },
   {
    "panel": "D",
    "description": "falls into one very long flat stretch at a single height midway between the two data temperatures, then falls"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: falls, holds exactly flat at 208 °C, falls, holds exactly flat at 19 °C, falls; Panel B: rises, holds flat at 19 °C, rises, holds flat at 208 °C, rises; Panel C: falls, holds flat at 100 °C, falls, holds flat at 0 °C, falls; Panel D: falls into one very long flat stretch at a single height midway between the two data temperatures, then falls"
 }
}
Panel A KEY
Panel B
Panel C
Panel D
THM-040 · medium · application · seq 16 · authored fresh (stage 2) · mcq4
Lithium chloride melts at 605 °C and boils at 1382 °C. In the figure, a heating curve recorded for lithium chloride runs from 460 °C to 1550 °C. Check the curve against the data. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "lithium chloride" · xAxis: "energy added" · yAxis: "temperature (°C), 300 to 1700, gridlines every 200" · plateaus: [{"temp": 605}, {"temp": 1382}] · range: "curve runs from 460 °C to 1550 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 300 to 1700, gridlines every 200; the trace ri…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "lithium chloride",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 300 to 1700, gridlines every 200",
  "plateaus": [
   {
    "temp": 605
   },
   {
    "temp": 1382
   }
  ],
  "range": "curve runs from 460 °C to 1550 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 300 to 1700, gridlines every 200; the trace rises from 460 °C, holds exactly flat at 605 °C, rises, holds exactly flat at 1382 °C, then rises to 1550 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Correct — flat plateaus at 605 °C and 1382 °C, rising segments everywhere else. KEY
Flawed — the plateaus should slope gently upward instead of lying flat.
Flawed — a correct curve needs a third plateau between the two.
Flawed — after the second plateau the curve should level off, not keep rising.
THM-038 · hard · transfer · seq 17 · authored fresh (stage 2); pool[6] class on the melting side · mcq4
A slab of salol melts slowly in a warming cabinet, the probe inside it holding one reading. The energy flowing in each second is then doubled — yet the reading does not move. What does the extra energy do?
It pulls particles away from their neighbors faster, so the slab melts sooner — at the same steady reading. KEY
It raises the slab's temperature while it melts.
It is turned away at the surface, because a solid that is already melting can only ever absorb energy at one fixed, unchangeable rate.
It breaks the slab down into new substances instead of melting it.
THM-037 · hard · transfer · seq 18 · authored fresh (stage 2); single-plateau window variant · mcq4
In the figure, a dashed guide marks a point partway along the flat segment of indium's heating curve. Which statement describes the sample at the marked point?
FIGURE (heating-curve · stimulus) — substance: "indium" · xAxis: "energy added" · yAxis: "temperature (°C), 50 to 350, gridlines every 50" · plateaus: [{"temp": 157}] · range: "curve runs from 100 °C to 320 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 50 to 350, gridlines every 50; the trace rises…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "indium",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 50 to 350, gridlines every 50",
  "plateaus": [
   {
    "temp": 157
   }
  ],
  "range": "curve runs from 100 °C to 320 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 50 to 350, gridlines every 50; the trace rises from 100 °C, holds exactly flat at 157 °C, then rises to 320 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis; a dashed guide drops from a point partway along the flat segment"
 }
}
A mixture of solid and liquid indium, with melting underway. KEY
Entirely solid indium, warming toward its melting temperature.
Entirely liquid indium, warming toward its boiling temperature.
A mixture of liquid and gaseous indium.
THM-040 · hard · transfer · seq 19 · authored fresh (stage 2); pool[12] class, second-plateau rotation · mcq4
Silver melts at 962 °C and boils at 2162 °C. In the figure, silver's heating curve matches the data everywhere except one feature: its second plateau is drawn drifting gently upward before the curve climbs on. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "silver" · xAxis: "energy added" · yAxis: "temperature (°C), 700 to 2400, gridlines every 200" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 700 to 2400, gridlines every 200; the trace ri…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "silver",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 700 to 2400, gridlines every 200",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 700 to 2400, gridlines every 200; the trace rises from 760 °C, holds exactly flat at 962 °C, rises, then a near-flat stretch drifts gently upward from 2162 °C before the trace rises to 2350 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the boiling plateau must be exactly flat, because the temperature holds during a phase change. KEY
Correct — a small upward drift on a plateau is within normal drawing tolerance, so no check fails.
Flawed — the melting plateau should also drift upward, to match the other one.
Flawed — silver must be impure, so the data given for it are wrong.
THM-040 · hard · transfer · seq 20 · seed:U12-G4 pool[14] — instance freshened (benzene's 5.5/80 are barred spec numbers -> dodecane; the drawn-at-0 freezing flaw kept — '0' and '−10' are ignored constants); placed on form B (second seed of the seq-20 class) · mcq4
Dodecane melts at -10 °C and boils at 216 °C. In the figure, a student's cooling curve for dodecane falls, holds flat at 216 °C, falls, holds flat at 0 °C, then falls again. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "dodecane" · xAxis: "energy removed" · yAxis: "temperature (°C), −40 to 250, gridlines every 30" · style: "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running −40 to 250, gridlines every 30; the trace fa…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "dodecane",
  "xAxis": "energy removed",
  "yAxis": "temperature (°C), −40 to 250, gridlines every 30",
  "style": "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running −40 to 250, gridlines every 30; the trace falls from 240 °C, holds exactly flat at 216 °C, falls, holds exactly flat at 0 °C, then falls to −30 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the freezing plateau sits at 0 °C, but dodecane freezes at -10 °C. KEY
Correct — both plateaus are exactly flat, so the curve passes.
Flawed — a cooling curve should rise from left to right.
Flawed — the plateau at 216 °C is wrong, because a plateau at the boiling temperature belongs only on a heating curve.
THM-039 · medium · application · seq 21 · authored fresh (stage 2); full five-piece plan (fluency production family, fresh instance) · frq
Calcium fluoride melts at 1418 °C and boils at 2533 °C. A worksheet asks for calcium fluoride's heating curve, drawn across the window 1100 °C to 2700 °C. Do not draw it. Instead, type the plan for the curve:
Calcium fluoride melts at 1418 °C and boils at 2533 °C. A worksheet asks for calcium fluoride's heating curve, drawn across the window 1100 °C to 2700 °C. Do not draw it. Instead, type the plan for the curve: (a) Give the label for each axis, and name the state of the calcium fluoride at 1100 °C. (b) List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there. (c) For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Part a. Give the label for each axis, and name the state of the calcium fluoride at 1100 °C.
Model: Vertical axis: temperature (°C). Horizontal axis: energy added. At 1100 °C calcium fluoride is a solid, because 1100 °C is below its 1418 °C melting temperature.
Part b. List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there.
Model: In order: a rising sloped piece from 1100 °C to 1418 °C — the solid warming; a plateau exactly flat at 1418 °C — melting; a rising sloped piece from 1418 °C to 2533 °C — the liquid warming; a plateau exactly flat at 2533 °C — boiling; a rising sloped piece from 2533 °C to 2700 °C — the gas warming.
Part c. For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Model: Both plateaus appear: 1418 °C and 2533 °C each lie inside the 1100–2700 °C window, so the curve flattens at both phase-change temperatures.
Full model answer. (a) Vertical axis: temperature (°C). Horizontal axis: energy added. At 1100 °C calcium fluoride is a solid, because 1100 °C is below its 1418 °C melting temperature. (b) In order: a rising sloped piece from 1100 °C to 1418 °C — the solid warming; a plateau exactly flat at 1418 °C — melting; a rising sloped piece from 1418 °C to 2533 °C — the liquid warming; a plateau exactly flat at 2533 °C — boiling; a rising sloped piece from 2533 °C to 2700 °C — the gas warming. (c) Both plateaus appear: 1418 °C and 2533 °C each lie inside the 1100–2700 °C window, so the curve flattens at both phase-change temperatures.

Form C

THM-036 · easy · recall · seq 1 · authored fresh (stage 2); fluency[0] pairing family, stem reworded (corpus) · mcq4
Each option pairs one phase change with an energy direction. Which pairing is right?
Melting — absorbs energy KEY
Freezing — absorbs energy
Vaporization — releases energy
Condensation — absorbs energy
THM-038 · easy · recall · seq 2 · authored fresh (stage 2); fluency[2] end-of-plateau family, reworded · mcq4
A melting solid's final crystal disappears while the heater stays on. What does the temperature do from that moment?
It starts rising, because the added energy now goes into speeding the particles up. KEY
It keeps holding steady, because plateaus continue as long as energy flows in.
It falls briefly, because melting used up the sample's energy.
It jumps at once to the boiling temperature.
THM-039 · easy · recall · seq 3 · authored fresh (stage 2); rule-line recall rotation · mcq4
A sketch starts below the substance's melting temperature. What is the FIRST piece of a correctly drawn heating curve?
A rising sloped segment — the solid warming. KEY
A flat plateau at the melting temperature.
A falling sloped segment down to the melting temperature.
A flat plateau at the starting temperature.
THM-040 · easy · recall · seq 4 · authored fresh (stage 2); rule-line recall rotation · mcq4
What does the heights check compare?
Each plateau's height against the substance's melting and boiling temperatures. KEY
Each plateau's height against the midpoint of the temperature axis on the graph.
The two plateaus' heights against each other, to be sure the second sits above the first.
Each plateau's height against zero, the reference every graph is assumed to start from.
THM-036 · medium · application · seq 5 · authored fresh (stage 2); pool[1] family, reverse-pair distractors · mcq4
A revision card should name just the two phase changes that absorb energy. Which card is right?
Vaporization and melting KEY
Vaporization and condensation
Condensation and freezing
Melting and freezing
THM-036 · medium · application · seq 6 · authored fresh (stage 2); condensation-release scene · mcq4
As fog forms over a pond on a chilly evening, the shoreline stays noticeably milder than open ground nearby. What does the forming fog contribute?
Each droplet that forms releases energy, and that release keeps the shoreline milder. KEY
The fog absorbs the evening's cold before it reaches the shore.
The fog absorbs energy from the shoreline and hides it away inside the droplets.
Fog only blocks the view; it cannot change any temperature.
THM-036 · medium · application · seq 7 · authored fresh (stage 2); freezing-release scene · mcq4
A skating rink is resurfaced with a thin layer of liquid. Sensors in the slab register a small burst of warmth while the fresh layer hardens. Where does that warmth come from?
The hardening layer is freezing, and freezing releases energy to the slab. KEY
The slab absorbs coldness from the fresh layer as it hardens.
The fresh layer absorbs energy from the slab, which the sensors read as warmth.
Hardening is a chemical change that produces heat in the layer.
THM-037 · medium · application · seq 8 · authored fresh (stage 2) · mcq4
The figure presents 1-propanol's heating curve. What is happening along the second flat segment?
FIGURE (heating-curve · stimulus) — substance: "1-propanol" · xAxis: "energy added" · yAxis: "temperature (°C), −150 to 130, gridlines every 25" · plateaus: [{"temp": -126}, {"temp": 97}] · range: "curve runs from −144 °C to 119 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −150 to 130, gridlines every 25; the trace ris…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "1-propanol",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −150 to 130, gridlines every 25",
  "plateaus": [
   {
    "temp": -126
   },
   {
    "temp": 97
   }
  ],
  "range": "curve runs from −144 °C to 119 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −150 to 130, gridlines every 25; the trace rises from −144 °C, holds exactly flat at -126 °C, rises, holds exactly flat at 97 °C, then rises to 119 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
The liquid is boiling — turning to gas. KEY
The liquid is warming toward its boiling temperature.
The solid is melting.
The gas is warming.
THM-037 · medium · application · seq 9 · authored fresh (stage 2) · numeric
The figure gives anthracene's heating curve. Read anthracene's melting temperature from the curve, in °C.
FIGURE (heating-curve · stimulus) — substance: "anthracene" · xAxis: "energy added" · yAxis: "temperature (°C), 100 to 380, gridlines every 40" · plateaus: [{"temp": 216}, {"temp": 340}] · range: "curve runs from 150 °C to 370 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 100 to 380, gridlines every 40; the trace rise…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "anthracene",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 100 to 380, gridlines every 40",
  "plateaus": [
   {
    "temp": 216
   },
   {
    "temp": 340
   }
  ],
  "range": "curve runs from 150 °C to 370 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 100 to 380, gridlines every 40; the trace rises from 150 °C, holds exactly flat at 216 °C, rises, holds exactly flat at 340 °C, then rises to 370 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Answer: 216.0 °C KEY
also accepted: 216.0
wrongValueDiagnostics
[
 {
  "value": 340.0,
  "misconception": "you read the second plateau — that is the boiling temperature; melting is the FIRST plateau, the lower one",
  "feedback": "This answer is wrong — you read the second plateau — that is the boiling temperature; melting is the FIRST plateau, the lower one."
 },
 {
  "value": 150.0,
  "misconception": "you read the start of the curve instead of a plateau — the melting temperature is the height where the curve first flattens",
  "feedback": "This answer is wrong — you read the start of the curve instead of a plateau — the melting temperature is the height where the curve first flattens."
 }
]
feedback
{
 "keyExplanation": "Find the first flat plateau — its height is the melting temperature. The plateau sits at 216 °C, so anthracene melts at 216 °C. The other plateau is the boiling temperature."
}
THM-037 · medium · application · seq 10 · authored fresh (stage 2) · mcq4
In the figure, methane's heating curve carries a small arrow on its opening rising stretch, below the first plateau. What state is the methane in along the arrowed stretch?
FIGURE (heating-curve · stimulus) — substance: "methane" · xAxis: "energy added" · yAxis: "temperature (°C), −200 to −140, gridlines every 10" · plateaus: [{"temp": -182}, {"temp": -162}] · range: "curve runs from −196 °C to −146 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −200 to −140, gridlines every 10; the trace ri…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "methane",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −200 to −140, gridlines every 10",
  "plateaus": [
   {
    "temp": -182
   },
   {
    "temp": -162
   }
  ],
  "range": "curve runs from −196 °C to −146 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −200 to −140, gridlines every 10; the trace rises from −196 °C, holds exactly flat at -182 °C, rises, holds exactly flat at -162 °C, then rises to −146 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis; a small arrow marks the opening rising stretch, below the first plateau"
 }
}
Solid KEY
Liquid
Gas
A mixture of solid and liquid
THM-037 · medium · application · seq 11 · authored fresh (stage 2) · mcq4
A foundry pour of molten magnesium is left to lose energy in its mold. The figure tracks its cooling curve: the trace falls, levels out once, then falls again. What is happening along the level stretch?
FIGURE (heating-curve · stimulus) — substance: "magnesium" · xAxis: "energy removed" · yAxis: "temperature (°C), 400 to 900, gridlines every 50" · plateaus: [{"temp": 650}] · range: "curve descends from 840 °C to 440 °C" · style: "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 400 to 900, gridlines every 50; the trace fa…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "magnesium",
  "xAxis": "energy removed",
  "yAxis": "temperature (°C), 400 to 900, gridlines every 50",
  "plateaus": [
   {
    "temp": 650
   }
  ],
  "range": "curve descends from 840 °C to 440 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 400 to 900, gridlines every 50; the trace falls from 840 °C, holds exactly flat at 650 °C, then falls to 440 °C; a dashed guide ties the flat stretch to its labeled value on the temperature axis"
 }
}
The liquid magnesium is freezing into solid magnesium. KEY
The liquid magnesium is boiling.
Gaseous magnesium is condensing into liquid magnesium there.
The solid magnesium is melting.
THM-038 · medium · application · seq 12 · authored fresh (stage 2) · mcq4
A round flask of hexane boils above a heating mantle. Energy keeps arriving, yet the thermometer's reading stays put while the liquid boils away. Why?
Because during a phase change the added energy goes into pulling particles away from their neighbors and rearranging them, not into speeding them up. KEY
The energy added during the boiling is destroyed at the moment the liquid turns to gas, so there is nothing left over to raise the reading.
It stops absorbing energy from the heater while the boiling is underway, and only begins absorbing again once every drop of the liquid has become gas.
The extra energy passes straight through the liquid and out into the surroundings exactly as fast as the heater can supply it.
THM-038 · medium · application · seq 13 · authored fresh (stage 2) · mcq4
In a filament works, a thimble of molten tungsten cools after the arc is cut. Its temperature holds steady while the metal solidifies, even though the surroundings keep drawing energy from it. Why does the temperature hold?
Particles settling back beside their neighbors release energy, and that release replaces what is being removed until the freezing finishes. KEY
The surroundings stop removing energy from the metal the moment freezing begins, so its temperature cannot change until the freezing has finished.
The layer of solid forming around the remaining liquid acts as insulation, blocking any more energy from escaping to the surroundings.
The particles keep moving at exactly the same speed, because nothing that happens during a phase change can ever slow particles down.
THM-039 · medium · application · seq 14 · authored fresh (stage 2); defect rotation incl. extra-plateau class · mcq4
A pure substance has a melting temperature of 46 °C and a boiling temperature of 231 °C. Panels A through D each graph a curve for it over the window from 22 °C to 275 °C. Which panel shows a correct heating curve?
FIGURE (heating-curve-panels · image-options) — kind: "heating" · panels: [{"panel": "A", "description": "rises, holds exactly flat at 46 °C, rises, holds exactly flat at 231 °C, rises"}, {"panel": "B", "description": "rises, holds… · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose bes…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "heating",
  "panels": [
   {
    "panel": "A",
    "description": "rises, holds exactly flat at 46 °C, rises, holds exactly flat at 231 °C, rises"
   },
   {
    "panel": "B",
    "description": "rises, holds flat at 231 °C only, rises — no flat stretch at 46 °C"
   },
   {
    "panel": "C",
    "description": "rises, holds flat at 46 °C, rises, holds flat midway between the two data temperatures, rises, holds flat at 231 °C, rises"
   },
   {
    "panel": "D",
    "description": "falls, holds flat at 231 °C, falls, holds flat at 46 °C, falls — a descending trace"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: rises, holds exactly flat at 46 °C, rises, holds exactly flat at 231 °C, rises; Panel B: rises, holds flat at 231 °C only, rises — no flat stretch at 46 °C; Panel C: rises, holds flat at 46 °C, rises, holds flat midway between the two data temperatures, rises, holds flat at 231 °C, rises; Panel D: falls, holds flat at 231 °C, falls, holds flat at 46 °C, falls — a descending trace"
 }
}
Panel A KEY
Panel B
Panel C
Panel D
THM-039 · medium · application · seq 15 · authored fresh (stage 2) · mcq4
A pure substance boils at 67 °C and melts at -41 °C. In the figure, four panels labeled A, B, C, and D each graph a curve recorded as a gas sample of the substance loses energy, from 92 °C down to -72 °C. Which panel shows a correct cooling curve?
FIGURE (heating-curve-panels · image-options) — kind: "cooling" · panels: [{"panel": "A", "description": "falls, holds flat at 0 °C only, falls — no other flat stretch"}, {"panel": "B", "description": "falls, then a near-flat stret… · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose b…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "cooling",
  "panels": [
   {
    "panel": "A",
    "description": "falls, holds flat at 0 °C only, falls — no other flat stretch"
   },
   {
    "panel": "B",
    "description": "falls, then a near-flat stretch drifting downward from 67 °C, falls, then a near-flat stretch drifting downward from −41 °C, falls"
   },
   {
    "panel": "C",
    "description": "rises, holds flat at −41 °C, rises, holds flat at 67 °C, rises"
   },
   {
    "panel": "D",
    "description": "falls, holds exactly flat at 67 °C, falls, holds exactly flat at −41 °C, falls"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: falls, holds flat at 0 °C only, falls — no other flat stretch; Panel B: falls, then a near-flat stretch drifting downward from 67 °C, falls, then a near-flat stretch drifting downward from −41 °C, falls; Panel C: rises, holds flat at −41 °C, rises, holds flat at 67 °C, rises; Panel D: falls, holds exactly flat at 67 °C, falls, holds exactly flat at −41 °C, falls"
 }
}
Panel D KEY
Panel A
Panel B
Panel C
THM-040 · medium · application · seq 16 · authored fresh (stage 2) | sol loop-1 S4b: glycerol (boils ~290 °C with decomposition) -> hexadecane · mcq4
Hexadecane melts at 18 °C and boils at 287 °C. In the figure, a heating curve recorded for hexadecane runs from -28 °C to 330 °C. Check the curve against the data. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "hexadecane" · xAxis: "energy added" · yAxis: "temperature (°C), −60 to 360, gridlines every 60" · plateaus: [{"temp": 18}, {"temp": 287}] · range: "curve runs from -28 °C to 330 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −60 to 360, gridlines every 60; the trace rise…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "hexadecane",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −60 to 360, gridlines every 60",
  "plateaus": [
   {
    "temp": 18
   },
   {
    "temp": 287
   }
  ],
  "range": "curve runs from -28 °C to 330 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −60 to 360, gridlines every 60; the trace rises from -28 °C, holds exactly flat at 18 °C, rises, holds exactly flat at 287 °C, then rises to 330 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Correct — flat plateaus at 18 °C and 287 °C, rising segments everywhere else. KEY
Flawed — the first plateau should sit at 0 °C.
Flawed — a correct curve needs a third plateau between the two.
Flawed — after the second plateau the curve should level off, not keep rising.
THM-038 · hard · transfer · seq 17 · authored fresh (stage 2) · mcq4
Crystals of sodium bromide melt in a test furnace, the furnace probe holding one reading. The energy flowing in each second is then doubled — yet the reading does not move. What does the extra energy do?
It pulls particles away from their neighbors faster, so the crystals melt sooner — at the same steady reading. KEY
It raises the crystals' temperature while they melt.
It is turned away at the surface, because a solid that is already melting can only ever absorb energy at one fixed, unchangeable rate.
It breaks the crystals down into new substances instead of melting them.
THM-037 · hard · transfer · seq 18 · authored fresh (stage 2) · mcq4
In the figure, a dashed guide marks a point partway along the first flat segment of decane's heating curve. Which statement describes the sample at the marked point?
FIGURE (heating-curve · stimulus) — substance: "decane" · xAxis: "energy added" · yAxis: "temperature (°C), −60 to 210, gridlines every 30" · plateaus: [{"temp": -30}, {"temp": 174}] · range: "curve runs from −50 °C to 190 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −60 to 210, gridlines every 30; the trace rise…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "decane",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −60 to 210, gridlines every 30",
  "plateaus": [
   {
    "temp": -30
   },
   {
    "temp": 174
   }
  ],
  "range": "curve runs from −50 °C to 190 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −60 to 210, gridlines every 30; the trace rises from −50 °C, holds exactly flat at -30 °C, rises, holds exactly flat at 174 °C, then rises to 190 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis; a dashed guide drops from a point partway along the first flat segment"
 }
}
A mixture of solid and liquid decane, with melting underway. KEY
Entirely solid decane, warming toward its melting temperature.
Entirely liquid decane, warming toward its boiling temperature.
A mixture of liquid and gaseous decane.
THM-040 · hard · transfer · seq 19 · authored fresh (stage 2); cryo-range instance · mcq4
Propane melts at -188 °C and boils at -42 °C. In the figure, propane's heating curve matches the data everywhere except one feature: its first plateau is drawn drifting gently upward before the curve climbs on. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "propane" · xAxis: "energy added" · yAxis: "temperature (°C), −210 to −20, gridlines every 20" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −210 to −20, gridlines every 20; the trace ris…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "propane",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −210 to −20, gridlines every 20",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −210 to −20, gridlines every 20; the trace rises from −205 °C, then a near-flat stretch drifts gently upward from −188 °C to −176 °C, then the trace rises, holds exactly flat at −42 °C, and rises to −25 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the melting plateau must be exactly flat, because the temperature holds during a phase change. KEY
Correct — a small upward drift on a plateau is within normal drawing tolerance, so no check fails.
Flawed — the boiling plateau should also drift upward, to match the other one.
Flawed — the melting plateau belongs at 0 °C, not below zero.
THM-040 · hard · transfer · seq 20 · authored fresh (stage 2); pool[13] class, fresh instance (wintergreen oil) · mcq4
Methyl salicylate melts at -9 °C and boils at 222 °C. In the figure, a classmate has drawn methyl salicylate's heating curve: both plateaus sit exactly flat at the right heights, but the stretch between them first dips downward before climbing to the second plateau as energy is added. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "methyl salicylate" · xAxis: "energy added" · yAxis: "temperature (°C), −40 to 260, gridlines every 30" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −40 to 260, gridlines every 30; the trace rise…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "methyl salicylate",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −40 to 260, gridlines every 30",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −40 to 260, gridlines every 30; the trace rises from −30 °C, holds exactly flat at −9 °C, then dips below that height before climbing to hold exactly flat at 222 °C, then rises to 250 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the stretch between the plateaus must rise the whole way, because the liquid warms as energy is added. KEY
Correct — the plateau heights match the data, and heights are the only check.
Flawed — the middle stretch should be exactly flat, making one long plateau between the two temperatures.
Flawed — the melting plateau belongs at 0 °C.
THM-039 · medium · application · seq 21 · seed:U12-G4 pool[10] (= demo_curated[1], dual ref) — benzene -> 1-heptanol (5.5/80 are barred spec numbers); D9 cooling-plan structure carried, plus the off-range check moved to the freezing plateau; converted to the typed 3-part plan (V-T12) · frq
1-heptanol melts at −34 °C and boils at 176 °C. A worksheet asks for a COOLING curve of 1-heptanol, drawn while a gaseous sample of 1-heptanol loses energy across the window 185 °C down to −25 °C. Do not draw it. Instead, type the plan for the curve:
1-heptanol melts at −34 °C and boils at 176 °C. A worksheet asks for a COOLING curve of 1-heptanol, drawn while a gaseous sample of 1-heptanol loses energy across the window 185 °C down to −25 °C. Do not draw it. Instead, type the plan for the curve: (a) Give the label for each axis, and name the state of the 1-heptanol at 185 °C. (b) List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there. (c) For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Part a. Give the label for each axis, and name the state of the 1-heptanol at 185 °C.
Model: Vertical axis: temperature (°C). Horizontal axis: energy removed. At 185 °C the 1-heptanol is a gas, because 185 °C is above its 176 °C boiling temperature.
Part b. List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there.
Model: In order: a falling sloped piece from 185 °C to 176 °C — the gas cooling; a plateau exactly flat at 176 °C — condensation, at the boiling temperature; a falling sloped piece from 176 °C to −25 °C — the liquid cooling. That is the whole curve for this window.
Part c. For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Model: The condensation plateau appears, because 176 °C lies inside the 185 to −25 °C window. The freezing plateau does not appear, because 1-heptanol freezes at its melting temperature, −34 °C, which lies below the window's floor of −25 °C — a plateau outside the drawn range simply does not appear.
Full model answer. (a) Vertical axis: temperature (°C). Horizontal axis: energy removed. At 185 °C the 1-heptanol is a gas, because 185 °C is above its 176 °C boiling temperature. (b) In order: a falling sloped piece from 185 °C to 176 °C — the gas cooling; a plateau exactly flat at 176 °C — condensation, at the boiling temperature; a falling sloped piece from 176 °C to −25 °C — the liquid cooling. That is the whole curve for this window. (c) The condensation plateau appears, because 176 °C lies inside the 185 to −25 °C window. The freezing plateau does not appear, because 1-heptanol freezes at its melting temperature, −34 °C, which lies below the window's floor of −25 °C — a plateau outside the drawn range simply does not appear.

Form D

THM-036 · easy · recall · seq 1 · authored fresh (stage 2); fluency[0] pairing family, stem reworded (corpus) · mcq4
One of these pairings states a phase change's energy direction correctly. Which one?
Condensation — releases energy KEY
Melting — releases energy
Freezing — absorbs energy
Vaporization — releases energy
THM-038 · easy · recall · seq 2 · authored fresh (stage 2); rule-line-3/4 definitional read · mcq4
A hot plate feeds energy toward a sample the whole time its phase change is underway. Why can a thermometer's reading not climb?
The added energy is pulling particles away from their neighbors, not speeding them up — and particles that are not speeding up cannot read hotter. KEY
A thermometer simply pauses and repeats its last reading whenever two different states of matter are touching its bulb at the same time.
The sample refuses to take in any more energy until the phase change has finished, so there is no new energy to change the reading.
The added energy is destroyed as the new state forms, leaving nothing behind that could push the reading upward.
THM-039 · easy · recall · seq 3 · authored fresh (stage 2); rule-line recall rotation · mcq4
At what height must a heating curve's first plateau sit?
At the melting temperature. KEY
At the boiling temperature.
Halfway between the melting and boiling temperatures.
At whatever height keeps the two plateaus evenly spaced.
THM-040 · easy · recall · seq 4 · authored fresh (stage 2); rule-line recall rotation · mcq4
What does the segments check require of the pieces between and beyond the plateaus on a heating curve?
Every one of them must slope upward, because a single state warms as energy is added. KEY
They must all be drawn horizontal, so that they match the plateaus on either side of them.
They may rise or they may fall, as long as each one connects its two plateaus without a break.
Only the first segment has to rise; the pieces after the first plateau are free to go either way.
THM-036 · medium · application · seq 5 · authored fresh (stage 2); pool[1] family, releasing card · mcq4
A revision card should name just the two phase changes that release energy. Which card is right?
Condensation and freezing KEY
Condensation and vaporization
Melting and freezing
Vaporization and melting
THM-036 · medium · application · seq 6 · authored fresh (stage 2); condensation-release scene · mcq4
A student breathes on a cold windowpane. The pane fogs over — and a sensor on the glass shows it warmed slightly more than plain warm breath blowing past could manage. Why?
The vapor in the breath condenses on the glass, and condensation releases energy into the pane. KEY
The breath's vapor absorbs energy from the glass as it lands.
The film of moisture acts as a thin blanket of insulation, trapping warmth inside the pane.
Fogging glass creates brand-new warmth by changing the breath into a different substance.
THM-036 · medium · application · seq 7 · authored fresh (stage 2); freezing-release scene · mcq4
In an old root cellar, tubs of liquid are set out before a hard winter night. As the tubs freeze, the stored produce nearby is spared from freezing. How do the tubs protect the produce?
The freezing tubs release energy, and that release keeps the cellar milder through the night. KEY
The tubs soak up the cellar's cold into the forming solid, storing it there until morning.
The tubs absorb energy out of the stored produce, hardening faster in exchange for chilling it.
The tubs only add moisture to the cellar, and moisture on its own cannot change any temperature.
THM-037 · medium · application · seq 8 · authored fresh (stage 2) · mcq4
The figure presents biphenyl's heating curve. What is happening along the first flat segment?
FIGURE (heating-curve · stimulus) — substance: "biphenyl" · xAxis: "energy added" · yAxis: "temperature (°C), 0 to 300 by 30" · plateaus: [{"temp": 69}, {"temp": 255}] · range: "curve runs from 21 °C to 288 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 300 by 30; the trace rises from 21 °C, ho…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "biphenyl",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 0 to 300 by 30",
  "plateaus": [
   {
    "temp": 69
   },
   {
    "temp": 255
   }
  ],
  "range": "curve runs from 21 °C to 288 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 300 by 30; the trace rises from 21 °C, holds exactly flat at 69 °C, rises, holds exactly flat at 255 °C, then rises to 288 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
The solid is melting. KEY
The solid is warming toward its melting temperature.
The liquid is boiling — turning to gas.
The gas is condensing.
THM-037 · medium · application · seq 9 · authored fresh (stage 2) · numeric
The figure gives lauric acid's heating curve. Read lauric acid's melting temperature from the curve, in °C.
FIGURE (heating-curve · stimulus) — substance: "lauric acid" · xAxis: "energy added" · yAxis: "temperature (°C), 0 to 340, gridlines every 40" · plateaus: [{"temp": 44}, {"temp": 299}] · range: "curve runs from 15 °C to 325 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 340, gridlines every 40; the trace rises …
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "lauric acid",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 0 to 340, gridlines every 40",
  "plateaus": [
   {
    "temp": 44
   },
   {
    "temp": 299
   }
  ],
  "range": "curve runs from 15 °C to 325 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 340, gridlines every 40; the trace rises from 15 °C, holds exactly flat at 44 °C, rises, holds exactly flat at 299 °C, then rises to 325 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Answer: 44.0 °C KEY
also accepted: 44.0
wrongValueDiagnostics
[
 {
  "value": 299.0,
  "misconception": "you read the second plateau — that is the boiling temperature; melting is the FIRST plateau, the lower one",
  "feedback": "This answer is wrong — you read the second plateau — that is the boiling temperature; melting is the FIRST plateau, the lower one."
 },
 {
  "value": 15.0,
  "misconception": "you read the start of the curve instead of a plateau — the melting temperature is the height where the curve first flattens",
  "feedback": "This answer is wrong — you read the start of the curve instead of a plateau — the melting temperature is the height where the curve first flattens."
 }
]
feedback
{
 "keyExplanation": "Find the first flat plateau — its height is the melting temperature. The plateau sits at 44 °C, so lauric acid melts at 44 °C. The other plateau is the boiling temperature."
}
THM-037 · medium · application · seq 10 · authored fresh (stage 2) · mcq4
In the figure, benzoic acid's heating curve carries a small arrow on its middle sloped stretch, between the first plateau and the second. What state is the benzoic acid in along the arrowed stretch?
FIGURE (heating-curve · stimulus) — substance: "benzoic acid" · xAxis: "energy added" · yAxis: "temperature (°C), 50 to 300, gridlines every 25" · plateaus: [{"temp": 122}, {"temp": 249}] · range: "curve runs from 72 °C to 286 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 50 to 300, gridlines every 25; the trace rises…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "benzoic acid",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 50 to 300, gridlines every 25",
  "plateaus": [
   {
    "temp": 122
   },
   {
    "temp": 249
   }
  ],
  "range": "curve runs from 72 °C to 286 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 50 to 300, gridlines every 25; the trace rises from 72 °C, holds exactly flat at 122 °C, rises, holds exactly flat at 249 °C, then rises to 286 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis; a small arrow marks the middle sloped stretch, between the first plateau and the second"
 }
}
Liquid KEY
Solid
Gas
A mixture of solid and liquid
THM-037 · medium · application · seq 11 · authored fresh (stage 2) · mcq4
A titanium casting is left to lose energy after the pour. The figure tracks its cooling curve: the trace falls, levels out once, then falls again. What is happening along the level stretch?
FIGURE (heating-curve · stimulus) — substance: "titanium" · xAxis: "energy removed" · yAxis: "temperature (°C), 1300 to 2000, gridlines every 100" · plateaus: [{"temp": 1668}] · range: "curve descends from 1940 °C to 1360 °C" · style: "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 1300 to 2000, gridlines every 100; the trace…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "titanium",
  "xAxis": "energy removed",
  "yAxis": "temperature (°C), 1300 to 2000, gridlines every 100",
  "plateaus": [
   {
    "temp": 1668
   }
  ],
  "range": "curve descends from 1940 °C to 1360 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 1300 to 2000, gridlines every 100; the trace falls from 1940 °C, holds exactly flat at 1668 °C, then falls to 1360 °C; a dashed guide ties the flat stretch to its labeled value on the temperature axis"
 }
}
The liquid titanium is freezing into solid titanium. KEY
The liquid titanium is boiling.
Gaseous titanium is condensing into liquid titanium there.
The solid titanium is melting.
THM-038 · medium · application · seq 12 · authored fresh (stage 2) · mcq4
A pan of methanol boils under a fume hood. Energy keeps arriving, yet the thermometer's reading stays put while the liquid boils away. Why?
Because during a phase change the added energy goes into pulling particles away from their neighbors and rearranging them, not into speeding them up. KEY
The extra energy passes straight through the liquid and out into the surroundings exactly as fast as the heater can supply it.
A thermometer is unable to give an accurate reading while bubbles of vapor keep forming and collapsing around its bulb inside the liquid.
The energy added during the boiling is destroyed at the moment the liquid turns to gas, so there is nothing left over to raise the reading.
THM-038 · medium · application · seq 13 · authored fresh (stage 2) · mcq4
In a crystal-growing lab, a boat of molten germanium cools once the furnace is opened. Its temperature holds steady while the sample solidifies, even though the surroundings keep drawing energy from it. Why does the temperature hold?
Particles settling back beside their neighbors release energy, and that release replaces what is being removed until the freezing finishes. KEY
The surroundings stop removing energy from the sample the moment freezing begins, so its temperature cannot change until the freezing has finished.
The layer of solid forming around the remaining liquid acts as insulation, blocking any more energy from escaping to the surroundings.
The particles keep moving at exactly the same speed, because nothing that happens during a phase change can ever slow particles down.
THM-039 · medium · application · seq 14 · authored fresh (stage 2); shifted-heights class · mcq4
A pure substance has a melting temperature of -88 °C and a boiling temperature of 21 °C. Panels A through D each graph a curve for it over the window from -105 °C to 45 °C. Which panel shows a correct heating curve?
FIGURE (heating-curve-panels · image-options) — kind: "heating" · panels: [{"panel": "A", "description": "rises, holds flat at −60 °C, rises, holds flat at 30 °C, rises — both flats away from the data temperatures"}, {"panel": "B",… · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose bes…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "heating",
  "panels": [
   {
    "panel": "A",
    "description": "rises, holds flat at −60 °C, rises, holds flat at 30 °C, rises — both flats away from the data temperatures"
   },
   {
    "panel": "B",
    "description": "one straight rising line with no flat stretches"
   },
   {
    "panel": "C",
    "description": "rises, holds flat at 21 °C, falls, holds flat at −88 °C, rises"
   },
   {
    "panel": "D",
    "description": "rises, holds exactly flat at −88 °C, rises, holds exactly flat at 21 °C, rises"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: rises, holds flat at −60 °C, rises, holds flat at 30 °C, rises — both flats away from the data temperatures; Panel B: one straight rising line with no flat stretches; Panel C: rises, holds flat at 21 °C, falls, holds flat at −88 °C, rises; Panel D: rises, holds exactly flat at −88 °C, rises, holds exactly flat at 21 °C, rises"
 }
}
Panel D KEY
Panel A
Panel B
Panel C
THM-039 · medium · application · seq 15 · authored fresh (stage 2) · mcq4
A pure substance boils at 312 °C and melts at 86 °C. In the figure, four panels labeled A, B, C, and D each graph a curve recorded as a gas sample of the substance loses energy, from 345 °C down to 58 °C. Which panel shows a correct cooling curve?
FIGURE (heating-curve-panels · image-options) — kind: "cooling" · panels: [{"panel": "A", "description": "falls, holds flat at 312 °C only, falls — no second flat stretch"}, {"panel": "B", "description": "falls, holds exactly flat … · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose b…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "cooling",
  "panels": [
   {
    "panel": "A",
    "description": "falls, holds flat at 312 °C only, falls — no second flat stretch"
   },
   {
    "panel": "B",
    "description": "falls, holds exactly flat at 312 °C, falls, holds exactly flat at 86 °C, falls"
   },
   {
    "panel": "C",
    "description": "falls, holds exactly flat at 86 °C, falls — its only flat stretch; no flat stretch at 312 °C"
   },
   {
    "panel": "D",
    "description": "rises, holds flat at 86 °C, rises, holds flat at 312 °C, rises"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: falls, holds flat at 312 °C only, falls — no second flat stretch; Panel B: falls, holds exactly flat at 312 °C, falls, holds exactly flat at 86 °C, falls; Panel C: falls, holds exactly flat at 86 °C, falls — its only flat stretch; no flat stretch at 312 °C; Panel D: rises, holds flat at 86 °C, rises, holds flat at 312 °C, rises"
 }
}
Panel B KEY
Panel A
Panel C
Panel D
THM-040 · medium · application · seq 16 · authored fresh (stage 2) · mcq4
Iron melts at 1538 °C and boils at 2862 °C. In the figure, a heating curve recorded for iron runs from 1300 °C to 3050 °C. Check the curve against the data. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "iron" · xAxis: "energy added" · yAxis: "temperature (°C), 1100 to 3300, gridlines every 300" · plateaus: [{"temp": 1538}, {"temp": 2862}] · range: "curve runs from 1300 °C to 3050 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 1100 to 3300, gridlines every 300; the trace r…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "iron",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 1100 to 3300, gridlines every 300",
  "plateaus": [
   {
    "temp": 1538
   },
   {
    "temp": 2862
   }
  ],
  "range": "curve runs from 1300 °C to 3050 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 1100 to 3300, gridlines every 300; the trace rises from 1300 °C, holds exactly flat at 1538 °C, rises, holds exactly flat at 2862 °C, then rises to 3050 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Correct — flat plateaus at 1538 °C and 2862 °C, rising segments everywhere else. KEY
Flawed — the plateaus should slope gently upward instead of lying flat.
Flawed — the first plateau should sit at 0 °C.
Flawed — a correct curve needs a third plateau between the two.
THM-038 · hard · transfer · seq 17 · authored fresh (stage 2) · mcq4
A charge of table salt melts in a glass studio's kiln, the kiln probe holding one reading. The energy flowing in each second is then doubled — yet the reading does not move. What does the extra energy do?
It pulls particles away from their neighbors faster, so the charge melts sooner — at the same steady reading. KEY
It raises the charge's temperature while it melts.
It is turned away at the surface, because a solid that is already melting can only ever absorb energy at one fixed, unchangeable rate.
It breaks the charge down into new substances instead of melting it.
THM-037 · hard · transfer · seq 18 · authored fresh (stage 2) · mcq4
In the figure, a dashed guide marks a point partway along the first flat segment of sulfur's heating curve. Which statement describes the sample at the marked point?
FIGURE (heating-curve · stimulus) — substance: "sulfur" · xAxis: "energy added" · yAxis: "temperature (°C), 0 to 500, gridlines every 50" · plateaus: [{"temp": 115}, {"temp": 445}] · range: "curve runs from 60 °C to 480 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 500, gridlines every 50; the trace rises …
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "sulfur",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 0 to 500, gridlines every 50",
  "plateaus": [
   {
    "temp": 115
   },
   {
    "temp": 445
   }
  ],
  "range": "curve runs from 60 °C to 480 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 500, gridlines every 50; the trace rises from 60 °C, holds exactly flat at 115 °C, rises, holds exactly flat at 445 °C, then rises to 480 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis; a dashed guide drops from a point partway along the first flat segment"
 }
}
A mixture of solid and liquid sulfur, with melting underway. KEY
Entirely solid sulfur, warming toward its melting temperature.
Entirely liquid sulfur, warming toward its boiling temperature.
A mixture of liquid and gaseous sulfur.
THM-040 · hard · transfer · seq 19 · authored fresh (stage 2) · mcq4
Copper melts at 1085 °C and boils at 2562 °C. In the figure, copper's heating curve matches the data everywhere except one feature: its second plateau is drawn drifting gently upward before the curve climbs on. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "copper" · xAxis: "energy added" · yAxis: "temperature (°C), 800 to 2800, gridlines every 200" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 800 to 2800, gridlines every 200; the trace ri…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "copper",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 800 to 2800, gridlines every 200",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 800 to 2800, gridlines every 200; the trace rises from 900 °C, holds exactly flat at 1085 °C, rises, then a near-flat stretch drifts gently upward from 2562 °C before the trace rises to 2750 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the boiling plateau must be exactly flat, because the temperature holds during a phase change. KEY
Correct — a small upward drift on a plateau is within normal drawing tolerance, so no check fails.
Flawed — the melting plateau should also drift upward, to match the other one.
Flawed — copper must be impure, so the data given for it are wrong.
THM-040 · hard · transfer · seq 20 · authored fresh (stage 2) · mcq4
Manganese melts at 1246 °C and boils at 2061 °C. In the figure, a classmate has drawn manganese's heating curve: both plateaus sit exactly flat at the right heights, but the stretch between them first dips downward before climbing to the second plateau as energy is added. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "manganese" · xAxis: "energy added" · yAxis: "temperature (°C), 1000 to 2300, gridlines every 200" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 1000 to 2300, gridlines every 200; the trace r…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "manganese",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 1000 to 2300, gridlines every 200",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 1000 to 2300, gridlines every 200; the trace rises from 1100 °C, holds exactly flat at 1246 °C, then dips below that height before climbing to hold exactly flat at 2061 °C, then rises to 2250 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the stretch between the plateaus must rise the whole way, because the liquid warms as energy is added. KEY
Correct — the plateau heights match the data, and heights are the only check.
Flawed — the middle stretch should be exactly flat, making one long plateau between the two temperatures.
Flawed — the melting plateau belongs at 0 °C.
THM-039 · medium · application · seq 21 · authored fresh (stage 2); sub-zero-plateau five-piece plan (fluency ethanol-production family, fresh instance) · frq
Diethyl ether melts at -116 °C and boils at 35 °C. A worksheet asks for diethyl ether's heating curve, drawn across the window -125 °C to 50 °C. Do not draw it. Instead, type the plan for the curve:
Diethyl ether melts at -116 °C and boils at 35 °C. A worksheet asks for diethyl ether's heating curve, drawn across the window -125 °C to 50 °C. Do not draw it. Instead, type the plan for the curve: (a) Give the label for each axis, and name the state of the diethyl ether at -125 °C. (b) List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there. (c) For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Part a. Give the label for each axis, and name the state of the diethyl ether at -125 °C.
Model: Vertical axis: temperature (°C). Horizontal axis: energy added. At −125 °C diethyl ether is a solid, because −125 °C is below its −116 °C melting temperature.
Part b. List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there.
Model: In order: a rising sloped piece from −125 °C to −116 °C — the solid warming; a plateau exactly flat at −116 °C — melting; a rising sloped piece from −116 °C to 35 °C — the liquid warming; a plateau exactly flat at 35 °C — boiling; a rising sloped piece from 35 °C to 50 °C — the gas warming.
Part c. For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Model: Both plateaus appear: −116 °C and 35 °C each lie inside the −125 to 50 °C window. The melting temperature being negative changes nothing — the plateau is drawn below 0 °C on the temperature axis, still exactly flat.
Full model answer. (a) Vertical axis: temperature (°C). Horizontal axis: energy added. At −125 °C diethyl ether is a solid, because −125 °C is below its −116 °C melting temperature. (b) In order: a rising sloped piece from −125 °C to −116 °C — the solid warming; a plateau exactly flat at −116 °C — melting; a rising sloped piece from −116 °C to 35 °C — the liquid warming; a plateau exactly flat at 35 °C — boiling; a rising sloped piece from 35 °C to 50 °C — the gas warming. (c) Both plateaus appear: −116 °C and 35 °C each lie inside the −125 to 50 °C window. The melting temperature being negative changes nothing — the plateau is drawn below 0 °C on the temperature axis, still exactly flat.

Form E

THM-036 · easy · recall · seq 1 · authored fresh (stage 2); fluency[0] pairing family, stem reworded (corpus) · mcq4
Which option gives a phase change together with its true energy direction?
Vaporization — absorbs energy KEY
Condensation — absorbs energy
Freezing — absorbs energy
Melting — releases energy
THM-038 · easy · recall · seq 2 · authored fresh (stage 2); pool[8] slope-side family, fresh surface · mcq4
Along a heating curve's rising stretches, what job is the added energy doing?
Speeding the particles up — which is why the temperature climbs there. KEY
Pulling particles away from their neighbors — which is why the temperature climbs there.
Splitting the particles into smaller pieces as the sample warms.
Nothing measurable — rising stretches happen on their own.
THM-039 · easy · recall · seq 3 · authored fresh (stage 2); rule-line recall rotation · mcq4
After the boiling plateau ends, what does a correctly drawn heating curve do?
It rises again — the gas warming. KEY
It stays flat for the rest of the graph.
It stops — nothing can be drawn past the boiling plateau.
It falls back toward the melting temperature.
THM-040 · easy · recall · seq 4 · authored fresh (stage 2); rule-line recall rotation · mcq4
How many failed checks does it take to make a supplied heating curve flawed?
One — a curve that fails any single check misrepresents the substance. KEY
Two — any single failed check on its own is within drawing tolerance.
All three — only a fully wrong curve counts as flawed.
None — a neatly drawn curve cannot be flawed.
THM-036 · medium · application · seq 5 · authored fresh (stage 2); pool[1] family, direction-consistency framing · mcq4
Which list keeps to a single energy direction for both of its phase changes?
Melting and vaporization KEY
Melting and freezing
Vaporization and condensation
Freezing and vaporization
THM-036 · medium · application · seq 6 · authored fresh (stage 2); condensation-release scene · mcq4
A chilled can carried outdoors on a muggy afternoon films over with droplets, and it loses its chill faster than an identical chilled can beside it, sealed in a clear dry bag where no droplets can form. Why?
Vapor condensing on the can releases energy into it, on top of the warmth the surroundings supply. KEY
The droplets soak the can's coldness away into themselves.
The droplets absorb energy from the can as they form, so the can should actually stay cold longer.
Condensation moves no energy, so the two cans must warm at the same rate.
THM-036 · medium · application · seq 7 · authored fresh (stage 2); freezing-release scene · mcq4
A batch of molten sugar candy is poured out to set, and the counter under the tray grows noticeably warm while the candy hardens. Why?
The candy is freezing, and freezing releases energy into the tray and counter. KEY
The counter's coldness drains up into the soft candy.
The hardening candy absorbs energy from the counter, which the counter feels as warmth.
Setting candy is a chemical change that produces new warmth.
THM-037 · medium · application · seq 8 · authored fresh (stage 2) · mcq4
The figure presents ethylene glycol's heating curve. What is happening along the second flat segment?
FIGURE (heating-curve · stimulus) — substance: "ethylene glycol" · xAxis: "energy added" · yAxis: "temperature (°C), −40 to 230 by 30" · plateaus: [{"temp": -13}, {"temp": 197}] · range: "curve runs from −31 °C to 221 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −40 to 230 by 30; the trace rises from −31 °C,…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "ethylene glycol",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −40 to 230 by 30",
  "plateaus": [
   {
    "temp": -13
   },
   {
    "temp": 197
   }
  ],
  "range": "curve runs from −31 °C to 221 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −40 to 230 by 30; the trace rises from −31 °C, holds exactly flat at -13 °C, rises, holds exactly flat at 197 °C, then rises to 221 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
The liquid is boiling — turning to gas. KEY
The liquid is warming toward its boiling temperature.
The solid is melting.
The gas is warming.
THM-037 · medium · application · seq 9 · authored fresh (stage 2) · numeric
The figure gives antimony's heating curve. Read antimony's boiling temperature from the curve, in °C.
FIGURE (heating-curve · stimulus) — substance: "antimony" · xAxis: "energy added" · yAxis: "temperature (°C), 400 to 1800, gridlines every 200" · plateaus: [{"temp": 631}, {"temp": 1587}] · range: "curve runs from 500 °C to 1700 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 400 to 1800, gridlines every 200; the trace ri…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "antimony",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 400 to 1800, gridlines every 200",
  "plateaus": [
   {
    "temp": 631
   },
   {
    "temp": 1587
   }
  ],
  "range": "curve runs from 500 °C to 1700 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 400 to 1800, gridlines every 200; the trace rises from 500 °C, holds exactly flat at 631 °C, rises, holds exactly flat at 1587 °C, then rises to 1700 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Answer: 1587.0 °C KEY
also accepted: 1587.0
wrongValueDiagnostics
[
 {
  "value": 631.0,
  "misconception": "you read the first plateau — that is the melting temperature; boiling is the SECOND plateau, the higher one",
  "feedback": "This answer is wrong — you read the first plateau — that is the melting temperature; boiling is the SECOND plateau, the higher one."
 },
 {
  "value": 1700.0,
  "misconception": "you read the top of the curve instead of a plateau — the boiling temperature is the height where the curve flattens the second time",
  "feedback": "This answer is wrong — you read the top of the curve instead of a plateau — the boiling temperature is the height where the curve flattens the second time."
 }
]
feedback
{
 "keyExplanation": "Find the second flat plateau — its height is the boiling temperature. The plateau sits at 1587 °C, so antimony boils at 1587 °C. The other plateau is the melting temperature."
}
THM-037 · medium · application · seq 10 · authored fresh (stage 2) · mcq4
In the figure, cobalt's heating curve carries a small arrow on its final rising stretch, above the second plateau. What state is the cobalt in along the arrowed stretch?
FIGURE (heating-curve · stimulus) — substance: "cobalt" · xAxis: "energy added" · yAxis: "temperature (°C), 1200 to 3200, gridlines every 250" · plateaus: [{"temp": 1495}, {"temp": 2927}] · range: "curve runs from 1290 °C to 3140 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 1200 to 3200, gridlines every 250; the trace r…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "cobalt",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 1200 to 3200, gridlines every 250",
  "plateaus": [
   {
    "temp": 1495
   },
   {
    "temp": 2927
   }
  ],
  "range": "curve runs from 1290 °C to 3140 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 1200 to 3200, gridlines every 250; the trace rises from 1290 °C, holds exactly flat at 1495 °C, rises, holds exactly flat at 2927 °C, then rises to 3140 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis; a small arrow marks the final rising stretch, above the second plateau"
 }
}
Gas KEY
Liquid
Solid
A mixture of liquid and gas
THM-037 · medium · application · seq 11 · authored fresh (stage 2) · mcq4
A molten chromium sample is left to lose energy in a furnace lab. The figure tracks its cooling curve: the trace falls, levels out once, then falls again. What is happening along the level stretch?
FIGURE (heating-curve · stimulus) — substance: "chromium" · xAxis: "energy removed" · yAxis: "temperature (°C), 1500 to 2300, gridlines every 100" · plateaus: [{"temp": 1907}] · range: "curve descends from 2240 °C to 1560 °C" · style: "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 1500 to 2300, gridlines every 100; the trace…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "chromium",
  "xAxis": "energy removed",
  "yAxis": "temperature (°C), 1500 to 2300, gridlines every 100",
  "plateaus": [
   {
    "temp": 1907
   }
  ],
  "range": "curve descends from 2240 °C to 1560 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running 1500 to 2300, gridlines every 100; the trace falls from 2240 °C, holds exactly flat at 1907 °C, then falls to 1560 °C; a dashed guide ties the flat stretch to its labeled value on the temperature axis"
 }
}
The liquid chromium is freezing into solid chromium. KEY
The liquid chromium is boiling.
Gaseous chromium is condensing into liquid chromium there.
The solid chromium is melting.
THM-038 · medium · application · seq 12 · authored fresh (stage 2) · mcq4
A boiling tube of toluene bubbles steadily over its burner. Energy keeps arriving, yet the thermometer's reading stays put while the liquid boils away. Why?
Because during a phase change the added energy goes into pulling particles away from their neighbors and rearranging them, not into speeding them up. KEY
It stops absorbing energy from the heater while the boiling is underway, and only begins absorbing again once every drop of the liquid has become gas.
The energy added during the boiling is destroyed at the moment the liquid turns to gas, so there is nothing left over to raise the reading.
A thermometer is unable to give an accurate reading while bubbles of vapor keep forming and collapsing around its bulb inside the liquid.
THM-038 · medium · application · seq 13 · authored fresh (stage 2) · mcq4
At an ingot line, a mold of molten silicon cools after the pour. Its temperature holds steady while the sample solidifies, even though the surroundings keep drawing energy from it. Why does the temperature hold?
Particles settling back beside their neighbors release energy, and that release replaces what is being removed until the freezing finishes. KEY
The surroundings stop removing energy from the sample the moment freezing begins, so its temperature cannot change until the freezing has finished.
The layer of solid forming around the remaining liquid acts as insulation, blocking any more energy from escaping to the surroundings.
The particles keep moving at exactly the same speed, because nothing that happens during a phase change can ever slow particles down.
THM-039 · medium · application · seq 14 · authored fresh (stage 2); water-default + drift rotation · mcq4
A pure substance has a melting temperature of 64 °C and a boiling temperature of 342 °C. Panels A through D each graph a curve for it over the window from 33 °C to 380 °C. Which panel shows a correct heating curve?
FIGURE (heating-curve-panels · image-options) — kind: "heating" · panels: [{"panel": "A", "description": "rises, then a near-flat stretch drifting upward from 64 °C, rises, then a near-flat stretch drifting upward from 342 °C, rise… · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose bes…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "heating",
  "panels": [
   {
    "panel": "A",
    "description": "rises, then a near-flat stretch drifting upward from 64 °C, rises, then a near-flat stretch drifting upward from 342 °C, rises"
   },
   {
    "panel": "B",
    "description": "rises, holds flat at 100 °C only, rises — no other flat stretch"
   },
   {
    "panel": "C",
    "description": "rises, holds exactly flat at 64 °C, rises, holds exactly flat at 342 °C, rises"
   },
   {
    "panel": "D",
    "description": "falls, holds flat at 342 °C, falls, holds flat at 64 °C, falls — a descending trace"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy added' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: rises, then a near-flat stretch drifting upward from 64 °C, rises, then a near-flat stretch drifting upward from 342 °C, rises; Panel B: rises, holds flat at 100 °C only, rises — no other flat stretch; Panel C: rises, holds exactly flat at 64 °C, rises, holds exactly flat at 342 °C, rises; Panel D: falls, holds flat at 342 °C, falls, holds flat at 64 °C, falls — a descending trace"
 }
}
Panel C KEY
Panel A
Panel B
Panel D
THM-039 · medium · application · seq 15 · authored fresh (stage 2) · mcq4
A pure substance boils at 129 °C and melts at -62 °C. In the figure, four panels labeled A, B, C, and D each graph a curve recorded as a gas sample of the substance loses energy, from 148 °C down to -87 °C. Which panel shows a correct cooling curve?
FIGURE (heating-curve-panels · image-options) — kind: "cooling" · panels: [{"panel": "A", "description": "falls, holds exactly flat at 129 °C, falls, holds exactly flat at −62 °C, falls"}, {"panel": "B", "description": "rises, hold… · style: "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose b…
raw spec
{
 "figureShape": "image-options",
 "render_contract": "single 4-panel stimulus figure; options are the bare panel labels (R11); panel pictures carry no prose",
 "figureSpec": {
  "figureType": "heating-curve-panels",
  "kind": "cooling",
  "panels": [
   {
    "panel": "A",
    "description": "falls, holds exactly flat at 129 °C, falls, holds exactly flat at −62 °C, falls"
   },
   {
    "panel": "B",
    "description": "rises, holds flat at −62 °C, rises, holds flat at 129 °C, rises"
   },
   {
    "panel": "C",
    "description": "falls, holds flat at 100 °C, falls, holds flat at 0 °C, falls"
   },
   {
    "panel": "D",
    "description": "falls into one very long flat stretch at a single height midway between the two data temperatures, then falls"
   }
  ],
  "style": "four small gridded graphs in one figure, each with its horizontal axis labeled 'energy removed' and its vertical axis labeled 'temperature (°C)'; no prose beside the panels; Panel A: falls, holds exactly flat at 129 °C, falls, holds exactly flat at −62 °C, falls; Panel B: rises, holds flat at −62 °C, rises, holds flat at 129 °C, rises; Panel C: falls, holds flat at 100 °C, falls, holds flat at 0 °C, falls; Panel D: falls into one very long flat stretch at a single height midway between the two data temperatures, then falls"
 }
}
Panel A KEY
Panel B
Panel C
Panel D
THM-040 · medium · application · seq 16 · authored fresh (stage 2) · mcq4
Potassium bromide melts at 734 °C and boils at 1435 °C. In the figure, a heating curve recorded for potassium bromide runs from 550 °C to 1600 °C. Check the curve against the data. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "potassium bromide" · xAxis: "energy added" · yAxis: "temperature (°C), 400 to 1800, gridlines every 200" · plateaus: [{"temp": 734}, {"temp": 1435}] · range: "curve runs from 550 °C to 1600 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 400 to 1800, gridlines every 200; the trace ri…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "potassium bromide",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 400 to 1800, gridlines every 200",
  "plateaus": [
   {
    "temp": 734
   },
   {
    "temp": 1435
   }
  ],
  "range": "curve runs from 550 °C to 1600 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 400 to 1800, gridlines every 200; the trace rises from 550 °C, holds exactly flat at 734 °C, rises, holds exactly flat at 1435 °C, then rises to 1600 °C; dashed guides tie each flat stretch to its labeled value on the temperature axis"
 }
}
Correct — flat plateaus at 734 °C and 1435 °C, rising segments everywhere else. KEY
Flawed — after the second plateau the curve should level off, not keep rising.
Flawed — the first plateau should sit at 0 °C.
Flawed — the plateaus should slope gently upward instead of lying flat.
THM-038 · hard · transfer · seq 17 · authored fresh (stage 2) · mcq4
A pot of butanol boils on a heater plate, its thermometer holding one reading. The energy flowing in each second is then doubled — yet the reading does not move. What does the extra energy do?
It pulls particles away from their neighbors faster, so the liquid boils away sooner — at the same steady reading. KEY
It raises the liquid's temperature while it boils.
It is turned away at the surface, because a liquid that is already boiling can only ever absorb energy at one fixed, unchangeable rate.
It tears the liquid molecules apart into new substances instead of boiling them.
THM-037 · hard · transfer · seq 18 · authored fresh (stage 2); single-plateau window variant | sol loop-1 S4c: urea (decomposes at its melt) -> benzophenone · mcq4
In the figure, a dashed guide marks a point partway along the flat segment of benzophenone's heating curve. Which statement describes the sample at the marked point?
FIGURE (heating-curve · stimulus) — substance: "benzophenone" · xAxis: "energy added" · yAxis: "temperature (°C), 0 to 100, gridlines every 10" · plateaus: [{"temp": 48}] · range: "curve runs from 25 °C to 85 °C" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 100, gridlines every 10; the trace rises …
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "benzophenone",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), 0 to 100, gridlines every 10",
  "plateaus": [
   {
    "temp": 48
   }
  ],
  "range": "curve runs from 25 °C to 85 °C",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running 0 to 100, gridlines every 10; the trace rises from 25 °C, holds exactly flat at 48 °C, then rises to 85 °C; dashed guides tie the flat stretch to its labeled value on the temperature axis; a dashed guide drops from a point partway along the flat segment"
 }
}
A mixture of solid and liquid benzophenone, with melting underway. KEY
Entirely solid benzophenone, warming toward its melting temperature.
Entirely liquid benzophenone, warming toward its boiling temperature.
A mixture of liquid and gaseous benzophenone.
THM-040 · hard · transfer · seq 19 · authored fresh (stage 2); cryo-logger instance · mcq4
Krypton melts at -157 °C and boils at -153 °C. In the figure, krypton's heating curve matches the data everywhere except one feature: its first plateau is drawn drifting gently upward before the curve climbs on. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "krypton" · xAxis: "energy added" · yAxis: "temperature (°C), −170 to −140, gridlines every 5" · style: "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −170 to −140, gridlines every 5; the trace ris…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "krypton",
  "xAxis": "energy added",
  "yAxis": "temperature (°C), −170 to −140, gridlines every 5",
  "style": "clean gridded graph; horizontal axis labeled 'energy added', vertical axis labeled 'temperature (°C)' running −170 to −140, gridlines every 5; the trace rises from −166 °C, then a near-flat stretch drifts gently upward from −157 °C to −155 °C, then the trace rises, holds exactly flat at −153 °C, and rises to −144 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the melting plateau must be exactly flat, because the temperature holds during a phase change. KEY
Correct — a small upward drift on a plateau is within normal drawing tolerance, so no check fails.
Flawed — the boiling plateau should also drift upward, to match the other one.
Flawed — the melting plateau belongs at 0 °C, not below zero.
THM-040 · hard · transfer · seq 20 · authored fresh (stage 2); pool[14] class, second cooling instance · mcq4
Oleic acid melts at 13 °C and boils at 360 °C. In the figure, a student's cooling curve for oleic acid falls, holds flat at 360 °C, falls, holds flat at 0 °C, then falls again. Which verdict is correct?
FIGURE (heating-curve · stimulus) — substance: "oleic acid" · xAxis: "energy removed" · yAxis: "temperature (°C), −30 to 400, gridlines every 50" · style: "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running −30 to 400, gridlines every 50; the trace fa…
raw spec
{
 "figureShape": "stimulus",
 "figureSpec": {
  "figureType": "heating-curve",
  "substance": "oleic acid",
  "xAxis": "energy removed",
  "yAxis": "temperature (°C), −30 to 400, gridlines every 50",
  "style": "clean gridded graph; horizontal axis labeled 'energy removed', vertical axis labeled 'temperature (°C)' running −30 to 400, gridlines every 50; the trace falls from 390 °C, holds exactly flat at 360 °C, falls, holds exactly flat at 0 °C, then falls to −20 °C; dashed guides tie the flat stretches to labeled axis values"
 }
}
Flawed — the freezing plateau sits at 0 °C, but oleic acid freezes at 13 °C. KEY
Correct — both plateaus are exactly flat, so the curve passes.
Flawed — a cooling curve should rise from left to right.
Flawed — the plateau at 360 °C is wrong, because a plateau at the boiling temperature belongs only on a heating curve.
THM-039 · medium · application · seq 21 · authored fresh (stage 2); melting-off-range-below plan (starts liquid; WE2 off-range family on the other side) · frq
Nonane melts at -53 °C and boils at 151 °C. A worksheet asks for nonane's heating curve, drawn across the window -15 °C to 175 °C. Do not draw it. Instead, type the plan for the curve:
Nonane melts at -53 °C and boils at 151 °C. A worksheet asks for nonane's heating curve, drawn across the window -15 °C to 175 °C. Do not draw it. Instead, type the plan for the curve: (a) Give the label for each axis, and name the state of the nonane at -15 °C. (b) List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there. (c) For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Part a. Give the label for each axis, and name the state of the nonane at -15 °C.
Model: Vertical axis: temperature (°C). Horizontal axis: energy added. At −15 °C nonane is a liquid, because −15 °C is above its −53 °C melting temperature and below its 151 °C boiling temperature.
Part b. List the pieces of the curve in order from left to right. For every plateau, give its temperature and name the phase change happening there.
Model: In order: a rising sloped piece from −15 °C to 151 °C — the liquid warming; a plateau exactly flat at 151 °C — boiling; a rising sloped piece from 151 °C to 175 °C — the gas warming. That is the whole curve for this window.
Part c. For each of the two phase-change temperatures, state whether its plateau appears in this window, and why.
Model: The boiling plateau appears, because 151 °C lies inside the −15 to 175 °C window. The melting plateau does not appear, because nonane melts at −53 °C, below the window's start — the sample enters the window already liquid, so no melting happens on this curve.
Full model answer. (a) Vertical axis: temperature (°C). Horizontal axis: energy added. At −15 °C nonane is a liquid, because −15 °C is above its −53 °C melting temperature and below its 151 °C boiling temperature. (b) In order: a rising sloped piece from −15 °C to 151 °C — the liquid warming; a plateau exactly flat at 151 °C — boiling; a rising sloped piece from 151 °C to 175 °C — the gas warming. That is the whole curve for this window. (c) The boiling plateau appears, because 151 °C lies inside the −15 to 175 °C window. The melting plateau does not appear, because nonane melts at −53 °C, below the window's start — the sample enters the window already liquid, so no melting happens on this curve.