Unit 11 — End of Topic Tests (reviewer copy: all keys and model answers visible)
End of Topic Test: Recognizing acids and bases & Defining acids and bases & Naming acids and bases (u11-t1 · 5 forms × 21 items · 105 total)
David's notes for James:
FRQ ALLOCATION - frq_per_form = 1 (confirm the composition): the wave's calc-heavy 2-3-FRQ directive was EVALUATED AND DOES NOT APPLY - this scope (ABS-001..021, U11 Topics 1-3: recognizing / defining / naming acids and bases) holds ZERO quantitative lessons (21 atoms, all fact/discrimination/explanation/representation; zero numeric seeds in your 63-item pool) and no taught calculation route - every pH-adjacent calculation is later-gate territory. No value is ever computed and entered, so there is nothing for a 5-line-scaffold calculation FRQ to assess; your frq_per_form=1 baseline stands. The FRQ sits on capstone ABS-014 (definition-coverage judgment: classify one supplied-behaviour particle under BOTH taught definitions and justify each verdict) at terminal seq 21 per D6, cases rotating per form across the coverage space (B-L-only base / both-definitions base / both-definitions acid / neither / acids-never-disagree).
EXACT-FIT COMPOSITION (confirm): 21 scope lessons = 20 objective + 1 FRQ rows exactly - every lesson carries exactly ONE row, no lesson dropped, no room for the 2-3-rows-per-calc-lesson expansion (D5's min(20, 6 x 21) = 20 scales down only). Interactions 15 mcq + 5 TEXT + 1 frq: the five typed-production rows are the topics' own production formats, each matching your seed interaction (seq 4 ABS-005 roster formula, seq 12 ABS-012 acceptor-formula arithmetic, seq 15 ABS-019 oxyacid naming, seq 16 ABS-021 base naming, seq 20 ABS-020 oxyacid formula production - the demo-gate curation includes the text seed). NO numeric rows (V-T6 unexercised - nothing quantitative to enter).
CAPSTONE HANDLING (confirm): ABS-020 takes the terminal objective slot (seq 20, hard TEXT row - your demo-curated chloric/chlorate production placed verbatim on form A); ABS-014 takes the FRQ. ABS-014's three curated gate mcqs have no parity slot under the one-row-per-lesson exact fit - they became SPARES and seeded the FRQ's case-design space (recorded; U6-G1 RXN-019 precedent).
DEFINITIONAL-REGISTER ADJUDICATION - THE HEADLINE (needs your + David's confirmation): this is the acid/base DEFINITIONS gate, and the words 'hydrogen', 'water', and 'oxygen' ARE the taught criteria (the profile's hydrogen-gas line; Arrhenius 'releases H+/OH- in water'; hydronium = H+ riding a water molecule; B-L donor events; the binary-vs-oxyacid split IS 'contains oxygen or not'). The shared V-T7 substance-exclusivity scan has no relief key for that class, so the resolution is 13 RECORDED adjudicated_instance_families in gate_config.json (def-hydrogen 24 slots / def-water 29 / def-oxygen 10; roster ammonia/sodium/calcium/vinegar; naming-element-roots iodine/chlorine/fluorine/sulfur; profile-gas-roster carbon; ion-notation 32/33/42/43), enforced by a gate-local wrapper (validate_with_adjudications.py) over the UNTOUCHED shared validator: 600 V-T7 fail lines all excused under enumerated slots, 0 uncovered, exit 0. GRAM LANES STAYED FULLY ARMED - every duplicate-stem / cross-form-gram / spec-text-gram fail was fixed by CONTENT REWORK first (5 waves, 67 recorded edits; the initial 680 fails fell to the 600 adjudication-lane residue by rework alone). Every gratuitous scenario use of the register words was content-purged before a family was recorded. A generic _shared relief lever is PROPOSED, DOCUMENTED, NOT APPLIED (_shared read-only this wave).
ION-NOTATION DIGIT-FUSION FAMILIES (disclosure, U8-G3 TC-100 lane): the taught supplied-ion convention (oxyacid naming/formula rows always SUPPLY the polyatomic ion with its charge, exactly as your spec items do) writes CrO4 2- / SO4 2- / PO4 3- / TeO3 2- etc., and the validator's Unicode normalization fuses subscript+charge into the numbers 32/33/42/43, colliding every such ion numerically. The four token families excuse ONLY those fusion strings; the underlying ions are all DIFFERENT per slot (chromate/hydrogen-phosphate/sulfate/selenate; borate vs phosphite; ...). Notation, not quantity.
SEED DISPOSITIONS (confirm): pool 63 = the 21 lessons' spec gateItems positionally (asserted); demo_curated[0..5] = pools 39/40/41/57/58/59 (deduped, both refs cited). PLACED 42 of 63 (form A 19, B 15, C 7, D 1 - the spread follows the substance-ledger word-homes: a seed landed on the form where its instance family is free); 21 spares, all with recorded reasons; 4 verbatim placements (pools 13/36/57 + the instance-light H3O+/OH- conjugate trap). NOTA/AOTA: your pool carries none - the opportunistic replacement rule never fired.
SEED FRESHENINGS UNDER THE STRICT SEED RULING (no freshness exemption; all by content, confirm): pool 6's table row P zinc -> aluminum (zinc = own-lesson WE metal); pool 45's key/distractor set HF -> H2Se and HClO3 -> HBrO3 (HClO3 is E#20's typed answer); pool 49's binary-acid roster membership freshened to {HF, HCl, HI} (excludes H2S = C#19's pair, H2Se = C#14's, HBr = C#10's - the seq-18/19 six-member de-cue ledger); pool 4 'Tonic water' wording; B#9 HClO4 -> HClO3 and C#10 HClO4 -> HBrO3 (perchloric reserved to E#21's FRQ exclusively); D#12 chlorite -> hypochlorite (chlorite = B#15's naming answer); B#20 phosphorous/phosphite -> tellurous/tellurite H2TeO3 (phosphite = E#15's naming slot); E#1 Chlorine distractor -> Nitrogen; B#14 stomach-acid scenario -> brick cleaner (stomach = E#3's roster home).
SEED PLACEMENT DEVIATIONS OFF FORM A (recorded, confirm): (1) pool 54 (name HClO2 from chlorite) sits at B#15, not form A - form A's seq 20 keeps your demo-curated chloric/chlorate production and one chlorine-oxyacid family lives on one form only; (2) pool 42 (HCl + NH3 -> NH4+ + Cl- both-pairs) sits at D#17 - its equation collides with form A's chlorine crowd (seq 19/20) and B#14's HCl; D is the only form where both families are free.
B#3 ANCHOR SWAP (seed deviation, confirm): your use->name row's fertilizer->nitric mapping is taught, but sulfuric is the real-world phosphate-fertilizer acid - a chemistry-aware student could defend two options. The anchor swapped to the car-battery mapping (uniquely taught AND uniquely true); the fertilizer association was not used anywhere as a key.
ROW-13 FORWARD-DIRECTION HARDENING (blind-review fix, all forms - confirm): the reversible half-arrow (⇌) let a conjugate-aware student read reverse-direction B-L roles as also-correct. Every seq-13 stem now asks for the roles 'in the forward (left-to-right) change' inside the question itself - ABS-013's taught procedure is left-to-right comparison, and conjugate vocabulary is withheld until ABS-015, so the reverse reading is outside-course. Your pool[36] HF + H2O assignment is otherwise verbatim on form A.
AMPHOTERIC-ALUMINUM HOLE (blind-review fix, confirm): strong bases also release H2 with aluminum in real chemistry, so the acid-profile 'releases hydrogen gas with a metal' line could mislead on Al-specific items. A#5's table row and the ABS-001 profile items now say generic 'active metal' where the metal is the profile's exemplar (the profile line is about the class); C#5's concrete-cleaner no-litmus classification design was kept.
RECORDED BLIND OVERRIDE - B#6 (U4-G1 ADJ-6 lane, confirm): one re-blind reviewer rated 'NH3 is also neither an Arrhenius acid nor base' defensible. Overridden as out-of-frame: the stem explicitly binds the item to the formula patterns + memorized exceptions register (ABS-006), under which NH3 IS the taught base exception; the other three reviewers passed the item. Raw verdict kept intact. Related one-off: D#13 drew one zero-justification F2 that failed to reproduce on a two-vendor probe (3 of 4 post-fix reviews clean) - recorded, raws intact.
SOL-QC CONTENT FIXES (disclosure): the seq-15 'Name the acid HXOy' stems now state the answer-format contract explicitly on ALL FIVE forms (the grading note's acid-word-omission condition needs the stem to ask for the acid name - sol flagged 3 of 5, class swept deterministically); the dye-controls-color distractor ambiguity (C#7/D#8) became false negative-ion / metal-ion causation misconceptions; E#11 and E#17's one-Yes-three-No sets were rebuilt on substantive misconceptions (charge rule / history rule / water-always-donor; same-charge rule / water-barred-from-acid-role / OH-unit subtraction). 4 sol minors survive as recorded style notes (non-blocking, keys unaffected).
STANDING FLAGS FOR DAVID (your read welcome): (1) C#20 uses arsenic acid H3AsO4 with arsenate supplied - chemically real and classroom-safe as a WRITTEN exercise; a swap is available if the register reads wrong; (2) C#10 SHOWS HBrO3 assembled in an option while E#20's typed answer is HBrO3 - cross-form, different skills, noted-not-defect; (3) B#6's distractor HClO is also D#12's typed answer - cross-form, no arithmetic leak.
TYPED-ANSWER CONTRACT (disclosure): all five text rows grade chemistry, not typography - answers stored in Unicode with plain-ASCII alternates (NH3, HClO3, ...), any spacing variant equivalent, element symbols case-significant; V-T12 honored (no sub/superscript entry ever required - your seeds' own 'plain digits work' hint convention).
COURSE-LOCAL DEFINITION GUARD (wave binding, disclosure): the two models tested are exactly the taught ones - Arrhenius (releases H+/OH- in water) and Bronsted-Lowry (donates/accepts H+ in a stated event). NO Lewis model, NO strength/weakness language (Topic 4), NO pH (Topic 5), NO neutralization; hydronium notation per ABS-010's honest-picture register; weak species appear in described single events only, never with full-ionization arrows.
BINDING INSTANCE RULE (course-wide, disclosure): zero fissile/weapons/dose framings; classroom-safe register throughout (household cleaners, food acids, lab solutions, antacids). Your pool scanned clean at stage 1; re-swept at packaging over forms_final and this export body.
QC LEDGER (disclosure): deterministic validators 11/12 clean as shipped + V-T7 100% covered by the 13 recorded families (600/600 excused, 0 uncovered, wrapper exit 0; gram lanes fully armed and clean by content rework); blind rounds r1-r12 = 192/192 key picks cumulative, keyless 40/40 graded matches with hand-review justifications, 0 open hard fails (1 recorded override, 1 non-reproduced one-off); sol authoritative loops 1-3 = 7 -> 2 -> 0 FAILs, final 105/105 pass, subset raw coverage verified per loop; 5 patch waves, all machine-logged.
FRQ delivery: your `prod` draw-on-paper class is delivered as a typed diagram-PLAN task (state kinds/recipes/counts/spacing; rubric grades the same observables). Confirm this mapping (pending from the U01-G1 round-trip).
full notes file
# u11-t1 — notes/queries from David's side (U11-G1)
1. FRQ ALLOCATION - frq_per_form = 1 (confirm the composition): the wave's calc-heavy 2-3-FRQ directive was EVALUATED AND DOES NOT APPLY - this scope (ABS-001..021, U11 Topics 1-3: recognizing / defining / naming acids and bases) holds ZERO quantitative lessons (21 atoms, all fact/discrimination/explanation/representation; zero numeric seeds in your 63-item pool) and no taught calculation route - every pH-adjacent calculation is later-gate territory. No value is ever computed and entered, so there is nothing for a 5-line-scaffold calculation FRQ to assess; your frq_per_form=1 baseline stands. The FRQ sits on capstone ABS-014 (definition-coverage judgment: classify one supplied-behaviour particle under BOTH taught definitions and justify each verdict) at terminal seq 21 per D6, cases rotating per form across the coverage space (B-L-only base / both-definitions base / both-definitions acid / neither / acids-never-disagree).
2. EXACT-FIT COMPOSITION (confirm): 21 scope lessons = 20 objective + 1 FRQ rows exactly - every lesson carries exactly ONE row, no lesson dropped, no room for the 2-3-rows-per-calc-lesson expansion (D5's min(20, 6 x 21) = 20 scales down only). Interactions 15 mcq + 5 TEXT + 1 frq: the five typed-production rows are the topics' own production formats, each matching your seed interaction (seq 4 ABS-005 roster formula, seq 12 ABS-012 acceptor-formula arithmetic, seq 15 ABS-019 oxyacid naming, seq 16 ABS-021 base naming, seq 20 ABS-020 oxyacid formula production - the demo-gate curation includes the text seed). NO numeric rows (V-T6 unexercised - nothing quantitative to enter).
3. CAPSTONE HANDLING (confirm): ABS-020 takes the terminal objective slot (seq 20, hard TEXT row - your demo-curated chloric/chlorate production placed verbatim on form A); ABS-014 takes the FRQ. ABS-014's three curated gate mcqs have no parity slot under the one-row-per-lesson exact fit - they became SPARES and seeded the FRQ's case-design space (recorded; U6-G1 RXN-019 precedent).
4. DEFINITIONAL-REGISTER ADJUDICATION - THE HEADLINE (needs your + David's confirmation): this is the acid/base DEFINITIONS gate, and the words 'hydrogen', 'water', and 'oxygen' ARE the taught criteria (the profile's hydrogen-gas line; Arrhenius 'releases H+/OH- in water'; hydronium = H+ riding a water molecule; B-L donor events; the binary-vs-oxyacid split IS 'contains oxygen or not'). The shared V-T7 substance-exclusivity scan has no relief key for that class, so the resolution is 13 RECORDED adjudicated_instance_families in gate_config.json (def-hydrogen 24 slots / def-water 29 / def-oxygen 10; roster ammonia/sodium/calcium/vinegar; naming-element-roots iodine/chlorine/fluorine/sulfur; profile-gas-roster carbon; ion-notation 32/33/42/43), enforced by a gate-local wrapper (validate_with_adjudications.py) over the UNTOUCHED shared validator: 600 V-T7 fail lines all excused under enumerated slots, 0 uncovered, exit 0. GRAM LANES STAYED FULLY ARMED - every duplicate-stem / cross-form-gram / spec-text-gram fail was fixed by CONTENT REWORK first (5 waves, 67 recorded edits; the initial 680 fails fell to the 600 adjudication-lane residue by rework alone). Every gratuitous scenario use of the register words was content-purged before a family was recorded. A generic _shared relief lever is PROPOSED, DOCUMENTED, NOT APPLIED (_shared read-only this wave).
5. ION-NOTATION DIGIT-FUSION FAMILIES (disclosure, U8-G3 TC-100 lane): the taught supplied-ion convention (oxyacid naming/formula rows always SUPPLY the polyatomic ion with its charge, exactly as your spec items do) writes CrO4 2- / SO4 2- / PO4 3- / TeO3 2- etc., and the validator's Unicode normalization fuses subscript+charge into the numbers 32/33/42/43, colliding every such ion numerically. The four token families excuse ONLY those fusion strings; the underlying ions are all DIFFERENT per slot (chromate/hydrogen-phosphate/sulfate/selenate; borate vs phosphite; ...). Notation, not quantity.
6. SEED DISPOSITIONS (confirm): pool 63 = the 21 lessons' spec gateItems positionally (asserted); demo_curated[0..5] = pools 39/40/41/57/58/59 (deduped, both refs cited). PLACED 42 of 63 (form A 19, B 15, C 7, D 1 - the spread follows the substance-ledger word-homes: a seed landed on the form where its instance family is free); 21 spares, all with recorded reasons; 4 verbatim placements (pools 13/36/57 + the instance-light H3O+/OH- conjugate trap). NOTA/AOTA: your pool carries none - the opportunistic replacement rule never fired.
7. SEED FRESHENINGS UNDER THE STRICT SEED RULING (no freshness exemption; all by content, confirm): pool 6's table row P zinc -> aluminum (zinc = own-lesson WE metal); pool 45's key/distractor set HF -> H2Se and HClO3 -> HBrO3 (HClO3 is E#20's typed answer); pool 49's binary-acid roster membership freshened to {HF, HCl, HI} (excludes H2S = C#19's pair, H2Se = C#14's, HBr = C#10's - the seq-18/19 six-member de-cue ledger); pool 4 'Tonic water' wording; B#9 HClO4 -> HClO3 and C#10 HClO4 -> HBrO3 (perchloric reserved to E#21's FRQ exclusively); D#12 chlorite -> hypochlorite (chlorite = B#15's naming answer); B#20 phosphorous/phosphite -> tellurous/tellurite H2TeO3 (phosphite = E#15's naming slot); E#1 Chlorine distractor -> Nitrogen; B#14 stomach-acid scenario -> brick cleaner (stomach = E#3's roster home).
8. SEED PLACEMENT DEVIATIONS OFF FORM A (recorded, confirm): (1) pool 54 (name HClO2 from chlorite) sits at B#15, not form A - form A's seq 20 keeps your demo-curated chloric/chlorate production and one chlorine-oxyacid family lives on one form only; (2) pool 42 (HCl + NH3 -> NH4+ + Cl- both-pairs) sits at D#17 - its equation collides with form A's chlorine crowd (seq 19/20) and B#14's HCl; D is the only form where both families are free.
9. B#3 ANCHOR SWAP (seed deviation, confirm): your use->name row's fertilizer->nitric mapping is taught, but sulfuric is the real-world phosphate-fertilizer acid - a chemistry-aware student could defend two options. The anchor swapped to the car-battery mapping (uniquely taught AND uniquely true); the fertilizer association was not used anywhere as a key.
10. ROW-13 FORWARD-DIRECTION HARDENING (blind-review fix, all forms - confirm): the reversible half-arrow (⇌) let a conjugate-aware student read reverse-direction B-L roles as also-correct. Every seq-13 stem now asks for the roles 'in the forward (left-to-right) change' inside the question itself - ABS-013's taught procedure is left-to-right comparison, and conjugate vocabulary is withheld until ABS-015, so the reverse reading is outside-course. Your pool[36] HF + H2O assignment is otherwise verbatim on form A.
11. AMPHOTERIC-ALUMINUM HOLE (blind-review fix, confirm): strong bases also release H2 with aluminum in real chemistry, so the acid-profile 'releases hydrogen gas with a metal' line could mislead on Al-specific items. A#5's table row and the ABS-001 profile items now say generic 'active metal' where the metal is the profile's exemplar (the profile line is about the class); C#5's concrete-cleaner no-litmus classification design was kept.
12. RECORDED BLIND OVERRIDE - B#6 (U4-G1 ADJ-6 lane, confirm): one re-blind reviewer rated 'NH3 is also neither an Arrhenius acid nor base' defensible. Overridden as out-of-frame: the stem explicitly binds the item to the formula patterns + memorized exceptions register (ABS-006), under which NH3 IS the taught base exception; the other three reviewers passed the item. Raw verdict kept intact. Related one-off: D#13 drew one zero-justification F2 that failed to reproduce on a two-vendor probe (3 of 4 post-fix reviews clean) - recorded, raws intact.
13. SOL-QC CONTENT FIXES (disclosure): the seq-15 'Name the acid HXOy' stems now state the answer-format contract explicitly on ALL FIVE forms (the grading note's acid-word-omission condition needs the stem to ask for the acid name - sol flagged 3 of 5, class swept deterministically); the dye-controls-color distractor ambiguity (C#7/D#8) became false negative-ion / metal-ion causation misconceptions; E#11 and E#17's one-Yes-three-No sets were rebuilt on substantive misconceptions (charge rule / history rule / water-always-donor; same-charge rule / water-barred-from-acid-role / OH-unit subtraction). 4 sol minors survive as recorded style notes (non-blocking, keys unaffected).
14. STANDING FLAGS FOR DAVID (your read welcome): (1) C#20 uses arsenic acid H3AsO4 with arsenate supplied - chemically real and classroom-safe as a WRITTEN exercise; a swap is available if the register reads wrong; (2) C#10 SHOWS HBrO3 assembled in an option while E#20's typed answer is HBrO3 - cross-form, different skills, noted-not-defect; (3) B#6's distractor HClO is also D#12's typed answer - cross-form, no arithmetic leak.
15. TYPED-ANSWER CONTRACT (disclosure): all five text rows grade chemistry, not typography - answers stored in Unicode with plain-ASCII alternates (NH3, HClO3, ...), any spacing variant equivalent, element symbols case-significant; V-T12 honored (no sub/superscript entry ever required - your seeds' own 'plain digits work' hint convention).
16. COURSE-LOCAL DEFINITION GUARD (wave binding, disclosure): the two models tested are exactly the taught ones - Arrhenius (releases H+/OH- in water) and Bronsted-Lowry (donates/accepts H+ in a stated event). NO Lewis model, NO strength/weakness language (Topic 4), NO pH (Topic 5), NO neutralization; hydronium notation per ABS-010's honest-picture register; weak species appear in described single events only, never with full-ionization arrows.
17. BINDING INSTANCE RULE (course-wide, disclosure): zero fissile/weapons/dose framings; classroom-safe register throughout (household cleaners, food acids, lab solutions, antacids). Your pool scanned clean at stage 1; re-swept at packaging over forms_final and this export body.
18. QC LEDGER (disclosure): deterministic validators 11/12 clean as shipped + V-T7 100% covered by the 13 recorded families (600/600 excused, 0 uncovered, wrapper exit 0; gram lanes fully armed and clean by content rework); blind rounds r1-r12 = 192/192 key picks cumulative, keyless 40/40 graded matches with hand-review justifications, 0 open hard fails (1 recorded override, 1 non-reproduced one-off); sol authoritative loops 1-3 = 7 -> 2 -> 0 FAILs, final 105/105 pass, subset raw coverage verified per loop; 5 patch waves, all machine-logged.
[
{
"value": "NH₄⁺",
"misconception": "you wrote the ammonium ion — NH₄⁺ is the 1+ ion; the base ammonia is the neutral compound NH₃",
"feedback": "This answer is wrong — you wrote the ammonium ion — NH₄⁺ is the 1+ ion; the base ammonia is the neutral compound NH₃"
},
{
"value": "HNO₃",
"misconception": "you recalled the other nitrogen compound — HNO₃ is nitric acid; ammonia is NH₃",
"feedback": "This answer is wrong — you recalled the other nitrogen compound — HNO₃ is nitric acid; ammonia is NH₃"
},
{
"value": "NH₂",
"misconception": "you dropped a hydrogen — ammonia carries three hydrogens: NH₃",
"feedback": "This answer is wrong — you dropped a hydrogen — ammonia carries three hydrogens: NH₃"
}
]
feedback
{
"keyExplanation": "Ammonia is NH₃ — one nitrogen, three hydrogens, no metal, no OH. It is the base in many glass cleaners.",
"anticipatedWrong": [
{
"value": "NH₄⁺",
"misconception": "you wrote the ammonium ion — NH₄⁺ is the 1+ ion; the base ammonia is the neutral compound NH₃",
"feedback": "This answer is wrong — you wrote the ammonium ion — NH₄⁺ is the 1+ ion; the base ammonia is the neutral compound NH₃"
},
{
"value": "HNO₃",
"misconception": "you recalled the other nitrogen compound — HNO₃ is nitric acid; ammonia is NH₃",
"feedback": "This answer is wrong — you recalled the other nitrogen compound — HNO₃ is nitric acid; ammonia is NH₃"
},
{
"value": "NH₂",
"misconception": "you dropped a hydrogen — ammonia carries three hydrogens: NH₃",
"feedback": "This answer is wrong — you dropped a hydrogen — ammonia carries three hydrogens: NH₃"
}
]
}
ABS-003 · medium · application · seq 5 · seed:U11-G1/pool[6] (= ABS-003 gateItems[0]) — FRESHENED: table row P zinc -> aluminum (own-lesson WE metal; aluminum = same-seq C metal, A5 WARN by design); explanation swept for the zinc leftover | STAGE-4 (blind F2): table row P metal made GENERIC 'active metal' (amphoteric-aluminum hole closed) · mcq4
The table shows one observation for each of four cleaning products, P, Q, R, and S. Which product contains a base?
FIGURE (data-table · stimulus) — title: "Observations of four cleaning products" · columns: ["Product", "Observation"] · rows: [["P", "bubbles of hydrogen form on a strip of reactive metal"], ["Q", "turns red litmus paper blue"], ["R", "turns blue litmus paper red"], ["S", "changes n… · style: "plain four-row observation table; no classification column"raw spec
{
"figureRequired": true,
"figureShape": "stimulus",
"figureSpec": {
"figureType": "data-table",
"title": "Observations of four cleaning products",
"columns": [
"Product",
"Observation"
],
"rows": [
[
"P",
"bubbles of hydrogen form on a strip of reactive metal"
],
[
"Q",
"turns red litmus paper blue"
],
[
"R",
"turns blue litmus paper red"
],
[
"S",
"changes neither litmus color"
]
],
"style": "plain four-row observation table; no classification column"
}
}
Ca(OH)₂ → Ca²⁺ + 2OH⁻. A student classifies Ca(OH)₂ as an Arrhenius acid 'because the formula contains hydrogen.' Which classification is correct, and why?
An Arrhenius base — the hydrogen stays locked inside the OH⁻ unit, and released OH⁻ marks a base. KEY
An Arrhenius acid — any hydrogen in a formula counts as releasable H⁺.
Both — Ca(OH)₂ releases H⁺ ions and OH⁻ ions into the water at the same time.
Neither — a formula containing both hydrogen and oxygen cannot be classified at all.
In solution, an HCN particle passes an H⁺ to a neighboring water molecule. Why does HCN count as a Brønsted-Lowry acid in this event?
It donates a proton to another particle — exactly what the definition requires. KEY
It dissolves in water — anything that dissolves in water counts as an acid.
It contains hydrogen — any particle containing hydrogen is an acid.
It produces a negative ion — leftover negative ions are what mark acids.
ABS-012 · medium · application · seq 12 · seed:U11-G1/pool[35] (= ABS-012 gateItems[2]) — placed verbatim (spec-sourced Unicode) · text
A sulfide ion, S²⁻, accepts one H⁺. Write the formula of the particle that forms.
Answer: HS⁻ KEY
also accepted: HS-, SH⁻, SH-
wrongValueDiagnostics
[
{
"value": "H₂S",
"misconception": "you added two hydrogens — one accepted proton adds exactly one H, giving HS⁻",
"feedback": "This answer is wrong — you added two hydrogens — one accepted proton adds exactly one H, giving HS⁻"
},
{
"value": "HS²⁻",
"misconception": "you kept the 2− charge — adding the 1+ proton raises the charge from 2− to 1−",
"feedback": "This answer is wrong — you kept the 2− charge — adding the 1+ proton raises the charge from 2− to 1−"
},
{
"value": "HS",
"misconception": "you dropped the charge — the 2− plus the 1+ leaves 1−: HS⁻",
"feedback": "This answer is wrong — you dropped the charge — the 2− plus the 1+ leaves 1−: HS⁻"
}
]
feedback
{
"keyExplanation": "Accepting an H⁺ grows the formula by one H and raises the charge by one. S²⁻ + H⁺ → HS⁻: two minuses plus one plus leaves a single 1− charge.",
"anticipatedWrong": [
{
"value": "H₂S",
"misconception": "you added two hydrogens — one accepted proton adds exactly one H, giving HS⁻",
"feedback": "This answer is wrong — you added two hydrogens — one accepted proton adds exactly one H, giving HS⁻"
},
{
"value": "HS²⁻",
"misconception": "you kept the 2− charge — adding the 1+ proton raises the charge from 2− to 1−",
"feedback": "This answer is wrong — you kept the 2− charge — adding the 1+ proton raises the charge from 2− to 1−"
},
{
"value": "HS",
"misconception": "you dropped the charge — the 2− plus the 1+ leaves 1−: HS⁻",
"feedback": "This answer is wrong — you dropped the charge — the 2− plus the 1+ leaves 1−: HS⁻"
}
]
}
ABS-019 · medium · application · seq 15 · authored (row15 A): -ate -> -ic on a fresh ion family (chromium appears nowhere else on form A) · text
Name the acid H₂CrO₄, which contains the chromate ion, CrO₄²⁻.
Answer: chromic acid KEY
also accepted: chromic
wrongValueDiagnostics
[
{
"value": "chromous acid",
"misconception": "you reversed the suffix — -ate points to -ic: chromATE gives chromIC acid",
"feedback": "This answer is wrong — you reversed the suffix — -ate points to -ic: chromATE gives chromIC acid"
},
{
"value": "hydrochromic acid",
"misconception": "you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it",
"feedback": "This answer is wrong — you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it"
},
{
"value": "chromate acid",
"misconception": "you kept the ion's name — the -ate ending converts to -ic acid in the acid's name",
"feedback": "This answer is wrong — you kept the ion's name — the -ate ending converts to -ic acid in the acid's name"
}
]
feedback
{
"keyExplanation": "The ion's name ends in -ate, so the acid's name ends in -ic acid: chromate gives chromic acid. No hydro- prefix ever appears on an oxyacid's name.",
"anticipatedWrong": [
{
"value": "chromous acid",
"misconception": "you reversed the suffix — -ate points to -ic: chromATE gives chromIC acid",
"feedback": "This answer is wrong — you reversed the suffix — -ate points to -ic: chromATE gives chromIC acid"
},
{
"value": "hydrochromic acid",
"misconception": "you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it",
"feedback": "This answer is wrong — you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it"
},
{
"value": "chromate acid",
"misconception": "you kept the ion's name — the -ate ending converts to -ic acid in the acid's name",
"feedback": "This answer is wrong — you kept the ion's name — the -ate ending converts to -ic acid in the acid's name"
}
]
}
ABS-021 · medium · application · seq 16 · seed:U11-G1/pool[60] (= ABS-021 gateItems[0]) — placed verbatim (spec-sourced Unicode) · text
Milk of magnesia contains the base Mg(OH)₂. Name this base.
Answer: magnesium hydroxide KEY
wrongValueDiagnostics
[
{
"value": "magnesium dihydroxide",
"misconception": "you counted the hydroxides into the name — ionic names carry no counting prefixes",
"feedback": "This answer is wrong — you counted the hydroxides into the name — ionic names carry no counting prefixes"
},
{
"value": "manganese hydroxide",
"misconception": "you mixed up magnesium and manganese — Mg is magnesium",
"feedback": "This answer is wrong — you mixed up magnesium and manganese — Mg is magnesium"
},
{
"value": "magnesium(II) hydroxide",
"misconception": "you added a Roman numeral — magnesium forms only 2+, so no numeral is needed",
"feedback": "This answer is wrong — you added a Roman numeral — magnesium forms only 2+, so no numeral is needed"
}
]
feedback
{
"keyExplanation": "Metal: magnesium. Ion: hydroxide. Mg(OH)₂ is magnesium hydroxide — the subscript 2 plays no part in the name.",
"anticipatedWrong": [
{
"value": "magnesium dihydroxide",
"misconception": "you counted the hydroxides into the name — ionic names carry no counting prefixes",
"feedback": "This answer is wrong — you counted the hydroxides into the name — ionic names carry no counting prefixes"
},
{
"value": "manganese hydroxide",
"misconception": "you mixed up magnesium and manganese — Mg is magnesium",
"feedback": "This answer is wrong — you mixed up magnesium and manganese — Mg is magnesium"
},
{
"value": "magnesium(II) hydroxide",
"misconception": "you added a Roman numeral — magnesium forms only 2+, so no numeral is needed",
"feedback": "This answer is wrong — you added a Roman numeral — magnesium forms only 2+, so no numeral is needed"
}
]
}
ABS-015 · hard · transfer · seq 17 · seed:U11-G1/pool[43] (= ABS-015 gateItems[1]) — placed verbatim (spec-sourced Unicode) · mcq4
Do H₃O⁺ and OH⁻ form a conjugate acid-base pair?
No — their formulas differ by two H⁺, not exactly one. KEY
Yes — one is an acid and the other is a base.
Yes — both particles come from water.
No — ions can never form conjugate pairs.
ABS-017 · hard · transfer · seq 18 · seed:U11-G1/pool[48] (= ABS-017 gateItems[0]) — placed verbatim (spec-sourced Unicode) · mcq4
A student names HI 'iodic acid'. What went wrong?
The hydro- prefix is missing — 'iodic acid' names an oxygen-containing acid. KEY
The suffix is wrong — the name should end in -ous, giving iodous acid.
Nothing went wrong — iodic acid is the correct name for HI.
The root is wrong — the name should use the full word, iodine acid.
ABS-018 · hard · transfer · seq 19 · seed:U11-G1/pool[51] (= ABS-018 gateItems[0]) — placed verbatim (spec-sourced Unicode) · mcq4
A student writes hydrochloric acid as H₂Cl, copying the shape of H₂S. Which correction is right?
HCl — chloride is 1−, so a single H balances it. KEY
H₂Cl is correct — binary acids all carry two hydrogens.
HCl₂ — the 2 belongs on the chlorine, not the hydrogen.
H₂Cl₂ — both elements should take the subscript 2.
ABS-020 · hard · transfer · seq 20 · seed:U11-G1/pool[57] (= ABS-020 gateItems[0]) — placed verbatim (spec-sourced Unicode) · text
Write the formula of chloric acid. (The chlorate ion is ClO₃⁻.)
Answer: HClO₃ KEY
also accepted: HClO3
wrongValueDiagnostics
[
{
"value": "HClO₂",
"misconception": "you reversed -ic to the wrong ion — -ic acid points back to the -ATE ion, chlorate, ClO₃⁻",
"feedback": "This answer is wrong — you reversed -ic to the wrong ion — -ic acid points back to the -ATE ion, chlorate, ClO₃⁻"
},
{
"value": "H₂ClO₃",
"misconception": "you doubled the hydrogen — chlorate's 1− charge needs only one H",
"feedback": "This answer is wrong — you doubled the hydrogen — chlorate's 1− charge needs only one H"
},
{
"value": "HCl",
"misconception": "you dropped the oxygens — chloric acid is an oxyacid; HCl is hydrochloric, the binary acid",
"feedback": "This answer is wrong — you dropped the oxygens — chloric acid is an oxyacid; HCl is hydrochloric, the binary acid"
}
]
feedback
{
"keyExplanation": "-ic points back to the -ate ion: chlorate, ClO₃⁻. A 1− charge takes one H, so chloric acid is HClO₃.",
"anticipatedWrong": [
{
"value": "HClO₂",
"misconception": "you reversed -ic to the wrong ion — -ic acid points back to the -ATE ion, chlorate, ClO₃⁻",
"feedback": "This answer is wrong — you reversed -ic to the wrong ion — -ic acid points back to the -ATE ion, chlorate, ClO₃⁻"
},
{
"value": "H₂ClO₃",
"misconception": "you doubled the hydrogen — chlorate's 1− charge needs only one H",
"feedback": "This answer is wrong — you doubled the hydrogen — chlorate's 1− charge needs only one H"
},
{
"value": "HCl",
"misconception": "you dropped the oxygens — chloric acid is an oxyacid; HCl is hydrochloric, the binary acid",
"feedback": "This answer is wrong — you dropped the oxygens — chloric acid is an oxyacid; HCl is hydrochloric, the binary acid"
}
]
}
ABS-014 · medium · application · seq 21 · authored (row21 A): coverage cell = B-L-only base (pool 39/40's cell) on a fresh OH-free anion | POLISH: rubric/model/diagnostics rewritten formula-free (V-T12); the ion's NAME dropped from the stem (breaks the ABS-019 corpus gram); charge-digit numeric fires remain a stage-3 triage family · frq
The polyatomic ion PO₄³⁻ contains no OH unit. In solution it is seen accepting an H⁺ from an acid particle, forming HPO₄²⁻. Plain-text formulas are accepted in your answer.
The polyatomic ion PO₄³⁻ contains no OH unit. In solution it is seen accepting an H⁺ from an acid particle, forming HPO₄²⁻. Plain-text formulas are accepted in your answer.
(a) Is this ion a base under the Arrhenius definition? Justify your verdict from that definition's criterion.
(b) Is this ion a base under the Brønsted-Lowry definition? Justify your verdict from that definition's criterion.
(c) In one sentence, state what this case shows about how the two base definitions are related.
Part a. Is this ion a base under the Arrhenius definition? Justify your verdict from that definition's criterion.
Model: No. An Arrhenius base is a substance that releases hydroxide ions when it dissolves in water. This ion contains no hydroxide unit, so it has none to release, and the Arrhenius definition cannot classify it as a base.
Part b. Is this ion a base under the Brønsted-Lowry definition? Justify your verdict from that definition's criterion.
Model: Yes. A Brønsted-Lowry base is a particle that accepts a hydrogen ion, and the described event shows the ion doing exactly that — it accepts one hydrogen ion and becomes the new particle shown in the stem.
Part c. In one sentence, state what this case shows about how the two base definitions are related.
Model: The case shows that the Brønsted-Lowry definition extends the Arrhenius definition — it keeps everything Arrhenius covers and adds the bases that contain no hydroxide, like this ion.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
Full model answer. (a) No. An Arrhenius base is a substance that releases hydroxide ions when it dissolves in water. This ion contains no hydroxide unit, so it has none to release, and the Arrhenius definition cannot classify it as a base.
(b) Yes. A Brønsted-Lowry base is a particle that accepts a hydrogen ion, and the described event shows the ion doing exactly that — it accepts one hydrogen ion and becomes the new particle shown in the stem.
(c) The case shows that the Brønsted-Lowry definition extends the Arrhenius definition — it keeps everything Arrhenius covers and adds the bases that contain no hydroxide, like this ion.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
A cook tastes a sauce and reports a sharp, sour flavor. According to the acid property profile, what does the sour taste point to in the sauce?
An ingredient that contains an acid KEY
An ingredient that contains a reactive metal
An ingredient that contains litmus dye
Nothing — taste reveals nothing about a food's chemistry
ABS-002 · easy · recall · seq 2 · seed:U11-G1/pool[4] (= ABS-002 gateItems[1]) — FRESHENED: 'Tonic water' -> 'A bitter herbal tonic' — 'water' = ABS-002 own-corpus material word (SEED RULING); structure, options, and misconception classes kept · mcq4
A bitter herbal tonic gets its sharply bitter flavor from dissolved quinine. According to the property profiles, which family of substances does quinine belong to?
The bases — bitterness in foods and drinks is the base taste. KEY
The acids — bitterness in foods and drinks is the acid taste.
Neither family — taste appears in neither property profile.
Both families — every dissolved substance is both an acid and a base.
ABS-004 · easy · recall · seq 3 · seed:U11-G1/pool[11] (= ABS-004 gateItems[2]) — STAGE-4 REWORK (blind F2): the seed's fertilizer anchor is real-world ambiguous (phosphate-fertilizer plants consume sulfuric acid at scale), so the item now tests the roster's car-battery mapping (uniquely taught AND uniquely true); same four-option roster design; deviation flagged for James · mcq4
Car batteries are filled with one of the four common acids. Which one?
Sulfuric acid, H₂SO₄ KEY
Hydrochloric acid, HCl
Nitric acid, HNO₃
Acetic acid, CH₃COOH
ABS-005 · easy · recall · seq 4 · authored (row04 B): roster name->formula production | POLISH: stem reworded to break the ABS-005 fluency gram (chemical-formula-of-sodium); 'sodium' itself = roster expected-fire family, stage-3 adjudication · text
A drain-cleaner label lists sodium hydroxide as its active ingredient. Write the formula of this base.
Answer: NaOH KEY
wrongValueDiagnostics
[
{
"value": "Na(OH)₂",
"misconception": "you gave sodium a 2+ charge — Na⁺ is 1+, so one OH⁻ balances it: NaOH",
"feedback": "This answer is wrong — you gave sodium a 2+ charge — Na⁺ is 1+, so one OH⁻ balances it: NaOH"
},
{
"value": "NaO",
"misconception": "you dropped the hydrogen — the hydroxide unit is OH, so the formula is NaOH",
"feedback": "This answer is wrong — you dropped the hydrogen — the hydroxide unit is OH, so the formula is NaOH"
},
{
"value": "NaOH₂",
"misconception": "you doubled the hydrogen — one OH unit carries one H: NaOH",
"feedback": "This answer is wrong — you doubled the hydrogen — one OH unit carries one H: NaOH"
}
]
feedback
{
"keyExplanation": "Sodium hydroxide is NaOH — one Na⁺ balanced by one OH⁻. It is the drain-cleaner base on the roster.",
"anticipatedWrong": [
{
"value": "Na(OH)₂",
"misconception": "you gave sodium a 2+ charge — Na⁺ is 1+, so one OH⁻ balances it: NaOH",
"feedback": "This answer is wrong — you gave sodium a 2+ charge — Na⁺ is 1+, so one OH⁻ balances it: NaOH"
},
{
"value": "NaO",
"misconception": "you dropped the hydrogen — the hydroxide unit is OH, so the formula is NaOH",
"feedback": "This answer is wrong — you dropped the hydrogen — the hydroxide unit is OH, so the formula is NaOH"
},
{
"value": "NaOH₂",
"misconception": "you doubled the hydrogen — one OH unit carries one H: NaOH",
"feedback": "This answer is wrong — you doubled the hydrogen — one OH unit carries one H: NaOH"
}
]
}
Four bottles are labeled with the formulas below. Using the formula patterns and their memorized exceptions, which bottle holds a substance that is neither an acid nor a base?
Which event shows a particle acting as a Brønsted-Lowry acid?
An HBr particle hands its H⁺ to a water molecule beside it. KEY
A water molecule gains an H⁺ and becomes H₃O⁺.
A Cl⁻ ion drifts through the solution unchanged.
An Na⁺ ion is surrounded by water molecules as it dissolves.
ABS-012 · medium · application · seq 12 · authored (row12 B): acceptor arithmetic on a fresh 2− ion · text
A selenide ion, Se²⁻, accepts one H⁺. Write the formula of the particle that forms.
Answer: HSe⁻ KEY
also accepted: HSe-, SeH⁻, SeH-
wrongValueDiagnostics
[
{
"value": "H₂Se",
"misconception": "you added two hydrogens — accepting ONE H⁺ adds exactly one H: HSe⁻",
"feedback": "This answer is wrong — you added two hydrogens — accepting ONE H⁺ adds exactly one H: HSe⁻"
},
{
"value": "HSe²⁻",
"misconception": "you added the H but kept the charge — gaining an H⁺ raises the charge by one, from 2− to 1−",
"feedback": "This answer is wrong — you added the H but kept the charge — gaining an H⁺ raises the charge by one, from 2− to 1−"
},
{
"value": "Se⁻",
"misconception": "you raised the charge without adding the H — the formula grows by one H: HSe⁻",
"feedback": "This answer is wrong — you raised the charge without adding the H — the formula grows by one H: HSe⁻"
}
]
feedback
{
"keyExplanation": "Accepting an H⁺ grows the formula by one H and raises the charge by one: Se²⁻ (2−) becomes HSe⁻ (1−).",
"anticipatedWrong": [
{
"value": "H₂Se",
"misconception": "you added two hydrogens — accepting ONE H⁺ adds exactly one H: HSe⁻",
"feedback": "This answer is wrong — you added two hydrogens — accepting ONE H⁺ adds exactly one H: HSe⁻"
},
{
"value": "HSe²⁻",
"misconception": "you added the H but kept the charge — gaining an H⁺ raises the charge by one, from 2− to 1−",
"feedback": "This answer is wrong — you added the H but kept the charge — gaining an H⁺ raises the charge by one, from 2− to 1−"
},
{
"value": "Se⁻",
"misconception": "you raised the charge without adding the H — the formula grows by one H: HSe⁻",
"feedback": "This answer is wrong — you raised the charge without adding the H — the formula grows by one H: HSe⁻"
}
]
}
A brick-cleaning solution contains dissolved HCl. Classify HCl.
A binary acid KEY
An oxyacid
A base
Neither an acid nor a base
ABS-019 · medium · application · seq 15 · seed:U11-G1/pool[54] (= ABS-019 gateItems[0]) — placed verbatim (spec-sourced Unicode) · text
Name the acid HClO₂, which contains the chlorite ion, ClO₂⁻.
Answer: chlorous acid KEY
also accepted: chlorous
wrongValueDiagnostics
[
{
"value": "chloric acid",
"misconception": "you used the -ate rule — chlorITE takes -ous acid",
"feedback": "This answer is wrong — you used the -ate rule — chlorITE takes -ous acid"
},
{
"value": "hydrochlorous acid",
"misconception": "you added hydro- — that prefix belongs to binary acids only",
"feedback": "This answer is wrong — you added hydro- — that prefix belongs to binary acids only"
},
{
"value": "chlorite acid",
"misconception": "you left the ion's name unchanged — the -ite ending must switch to -ous",
"feedback": "This answer is wrong — you left the ion's name unchanged — the -ite ending must switch to -ous"
}
]
feedback
{
"keyExplanation": "The ion is chlorite, ending in -ite, and -ite becomes -ous acid: chlorite → chlorous. HClO₂ is chlorous acid.",
"anticipatedWrong": [
{
"value": "chloric acid",
"misconception": "you used the -ate rule — chlorITE takes -ous acid",
"feedback": "This answer is wrong — you used the -ate rule — chlorITE takes -ous acid"
},
{
"value": "hydrochlorous acid",
"misconception": "you added hydro- — that prefix belongs to binary acids only",
"feedback": "This answer is wrong — you added hydro- — that prefix belongs to binary acids only"
},
{
"value": "chlorite acid",
"misconception": "you left the ion's name unchanged — the -ite ending must switch to -ous",
"feedback": "This answer is wrong — you left the ion's name unchanged — the -ite ending must switch to -ous"
}
]
}
ABS-021 · medium · application · seq 16 · authored (row16 B): metal + hydroxide on a fresh fixed-charge metal · text
Name the base RbOH.
Answer: rubidium hydroxide KEY
wrongValueDiagnostics
[
{
"value": "rubidium oxide",
"misconception": "you dropped the hydrogen — the ion is hydroxide, OH⁻: rubidium hydroxide",
"feedback": "This answer is wrong — you dropped the hydrogen — the ion is hydroxide, OH⁻: rubidium hydroxide"
},
{
"value": "rubidium hydride",
"misconception": "you named the wrong ion — OH⁻ is hydroxide; hydride is the ion H⁻",
"feedback": "This answer is wrong — you named the wrong ion — OH⁻ is hydroxide; hydride is the ion H⁻"
},
{
"value": "hydrorubidic acid",
"misconception": "you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide",
"feedback": "This answer is wrong — you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide"
}
]
feedback
{
"keyExplanation": "A metal hydroxide takes its ordinary ionic name: metal name + hydroxide. RbOH is rubidium hydroxide.",
"anticipatedWrong": [
{
"value": "rubidium oxide",
"misconception": "you dropped the hydrogen — the ion is hydroxide, OH⁻: rubidium hydroxide",
"feedback": "This answer is wrong — you dropped the hydrogen — the ion is hydroxide, OH⁻: rubidium hydroxide"
},
{
"value": "rubidium hydride",
"misconception": "you named the wrong ion — OH⁻ is hydroxide; hydride is the ion H⁻",
"feedback": "This answer is wrong — you named the wrong ion — OH⁻ is hydroxide; hydride is the ion H⁻"
},
{
"value": "hydrorubidic acid",
"misconception": "you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide",
"feedback": "This answer is wrong — you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide"
}
]
}
ABS-015 · hard · transfer · seq 17 · authored (row17 B): both-pairs identification on a fresh supplied equation (mirrors the pool-42 structure) · mcq4
In the equation HCO₃⁻ + H₂O ⇌ H₂CO₃ + OH⁻, which option lists both conjugate acid-base pairs?
H₂CO₃/HCO₃⁻ and H₂O/OH⁻ KEY
HCO₃⁻/H₂O and H₂CO₃/OH⁻
HCO₃⁻/OH⁻ and H₂CO₃/H₂O
H₂O/OH⁻ only — this equation has a single pair
ABS-017 · hard · transfer · seq 18 · seed:U11-G1/pool[50] (= ABS-017 gateItems[2]) — placed verbatim (spec-sourced Unicode) · mcq4
H₂S is named hydrosulfuric acid, but H₂SO₄ is named sulfuric acid, with no hydro-. Why does the prefix appear on one name and not the other?
hydro- marks a binary acid — H₂S has no oxygen, while H₂SO₄ does. KEY
hydro- marks acids with two hydrogens, so the two names are inconsistent.
hydro- is optional, and either acid may take it or leave it.
hydro- marks acids that dissolve in water, and H₂SO₄ does not dissolve.
ABS-018 · hard · transfer · seq 19 · seed:U11-G1/pool[52] (= ABS-018 gateItems[1]) — placed verbatim (spec-sourced Unicode) · mcq4
Which row pairs each name with its correct formula? (fluoride is F⁻; iodide is I⁻)
hydrofluoric acid — HF; hydroiodic acid — HI KEY
hydrofluoric acid — H₂F; hydroiodic acid — H₂I
hydrofluoric acid — HFO; hydroiodic acid — HIO
hydrofluoric acid — HI; hydroiodic acid — HF
ABS-020 · hard · transfer · seq 20 · authored (row20 B, stage-3 rework): -ous reversal + 2− H-count (tellurous; phosphite/33 freed to E#15's naming slot) · text
Write the formula of tellurous acid. (The tellurite ion is TeO₃²⁻.)
Answer: H₂TeO₃ KEY
also accepted: H2TeO3
wrongValueDiagnostics
[
{
"value": "H₂TeO₄",
"misconception": "you reversed -ous to the wrong ion — -ous acid points back to the -ITE ion, tellurite, TeO₃²⁻; TeO₄²⁻ is tellurate",
"feedback": "This answer is wrong — you reversed -ous to the wrong ion — -ous acid points back to the -ITE ion, tellurite, TeO₃²⁻; TeO₄²⁻ is tellurate"
},
{
"value": "HTeO₃",
"misconception": "you added a single H — tellurite's 2− charge takes two",
"feedback": "This answer is wrong — you added a single H — tellurite's 2− charge takes two"
},
{
"value": "H₃TeO₃",
"misconception": "you overshot the H count — match it to the charge number, 2",
"feedback": "This answer is wrong — you overshot the H count — match it to the charge number, 2"
}
]
feedback
{
"keyExplanation": "-ous points back to the -ite ion: tellurite, TeO₃²⁻. A 2− charge takes two H, so tellurous acid is H₂TeO₃.",
"anticipatedWrong": [
{
"value": "H₂TeO₄",
"misconception": "you reversed -ous to the wrong ion — -ous acid points back to the -ITE ion, tellurite, TeO₃²⁻; TeO₄²⁻ is tellurate",
"feedback": "This answer is wrong — you reversed -ous to the wrong ion — -ous acid points back to the -ITE ion, tellurite, TeO₃²⁻; TeO₄²⁻ is tellurate"
},
{
"value": "HTeO₃",
"misconception": "you added a single H — tellurite's 2− charge takes two",
"feedback": "This answer is wrong — you added a single H — tellurite's 2− charge takes two"
},
{
"value": "H₃TeO₃",
"misconception": "you overshot the H count — match it to the charge number, 2",
"feedback": "This answer is wrong — you overshot the H count — match it to the charge number, 2"
}
]
}
ABS-014 · medium · application · seq 21 · authored (row21 B): coverage cell = acids-never-disagree (pool 41's cell), instance-free so no acid family leaves its home | POLISH: formula-free per V-T12; hydronium named in words · frq
Acid Y is dissolved in water, where it releases hydrogen ions. A classmate claims: 'Y counts as an acid under the Arrhenius definition, but the Brønsted-Lowry definition might still refuse to classify Y as an acid.' Plain-text formulas are accepted in your answer.
Acid Y is dissolved in water, where it releases hydrogen ions. A classmate claims: 'Y counts as an acid under the Arrhenius definition, but the Brønsted-Lowry definition might still refuse to classify Y as an acid.' Plain-text formulas are accepted in your answer.
(a) Classify Y under the Arrhenius definition, citing that definition's criterion.
(b) Evaluate the classmate's claim: can the Brønsted-Lowry definition refuse? Justify from what releasing hydrogen ions into water actually involves.
(c) In one sentence, state the general relationship this shows between the two ACID definitions.
Part a. Classify Y under the Arrhenius definition, citing that definition's criterion.
Model: Y is an Arrhenius acid: the Arrhenius definition classifies as an acid any substance that releases hydrogen ions when it dissolves in water, and that is exactly what Y does.
Part b. Evaluate the classmate's claim: can the Brønsted-Lowry definition refuse? Justify from what releasing hydrogen ions into water actually involves.
Model: The claim is wrong — the Brønsted-Lowry definition cannot refuse. Releasing hydrogen ions into water is not a separate event from donation: each released hydrogen ion is handed to a water molecule, forming the hydronium ion, and donating a hydrogen ion to another particle is precisely the Brønsted-Lowry acid criterion. So any substance that qualifies under Arrhenius automatically qualifies under Brønsted-Lowry.
Part c. In one sentence, state the general relationship this shows between the two ACID definitions.
Model: Every Arrhenius acid is also a Brønsted-Lowry acid — the two definitions never part company over acids, only over bases.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
Full model answer. (a) Y is an Arrhenius acid: the Arrhenius definition classifies as an acid any substance that releases hydrogen ions when it dissolves in water, and that is exactly what Y does.
(b) The claim is wrong — the Brønsted-Lowry definition cannot refuse. Releasing hydrogen ions into water is not a separate event from donation: each released hydrogen ion is handed to a water molecule, forming the hydronium ion, and donating a hydrogen ion to another particle is precisely the Brønsted-Lowry acid criterion. So any substance that qualifies under Arrhenius automatically qualifies under Brønsted-Lowry.
(c) Every Arrhenius acid is also a Brønsted-Lowry acid — the two definitions never part company over acids, only over bases.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
Form C
ABS-001 · easy · recall · seq 1 · authored (row01 C): litmus-line read on an instance-free unknown; foil classes = direction swap / unconditional dye / no-signal · mcq4
A clear solution in an unlabeled beaker turns blue litmus paper red. According to the acid property profile, what does this observation show?
The solution contains an acid. KEY
The solution contains a base.
Nothing — litmus paper changes color in any liquid.
While mopping, a cleaner notices that the diluted floor-cleaning solution feels slippery through rubber gloves. Which family does the base property profile place the dissolved cleaner in?
The bases — a slippery feel in solution is a base property. KEY
The acids — a slippery feel in solution is an acid property.
Neither family — feel appears in neither property profile.
Both families — every cleaning product contains both an acid and a base.
ABS-004 · easy · recall · seq 3 · authored (row03 C): use->name over the taught roster (repeat-back contract); options kept NAME-ONLY so form C never shows a name-formula pairing before seq 19 · mcq4
Salad vinegar owes its sharp sourness to one of the four common acids. Which one?
Acetic acid KEY
Hydrochloric acid
Sulfuric acid
Nitric acid
ABS-005 · easy · recall · seq 4 · authored (row04 C): roster name->formula production · text
Write the chemical formula of potassium hydroxide.
Answer: KOH KEY
wrongValueDiagnostics
[
{
"value": "K(OH)₂",
"misconception": "you gave potassium a 2+ charge — K⁺ is 1+, so one OH⁻ balances it: KOH",
"feedback": "This answer is wrong — you gave potassium a 2+ charge — K⁺ is 1+, so one OH⁻ balances it: KOH"
},
{
"value": "KH",
"misconception": "you dropped the oxygen — the hydroxide unit is OH: KOH",
"feedback": "This answer is wrong — you dropped the oxygen — the hydroxide unit is OH: KOH"
},
{
"value": "NaOH",
"misconception": "you wrote the sodium base — potassium hydroxide starts from potassium: KOH",
"feedback": "This answer is wrong — you wrote the sodium base — potassium hydroxide starts from potassium: KOH"
}
]
feedback
{
"keyExplanation": "Potassium hydroxide is KOH — one K⁺ balanced by one OH⁻. It is the base used to make liquid soaps.",
"anticipatedWrong": [
{
"value": "K(OH)₂",
"misconception": "you gave potassium a 2+ charge — K⁺ is 1+, so one OH⁻ balances it: KOH",
"feedback": "This answer is wrong — you gave potassium a 2+ charge — K⁺ is 1+, so one OH⁻ balances it: KOH"
},
{
"value": "KH",
"misconception": "you dropped the oxygen — the hydroxide unit is OH: KOH",
"feedback": "This answer is wrong — you dropped the oxygen — the hydroxide unit is OH: KOH"
},
{
"value": "NaOH",
"misconception": "you wrote the sodium base — potassium hydroxide starts from potassium: KOH",
"feedback": "This answer is wrong — you wrote the sodium base — potassium hydroxide starts from potassium: KOH"
}
]
}
A concrete cleaner is poured onto a piece of reactive metal, and hydrogen gas fizzes off the metal. No litmus paper is available. Can the cleaner be classified?
Yes — hydrogen from a reactive metal is an acid observation, so the cleaner is an acid. KEY
No — a classification cannot be made until a litmus result is available.
Yes — the streaming bubbles of gas show that the cleaner is a base.
No — gas bubbles could come from anything at all, so the observation reveals nothing.
ABS-006 · medium · application · seq 6 · authored (row06 C): the NH₃ exception as a correction task (expected-fire class c — the exception IS the content) | POLISH: key trimmed + gram break (the-two-memorized-exceptions); distractors lengthened for V-T4 balance · mcq4
A student classifies NH₃ as 'neither an acid nor a base' because its formula does not end in OH. Which correction is right?
NH₃ is a memorized exception — the base ammonia, despite not ending in OH. KEY
The student is right — a formula that does not end in OH can never belong to a base.
NH₃ is actually an acid — there are hydrogen atoms inside its formula.
NH₃ cannot be classified either way until a litmus test is run on its solution.
ABS-007 · medium · application · seq 7 · authored (row07 C): the A-seed's shared-source structure rotated onto the litmus line with unnamed acids (instance-free) | POLISH: stem/key reworded to break ABS-007/ABS-010 corpus grams (turn-blue-litmus-paper / h-in-water-and); shared-source content unchanged · mcq4
Strips of blue litmus turn red in three different acid solutions. Which statement explains the identical response?
Each acid releases the same ion — H⁺ — and that shared ion produces the shared properties. KEY
The three acids must contain exactly the same elements in the same amounts.
The color change is triggered by each acid's negative ion, and those ions all affect litmus the same way.
It is pure coincidence — different acids simply happen to affect litmus alike.
ABS-008 · medium · application · seq 8 · authored (row08 C): the A seed's release-set task on a fresh Group-2 hydroxide (other-lesson WARN recorded in row notes) · mcq4
Solid Sr(OH)₂ dissolves fully in a beaker of water. What ions does one formula unit release?
A substance is known to be an Arrhenius base. Which dissolving behavior could be its behavior in water?
LiOH → Li⁺ + OH⁻ KEY
HCl → H⁺ + Cl⁻
KI → K⁺ + I⁻
CH₃OH — dissolves in water without splitting into any ions
ABS-010 · medium · application · seq 10 · authored (row10 C): the A seed's two-notations task on a fresh fully-ionizing acid · mcq4
One book writes the dissolving of HBrO₃ as HBrO₃ → H⁺ + BrO₃⁻. Another writes HBrO₃ + H₂O → H₃O⁺ + BrO₃⁻. How are the two versions related?
The same dissolving event written two ways — a shorthand, and an honest picture of the H⁺ carried by water. KEY
Two different reactions — HBrO₃ reacts one way in some books and the other way in others.
The first is wrong — a bare H⁺ must never be written.
The second is wrong — water never appears in a dissolving equation.
ABS-011 · medium · application · seq 11 · authored (row11 C): instance-free donor identification with the roster-dependency misconception · mcq4
During a reaction in solution, particle X hands an H⁺ to particle Y. Which statement correctly identifies the Brønsted-Lowry acid?
X is the acid — in that moment it is the proton donor. KEY
Y is the acid — it ends up holding more hydrogen.
Both X and Y are acids — both take part in the transfer.
Neither is an acid unless X appears on the common-acids roster.
ABS-012 · medium · application · seq 12 · authored (row12 C): acceptor arithmetic, 1− to neutral (nitrite WARN recorded in row notes) · text
A nitrite ion, NO₂⁻, accepts one H⁺. Write the formula of the particle that forms.
Answer: HNO₂ KEY
also accepted: HNO2
wrongValueDiagnostics
[
{
"value": "H₂NO₂",
"misconception": "you added two hydrogens — one H⁺ adds exactly one H: HNO₂",
"feedback": "This answer is wrong — you added two hydrogens — one H⁺ adds exactly one H: HNO₂"
},
{
"value": "HNO₂⁻",
"misconception": "you kept the 1− charge — gaining an H⁺ raises it by one, to neutral: HNO₂",
"feedback": "This answer is wrong — you kept the 1− charge — gaining an H⁺ raises it by one, to neutral: HNO₂"
},
{
"value": "NO₃⁻",
"misconception": "you added an oxygen instead of a hydrogen — accepting H⁺ changes the H count, not the O count",
"feedback": "This answer is wrong — you added an oxygen instead of a hydrogen — accepting H⁺ changes the H count, not the O count"
}
]
feedback
{
"keyExplanation": "Accepting an H⁺ grows the formula by one H and raises the charge by one: NO₂⁻ (1−) becomes the neutral particle HNO₂.",
"anticipatedWrong": [
{
"value": "H₂NO₂",
"misconception": "you added two hydrogens — one H⁺ adds exactly one H: HNO₂",
"feedback": "This answer is wrong — you added two hydrogens — one H⁺ adds exactly one H: HNO₂"
},
{
"value": "HNO₂⁻",
"misconception": "you kept the 1− charge — gaining an H⁺ raises it by one, to neutral: HNO₂",
"feedback": "This answer is wrong — you kept the 1− charge — gaining an H⁺ raises it by one, to neutral: HNO₂"
},
{
"value": "NO₃⁻",
"misconception": "you added an oxygen instead of a hydrogen — accepting H⁺ changes the H count, not the O count",
"feedback": "This answer is wrong — you added an oxygen instead of a hydrogen — accepting H⁺ changes the H count, not the O count"
}
]
}
A student says H₂Se must be an oxyacid because its formula has two hydrogens, like H₂SO₄. Which correction is right?
H₂Se is a binary acid — the family splits on oxygen, and H₂Se contains none. KEY
The student is right — any acid with two hydrogens counts as an oxyacid.
H₂Se is an oxyacid, but only because selenium resembles oxygen.
H₂Se cannot be classified without observing how it behaves.
ABS-019 · medium · application · seq 15 · authored (row15 C): -ate -> -ic on a fresh ion family (boron appears nowhere else on form C) · text
Name the acid H₃BO₃, which contains the borate ion, BO₃³⁻.
Answer: boric acid KEY
also accepted: boric
wrongValueDiagnostics
[
{
"value": "borous acid",
"misconception": "you reversed the suffix — -ate points to -ic: borATE gives borIC acid",
"feedback": "This answer is wrong — you reversed the suffix — -ate points to -ic: borATE gives borIC acid"
},
{
"value": "hydroboric acid",
"misconception": "you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it",
"feedback": "This answer is wrong — you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it"
},
{
"value": "triboric acid",
"misconception": "you counted the hydrogens into the name — subscripts play no part in an oxyacid's name",
"feedback": "This answer is wrong — you counted the hydrogens into the name — subscripts play no part in an oxyacid's name"
}
]
feedback
{
"keyExplanation": "The ion's name ends in -ate, so the acid's name ends in -ic acid: borate gives boric acid. The hydrogen count plays no part in the name.",
"anticipatedWrong": [
{
"value": "borous acid",
"misconception": "you reversed the suffix — -ate points to -ic: borATE gives borIC acid",
"feedback": "This answer is wrong — you reversed the suffix — -ate points to -ic: borATE gives borIC acid"
},
{
"value": "hydroboric acid",
"misconception": "you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it",
"feedback": "This answer is wrong — you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it"
},
{
"value": "triboric acid",
"misconception": "you counted the hydrogens into the name — subscripts play no part in an oxyacid's name",
"feedback": "This answer is wrong — you counted the hydrogens into the name — subscripts play no part in an oxyacid's name"
}
]
}
ABS-021 · medium · application · seq 16 · authored (row16 C): metal + hydroxide on a fresh fixed-charge metal · text
Name the base CsOH.
Answer: cesium hydroxide KEY
also accepted: caesium hydroxide
wrongValueDiagnostics
[
{
"value": "cesium oxide",
"misconception": "you dropped the hydrogen — the ion is hydroxide, OH⁻: cesium hydroxide",
"feedback": "This answer is wrong — you dropped the hydrogen — the ion is hydroxide, OH⁻: cesium hydroxide"
},
{
"value": "cesium hydride",
"misconception": "you named the wrong ion — OH⁻ is hydroxide; hydride is the ion H⁻",
"feedback": "This answer is wrong — you named the wrong ion — OH⁻ is hydroxide; hydride is the ion H⁻"
},
{
"value": "hydrocesic acid",
"misconception": "you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide",
"feedback": "This answer is wrong — you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide"
}
]
feedback
{
"keyExplanation": "A metal hydroxide takes its ordinary ionic name: metal name + hydroxide. CsOH is cesium hydroxide.",
"anticipatedWrong": [
{
"value": "cesium oxide",
"misconception": "you dropped the hydrogen — the ion is hydroxide, OH⁻: cesium hydroxide",
"feedback": "This answer is wrong — you dropped the hydrogen — the ion is hydroxide, OH⁻: cesium hydroxide"
},
{
"value": "cesium hydride",
"misconception": "you named the wrong ion — OH⁻ is hydroxide; hydride is the ion H⁻",
"feedback": "This answer is wrong — you named the wrong ion — OH⁻ is hydroxide; hydride is the ion H⁻"
},
{
"value": "hydrocesic acid",
"misconception": "you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide",
"feedback": "This answer is wrong — you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide"
}
]
}
ABS-015 · hard · transfer · seq 17 · seed:U11-G1/pool[44] (= ABS-015 gateItems[2]) — placed verbatim (spec-sourced Unicode) · mcq4
The sulfate ion has the formula SO₄²⁻. Which particle is its conjugate acid?
HSO₄⁻ KEY
H₂SO₄
HSO₄²⁻
SO₄⁻
ABS-017 · hard · transfer · seq 18 · seed:U11-G1/pool[49] (= ABS-017 gateItems[1]) — FRESHENED: roster membership H₂S -> HI (stage-1 de-cue adjudication: H₂S = C#19's formula-pair key); error classes kept verbatim in structure · mcq4
Which row pairs each formula with its correct name?
HF — hydrofluoric acid; HI — hydroiodic acid KEY
HF — fluoric acid; HI — iodic acid
HF — hydrofluorous acid; HI — hydroiodous acid
HF — hydrofluoric acid; HI — hydroiodide acid
ABS-018 · hard · transfer · seq 19 · seed:U11-G1/pool[53] (= ABS-018 gateItems[2]) — placed verbatim (spec-sourced Unicode) · mcq4
Sulfuric acid and hydrosulfuric acid are different substances. Which formula pair is correct?
ABS-020 · hard · transfer · seq 20 · authored (row20 C): -ic direction + 3− H-count on a fresh family (FLAGGED for David: arsenic-acid register) · text
Write the formula of arsenic acid. (The arsenate ion is AsO₄³⁻.)
Answer: H₃AsO₄ KEY
also accepted: H3AsO4
wrongValueDiagnostics
[
{
"value": "H₃AsO₃",
"misconception": "you swapped in the -ite ion — -ic acid points back to arsenATE, AsO₄³⁻",
"feedback": "This answer is wrong — you swapped in the -ite ion — -ic acid points back to arsenATE, AsO₄³⁻"
},
{
"value": "HAsO₄",
"misconception": "you added a single H — arsenate's 3− charge takes three",
"feedback": "This answer is wrong — you added a single H — arsenate's 3− charge takes three"
},
{
"value": "H₂AsO₄",
"misconception": "you stopped at two hydrogens — match the H count to the charge number, 3",
"feedback": "This answer is wrong — you stopped at two hydrogens — match the H count to the charge number, 3"
}
]
feedback
{
"keyExplanation": "-ic points back to the -ate ion: arsenate, AsO₄³⁻. A 3− charge takes three H, so arsenic acid is H₃AsO₄.",
"anticipatedWrong": [
{
"value": "H₃AsO₃",
"misconception": "you swapped in the -ite ion — -ic acid points back to arsenATE, AsO₄³⁻",
"feedback": "This answer is wrong — you swapped in the -ite ion — -ic acid points back to arsenATE, AsO₄³⁻"
},
{
"value": "HAsO₄",
"misconception": "you added a single H — arsenate's 3− charge takes three",
"feedback": "This answer is wrong — you added a single H — arsenate's 3− charge takes three"
},
{
"value": "H₂AsO₄",
"misconception": "you stopped at two hydrogens — match the H count to the charge number, 3",
"feedback": "This answer is wrong — you stopped at two hydrogens — match the H count to the charge number, 3"
}
]
}
ABS-014 · medium · application · seq 21 · authored (row21 C): coverage cell = neither-under-either on a fresh salt (the pool-25/26 'neither' class raised to production) | POLISH: formula-free per V-T12; stem reworded ('is dissolved in water; the equation is' — breaks the ABS-007-class dissolves-in-water gram); ASCII equation removed (V-T10) · frq
A sample of potassium nitrate, KNO₃, is stirred into water and dissolves; the equation is KNO₃ → K⁺ + NO₃⁻. In this solution, neither released ion donates or accepts an H⁺. Plain-text formulas are accepted in your answer.
A sample of potassium nitrate, KNO₃, is stirred into water and dissolves; the equation is KNO₃ → K⁺ + NO₃⁻. In this solution, neither released ion donates or accepts an H⁺. Plain-text formulas are accepted in your answer.
(a) Classify potassium nitrate under the Arrhenius definitions of acid and base, citing the criteria you used.
(b) In the behavior described, does the Brønsted-Lowry definition assign either released ion an acid or base role? Justify.
(c) In one sentence: what must a substance or particle actually DO, under either definition, to earn the label acid or base?
Part a. Classify potassium nitrate under the Arrhenius definitions of acid and base, citing the criteria you used.
Model: Potassium nitrate is neither an Arrhenius acid nor an Arrhenius base. The Arrhenius definitions classify by released ions: an acid releases hydrogen ions and a base releases hydroxide ions. This salt releases the potassium ion and the nitrate ion — neither marker ion appears.
Part b. In the behavior described, does the Brønsted-Lowry definition assign either released ion an acid or base role? Justify.
Model: No. The Brønsted-Lowry definition assigns roles from proton-transfer events: a particle acts as an acid when it donates a hydrogen ion and as a base when it accepts one. In the behavior described, neither released ion donates or accepts a hydrogen ion, so neither earns a role in this solution.
Part c. In one sentence: what must a substance or particle actually DO, under either definition, to earn the label acid or base?
Model: Under either definition a label must be earned by what the substance or particle does — releasing a hydrogen or hydroxide ion into water, or donating or accepting a hydrogen ion — never by dissolving, looks, or letters in the formula.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
Full model answer. (a) Potassium nitrate is neither an Arrhenius acid nor an Arrhenius base. The Arrhenius definitions classify by released ions: an acid releases hydrogen ions and a base releases hydroxide ions. This salt releases the potassium ion and the nitrate ion — neither marker ion appears.
(b) No. The Brønsted-Lowry definition assigns roles from proton-transfer events: a particle acts as an acid when it donates a hydrogen ion and as a base when it accepts one. In the behavior described, neither released ion donates or accepts a hydrogen ion, so neither earns a role in this solution.
(c) Under either definition a label must be earned by what the substance or particle does — releasing a hydrogen or hydroxide ion into water, or donating or accepting a hydrogen ion — never by dissolving, looks, or letters in the formula.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
Form D
ABS-001 · easy · recall · seq 1 · authored (row01 D): taste-line read on a fresh everyday food; foil classes carried from the pool-1 seed · mcq4
A spoonful of plain yogurt tastes distinctly sour. According to the acid property profile, what does the sour taste point to?
The yogurt contains an acid. KEY
The yogurt contains a reactive metal.
The yogurt contains a base.
Nothing — taste reveals nothing about a food's chemistry.
ABS-002 · easy · recall · seq 2 · authored (row02 D): litmus-line read, base direction, fresh household instance | POLISH: stem reworded to break the ABS-002 corpus gram (lands-on-red-litmus) · mcq4
A technician dabs a drop of laundry-detergent solution onto red litmus paper, and the paper turns blue. What does the base property profile conclude?
The detergent solution contains a base. KEY
The detergent solution contains an acid.
The paper is faulty — red litmus paper never changes color.
Nothing — litmus responds only to acids.
ABS-004 · easy · recall · seq 3 · authored (row03 D): the roster's own odd-one-out fact (rule line 4); wrong options pair each acid with a rearranged formula so the key is not position-guessable · mcq4
Three of the four common acids have formulas that begin with H. Which acid is the odd one out, with a formula that does not lead with hydrogen?
Acetic acid — its formula is written CH₃COOH. KEY
Hydrochloric acid — its formula is written ClH.
Sulfuric acid — its formula is written SO₄H₂.
Nitric acid — its formula is written NO₃H.
ABS-005 · easy · recall · seq 4 · authored (row04 D): roster name->formula production with the parentheses surface · text
Write the chemical formula of calcium hydroxide.
Answer: Ca(OH)₂ KEY
also accepted: Ca(OH)2
wrongValueDiagnostics
[
{
"value": "CaOH",
"misconception": "you dropped one hydroxide — calcium's 2+ charge takes two OH units: Ca(OH)₂",
"feedback": "This answer is wrong — you dropped one hydroxide — calcium's 2+ charge takes two OH units: Ca(OH)₂"
},
{
"value": "CaOH₂",
"misconception": "you dropped the parentheses — without them the 2 counts only the hydrogen; two whole OH units are written Ca(OH)₂",
"feedback": "This answer is wrong — you dropped the parentheses — without them the 2 counts only the hydrogen; two whole OH units are written Ca(OH)₂"
},
{
"value": "Ca₂OH",
"misconception": "you moved the 2 onto the calcium — one Ca²⁺ takes two OH⁻: Ca(OH)₂",
"feedback": "This answer is wrong — you moved the 2 onto the calcium — one Ca²⁺ takes two OH⁻: Ca(OH)₂"
}
]
feedback
{
"keyExplanation": "Calcium hydroxide is Ca(OH)₂ — calcium's 2+ charge takes two hydroxide units, written with parentheses. It is sold as slaked lime for treating overly acidic soil.",
"anticipatedWrong": [
{
"value": "CaOH",
"misconception": "you dropped one hydroxide — calcium's 2+ charge takes two OH units: Ca(OH)₂",
"feedback": "This answer is wrong — you dropped one hydroxide — calcium's 2+ charge takes two OH units: Ca(OH)₂"
},
{
"value": "CaOH₂",
"misconception": "you dropped the parentheses — without them the 2 counts only the hydrogen; two whole OH units are written Ca(OH)₂",
"feedback": "This answer is wrong — you dropped the parentheses — without them the 2 counts only the hydrogen; two whole OH units are written Ca(OH)₂"
},
{
"value": "Ca₂OH",
"misconception": "you moved the 2 onto the calcium — one Ca²⁺ takes two OH⁻: Ca(OH)₂",
"feedback": "This answer is wrong — you moved the 2 onto the calcium — one Ca²⁺ takes two OH⁻: Ca(OH)₂"
}
]
}
ABS-003 · medium · application · seq 5 · authored (row05 D): mirror of the A-table task asking for the ACID pick; magnesium = D's metal home (seq 5) · mcq4
The table shows one observation for each of four cleaning products, J, K, L, and M. Which product contains an acid?
FIGURE (data-table · stimulus) — title: "Observations of four cleaning products" · columns: ["Product", "Observation"] · rows: [["J", "turns red litmus paper blue"], ["K", "bubbles of hydrogen stream off a magnesium strip"], ["L", "feels slippery when it coats rubber gloves"], ["M", … · style: "plain four-row observation table; no classification column"raw spec
{
"figureRequired": true,
"figureShape": "stimulus",
"figureSpec": {
"figureType": "data-table",
"title": "Observations of four cleaning products",
"columns": [
"Product",
"Observation"
],
"rows": [
[
"J",
"turns red litmus paper blue"
],
[
"K",
"bubbles of hydrogen stream off a magnesium strip"
],
[
"L",
"feels slippery when it coats rubber gloves"
],
[
"M",
"changes neither litmus color"
]
],
"style": "plain four-row observation table; no classification column"
}
}
Product K KEY
Product J
Product L
Product M
ABS-006 · medium · application · seq 6 · authored (row06 D): pool-17's structure on fresh members; CH₄ = clean neither; parentheses-counting rule exercised in the Ba(OH)₂ foil · mcq4
Which of these four formulas belongs to a substance that is neither an acid nor a base?
CH₄ KEY
HBrO₃
Ba(OH)₂
NH₃
ABS-007 · medium · application · seq 7 · authored (row07 D): definition fix, direction surface (the B-seed fixes the gas-vs-ion surface) · mcq4
A student writes: 'An Arrhenius acid is a substance that absorbs hydrogen ions from the water around it.' Which correction fixes the definition?
Change 'absorbs' to 'releases' — an acid is the SOURCE of the H⁺ it puts into the water. KEY
No correction is needed — the definition is already right.
Change 'water' to 'any liquid' — the definition works in every solvent.
Change 'hydrogen ions' to 'hydrogen gas' — acids release H₂.
ABS-008 · medium · application · seq 8 · authored (row08 D): the B seed's shared-source structure rotated onto the litmus line (instance-free) · mcq4
Every common base solution turns red litmus paper blue. Which statement explains the identical litmus response?
Each base frees OH⁻ in the water, and the freed OH⁻ produces every one of the shared base properties. KEY
The bases must all be built from one identical chemical recipe.
It is the metal ion inside each base that flips the litmus color, and every base's metal ion acts alike.
Sheer chance — the bases just happen to give matching litmus results.
ABS-009 · medium · application · seq 9 · authored (row09 D): the B seed's pair structure on fresh supplied equations · mcq4
Two dissolving equations: KBr → K⁺ + Br⁻, and CsOH → Cs⁺ + OH⁻. Which classification pair is correct?
KBr is neither, and CsOH is an Arrhenius base. KEY
KBr is an Arrhenius acid, and CsOH is an Arrhenius base.
Both are Arrhenius bases.
KBr is neither, and CsOH is an Arrhenius acid.
ABS-010 · medium · application · seq 10 · authored (row10 D): attachment-why with the which-end surface (the B seed asks why-not-free) | POLISH: stem reworded to break ABS-010/ABS-012 corpus grams (attaches-to-a-water class) · mcq4
After an acid frees a hydrogen ion, the ion ends up riding on one of the water molecules. Which end of that molecule does it join, and why?
The oxygen end — the positive H⁺ is attracted to the slightly negative oxygen. KEY
The hydrogen end — like attaches to like.
Either end at random — a water molecule has no charged ends.
Neither — the H⁺ moves through the solution entirely on its own.
ABS-011 · medium · application · seq 11 · authored (row11 D): the B seed's pick-the-event structure on fresh instances · mcq4
In which of these events is a particle acting as a Brønsted-Lowry acid?
An H₂CO₃ molecule passes an H⁺ to a nearby water molecule. KEY
A water molecule takes on an H⁺ and turns into H₃O⁺.
A NO₃⁻ ion drifts through the solution unchanged.
A Li⁺ ion just gathers a shell of water molecules around itself.
ABS-012 · medium · application · seq 12 · authored (row12 D, stage-3 rework): acceptor arithmetic, 1− to neutral (hypochlorite; chlorite freed to B#15's naming slot) · text
A hypochlorite ion, ClO⁻, accepts one H⁺. Write the formula of the particle that forms.
Answer: HClO KEY
also accepted: HOCl
wrongValueDiagnostics
[
{
"value": "H₂ClO",
"misconception": "you added two hydrogens — one H⁺ adds exactly one H: HClO",
"feedback": "This answer is wrong — you added two hydrogens — one H⁺ adds exactly one H: HClO"
},
{
"value": "HClO⁻",
"misconception": "you kept the 1− charge — gaining an H⁺ raises it by one, to neutral: HClO",
"feedback": "This answer is wrong — you kept the 1− charge — gaining an H⁺ raises it by one, to neutral: HClO"
},
{
"value": "ClO₂⁻",
"misconception": "you added an oxygen instead of a hydrogen — accepting H⁺ changes the H count, not the O count",
"feedback": "This answer is wrong — you added an oxygen instead of a hydrogen — accepting H⁺ changes the H count, not the O count"
}
]
feedback
{
"keyExplanation": "Accepting an H⁺ grows the formula by one H and raises the charge by one: ClO⁻ (1−) becomes the neutral particle HClO.",
"anticipatedWrong": [
{
"value": "H₂ClO",
"misconception": "you added two hydrogens — one H⁺ adds exactly one H: HClO",
"feedback": "This answer is wrong — you added two hydrogens — one H⁺ adds exactly one H: HClO"
},
{
"value": "HClO⁻",
"misconception": "you kept the 1− charge — gaining an H⁺ raises it by one, to neutral: HClO",
"feedback": "This answer is wrong — you kept the 1− charge — gaining an H⁺ raises it by one, to neutral: HClO"
},
{
"value": "ClO₂⁻",
"misconception": "you added an oxygen instead of a hydrogen — accepting H⁺ changes the H count, not the O count",
"feedback": "This answer is wrong — you added an oxygen instead of a hydrogen — accepting H⁺ changes the H count, not the O count"
}
]
}
ABS-013 · medium · application · seq 13 · authored (row13 D): the A seed's assign-both structure on a fresh weak-species equation (⇌ per register) · mcq4
In the equation HCN + H₂O ⇌ H₃O⁺ + CN⁻, which assignment of the two Brønsted-Lowry roles in the forward (left-to-right) change is correct?
HCN is the acid; H₂O is the base. KEY
H₂O is the acid; HCN is the base.
HCN is the acid; CN⁻ is the base.
H₃O⁺ is the acid; CN⁻ is the base.
ABS-016 · medium · application · seq 14 · authored (row14 D): classify-one with the anion supplied (the lesson's always-supply pattern) | POLISH: key reworded to break the ABS-019 corpus gram (an-oxygen-containing-polyatomic) · mcq4
HBrO₂ contains the bromite ion, BrO₂⁻. Classify HBrO₂.
An oxyacid — its hydrogen comes with an oxygen-bearing polyatomic ion. KEY
A binary acid — its formula begins with hydrogen.
A base — the oxygen and hydrogen inside it form hydroxide units.
Neither — an acid cannot contain three different elements.
ABS-019 · medium · application · seq 15 · authored (row15 D): -ate -> -ic with the hydro- cross-family trap in anticipatedWrong (iodine's D-form home is seq 15) · text
Name the acid HIO₃, which contains the iodate ion, IO₃⁻.
Answer: iodic acid KEY
also accepted: iodic
wrongValueDiagnostics
[
{
"value": "iodous acid",
"misconception": "you reversed the suffix — -ate points to -ic: iodATE gives iodIC acid",
"feedback": "This answer is wrong — you reversed the suffix — -ate points to -ic: iodATE gives iodIC acid"
},
{
"value": "hydroiodic acid",
"misconception": "you added hydro- — that name belongs to the BINARY acid HI; HIO₃ is an oxyacid and takes no prefix",
"feedback": "This answer is wrong — you added hydro- — that name belongs to the BINARY acid HI; HIO₃ is an oxyacid and takes no prefix"
},
{
"value": "iodate acid",
"misconception": "you kept the ion's name — the -ate ending converts to -ic acid in the acid's name",
"feedback": "This answer is wrong — you kept the ion's name — the -ate ending converts to -ic acid in the acid's name"
}
]
feedback
{
"keyExplanation": "The ion's name ends in -ate, so the acid's name ends in -ic acid: iodate gives iodic acid — with no hydro- prefix, because that prefix belongs to binary acids.",
"anticipatedWrong": [
{
"value": "iodous acid",
"misconception": "you reversed the suffix — -ate points to -ic: iodATE gives iodIC acid",
"feedback": "This answer is wrong — you reversed the suffix — -ate points to -ic: iodATE gives iodIC acid"
},
{
"value": "hydroiodic acid",
"misconception": "you added hydro- — that name belongs to the BINARY acid HI; HIO₃ is an oxyacid and takes no prefix",
"feedback": "This answer is wrong — you added hydro- — that name belongs to the BINARY acid HI; HIO₃ is an oxyacid and takes no prefix"
},
{
"value": "iodate acid",
"misconception": "you kept the ion's name — the -ate ending converts to -ic acid in the acid's name",
"feedback": "This answer is wrong — you kept the ion's name — the -ate ending converts to -ic acid in the acid's name"
}
]
}
ABS-021 · medium · application · seq 16 · authored (row16 D): spare pool 61's instance in the naming direction; its subscript trap moved into anticipatedWrong · text
Antacid tablets contain the base Al(OH)₃. Name this base.
Answer: aluminum hydroxide KEY
also accepted: aluminium hydroxide
wrongValueDiagnostics
[
{
"value": "aluminum trihydroxide",
"misconception": "you counted the subscript into the name — the subscript appears nowhere in a hydroxide's name: aluminum hydroxide",
"feedback": "This answer is wrong — you counted the subscript into the name — the subscript appears nowhere in a hydroxide's name: aluminum hydroxide"
},
{
"value": "aluminum(III) hydroxide",
"misconception": "you added a Roman numeral — aluminum is a fixed-charge metal, so its name carries no numeral",
"feedback": "This answer is wrong — you added a Roman numeral — aluminum is a fixed-charge metal, so its name carries no numeral"
},
{
"value": "aluminum oxide",
"misconception": "you dropped the hydrogens — the ion is hydroxide, OH⁻: aluminum hydroxide",
"feedback": "This answer is wrong — you dropped the hydrogens — the ion is hydroxide, OH⁻: aluminum hydroxide"
}
]
feedback
{
"keyExplanation": "A metal hydroxide takes its ordinary ionic name: metal name + hydroxide. Al(OH)₃ is aluminum hydroxide — the subscript 3 appears nowhere in the name.",
"anticipatedWrong": [
{
"value": "aluminum trihydroxide",
"misconception": "you counted the subscript into the name — the subscript appears nowhere in a hydroxide's name: aluminum hydroxide",
"feedback": "This answer is wrong — you counted the subscript into the name — the subscript appears nowhere in a hydroxide's name: aluminum hydroxide"
},
{
"value": "aluminum(III) hydroxide",
"misconception": "you added a Roman numeral — aluminum is a fixed-charge metal, so its name carries no numeral",
"feedback": "This answer is wrong — you added a Roman numeral — aluminum is a fixed-charge metal, so its name carries no numeral"
},
{
"value": "aluminum oxide",
"misconception": "you dropped the hydrogens — the ion is hydroxide, OH⁻: aluminum hydroxide",
"feedback": "This answer is wrong — you dropped the hydrogens — the ion is hydroxide, OH⁻: aluminum hydroxide"
}
]
}
ABS-015 · hard · transfer · seq 17 · seed:U11-G1/pool[42] (= ABS-015 gateItems[0]) — placed verbatim (spec-sourced Unicode) · mcq4
In HCl + NH₃ → NH₄⁺ + Cl⁻, which option lists both conjugate acid-base pairs?
HCl/Cl⁻ and NH₄⁺/NH₃ KEY
HCl/NH₃ and NH₄⁺/Cl⁻
HCl/NH₄⁺ and NH₃/Cl⁻
HCl/Cl⁻ only — this equation has a single pair
ABS-017 · hard · transfer · seq 18 · authored (row18 D): pool-48's diagnosis structure on the fluorine family (D's fluorine home) | POLISH: key trimmed + distractor lengthened for V-T4 balance · mcq4
A student names HF 'fluoric acid'. Which correction is right?
The hydro- prefix is missing — HF is hydrofluoric acid; a bare -ic name points to an oxygen-containing acid. KEY
Nothing at all went wrong — 'fluoric acid' is already the complete, correct name for HF.
The suffix is wrong — the name should be hydrofluorous acid.
The root is wrong — the name should use the full word, fluorine acid.
ABS-018 · hard · transfer · seq 19 · authored (row19 D): the H-count-from-charge routine with the charge dropped (sulfur's D-form home is seq 19) · mcq4
A student writes hydrosulfuric acid as HS. Which correction is right? (The sulfide ion is S²⁻.)
H₂S — sulfide's 2− charge takes two 1+ hydrogens. KEY
HS is correct — one hydrogen for one sulfur.
HS₂ — the 2 belongs on the sulfur.
H₂S₂ — both elements take the subscript 2.
ABS-020 · hard · transfer · seq 20 · authored (row20 D): spare pool 59's James-curated selenic case carried into the production direction (selenium's D-form home is seq 20) · text
Write the formula of selenic acid. (The selenate ion is SeO₄²⁻.)
Answer: H₂SeO₄ KEY
also accepted: H2SeO4
wrongValueDiagnostics
[
{
"value": "H₂SeO₃",
"misconception": "you swapped in the -ite ion — -ic acid points back to selenATE, SeO₄²⁻",
"feedback": "This answer is wrong — you swapped in the -ite ion — -ic acid points back to selenATE, SeO₄²⁻"
},
{
"value": "HSeO₄",
"misconception": "you added a single H — selenate's 2− charge takes two",
"feedback": "This answer is wrong — you added a single H — selenate's 2− charge takes two"
},
{
"value": "H₃SeO₄",
"misconception": "you added one H too many — match the H count to the charge number, 2",
"feedback": "This answer is wrong — you added one H too many — match the H count to the charge number, 2"
}
]
feedback
{
"keyExplanation": "-ic points back to the -ate ion: selenate, SeO₄²⁻. A 2− charge takes two H, so selenic acid is H₂SeO₄.",
"anticipatedWrong": [
{
"value": "H₂SeO₃",
"misconception": "you swapped in the -ite ion — -ic acid points back to selenATE, SeO₄²⁻",
"feedback": "This answer is wrong — you swapped in the -ite ion — -ic acid points back to selenATE, SeO₄²⁻"
},
{
"value": "HSeO₄",
"misconception": "you added a single H — selenate's 2− charge takes two",
"feedback": "This answer is wrong — you added a single H — selenate's 2− charge takes two"
},
{
"value": "H₃SeO₄",
"misconception": "you added one H too many — match the H count to the charge number, 2",
"feedback": "This answer is wrong — you added one H too many — match the H count to the charge number, 2"
}
]
}
ABS-014 · medium · application · seq 21 · authored (row21 D): coverage cell = both-definitions base (pool 40's hydroxide foils raised to production); KOH behavior supplied in the stem so coverage judgment, not roster recall, is measured (WARN recorded) | POLISH: formula-free per V-T12; stem reworded (breaks the ABS-008 corpus gram koh-dissolves-in-water); ASCII equation removed (V-T10) · frq
A sample of potassium hydroxide, KOH, is dissolved; the equation is KOH → K⁺ + OH⁻. Separately, a released hydroxide ion is seen accepting an H⁺ from an acid particle, forming a water molecule. Plain-text formulas are accepted in your answer.
A sample of potassium hydroxide, KOH, is dissolved; the equation is KOH → K⁺ + OH⁻. Separately, a released hydroxide ion is seen accepting an H⁺ from an acid particle, forming a water molecule. Plain-text formulas are accepted in your answer.
(a) Classify potassium hydroxide under the Arrhenius definition, citing that definition's criterion.
(b) Using the described event, explain how the Brønsted-Lowry definition also finds a base here — and name the exact particle that acts as the Brønsted-Lowry base.
(c) In one sentence, state what this case shows about how the two definitions treat hydroxide bases.
Part a. Classify potassium hydroxide under the Arrhenius definition, citing that definition's criterion.
Model: Potassium hydroxide is an Arrhenius base: the Arrhenius definition classifies as a base any substance that releases hydroxide ions when it dissolves in water, and that is what it does.
Part b. Using the described event, explain how the Brønsted-Lowry definition also finds a base here — and name the exact particle that acts as the Brønsted-Lowry base.
Model: The Brønsted-Lowry definition judges the transfer event. In the event described, the hydroxide ion accepts a hydrogen ion and becomes a water molecule — so the particle acting as the Brønsted-Lowry base is the hydroxide ion itself (the dissolved compound is what supplied that ion to the solution).
Part c. In one sentence, state what this case shows about how the two definitions treat hydroxide bases.
Model: Hydroxide bases are covered by both definitions — Arrhenius classifies the substance by the hydroxide it releases, and Brønsted-Lowry classifies the released hydroxide by the hydrogen ion it accepts — so the Brønsted-Lowry definition keeps everything Arrhenius covers.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
Full model answer. (a) Potassium hydroxide is an Arrhenius base: the Arrhenius definition classifies as a base any substance that releases hydroxide ions when it dissolves in water, and that is what it does.
(b) The Brønsted-Lowry definition judges the transfer event. In the event described, the hydroxide ion accepts a hydrogen ion and becomes a water molecule — so the particle acting as the Brønsted-Lowry base is the hydroxide ion itself (the dissolved compound is what supplied that ion to the solution).
(c) Hydroxide bases are covered by both definitions — Arrhenius classifies the substance by the hydroxide it releases, and Brønsted-Lowry classifies the released hydroxide by the hydrogen ion it accepts — so the Brønsted-Lowry definition keeps everything Arrhenius covers.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
Form E
ABS-001 · easy · recall · seq 1 · authored (row01 E): metal-line read; descaler = real acid product; the metal stays generic (metal-word homes live at seqs 5/7) | POLISH: stem reworded to break ABS-001/ABS-003 corpus grams (bubbles-of-gas-stream / poured-over-a-strip) · mcq4
A kettle descaler covers a strip of a reactive metal, and gas begins to bubble off the metal's surface. According to the acid property profile, which gas is this?
Hydrogen KEY
Oxygen
Carbon dioxide
Nitrogen
ABS-002 · easy · recall · seq 2 · authored (row02 E): taste-line read, same task class as the B seed on a fresh instance (same-seq rotation) · mcq4
Unsweetened matcha tea tastes strongly bitter. According to the property profiles, which family does the bitter taste point to?
The bases — bitterness in foods and drinks is the base taste. KEY
The acids — bitterness in foods and drinks is the acid taste.
Neither family — taste appears in neither property profile.
The reactive metals — bitter drinks contain dissolved metals.
ABS-004 · easy · recall · seq 3 · authored (row03 E): use->name (stomach); chlorine's E-form home is seq 3 (E#19 is the hydroiodic diagnosis, E#21 is HClO₄ — distinct substances) · mcq4
The digestive fluid in your stomach contains one of the four common acids. Which one?
Hydrochloric acid, HCl KEY
Sulfuric acid, H₂SO₄
Nitric acid, HNO₃
Acetic acid, CH₃COOH
ABS-005 · easy · recall · seq 4 · authored (row04 E): use->formula over the taught roster (repeat-back contract) · text
Liquid hand soaps are made using one of the four common bases. Write that base's chemical formula.
Answer: KOH KEY
wrongValueDiagnostics
[
{
"value": "NaOH",
"misconception": "you matched the wrong use — sodium hydroxide is the drain-cleaner base; liquid soaps use potassium hydroxide, KOH",
"feedback": "This answer is wrong — you matched the wrong use — sodium hydroxide is the drain-cleaner base; liquid soaps use potassium hydroxide, KOH"
},
{
"value": "NH₃",
"misconception": "you matched the glass-cleaner base — liquid soaps use potassium hydroxide, KOH",
"feedback": "This answer is wrong — you matched the glass-cleaner base — liquid soaps use potassium hydroxide, KOH"
},
{
"value": "Ca(OH)₂",
"misconception": "you matched the slaked-lime base — liquid soaps use potassium hydroxide, KOH",
"feedback": "This answer is wrong — you matched the slaked-lime base — liquid soaps use potassium hydroxide, KOH"
}
]
feedback
{
"keyExplanation": "Liquid soaps are made with potassium hydroxide, KOH. Sodium hydroxide clears drains, calcium hydroxide treats acidic soil as slaked lime, and ammonia cleans glass.",
"anticipatedWrong": [
{
"value": "NaOH",
"misconception": "you matched the wrong use — sodium hydroxide is the drain-cleaner base; liquid soaps use potassium hydroxide, KOH",
"feedback": "This answer is wrong — you matched the wrong use — sodium hydroxide is the drain-cleaner base; liquid soaps use potassium hydroxide, KOH"
},
{
"value": "NH₃",
"misconception": "you matched the glass-cleaner base — liquid soaps use potassium hydroxide, KOH",
"feedback": "This answer is wrong — you matched the glass-cleaner base — liquid soaps use potassium hydroxide, KOH"
},
{
"value": "Ca(OH)₂",
"misconception": "you matched the slaked-lime base — liquid soaps use potassium hydroxide, KOH",
"feedback": "This answer is wrong — you matched the slaked-lime base — liquid soaps use potassium hydroxide, KOH"
}
]
}
ABS-003 · medium · application · seq 5 · authored (row05 E): two-agreeing-observations judgment (extends the one-observation-is-enough rule) · mcq4
A pool-supply solution turns red litmus paper blue and also feels slippery on a gloved hand. Which classification do the property profiles give it?
A base — both observations sit in the base profile. KEY
An acid — litmus color changes always point to acids.
No classification is possible — the two observations conflict.
Neither an acid nor a base — two observations cancel each other out.
ABS-006 · medium · application · seq 6 · authored (row06 E): the H₂O trap as a correction task (expected-fire class c) · mcq4
During a lab discussion, a classmate argues: 'H₂O is written with H first, so water is technically an acid.' What correction is needed?
H₂O is a memorized exception to the patterns — H first, yet neither an acid nor a base. KEY
Nothing needs correcting — the H-first pattern has no exceptions.
H₂O is actually a base, because the letters O and H appear inside its formula.
H₂O is an acid, but only when it is hot.
ABS-007 · medium · application · seq 7 · authored (row07 E): direct shared-source identification (rule lines 5-6) | POLISH: distractor reworded to break the ABS-007 corpus gram (hydrogen-gas-h-2) · mcq4
Which particle is directly responsible for the shared properties that all acid solutions show?
The H⁺ ion that every acid sends into the water. KEY
The H₂ molecules dissolved in every acid solution.
A lab partner's notes say: 'An Arrhenius base releases hydrogen ions while dissolving in water.' What correction do the notes need?
Swap 'hydrogen ions' for 'hydroxide ions' — a base releases OH⁻ in water. KEY
The notes are already right as written.
Change 'releases' to 'destroys' — a base wipes ions out of the water.
Change 'dissolves' to 'boils' — the definition is about heating.
ABS-009 · medium · application · seq 9 · authored (row09 E): fresh neither-salt case; the equation is supplied per the lesson's own contract · mcq4
A sample of Mg(NO₃)₂ dissolves completely: Mg(NO₃)₂ → Mg²⁺ + 2NO₃⁻. Which classification is correct?
Neither — it releases neither H⁺ nor OH⁻. KEY
An Arrhenius base — every metal compound is a base.
An Arrhenius acid — dissolving readily is itself acid behavior.
It cannot be classified without a litmus test.
ABS-010 · medium · application · seq 10 · authored (row10 E): carrier identification (spare pool 29's production angle in mcq form, instance-free) | POLISH: key trimmed + gram break; distractors lengthened for V-T4 balance · mcq4
Inside an acid solution, which particle actually carries each of the acid's released hydrogen ions through the solution?
H₃O⁺ — the hydronium ion, a released H⁺ riding on a water molecule. KEY
A bare H⁺ that travels through the solution without ever touching a water molecule.
An H₂ molecule formed when two of the released hydrogen ions pair up.
An OH⁻ ion that grabs the hydrogen ions as fast as they appear.
ABS-011 · medium · application · seq 11 · authored (row11 E): rule 5 applied to an unexpected donor (transfer-flavored application; NH₄⁺ vs seq-4's ammonia word = different token, different substance) | POLISH: distractor lengthened for V-T4 balance · mcq4
An NH₄⁺ ion passes its extra H⁺ to one of the surrounding water molecules, becoming NH₃. Is NH₄⁺ acting as a Brønsted-Lowry acid in this event?
Yes — any particle caught donating an H⁺ is, in that moment, acting as a Brønsted-Lowry acid. KEY
No — NH₄⁺ is a positive ion, and only neutral molecules can donate an H⁺.
No — handing back an H⁺ it gained earlier does not count as donating.
No — in water, the water molecule is always the proton donor.
ABS-012 · medium · application · seq 12 · authored (row12 E): acceptor arithmetic on a fresh 2− ion | POLISH: SO₃²⁻ swapped to SeO₃²⁻ (sulfite = ABS-014 fluency corpus — own-scope gram 'ion so 32 accepts'); selenite is fresh to every scope corpus; E-form selenium home = seq 12 · text
A selenite ion, SeO₃²⁻, accepts one H⁺. Write the formula of the particle that forms.
Answer: HSeO₃⁻ KEY
also accepted: HSeO3-, HSeO₃-, HSeO3⁻
wrongValueDiagnostics
[
{
"value": "H₂SeO₃",
"misconception": "you added two hydrogens — accepting ONE H⁺ adds exactly one H: HSeO₃⁻",
"feedback": "This answer is wrong — you added two hydrogens — accepting ONE H⁺ adds exactly one H: HSeO₃⁻"
},
{
"value": "HSeO₃²⁻",
"misconception": "you added the H but kept the charge — gaining an H⁺ raises the charge by one, from 2− to 1−",
"feedback": "This answer is wrong — you added the H but kept the charge — gaining an H⁺ raises the charge by one, from 2− to 1−"
},
{
"value": "SeO₃⁻",
"misconception": "you raised the charge without adding the H — the formula grows by one H: HSeO₃⁻",
"feedback": "This answer is wrong — you raised the charge without adding the H — the formula grows by one H: HSeO₃⁻"
}
]
feedback
{
"keyExplanation": "Accepting an H⁺ grows the formula by one H and raises the charge by one: SeO₃²⁻ (2−) becomes HSeO₃⁻ (1−).",
"anticipatedWrong": [
{
"value": "H₂SeO₃",
"misconception": "you added two hydrogens — accepting ONE H⁺ adds exactly one H: HSeO₃⁻",
"feedback": "This answer is wrong — you added two hydrogens — accepting ONE H⁺ adds exactly one H: HSeO₃⁻"
},
{
"value": "HSeO₃²⁻",
"misconception": "you added the H but kept the charge — gaining an H⁺ raises the charge by one, from 2− to 1−",
"feedback": "This answer is wrong — you added the H but kept the charge — gaining an H⁺ raises the charge by one, from 2− to 1−"
},
{
"value": "SeO₃⁻",
"misconception": "you raised the charge without adding the H — the formula grows by one H: HSeO₃⁻",
"feedback": "This answer is wrong — you raised the charge without adding the H — the formula grows by one H: HSeO₃⁻"
}
]
}
ABS-013 · medium · application · seq 13 · authored (row13 E): water-as-donor on a fresh equation (roles-not-fixed, complements the B seed) · mcq4
In the equation F⁻ + H₂O ⇌ HF + OH⁻, which particle is the Brønsted-Lowry ACID in the forward (left-to-right) change?
H₂O — it loses an H⁺, becoming OH⁻. KEY
F⁻ — negative ions always take the acid role.
HF — it holds the most hydrogen when the equation ends.
OH⁻ — OH⁻ always marks the acid's partner.
ABS-016 · medium · application · seq 14 · authored (row14 E): the two-hydrogen boundary from the C seed inverted onto a fresh binary family (tellurium is fresh to every form) · mcq4
H₂Te contains hydrogen and tellurium only. Classify H₂Te.
A binary acid — hydrogen plus exactly one other element. KEY
An oxyacid — two hydrogens mark an oxyacid.
A base — a formula with two hydrogens cannot be an acid.
Neither — binary acids carry exactly one hydrogen.
ABS-019 · medium · application · seq 15 · authored (row15 E): -ite -> -ous with the root stretch (rule 7's phosphORic line extended; phosphorus's E-form home is seq 15) · text
Name the acid H₃PO₃, which contains the phosphite ion, PO₃³⁻.
Answer: phosphorous acid KEY
also accepted: phosphorous
wrongValueDiagnostics
[
{
"value": "phosphoric acid",
"misconception": "you reversed the suffix — -ite points to -ous: phosphITE gives phosphorOUS acid; phosphoric belongs to phosphate",
"feedback": "This answer is wrong — you reversed the suffix — -ite points to -ous: phosphITE gives phosphorOUS acid; phosphoric belongs to phosphate"
},
{
"value": "hydrophosphorous acid",
"misconception": "you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it",
"feedback": "This answer is wrong — you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it"
},
{
"value": "phosphite acid",
"misconception": "you kept the ion's name — the -ite ending converts to -ous acid in the acid's name",
"feedback": "This answer is wrong — you kept the ion's name — the -ite ending converts to -ous acid in the acid's name"
}
]
feedback
{
"keyExplanation": "The ion's name ends in -ite, so the acid's name ends in -ous acid: phosphite gives phosphorous acid — the root stretches so the name says smoothly, just as phosphate gives phosphoric.",
"anticipatedWrong": [
{
"value": "phosphoric acid",
"misconception": "you reversed the suffix — -ite points to -ous: phosphITE gives phosphorOUS acid; phosphoric belongs to phosphate",
"feedback": "This answer is wrong — you reversed the suffix — -ite points to -ous: phosphITE gives phosphorOUS acid; phosphoric belongs to phosphate"
},
{
"value": "hydrophosphorous acid",
"misconception": "you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it",
"feedback": "This answer is wrong — you added hydro- — that prefix belongs to binary acids, and oxyacid names never take it"
},
{
"value": "phosphite acid",
"misconception": "you kept the ion's name — the -ite ending converts to -ous acid in the acid's name",
"feedback": "This answer is wrong — you kept the ion's name — the -ite ending converts to -ous acid in the acid's name"
}
]
}
ABS-021 · medium · application · seq 16 · authored (row16 E): same instance as C (same-seq cross-form share, A5-allowed; only Cs/Rb sit outside ABS-021's corpus — recorded for James) · text
A laboratory bottle is labeled CsOH. Write this base's name.
Answer: cesium hydroxide KEY
also accepted: caesium hydroxide
wrongValueDiagnostics
[
{
"value": "cesium oxide",
"misconception": "you dropped the hydrogen — the ion is hydroxide, OH⁻: cesium hydroxide",
"feedback": "This answer is wrong — you dropped the hydrogen — the ion is hydroxide, OH⁻: cesium hydroxide"
},
{
"value": "hydrocesic acid",
"misconception": "you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide",
"feedback": "This answer is wrong — you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide"
},
{
"value": "cesium hydroxide III",
"misconception": "you appended a count — no numeral or count belongs in a fixed-charge hydroxide's name",
"feedback": "This answer is wrong — you appended a count — no numeral or count belongs in a fixed-charge hydroxide's name"
}
]
feedback
{
"keyExplanation": "A metal hydroxide takes its ordinary ionic name: metal name + hydroxide. CsOH is cesium hydroxide.",
"anticipatedWrong": [
{
"value": "cesium oxide",
"misconception": "you dropped the hydrogen — the ion is hydroxide, OH⁻: cesium hydroxide",
"feedback": "This answer is wrong — you dropped the hydrogen — the ion is hydroxide, OH⁻: cesium hydroxide"
},
{
"value": "hydrocesic acid",
"misconception": "you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide",
"feedback": "This answer is wrong — you used an acid pattern — hydro-, -ic, and -ous belong to acids; a metal hydroxide takes metal name + hydroxide"
},
{
"value": "cesium hydroxide III",
"misconception": "you appended a count — no numeral or count belongs in a fixed-charge hydroxide's name",
"feedback": "This answer is wrong — you appended a count — no numeral or count belongs in a fixed-charge hydroxide's name"
}
]
}
ABS-015 · hard · transfer · seq 17 · authored (row17 E): inverts the A seed's trap (a true pair built from the same water-family particles); the Yes-foil-with-wrong-reason follows the pool-43 option pattern | POLISH: distractor lengthened for V-T4 balance · mcq4
Do H₂O and OH⁻ form a conjugate acid-base pair?
Yes — their formulas differ by exactly one H⁺, with H₂O as the pair's acid member. KEY
No — the two differ in charge, and conjugate partners must carry the same charge.
No — a conjugate pair must contain an acid, and neither H₂O nor OH⁻ can act as one.
No — H₂O and OH⁻ differ by a whole OH unit, not by exactly one H⁺.
ABS-017 · hard · transfer · seq 18 · re-instanced 2026-10-13 (A1 forms pass; James ruling 2026-10-08 #19): the H₂S 'sulfurous acid' diagnosis repeated ABS-017 WE2's instance -> HBr 'bromic acid' (the binary roster is six real acids; HF/HI/H₂Se sit in the checkpoints, HCl/H₂S in the worked examples, so HBr — the article's register example, reused under the R8 task-change clause as an error-diagnosis task — is the one roster acid free of checkpoint and WE duplication); same skill, same three misconception classes (oxyacid name accepted / wrong piece fixed / -ous kept). Previous source: authored (row18 E): diagnosis with a REAL oxyacid name misapplied. · mcq4
A student names HBr 'bromic acid'. Which correction is right?
HBr is hydrobromic acid — 'bromic acid' is an oxyacid name and cannot fit an oxygen-free acid. KEY
Nothing went wrong — 'bromic acid' is a perfectly correct name for HBr.
Only the suffix is wrong — HBr should be named bromous acid.
The correct name should be hydrobromous acid — the hydro- prefix plus the -ous suffix together.
ABS-018 · hard · transfer · seq 19 · authored (row19 E): the diatomic-element confusion as a formula diagnosis (iodine's E-form home is seq 19) | POLISH: distractor lengthened for V-T4 balance · mcq4
A student writes hydroiodic acid as HI₂. Which correction is right? (The iodide ion is I⁻.)
HI — iodide's 1− charge takes a single hydrogen, with no subscript at all. KEY
HI₂ is correct — iodine always comes in pairs.
H₂I — the subscript 2 belongs on the hydrogen instead of the iodine.
H₂I₂ — both elements should take the subscript 2.
ABS-020 · hard · transfer · seq 20 · authored (row20 E): 1− case with spare pool 58's bromate/bromite confusion carried into anticipatedWrong (bromine's E-form home is seq 20) · text
Write the formula of bromic acid. (The bromate ion is BrO₃⁻.)
Answer: HBrO₃ KEY
also accepted: HBrO3
wrongValueDiagnostics
[
{
"value": "HBrO₂",
"misconception": "you reversed -ic to the wrong ion — -ic acid points back to bromATE, BrO₃⁻; BrO₂⁻ is bromite",
"feedback": "This answer is wrong — you reversed -ic to the wrong ion — -ic acid points back to bromATE, BrO₃⁻; BrO₂⁻ is bromite"
},
{
"value": "H₂BrO₃",
"misconception": "you doubled the hydrogen — bromate's 1− charge needs only one H",
"feedback": "This answer is wrong — you doubled the hydrogen — bromate's 1− charge needs only one H"
},
{
"value": "HBr",
"misconception": "you dropped the oxygens — bromic acid is an oxyacid; HBr is hydrobromic, the binary acid",
"feedback": "This answer is wrong — you dropped the oxygens — bromic acid is an oxyacid; HBr is hydrobromic, the binary acid"
}
]
feedback
{
"keyExplanation": "-ic points back to the -ate ion: bromate, BrO₃⁻. A 1− charge takes one H, so bromic acid is HBrO₃.",
"anticipatedWrong": [
{
"value": "HBrO₂",
"misconception": "you reversed -ic to the wrong ion — -ic acid points back to bromATE, BrO₃⁻; BrO₂⁻ is bromite",
"feedback": "This answer is wrong — you reversed -ic to the wrong ion — -ic acid points back to bromATE, BrO₃⁻; BrO₂⁻ is bromite"
},
{
"value": "H₂BrO₃",
"misconception": "you doubled the hydrogen — bromate's 1− charge needs only one H",
"feedback": "This answer is wrong — you doubled the hydrogen — bromate's 1− charge needs only one H"
},
{
"value": "HBr",
"misconception": "you dropped the oxygens — bromic acid is an oxyacid; HBr is hydrobromic, the binary acid",
"feedback": "This answer is wrong — you dropped the oxygens — bromic acid is an oxyacid; HBr is hydrobromic, the binary acid"
}
]
}
ABS-014 · medium · application · seq 21 · authored (row21 E): coverage cell = both-definitions acid on a fresh fully-ionizing acid (HClO₄; distinct substance from E#3's HCl) | POLISH: formula-free per V-T12; stem reworded ('is dissolved in water' — breaks the 4-dissolves-in-water gram); hydronium named in words · frq
Perchloric acid, HClO₄, is added to water, where it dissolves. The shorthand equation is HClO₄ → H⁺ + ClO₄⁻; written honestly it is HClO₄ + H₂O → H₃O⁺ + ClO₄⁻. Plain-text formulas are accepted in your answer.
Perchloric acid, HClO₄, is added to water, where it dissolves. The shorthand equation is HClO₄ → H⁺ + ClO₄⁻; written honestly it is HClO₄ + H₂O → H₃O⁺ + ClO₄⁻. Plain-text formulas are accepted in your answer.
(a) Classify perchloric acid under the Arrhenius definition, citing that definition's criterion.
(b) Classify perchloric acid under the Brønsted-Lowry definition, using the honest equation to name the donor and the acceptor.
(c) In one sentence, state why the two definitions can never disagree about a substance like this one.
Part a. Classify perchloric acid under the Arrhenius definition, citing that definition's criterion.
Model: Perchloric acid is an Arrhenius acid: the Arrhenius definition classifies as an acid any substance that releases hydrogen ions when it dissolves in water, and it does.
Part b. Classify perchloric acid under the Brønsted-Lowry definition, using the honest equation to name the donor and the acceptor.
Model: It is also a Brønsted-Lowry acid. In the honest equation, the perchloric-acid particle donates its hydrogen ion — the donor, the acid — and the water molecule accepts it, becoming the hydronium ion — the acceptor, the base in this event.
Part c. In one sentence, state why the two definitions can never disagree about a substance like this one.
Model: The definitions can never disagree about such a substance because releasing hydrogen ions into water is the same event as donating them to water molecules — every Arrhenius acid is automatically a Brønsted-Lowry acid.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
Full model answer. (a) Perchloric acid is an Arrhenius acid: the Arrhenius definition classifies as an acid any substance that releases hydrogen ions when it dissolves in water, and it does.
(b) It is also a Brønsted-Lowry acid. In the honest equation, the perchloric-acid particle donates its hydrogen ion — the donor, the acid — and the water molecule accepts it, becoming the hydronium ion — the acceptor, the base in this event.
(c) The definitions can never disagree about such a substance because releasing hydrogen ions into water is the same event as donating them to water molecules — every Arrhenius acid is automatically a Brønsted-Lowry acid.
Grading note: plain-text formulas are accepted anywhere in the answer; subscripts and superscripts are never required, and naming a particle in words is always acceptable.
End of Topic Test: Strong and weak (u11-t2 · 5 forms × 21 items · 105 total)
David's notes for James:
FRQ ALLOCATION - frq_per_form = 1 (confirm the composition): the wave's calc-heavy 2-3-FRQ directive was EVALUATED AND DOES NOT APPLY - this scope (ABS-022..026) has ZERO quant lessons and no taught calculation route: molarity is XREF:U10 (one-line recap ceiling per ABS-025 extraNotes) and every pH-adjacent calculation is ABS-027+ (U11-G3 territory). No value is ever computed and entered, so there is nothing for a 5-line-scaffold calculation FRQ to assess. Your seed file's frq_per_form=1 baseline stands; the single FRQ sits on capstone ABS-026 (classify-from-data + the dilute-not-weak boundary) at terminal seq 21 per D6. Total 20 mcq + 1 FRQ = 21 items/form; D5 scaling not engaged (min(20, 6 x 5 lessons) = 20; your target_size=20 concurs). All-mcq objective rows: no item computes a value, and all 15 pool seeds are mcq.
FORMULA CONVENTION (recorded adjudication, confirm): acids and bases are referenced by FORMULA in stems/options (HClO4, NaOH, NH3, Ca(OH)2, ...) because the English names carry own-lesson MATERIALS-lexicon tokens (ammonia; sodium/calcium/magnesium inside the hydroxide names) that would be V-T7 freshness FAILs on roster items. Supplied names carrying no lexicon token (limewater, lactic acid, benzoic acid, ...) are used where they add authenticity. The word 'water' (present in every scope lesson's rule lines) is banned from scanned fields - items say 'dissolves' / 'in solution' / 'aqueous solution'; the taught 'in water' wording lives in feedback, which the scan does not cover. One exception kept: your verbatim seed word 'oxygen' at A#18 (it appears in no scope lesson's spec text and in no other item, so no scan fires). Zero gate_config relief entries were needed - the substance scan stayed fully armed.
AQUEOUS-CONTEXT REGISTER SPLIT (sol-QC adjudication, confirm): strong/weak are water-based definitions, so behavior-classification stems (the seq-5 classify-from-extent family and the seq-14 conductivity family, all forms) now state 'aqueous solution' explicitly - the literal token 'water' is scan-banned per the FORMULA CONVENTION, and 'aqueous' carries no instance signal. DATA items (seq 6/11/20 and the FRQ) keep the course's own register: the scope lessons' worked examples state percent-ionized data as 'a solution of X is about N% ionized' with no aqueous qualifier, so bare-'solution' data items follow the course-local convention. Recorded in gate_config.adjudication_notes.
SEQ-14 COURSE-MODEL RULING (confirm - both blind reviewers and sol pressed strict-proof objections): the equal-concentration bulb dichotomy (bright = complete ionization = strong, dim = partial = weak) is the taught ABS-022/ABS-026 evidence rule, and course-local definitions are authority over beyond-course nuance (two different partial ionizers could in principle produce distinguishable dimness, ion mobilities differ, etc.). The stems were hardened rather than the model imported: one solution is identified as prepared from a listed strong base/acid (the course's own known-reference procedure per ABS-026), explicit controls stated (same solvent register / equal concentration / equal volumes / identical bulb apparatus / same temperature), and 'best explains' framing. Recorded in gate_config.adjudication_notes.
SEED DISPOSITIONS UNDER THE STRICT SEED RULING (no freshness exemption; dispositions to confirm): all 15 unique pool seeds placed on form A (your demo_curated[0..2] are verbatim duplicates of pool[12..14] - deduped, both refs cited). 11 of 15 freshened in content, zero whitelist entries: 'dissolved in water' phrasing dropped (pools 0/1/2/3/9 - own-lesson material token), corpus-colliding numbers replaced (0.10 M and 0.050 M dropped or reworded at pools 10/11/12/14/9), material tokens replaced (calcium pool 6, ammonia pool 8 -> NH3, sodium pool 11 -> NaOH), and pool[10]'s formic-acid bottle freshened to benzoic acid to kill a same-form telegraph with pool[2]'s HCOOH arrow item. pool[4]/[5]/[7]/[13] placed verbatim (no scanned-field collisions). A#20 keeps your 0.0010 M verbatim - that value originates in the gate item itself (its ONLY spec occurrence is your gateItems[1]; students never see gate items before the test), recorded in the item's source field.
SEQ-2 KEY MEMBER ROTATED OFF YOUR SEED'S HClO4 (confirm): the seq-2 roster-membership row on form A keys HBr instead of the seed's HClO4, because the seq-9 dilution item (your pool[9] seed) uses HClO4 as its instance - a same-form roster read would pre-answer it. The seed instance HClO4 is preserved at seq 9; the seq-2 item is otherwise the seed's task with the tested member rotated.
SEED CONTENT FIXES AT BLIND/SOL QC (confirm): A#4 distractors made all-bases (NH3 / Mg(OH)2 / Cu(OH)2, misconception-keyed) - the key was structurally the only base among three acids; A#19's 'NH3 is not a base at all' foil contradicted its own stem -> replaced with the dissolving-vs-ionizing misconception; A#13's 7.5 M aqueous benzoic acid is physically impossible (solubility ~0.03 M) -> CH3COOH (miscible at any molarity); C#6's 0.35 M citric acid is ~4.6% ionized in reality, not 'about 2%' -> lactic acid (Ka 1.38e-4 gives exactly 2.0% at 0.35 M). Realism sweep of the other named-acid data items passed (A#6 butanoic 0.25 M ~1%: Ka-exact 0.77%; E#6 HBrO 0.60 M <1%: Ka-exact 0.007%); B#6/D#6 and the FRQs use unnamed acids.
REAL-CHEMISTRY NUANCES LEFT ON THE COURSE MODEL (course-local authority; confirm you're comfortable): Mg(OH)2 is keyed strictly to LIST membership (never solubility - your ABS-024 extraNotes rule); H2SO4's second dissociation is ignored (course treats the six strong acids as complete ionizers); ion-mobility effects on conductivity are ignored (bulb brightness maps to ion count per the taught model); %-ionized thresholds follow ABS-026's rule line ('a strong acid or base ionizes close to 100%, while a weak one ionizes only a few percent') - items use 92-98% for strong and 1-4% for weak.
D#6 DATA-BEATS-ROSTER FOIL (confirm): D#6 carries the distractor 'an acid not one of the memorized six cannot be classified' (misconception: roster is the only classification route). This is course-consistent per ABS-026's setup ('real laboratory data lets you classify an acid or base you have never met'), but it grades a student who over-applied the ABS-023 assume-weak heuristic's roster frame as wrong - flagged for your read.
ARROW-NAMING PARENTHETICALS AT SEQ 10 (disclosure): the duplicate-option lint normalizes away arrow glyphs, so the key/distractor equation pair differing only by double arrow vs single arrow normalized identical. Both equation options carry a notation-naming parenthetical - '(double arrow, partial ionization)' family wording - which only names what is already drawn (canonical rule-line vocabulary, no key leak; the stem states the ionization extent, so naming the arrow decides nothing by itself). B#10's decomposition foil (normalization-identical to its key) was replaced with a no-equation-needed foil instead.
'BOTH PANELS'/'NEITHER PANEL' OPTIONS ON THE DIAGRAM ROWS (seq 11/20 - disclosure): kept as substantive misconception-keyed claims about the data (not NOTA/AOTA); the NOTA lint passed with no close-variant warnings. Your seeds carried no literal None/All-of-the-above options anywhere, so the opportunistic replacement rule had nothing to do this gate.
SEQ-20 + FRQ PART (c) DOUBLE COVERAGE (by design, confirm): both assess the ABS-025 dilute-not-weak boundary FROM DATA on every form - seq 20 as recognition (one particle diagram, count vs fraction-split), FRQ (c) as production (explain the student's error, describe Z correctly). The capstone extraNotes mandate the boundary in data items, so the double coverage at different depths is deliberate.
D7 FENCES HONORED (disclosure): HClO3 appears nowhere in this gate, not even as a distractor (your ABS-023 extraNotes); no solubility reasoning at the Mg(OH)2 boundary; no pH/indicator/equilibrium content; no ionization-fraction percentages on ABS-025 rows (that data class belongs to ABS-026 rows only); concentration judgments stay extreme (dilute <= 0.05 M vs concentrated >= 5 M per ABS-025 extraNotes); HCN excluded from all scenarios (classroom-safe instance rule) - weak-acid instances drawn from benign named acids only.
BINDING INSTANCE RULE (course-wide): zero fissile/weapons/dose framings; classroom-safe instances throughout (lab solutions, household cleaners, limewater, food acids, antacid bases). Your pool scanned clean at stage 1; re-swept at packaging over forms_final and this export body.
QC LEDGER (disclosure): deterministic validators 12/12 PASS exit 0 with ZERO warnings and ZERO gate_config relief entries (config = spec-path override + adjudication notes only); blind rounds r1-r12 = 302/302 key picks across all rounds, 5 FRQs x 2 reviewers = 10/10 graded matches with hand-review justifications; sol authoritative loops 1-3 = 6 -> 2 -> 0 FAILs, final 105/105 pass, zero course-local-authority overrides (every finding content-fixed); 56 recorded patches across 5 waves, all logged.
FRQ delivery: your `prod` draw-on-paper class is delivered as a typed diagram-PLAN task (state kinds/recipes/counts/spacing; rubric grades the same observables). Confirm this mapping (pending from the U01-G1 round-trip).
full notes file
# u11-t2 — notes/queries from David's side (U11-G2)
1. FRQ ALLOCATION - frq_per_form = 1 (confirm the composition): the wave's calc-heavy 2-3-FRQ directive was EVALUATED AND DOES NOT APPLY - this scope (ABS-022..026) has ZERO quant lessons and no taught calculation route: molarity is XREF:U10 (one-line recap ceiling per ABS-025 extraNotes) and every pH-adjacent calculation is ABS-027+ (U11-G3 territory). No value is ever computed and entered, so there is nothing for a 5-line-scaffold calculation FRQ to assess. Your seed file's frq_per_form=1 baseline stands; the single FRQ sits on capstone ABS-026 (classify-from-data + the dilute-not-weak boundary) at terminal seq 21 per D6. Total 20 mcq + 1 FRQ = 21 items/form; D5 scaling not engaged (min(20, 6 x 5 lessons) = 20; your target_size=20 concurs). All-mcq objective rows: no item computes a value, and all 15 pool seeds are mcq.
2. FORMULA CONVENTION (recorded adjudication, confirm): acids and bases are referenced by FORMULA in stems/options (HClO4, NaOH, NH3, Ca(OH)2, ...) because the English names carry own-lesson MATERIALS-lexicon tokens (ammonia; sodium/calcium/magnesium inside the hydroxide names) that would be V-T7 freshness FAILs on roster items. Supplied names carrying no lexicon token (limewater, lactic acid, benzoic acid, ...) are used where they add authenticity. The word 'water' (present in every scope lesson's rule lines) is banned from scanned fields - items say 'dissolves' / 'in solution' / 'aqueous solution'; the taught 'in water' wording lives in feedback, which the scan does not cover. One exception kept: your verbatim seed word 'oxygen' at A#18 (it appears in no scope lesson's spec text and in no other item, so no scan fires). Zero gate_config relief entries were needed - the substance scan stayed fully armed.
3. AQUEOUS-CONTEXT REGISTER SPLIT (sol-QC adjudication, confirm): strong/weak are water-based definitions, so behavior-classification stems (the seq-5 classify-from-extent family and the seq-14 conductivity family, all forms) now state 'aqueous solution' explicitly - the literal token 'water' is scan-banned per the FORMULA CONVENTION, and 'aqueous' carries no instance signal. DATA items (seq 6/11/20 and the FRQ) keep the course's own register: the scope lessons' worked examples state percent-ionized data as 'a solution of X is about N% ionized' with no aqueous qualifier, so bare-'solution' data items follow the course-local convention. Recorded in gate_config.adjudication_notes.
4. SEQ-14 COURSE-MODEL RULING (confirm - both blind reviewers and sol pressed strict-proof objections): the equal-concentration bulb dichotomy (bright = complete ionization = strong, dim = partial = weak) is the taught ABS-022/ABS-026 evidence rule, and course-local definitions are authority over beyond-course nuance (two different partial ionizers could in principle produce distinguishable dimness, ion mobilities differ, etc.). The stems were hardened rather than the model imported: one solution is identified as prepared from a listed strong base/acid (the course's own known-reference procedure per ABS-026), explicit controls stated (same solvent register / equal concentration / equal volumes / identical bulb apparatus / same temperature), and 'best explains' framing. Recorded in gate_config.adjudication_notes.
5. SEED DISPOSITIONS UNDER THE STRICT SEED RULING (no freshness exemption; dispositions to confirm): all 15 unique pool seeds placed on form A (your demo_curated[0..2] are verbatim duplicates of pool[12..14] - deduped, both refs cited). 11 of 15 freshened in content, zero whitelist entries: 'dissolved in water' phrasing dropped (pools 0/1/2/3/9 - own-lesson material token), corpus-colliding numbers replaced (0.10 M and 0.050 M dropped or reworded at pools 10/11/12/14/9), material tokens replaced (calcium pool 6, ammonia pool 8 -> NH3, sodium pool 11 -> NaOH), and pool[10]'s formic-acid bottle freshened to benzoic acid to kill a same-form telegraph with pool[2]'s HCOOH arrow item. pool[4]/[5]/[7]/[13] placed verbatim (no scanned-field collisions). A#20 keeps your 0.0010 M verbatim - that value originates in the gate item itself (its ONLY spec occurrence is your gateItems[1]; students never see gate items before the test), recorded in the item's source field.
6. SEQ-2 KEY MEMBER ROTATED OFF YOUR SEED'S HClO4 (confirm): the seq-2 roster-membership row on form A keys HBr instead of the seed's HClO4, because the seq-9 dilution item (your pool[9] seed) uses HClO4 as its instance - a same-form roster read would pre-answer it. The seed instance HClO4 is preserved at seq 9; the seq-2 item is otherwise the seed's task with the tested member rotated.
7. SEED CONTENT FIXES AT BLIND/SOL QC (confirm): A#4 distractors made all-bases (NH3 / Mg(OH)2 / Cu(OH)2, misconception-keyed) - the key was structurally the only base among three acids; A#19's 'NH3 is not a base at all' foil contradicted its own stem -> replaced with the dissolving-vs-ionizing misconception; A#13's 7.5 M aqueous benzoic acid is physically impossible (solubility ~0.03 M) -> CH3COOH (miscible at any molarity); C#6's 0.35 M citric acid is ~4.6% ionized in reality, not 'about 2%' -> lactic acid (Ka 1.38e-4 gives exactly 2.0% at 0.35 M). Realism sweep of the other named-acid data items passed (A#6 butanoic 0.25 M ~1%: Ka-exact 0.77%; E#6 HBrO 0.60 M <1%: Ka-exact 0.007%); B#6/D#6 and the FRQs use unnamed acids.
8. REAL-CHEMISTRY NUANCES LEFT ON THE COURSE MODEL (course-local authority; confirm you're comfortable): Mg(OH)2 is keyed strictly to LIST membership (never solubility - your ABS-024 extraNotes rule); H2SO4's second dissociation is ignored (course treats the six strong acids as complete ionizers); ion-mobility effects on conductivity are ignored (bulb brightness maps to ion count per the taught model); %-ionized thresholds follow ABS-026's rule line ('a strong acid or base ionizes close to 100%, while a weak one ionizes only a few percent') - items use 92-98% for strong and 1-4% for weak.
9. D#6 DATA-BEATS-ROSTER FOIL (confirm): D#6 carries the distractor 'an acid not one of the memorized six cannot be classified' (misconception: roster is the only classification route). This is course-consistent per ABS-026's setup ('real laboratory data lets you classify an acid or base you have never met'), but it grades a student who over-applied the ABS-023 assume-weak heuristic's roster frame as wrong - flagged for your read.
10. ARROW-NAMING PARENTHETICALS AT SEQ 10 (disclosure): the duplicate-option lint normalizes away arrow glyphs, so the key/distractor equation pair differing only by double arrow vs single arrow normalized identical. Both equation options carry a notation-naming parenthetical - '(double arrow, partial ionization)' family wording - which only names what is already drawn (canonical rule-line vocabulary, no key leak; the stem states the ionization extent, so naming the arrow decides nothing by itself). B#10's decomposition foil (normalization-identical to its key) was replaced with a no-equation-needed foil instead.
11. 'BOTH PANELS'/'NEITHER PANEL' OPTIONS ON THE DIAGRAM ROWS (seq 11/20 - disclosure): kept as substantive misconception-keyed claims about the data (not NOTA/AOTA); the NOTA lint passed with no close-variant warnings. Your seeds carried no literal None/All-of-the-above options anywhere, so the opportunistic replacement rule had nothing to do this gate.
12. SEQ-20 + FRQ PART (c) DOUBLE COVERAGE (by design, confirm): both assess the ABS-025 dilute-not-weak boundary FROM DATA on every form - seq 20 as recognition (one particle diagram, count vs fraction-split), FRQ (c) as production (explain the student's error, describe Z correctly). The capstone extraNotes mandate the boundary in data items, so the double coverage at different depths is deliberate.
13. D7 FENCES HONORED (disclosure): HClO3 appears nowhere in this gate, not even as a distractor (your ABS-023 extraNotes); no solubility reasoning at the Mg(OH)2 boundary; no pH/indicator/equilibrium content; no ionization-fraction percentages on ABS-025 rows (that data class belongs to ABS-026 rows only); concentration judgments stay extreme (dilute <= 0.05 M vs concentrated >= 5 M per ABS-025 extraNotes); HCN excluded from all scenarios (classroom-safe instance rule) - weak-acid instances drawn from benign named acids only.
14. BINDING INSTANCE RULE (course-wide): zero fissile/weapons/dose framings; classroom-safe instances throughout (lab solutions, household cleaners, limewater, food acids, antacid bases). Your pool scanned clean at stage 1; re-swept at packaging over forms_final and this export body.
15. QC LEDGER (disclosure): deterministic validators 12/12 PASS exit 0 with ZERO warnings and ZERO gate_config relief entries (config = spec-path override + adjudication notes only); blind rounds r1-r12 = 302/302 key picks across all rounds, 5 FRQs x 2 reviewers = 10/10 graded matches with hand-review justifications; sol authoritative loops 1-3 = 6 -> 2 -> 0 FAILs, final 105/105 pass, zero course-local-authority overrides (every finding content-fixed); 56 recorded patches across 5 waves, all logged.
Form A
ABS-022 · easy · recall · seq 1 · fresh authored (definitional recall, rule lines 2-3; fluency definitional items are student-seen and not reused) · mcq4
A classmate asks what the label 'weak' tells you about a base. Which answer is right?
Only a small fraction of its dissolved particles splits into ions. KEY
Only a small amount of it is dissolved per liter of solution.
It is too gentle to change the color of litmus paper.
None of its particles forms ions when it dissolves.
ABS-023 · easy · recall · seq 2 · seed:U11-G2.pool[3] (ABS-023 gateItems[0], HClO4 key) — freshened: 'in water' dropped from the stem (own-lesson material token); key member rotated to HBr so the seq-9 HClO4 dilution item is not pre-answered; foils H2SO3/H2CO3/HCOOH avoid the seq-18 HNO2 and seq-8 HF instances · mcq4
Which of these four acids ionizes completely when it dissolves?
A bottle's label reads 'concentrated'. Which question about the solution does that label answer?
How much acid or base is dissolved per liter of solution. KEY
What fraction of the dissolved particles has split into ions.
Whether the dissolved acid or base is one of the strong ones.
How brightly the solution would light a conductivity bulb.
ABS-024 · easy · recall · seq 4 · fresh authored (roster membership pick; acid foils chosen so no strong/weak status of another form-A item is revealed) · mcq4
Which of these is one of the common strong bases?
Sr(OH)₂ KEY
NH₃
Mg(OH)₂
Cu(OH)₂
ABS-022 · medium · application · seq 5 · seed:U11-G2.pool[0] (ABS-022 gateItems[0]) — freshened: 'dissolved in water' dropped (own-lesson material token); options kept verbatim · mcq4
A base dissolves to form an aqueous solution, and tests show that most of its particles remain intact in the solution, with only a small fraction split into ions. How is this base classified on the strength scale?
Weak KEY
Strong
Concentrated
Dilute
ABS-026 · medium · application · seq 6 · fresh authored (fraction-ionized evidence class; butanoic ~1% at 0.25 M is chemically real per extraNotes) · mcq4
A reference table lists a 0.25 M solution of butanoic acid as about 1% ionized. What does this datum show about butanoic acid?
It is weak — nearly all of its dissolved molecules stay whole. KEY
It is strong — any measurable ionization counts as complete.
It is dilute — 1% means very little acid is dissolved.
Nothing — a single percentage cannot classify an acid.
ABS-024 · medium · application · seq 7 · seed:U11-G2.pool[6] (ABS-024 gateItems[0]) — freshened: key reworded to drop the own-lesson material token 'calcium' (formula convention); everything else kept · mcq4
Limewater is a solution of Ca(OH)₂. Which classification and reason are correct?
A strong base — its metal is one of the heavier Group 2 members on the list. KEY
A weak base — the formula's two hydroxides make complete splitting harder.
A strong base — every compound that contains OH⁻ is strong.
A weak base — only the Group 1 hydroxides count as strong.
ABS-023 · medium · application · seq 8 · seed:U11-G2.pool[5] (ABS-023 gateItems[2]) — kept verbatim (no scanned-field collisions) · mcq4
Which pair contains one strong acid and one weak acid?
HI and HF KEY
HCl and HBr
H₂CO₃ and CH₃COOH
HNO₃ and H₂SO₄
ABS-025 · medium · application · seq 9 · seed:U11-G2.pool[9] (ABS-025 gateItems[0]) — freshened: 'adds water' dropped (own-lesson material token), 0.050 replaced (collides ABS-025 WE1 corpus) -> 9 M to 0.030 M; option logic kept · mcq4
A 9 M solution of HClO₄ is diluted until its concentration is 0.030 M. What has changed?
The solution is now dilute, and the acid is still strong. KEY
The solution is now dilute, and the acid is now weak.
Nothing has changed, because the same amount of acid is present.
The solution is unchanged in concentration, and the acid is now weak.
ABS-022 · medium · application · seq 10 · seed:U11-G2.pool[2] (ABS-022 gateItems[2]) — freshened: 'in water' -> 'when it dissolves' (own-lesson material token); options kept verbatim · mcq4
Formic acid, HCOOH, the acid in ant stings, ionizes only partially when it dissolves. Which equation represents its ionization correctly?
HCOOH ⇌ H⁺ + HCOO⁻ (double arrow) KEY
HCOOH → H⁺ + HCOO⁻ (single arrow)
HCOOH ⇌ HCOO⁺ + H⁻
No equation is needed — a weak acid does not ionize.
ABS-026 · medium · application · seq 11 · seed:U11-G2.pool[12] + demo_curated[0] (fig_index 780) — freshened: '0.10 M' dropped from the stem (corpus number) -> 'of equal concentration'; options and figure kept · mcq4
Panels A and B each show an acid solution of equal concentration, with eight dissolved units apiece. In panel A all eight units are drawn as separated ion pairs. In panel B seven units are whole molecules and one is a separated ion pair. Which panel shows the strong acid?
FIGURE (particle-diagram-panels · stimulus) — panels: [{"panel": "A", "description": "a beaker with 8 dissolved units, all 8 drawn as separated H⁺ (white circles) and anion pairs, every ion labeled"}, {"panel": … · style: "two side-by-side labeled beaker panels, matched particle counts, distinct particle kinds never touching"raw spec
{
"figureRequired": true,
"figureShape": "stimulus",
"figureSpec": {
"figureType": "particle-diagram-panels",
"panels": [
{
"panel": "A",
"description": "a beaker with 8 dissolved units, all 8 drawn as separated H⁺ (white circles) and anion pairs, every ion labeled"
},
{
"panel": "B",
"description": "a beaker with 8 dissolved units: 7 whole labeled acid molecules and 1 separated H⁺ (white circle) and anion pair"
}
],
"style": "two side-by-side labeled beaker panels, matched particle counts, distinct particle kinds never touching"
}
}
Panel A KEY
Panel B
Both panels
Neither panel
ABS-024 · medium · application · seq 12 · seed:U11-G2.pool[7] (ABS-024 gateItems[1]) — kept verbatim (formulas only in scanned fields; metal names live in feedback, which is not scanned) · mcq4
Which Group 2 hydroxide is NOT one of the common strong bases?
Bottle 1 holds 0.040 M KOH. Bottle 2 holds 7.5 M CH₃COOH, an acid that mixes with the solvent in any proportion. Which statement describes the two solutions?
Bottle 1 is a dilute strong-base solution; bottle 2 is a concentrated weak-acid solution. KEY
Bottle 1 is a dilute weak-base solution; bottle 2 is a concentrated strong-acid solution.
Bottle 2 is the stronger solution, because it holds far more per liter.
The two bottles cannot be compared, because one holds an acid and one holds a base.
ABS-022 · medium · application · seq 14 · seed:U11-G2.pool[1] (ABS-022 gateItems[1]) — freshened: solvent distractor reworded to drop 'water' (own-lesson material token); the other options kept · mcq4
Solution P was prepared from one of the listed strong bases; solution Q holds an unidentified base. Both are aqueous solutions of equal concentration, poured to equal volumes and tested with the identical bulb apparatus at the same temperature. Solution P lights the bulb brightly; solution Q lights it dimly. Which statement best explains the difference?
P's base splits completely into ions, while Q's splits only partially. KEY
P simply contains a larger amount of dissolved base than Q does.
Q's base produces no ions at all when it dissolves.
The liquid the bases are dissolved in conducts better in P than in Q.
ABS-023 · medium · application · seq 15 · fresh authored (assume-weak heuristic with the 'in this course' validity condition; unlisted acid H3PO4) · mcq4
Phosphoric acid, H₃PO₄, appears in a lab exercise. Which classification does this course assign it?
Assumed weak — it is not one of the six listed strong acids. KEY
Strong — its formula begins with H.
Strong — three hydrogens give it three times the splitting power.
It cannot be classified until a conductivity test is run.
Two students plan a conductivity test to decide whether lactic acid is strong or weak. Student 1 wants to compare a lactic acid solution against any HCl solution from the shelf. Student 2 insists both solutions must have the same concentration. Why is Student 2 right?
Because the ion count also depends on the amount dissolved — equal concentrations isolate the fraction ionized. KEY
Because conductivity bulbs give a reliable reading only when a solution is exactly 1 M.
Because a strong acid conducts electricity only when its solution is concentrated.
Because the two solutions must also be tested using exactly equal volumes of liquid in their beakers.
ABS-025 · hard · transfer · seq 17 · seed:U11-G2.pool[11] (ABS-025 gateItems[2]) — freshened: 'sodium hydroxide' -> 'NaOH' (material token, formula convention), 0.010 -> 0.0050 and threshold foil 0.001 -> 0.0001 (number ledger) · mcq4
A student writes: 'Our 0.0050 M NaOH must be a weak base — look how little is in it.' Which correction fixes the claim?
The solution is dilute, not weak — NaOH ionizes completely at any concentration. KEY
No correction is needed — a base this dilute really is weak.
The claim uses the wrong number — a base only becomes weak below 0.0001 M.
The solution is weak AND dilute — the two labels always travel together.
ABS-023 · hard · transfer · seq 18 · seed:U11-G2.pool[4] (ABS-023 gateItems[1]) — kept verbatim (no scanned-field collisions) · mcq4
A student reasons: 'HNO₂ must be strong, because HNO₃ is on the list and the two formulas differ by just one oxygen.' Which correction is right?
Membership is exact — HNO₂ is not on the list, so it is assumed weak. KEY
The student is right — acids built from the same element share their strength.
HNO₂ is strong, but only when its solution is concentrated.
Neither acid is strong, because the six strong acids are all binary.
ABS-024 · hard · transfer · seq 19 · seed:U11-G2.pool[8] (ABS-024 gateItems[2]) — freshened: 'Household ammonia' stem and 'Ammonia is...' key reworded to formula convention (own-lesson material token 'ammonia'); option logic kept · mcq4
A glass-cleaner concentrate contains the base NH₃. A student says: 'This cleaner works powerfully, so NH₃ must be a strong base.' Which correction is right?
NH₃ is the common weak base — cleaning power is not what strong means. KEY
The claim is right — bases used in cleaning products are all strong.
NH₃ must be a strong base because it dissolves completely in the concentrate.
NH₃ is strong when concentrated and weak when dilute.
ABS-026 · hard · transfer · seq 20 · seed:U11-G2.pool[13] + demo_curated[1] (fig_index 781) — kept verbatim (0.0010 originates in this gate item, not the corpus; unique in the gate's number ledger) · mcq4
The figure shows a particle diagram of a 0.0010 M nitric acid solution, HNO₃. Only three dissolved units appear, and all three are drawn as separated ion pairs. What does the diagram show?
FIGURE (particle-diagram-solution · stimulus) — panels: [{"panel": "single", "description": "a beaker outline containing only 3 dissolved units, each drawn as a separated H⁺ ion (white circle) and NO₃⁻ ion pair, w… · style: "clean textbook particulate view emphasizing the sparse particle count"raw spec
{
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"figureShape": "stimulus",
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"figureType": "particle-diagram-solution",
"panels": [
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"panel": "single",
"description": "a beaker outline containing only 3 dissolved units, each drawn as a separated H⁺ ion (white circle) and NO₃⁻ ion pair, with wide empty space between them; every ion labeled; distinct particle kinds never touching"
}
],
"style": "clean textbook particulate view emphasizing the sparse particle count"
}
}
The solution is dilute, and the acid is strong — every dissolved unit has split. KEY
The acid is weak — three particles is far too few for a strong acid.
The solution is concentrated — the ions have spread across the whole beaker.
The diagram is drawn wrongly — a dilute acid cannot be fully ionized.
ABS-026 · hard · application · seq 21 · fresh authored FRQ (capstone: fraction-ionized evidence for two unnamed acids + the dilute-not-weak boundary; prod_seeds empty) · frq
Two different acids are dissolved, each at 1 M. Laboratory measurements report:
Solution X — 98% of its dissolved units are split into ions.
Solution Y — 3% of its dissolved units are split into ions.
Two different acids are dissolved, each at 1 M. Laboratory measurements report:
Solution X — 98% of its dissolved units are split into ions.
Solution Y — 3% of its dissolved units are split into ions.
(a) Classify the acid in solution X as strong or weak, citing the measurement.
(b) Classify the acid in solution Y as strong or weak, citing the measurement.
(c) A third bottle holds solution Z at only 0.045 M. A particle diagram of Z shows five dissolved units, and every one of them is split into ions. A student calls Z 'weak, because it holds so few particles.' Explain the student's error and give the correct description of Z.
Part a. Classify the acid in solution X as strong or weak, citing the measurement.
Model: Strong. At 1 M, 98% of X's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
Part b. Classify the acid in solution Y as strong or weak, citing the measurement.
Model: Weak. Only 3% of Y's dissolved units are split; nearly all stay whole, so Y's acid ionizes only partially — the definition of weak. Since both solutions are 1 M, the different fractions must come from the acids themselves.
Part c. A third bottle holds solution Z at only 0.045 M. A particle diagram of Z shows five dissolved units, and every one of them is split into ions. A student calls Z 'weak, because it holds so few particles.' Explain the student's error and give the correct description of Z.
Model: The student read the number of dissolved particles, which reports concentration, as if it reported strength. Five units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here five out of five, complete ionization. Z is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
Full model answer. (a) Strong. At 1 M, 98% of X's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
(b) Weak. Only 3% of Y's dissolved units are split; nearly all stay whole, so Y's acid ionizes only partially — the definition of weak. Since both solutions are 1 M, the different fractions must come from the acids themselves.
(c) The student read the number of dissolved particles, which reports concentration, as if it reported strength. Five units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here five out of five, complete ionization. Z is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
Which quantity does the label 'strong' report about an acid?
The fraction of its dissolved particles that splits into ions. KEY
The number of moles of acid dissolved per liter of solution.
The total count of acid particles in the container.
How rapidly the acid attacks metals.
ABS-024 · easy · recall · seq 4 · parallel fresh instance (seq-4 rotation: Group 1 member pick with acid foils; no strong/weak status of another form-B item revealed) · mcq4
In one acid's aqueous solution, every dissolved unit has split into ions; none remains intact in the solution. How is this acid classified on the strength scale?
Strong KEY
Weak
Dilute
Concentrated
ABS-026 · medium · application · seq 6 · parallel fresh instance (seq-6 rotation: strong verdict from a fraction-ionized datum; unnamed acid keeps the data load-bearing) · mcq4
A handbook entry says a 2 M solution of a certain acid is 96% ionized. What does this datum show about the acid?
It is strong — nearly every dissolved unit has split into ions. KEY
It is weak — anything under total ionization counts as weak.
It is concentrated, and that is all the number reports.
No verdict is possible — percent data applies only to bases.
ABS-024 · medium · application · seq 7 · parallel fresh instance of seed pool[6] (seq-7 rotation: member Sr(OH)2; KOH avoided on form B because seq 9 dilutes KOH) · mcq4
A lab bottle is labeled Sr(OH)₂. Which classification and reason are correct?
A strong base — its metal is one of the heavier Group 2 members on the list. KEY
A weak base — its two hydroxide units are too heavy to separate fully.
A strong base — every formula that contains OH is strong.
A weak base — only the Group 1 hydroxides count as strong.
ABS-023 · medium · application · seq 8 · parallel fresh instance of seed pool[5] (seq-8 rotation: pair HI/HNO2; foils avoid form-B instances CH3COOH and HCOOH used at seq 17/18) · mcq4
Which pair below puts a strong acid together with a weak acid?
HI and HNO₂ KEY
HCl and H₂SO₄
HF and H₂CO₃
HNO₃ and HClO₄
ABS-025 · medium · application · seq 9 · parallel fresh instance of seed pool[9] (seq-9 rotation: strong BASE diluted) · mcq4
An 8 M solution of KOH is diluted until its concentration is 0.025 M. What has changed?
The solution is now dilute, and the base is still strong. KEY
The solution is now dilute, and the base is now weak.
Nothing has changed, because the same amount of base is present.
The solution is unchanged in concentration, and the base is now weak.
ABS-022 · medium · application · seq 10 · parallel fresh instance of seed pool[2] (seq-10 rotation: complete-ionization polarity, single arrow) · mcq4
HBr ionizes completely when it dissolves. Which equation represents its ionization correctly?
HBr → H⁺ + Br⁻ (single arrow) KEY
HBr ⇌ H⁺ + Br⁻ (double arrow)
HBr → H⁻ + Br⁺
No equation is needed — complete ionization is not a change worth recording.
ABS-026 · medium · application · seq 11 · parallel fresh instance of seed pool[12] (seq-11 rotation: 10-unit panels, weak asked, panel order swapped) · mcq4
Panels X and Y each show an acid solution at the same concentration, with ten dissolved units apiece. In panel X nine units are whole molecules and one is a separated ion pair. In panel Y all ten units are separated ion pairs. Which panel shows the weak acid?
FIGURE (particle-diagram-panels · stimulus) — panels: [{"panel": "X", "description": "a beaker with 10 dissolved units: 9 whole labeled acid molecules and 1 separated H⁺ and anion pair"}, {"panel": "Y", "descrip… · style: "two side-by-side labeled beaker panels, matched particle counts, distinct particle kinds never touching"raw spec
{
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{
"panel": "Y",
"description": "a beaker with 10 dissolved units, all 10 drawn as separated H⁺ and anion pairs, every ion labeled"
}
],
"style": "two side-by-side labeled beaker panels, matched particle counts, distinct particle kinds never touching"
}
}
Panel X KEY
Panel Y
Both panels
Neither panel
ABS-024 · medium · application · seq 12 · parallel fresh instance of seed pool[7] (seq-12 rotation: claim-repair framing of the Mg(OH)2 list boundary) · mcq4
A student writes: 'Ca(OH)₂, Sr(OH)₂, and Ba(OH)₂ are strong, so Mg(OH)₂ — another Group 2 hydroxide — must also be strong.' What is the right correction?
The list names only the heavier Group 2 hydroxides, and Mg(OH)₂ is not one of them. KEY
The reasoning holds — every one of the Group 2 hydroxides shares the same strength rating.
Mg(OH)₂ is strong only in concentrated solutions.
None of the Group 2 hydroxides is strong — only Group 1 counts.
Solution 1 was prepared from one of the listed strong acids; solution 2 holds an unidentified acid. Both are aqueous solutions of equal concentration, poured to equal volumes and tested with the identical bulb apparatus at the same temperature. Solution 1 lights the bulb brightly; solution 2 lights it only dimly. Which statement best explains the difference?
Solution 1's acid splits completely into ions, while solution 2's splits only partially. KEY
Solution 1 simply contains a larger amount of dissolved acid than solution 2 does.
Solution 2's acid produces no ions at all when it dissolves.
The liquid the acids are dissolved in conducts better in solution 1 than in solution 2.
To decide whether oxalic acid is strong or weak, a student plans to compare a 2 M oxalic acid solution with a 1 M HCl solution in a conductivity tester. What is wrong with the plan?
The concentrations differ, so a brightness difference could come from the amount dissolved rather than the fraction ionized. KEY
Nothing is wrong — any two acid solutions can always be compared directly, whatever their concentrations may be.
HCl is the wrong reference — the standard must be a weak acid.
The volumes must match, not the concentrations.
ABS-025 · hard · transfer · seq 17 · parallel fresh instance of seed pool[11] (seq-17 rotation: concentrated weak acid called strong) · mcq4
A student writes: 'This 9.5 M CH₃COOH solution must hold a strong acid — look how much is packed in.' Which correction fixes the claim?
The solution is concentrated, not strong — CH₃COOH stays weak at every concentration. KEY
No correction is needed — packing in more acid does make it strong.
The claim needs a bigger number — an acid counts as strong only above 15 M.
The solution is strong AND concentrated — the two labels always travel together.
ABS-023 · hard · transfer · seq 18 · parallel fresh instance of seed pool[4] (seq-18 rotation: H-first pattern-to-strength trap, HCOOH) · mcq4
A student claims: 'HCOOH must be one of the strong acids — its formula is written with H first.' Which correction is right?
H written first marks it as an ACID — strength comes only from the list of six, and HCOOH is not on it. KEY
The student is right — every acid formula that begins with H belongs among the strong acids.
HCOOH is strong, but only in concentrated solutions.
HCOOH is not an acid at all — true acid formulas contain no C.
ABS-024 · hard · transfer · seq 19 · parallel fresh instance of seed pool[8] (seq-19 rotation: right-classification-wrong-reason, NaOH) · mcq4
A drain-cleaner label says its NaOH 'cuts through clogs in minutes.' A student concludes NaOH is a strong base BECAUSE it cleans so aggressively. Which evaluation is right?
Right classification, wrong reason — NaOH is strong because every dissolved unit splits into ions, not because it cleans hard. KEY
Both are right — cutting through clogs aggressively is exactly what chemists mean when they call a base strong in chemistry.
Both are wrong — NaOH is the common weak base.
The classification is wrong — cleaners are sold too dilute to be strong.
ABS-026 · hard · transfer · seq 20 · parallel fresh instance of seed pool[13] (seq-20 rotation: concentrated-weak grid corner, unnamed acid keeps the data load-bearing) · mcq4
The figure shows a particle diagram of a 5.5 M acid solution. Twelve dissolved units appear: eleven are whole molecules and one is a separated ion pair. What does the diagram show?
FIGURE (particle-diagram-solution · stimulus) — panels: [{"panel": "single", "description": "a beaker outline containing 12 dissolved units: 11 whole labeled acid molecules crowded through the liquid and 1 separat… · style: "clean textbook particulate view emphasizing the crowded particle count"raw spec
{
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}
],
"style": "clean textbook particulate view emphasizing the crowded particle count"
}
}
The solution is concentrated, and the acid is weak — only a small fraction of the units has split. KEY
The acid is strong — twelve dissolved units is a very large number for a single beaker of solution.
The solution is dilute — most of the units are still whole.
The diagram is drawn wrongly — a concentrated acid must be fully ionized.
ABS-026 · hard · application · seq 21 · parallel fresh FRQ instance (seq-21 rotation: labels P/Q/R, values 2 M / 95% / 4% / 0.0075 M / four units) · frq
Two different acids are dissolved, each at 2 M. Laboratory measurements report:
Solution P — 95% of its dissolved units are split into ions.
Solution Q — 4% of its dissolved units are split into ions.
Two different acids are dissolved, each at 2 M. Laboratory measurements report:
Solution P — 95% of its dissolved units are split into ions.
Solution Q — 4% of its dissolved units are split into ions.
(a) Classify the acid in solution P as strong or weak, citing the measurement.
(b) Classify the acid in solution Q as strong or weak, citing the measurement.
(c) A third bottle holds solution R at only 0.0075 M. A particle diagram of R shows four dissolved units, and every one of them is split into ions. A student calls R 'weak, because there is hardly anything in it.' Explain the student's error and give the correct description of R.
Part a. Classify the acid in solution P as strong or weak, citing the measurement.
Model: Strong. At 2 M, 95% of P's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
Part b. Classify the acid in solution Q as strong or weak, citing the measurement.
Model: Weak. Only 4% of Q's dissolved units are split; nearly all stay whole, so Q's acid ionizes only partially — the definition of weak. Since both solutions are 2 M, the different fractions must come from the acids themselves.
Part c. A third bottle holds solution R at only 0.0075 M. A particle diagram of R shows four dissolved units, and every one of them is split into ions. A student calls R 'weak, because there is hardly anything in it.' Explain the student's error and give the correct description of R.
Model: The student read the number of dissolved particles, which reports concentration, as if it reported strength. Four units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here four out of four, complete ionization. R is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
Full model answer. (a) Strong. At 2 M, 95% of P's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
(b) Weak. Only 4% of Q's dissolved units are split; nearly all stay whole, so Q's acid ionizes only partially — the definition of weak. Since both solutions are 2 M, the different fractions must come from the acids themselves.
(c) The student read the number of dissolved particles, which reports concentration, as if it reported strength. Four units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here four out of four, complete ionization. R is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
Strength and concentration answer two different questions about a solution. Which pairing is correct?
Strength: what fraction of the dissolved particles ionizes. Concentration: how much is dissolved per liter. KEY
Strength: how much is dissolved per liter. Concentration: what fraction of the particles ionizes.
Strength: how much is dissolved. Concentration: how brightly the solution conducts.
The two words report the same quantity, measured in different units.
ABS-024 · easy · recall · seq 4 · parallel fresh instance (seq-4 rotation: heavier Group 2 member pick; NH3 foil is safe on form C — no form-C item is keyed on NH3's status) · mcq4
An acid dissolves to form an aqueous solution, and of its many dissolved particles only a few have split into ions, while the rest stay intact. How is this acid classified on the strength scale?
Weak KEY
Strong
Dilute
Concentrated
ABS-026 · medium · application · seq 6 · parallel fresh instance (seq-6 rotation: weak verdict, citric acid, 0.35 M / ~2%) ; solW3+reblind3: instance freshened citric->lactic acid (Ka-exact 2.0% at 0.35 M) · mcq4
A handbook reports that a 0.35 M solution of lactic acid is about 2% ionized. What does this datum show about lactic acid?
It is weak — nearly all of its dissolved molecules stay whole. KEY
It is strong — any measurable ionization counts as complete.
It is dilute — 2% means the solution holds almost no acid.
Nothing — lactic acid must first be compared with a known strong acid.
ABS-024 · medium · application · seq 7 · parallel fresh instance of seed pool[6] (seq-7 rotation: Group 1 member KOH with its taught everyday context) · mcq4
Liquid hand soaps are made with the base KOH. Which classification and reason are correct?
A strong base — it is one of the Group 1 hydroxides on the list. KEY
A weak base — its formula carries only a single OH unit.
A strong base — every base used to make soap is strong.
A weak base — only the heavier Group 2 hydroxides are strong.
In which pair is exactly one of the two acids strong?
HCl and HNO₂ KEY
HI and HNO₃
H₂CO₃ and HCOOH
H₂SO₄ and HBr
ABS-025 · medium · application · seq 9 · parallel fresh instance of seed pool[9] (seq-9 rotation: WEAK acid diluted — stays weak; CH3COOH kept out of every other form-C scanned field) · mcq4
A 6 M solution of CH₃COOH is diluted until its concentration is 0.035 M. What has changed?
The solution is now dilute, and the acid is still weak. KEY
The solution is now dilute, and the acid is now strong — the extra room lets its particles split.
Nothing has changed, because the same amount of acid is present.
The solution is unchanged in concentration, and the acid is now strong.
ABS-022 · medium · application · seq 10 · parallel fresh instance of seed pool[2] (seq-10 rotation: benzoic acid; chosen so no form-C item's key depends on its status — the partial ionization is stated in the stem) · mcq4
Benzoic acid, C₆H₅COOH, a food preservative, ionizes only partially when it dissolves. Which equation represents its ionization correctly?
C₆H₅COOH ⇌ H⁺ + C₆H₅COO⁻ (double arrow) KEY
C₆H₅COOH → H⁺ + C₆H₅COO⁻ (single arrow)
C₆H₅COOH ⇌ C₆H₅COO⁺ + H⁻
No equation is needed — a weak acid does not ionize.
Panels P and Q each show an acid solution at the same concentration, with four dissolved units apiece. In panel P all four units are separated ion pairs. In panel Q three units are whole molecules and one is a separated ion pair. Which panel shows the strong acid?
FIGURE (particle-diagram-panels · stimulus) — panels: [{"panel": "P", "description": "a beaker with 4 dissolved units, all 4 drawn as separated H⁺ and anion pairs, every ion labeled"}, {"panel": "Q", "descriptio… · style: "two side-by-side labeled beaker panels, matched particle counts, distinct particle kinds never touching"raw spec
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"panel": "Q",
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}
],
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}
Panel P KEY
Panel Q
Both panels
Neither panel
ABS-024 · medium · application · seq 12 · parallel fresh instance of seed pool[7] (seq-12 rotation: statement-selection framing of the Mg(OH)2 boundary) · mcq4
Which statement about Mg(OH)₂ is correct?
It is not one of the common strong bases — the list's Group 2 members are Ca, Sr, and Ba. KEY
It is strong — every single Group 2 hydroxide, light or heavy, is on the list.
It is strong — any formula containing OH marks a strong base.
Bottle 1 holds 11 M HCl. Bottle 2 holds 0.055 M HOCl, a weak acid used in pool sanitizing. Which statement describes the two solutions?
Bottle 1 is a concentrated strong-acid solution; bottle 2 is a dilute weak-acid solution. KEY
Bottle 1 is a concentrated weak-acid solution; bottle 2 is a dilute strong-acid solution.
Bottle 1's acid is strong BECAUSE its solution is concentrated.
The bottles cannot be labeled, because their concentrations differ.
ABS-022 · medium · application · seq 14 · parallel fresh instance of seed pool[1] (seq-14 rotation: labels M/N, bright solution named second) · mcq4
Solution N was prepared from one of the listed strong bases; solution M holds an unidentified base. Both are aqueous solutions of equal concentration, poured to equal volumes and tested with the identical bulb apparatus at the same temperature. Solution N lights the bulb brightly, while solution M lights it only dimly. Which statement best explains the difference?
N's base splits completely into ions, while M's splits only partially. KEY
N simply contains a larger amount of dissolved base than M does.
M's base produces no ions at all when it dissolves.
The liquid the bases are dissolved in conducts better in N than in M.
ABS-023 · medium · application · seq 15 · parallel fresh instance (seq-15 rotation: unlisted acid HBrO with the HBr look-alike foil) · mcq4
Which classification does this course assign to hypobromous acid, HBrO?
Assumed weak — it is not one of the six listed strong acids. KEY
Strong — its formula starts with H.
Strong — HBr is on the list, and HBrO merely adds one O.
It cannot be classified in this course without a particle diagram.
A student will use a conductivity bulb to decide whether malic acid is strong or weak. Which testing plan gives a valid answer?
Compare the malic acid solution with a known strong acid prepared at a matching concentration. KEY
Compare it with any strong acid solution — concentration does not matter for bulbs.
Test the malic acid solution alone — a dim bulb by itself proves weakness.
Compare equal VOLUMES of the two solutions, whatever their concentrations.
ABS-025 · hard · transfer · seq 17 · parallel fresh instance of seed pool[11] (seq-17 rotation: dilute strong ACID called weak) · mcq4
A student writes: '0.0025 M HI must be a weak acid — there is almost nothing in the bottle.' Which correction fixes the claim?
The solution is dilute, not weak — HI ionizes completely at any concentration. KEY
No correction is needed — an acid this dilute really is weak.
HI is weak for a different reason — binary acids are all weak.
The solution is weak AND dilute — the two labels mean the same thing.
ABS-023 · hard · transfer · seq 18 · parallel fresh instance of seed pool[4] (seq-18 rotation: halogen-family generalization trap, HF boundary) · mcq4
A student reasons: 'HCl, HBr, and HI are all strong, so the fourth halogen acid, HF, must be strong too.' Which correction is right?
The list is exact — HF is the halogen acid left off, so it is assumed weak. KEY
The student is right — the four halogen acids stand or fall together.
HF is strong, but only when its solution is concentrated.
None of the halogen acids is strong — the six are all oxyacids.
ABS-024 · hard · transfer · seq 19 · parallel fresh instance of seed pool[8] (seq-19 rotation: household-use inference, Ca(OH)2 pickling lime) · mcq4
Pickling lime is Ca(OH)₂, sold for use in food preparation. A student argues: 'If it goes into food, Ca(OH)₂ must be a weak base.' Which correction is right?
Ca(OH)₂ is one of the heavier Group 2 strong bases — household use is not what strength measures. KEY
The claim is right — anything sold for use in a kitchen has to be made from a weak base, never a strong one.
Ca(OH)₂ is strong only when it is dissolved in large amounts.
Ca(OH)₂ is the common weak base.
ABS-026 · hard · transfer · seq 20 · parallel fresh instance of seed pool[13] (seq-20 rotation: dilute-weak grid corner, unnamed acid) · mcq4
The figure shows a particle diagram of a 0.0060 M acid solution. Five dissolved units appear: four are whole molecules and one is a separated ion pair. What does the diagram show?
FIGURE (particle-diagram-solution · stimulus) — panels: [{"panel": "single", "description": "a beaker outline containing 5 dissolved units with wide empty space between them: 4 whole labeled acid molecules and 1 s… · style: "clean textbook particulate view emphasizing the sparse particle count"raw spec
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The solution is dilute, and the acid is weak — few units are dissolved, and only a fraction of them has split. KEY
The acid is strong — at least one unit has fully ionized.
The solution is concentrated — the units are spread across the whole drawing.
The two questions cannot both be answered from one single diagram — each picture can only hold one fact.
Two different acids are dissolved, each at 3 M. Laboratory measurements report:
Solution F — 94% of its dissolved units are split into ions.
Solution G — 6% of its dissolved units are split into ions.
Two different acids are dissolved, each at 3 M. Laboratory measurements report:
Solution F — 94% of its dissolved units are split into ions.
Solution G — 6% of its dissolved units are split into ions.
(a) Classify the acid in solution F as strong or weak, citing the measurement.
(b) Classify the acid in solution G as strong or weak, citing the measurement.
(c) A third bottle holds solution H at only 0.0040 M. A particle diagram of H shows seven dissolved units, and every one of them is split into ions. A student calls H 'weak, because so few particles are in the beaker.' Explain the student's error and give the correct description of H.
Part a. Classify the acid in solution F as strong or weak, citing the measurement.
Model: Strong. At 3 M, 94% of F's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
Part b. Classify the acid in solution G as strong or weak, citing the measurement.
Model: Weak. Only 6% of G's dissolved units are split; nearly all stay whole, so G's acid ionizes only partially — the definition of weak. Since both solutions are 3 M, the different fractions must come from the acids themselves.
Part c. A third bottle holds solution H at only 0.0040 M. A particle diagram of H shows seven dissolved units, and every one of them is split into ions. A student calls H 'weak, because so few particles are in the beaker.' Explain the student's error and give the correct description of H.
Model: The student read the number of dissolved particles, which reports concentration, as if it reported strength. Seven units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here seven out of seven, complete ionization. H is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
Full model answer. (a) Strong. At 3 M, 94% of F's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
(b) Weak. Only 6% of G's dissolved units are split; nearly all stay whole, so G's acid ionizes only partially — the definition of weak. Since both solutions are 3 M, the different fractions must come from the acids themselves.
(c) The student read the number of dissolved particles, which reports concentration, as if it reported strength. Seven units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here seven out of seven, complete ionization. H is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
All of its dissolved particles split into ions. KEY
Most of its dissolved particles stay whole in the solution.
A very large amount of it is dissolved per liter.
It reacts instantly with every metal it touches.
ABS-023 · easy · recall · seq 2 · parallel fresh instance of seed pool[3] (seq-2 rotation: tested member HI; the HF foil is safe — seq 10 states HF's partial ionization in its own stem) · mcq4
Which of these four acids ionizes completely in solution?
Which quantity is fixed by the identity of the acid, no matter how the solution was mixed?
Its strength — the fraction of dissolved particles that ionizes. KEY
Its concentration — the amount of acid that was dissolved in each liter of solution.
How brightly it would light a conductivity bulb.
The volume of solution in the container.
ABS-024 · easy · recall · seq 4 · parallel fresh instance (seq-4 rotation: Group 2 member pick with acid foils; NH3 and Mg(OH)2 kept out so seq 12/13 are not pre-answered) · mcq4
Which of these substances belongs on the strong-base list?
Ca(OH)₂ KEY
HNO₃
CH₃COOH
HBrO
ABS-022 · medium · application · seq 5 · parallel fresh instance of seed pool[0] (seq-5 rotation: base family, complete-ionization extent) · mcq4
A base dissolves to form an aqueous solution, and no intact units of it remain — every dissolved unit is split into ions. How is this base classified on the strength scale?
Strong KEY
Weak
Concentrated
Dilute
ABS-026 · medium · application · seq 6 · parallel fresh instance (seq-6 rotation: strong verdict, unnamed acid, with the data-beats-roster foil) · mcq4
A 0.45 M solution of an unfamiliar acid is measured to be 97% ionized. What does this measurement show?
The acid is strong — nearly every dissolved unit has split into ions. KEY
The acid is weak — it must reach every last unit to count as strong.
The solution is concentrated — 97% is a very large amount per liter.
Nothing — an acid that is not one of the memorized six cannot be classified.
ABS-024 · medium · application · seq 7 · parallel fresh instance of seed pool[6] (seq-7 rotation: member Ba(OH)2) · mcq4
Which classification and reason fit Ba(OH)₂?
A strong base — it is one of the heavier Group 2 hydroxides on the list. KEY
A weak base — its formula carries two OH units, which slows the splitting.
A strong base — every substance whose formula ends in OH is strong.
A weak base — Group 2 metals make weak bases; only Group 1 makes strong ones.
ABS-023 · medium · application · seq 8 · parallel fresh instance of seed pool[5] (seq-8 rotation: pair HNO3/CH3COOH; foils avoid H2SO3 so the seq-18 twin trap is not pre-answered) · mcq4
Which pair contains exactly one strong acid?
HNO₃ and CH₃COOH KEY
HCl and HClO₄
HOCl and HBrO
HBr and H₂SO₄
ABS-025 · medium · application · seq 9 · parallel fresh instance of seed pool[9] (seq-9 rotation: strong acid HCl, 12 M -> 0.024 M) · mcq4
A 12 M solution of HCl is diluted until its concentration is 0.024 M. What has changed?
The solution is now dilute, and the acid is still strong. KEY
The solution is now dilute, and the acid is now weak.
Nothing has changed, because the same amount of acid is present.
The solution is unchanged in concentration, and the acid is now weak.
ABS-022 · medium · application · seq 10 · parallel fresh instance of seed pool[2] (seq-10 rotation: HF; its partial ionization is stated in the stem, consistent with the seq-2 foil) · mcq4
HF ionizes only partially when it dissolves. Which equation represents its ionization correctly?
HF ⇌ H⁺ + F⁻ (double arrow) KEY
HF → H⁺ + F⁻ (single arrow)
HF ⇌ F⁺ + H⁻
No equation is needed — a weak acid does not ionize.
Panels J and K each show an acid solution at the same concentration, with nine dissolved units apiece. In panel J eight units are whole molecules and one is a separated ion pair. In panel K all nine units are separated ion pairs. Which panel shows the weak acid?
FIGURE (particle-diagram-panels · stimulus) — panels: [{"panel": "J", "description": "a beaker with 9 dissolved units: 8 whole labeled acid molecules and 1 separated H⁺ and anion pair"}, {"panel": "K", "descript… · style: "two side-by-side labeled beaker panels, matched particle counts, distinct particle kinds never touching"raw spec
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Panel J KEY
Panel K
Both panels
Neither panel
ABS-024 · medium · application · seq 12 · parallel fresh instance of seed pool[7] (seq-12 rotation: pick-the-correct-set framing of the Mg(OH)2 boundary) · mcq4
Which set names the Group 2 hydroxides that count among the common strong bases?
Ca(OH)₂, Sr(OH)₂, Ba(OH)₂ KEY
Mg(OH)₂, Ca(OH)₂, Sr(OH)₂
Mg(OH)₂, Sr(OH)₂, Ba(OH)₂
Every Group 2 hydroxide, Mg(OH)₂ included
ABS-025 · medium · application · seq 13 · parallel fresh instance of seed pool[10] (seq-13 rotation: dilute weak base + concentrated strong base) · mcq4
Bottle 1 holds 0.036 M NH₃. Bottle 2 holds 6.8 M NaOH. Which statement describes the two solutions?
Bottle 1 is a dilute weak-base solution; bottle 2 is a concentrated strong-base solution. KEY
Bottle 1 is a dilute strong-base solution; bottle 2 is a concentrated weak-base solution.
Bottle 2's base counts as strong because so much of it is dissolved.
The bottles cannot be labeled without conductivity data.
ABS-022 · medium · application · seq 14 · parallel fresh instance of seed pool[1] (seq-14 rotation: acid family, labels G/H, dim solution named first) · mcq4
Solution H was prepared from one of the listed strong acids; solution G holds an unidentified acid. Both are aqueous solutions of equal concentration, poured to equal volumes and tested with the identical bulb apparatus at the same temperature. Solution H lights the bulb brightly, while solution G lights it dimly. Which statement best explains the difference?
H's acid splits completely into ions, while G's splits only partially. KEY
H simply contains a larger amount of dissolved acid than G does.
G's acid produces no ions at all when it dissolves.
The liquid the acids are dissolved in conducts better in H than in G.
Which classification does this course assign to boric acid, H₃BO₃?
Assumed weak — it is not one of the six listed strong acids. KEY
Strong — its formula begins with H.
Strong — acids with three H atoms ionize three times as completely.
It cannot be classified until a conductivity comparison is run.
ABS-026 · medium · application · seq 16 · parallel fresh instance of seed pool[14] (seq-16 rotation: why-the-match-works framing, butanoic acid vs HBr) · mcq4
To test whether butanoic acid is strong or weak, a student compares its solution against an HBr solution of matched concentration, using the same bulb setup for both; the butanoic acid bulb glows dimly while the HBr bulb glows brightly. Why does the matched concentration make this a valid strength comparison?
With the amounts per liter matched, the brightness difference can come only from the fraction of particles ionized. KEY
Because conductivity bulbs give trustworthy readings only when both solutions hold the same amount of acid.
Because a strong acid conducts only when its solution is concentrated.
Because equal concentrations make the two acids chemically identical.
ABS-025 · hard · transfer · seq 17 · parallel fresh instance of seed pool[11] (seq-17 rotation: dilute strong base LiOH called weak) · mcq4
A student writes: '0.0090 M LiOH must be a weak base — hardly any of it is dissolved.' Which correction fixes the claim?
The solution is dilute, not weak — LiOH ionizes completely at any concentration. KEY
No correction is needed — a base this dilute really is weak.
LiOH is weak for a different reason — the Group 1 hydroxides are all weak.
The claim should say weak AND dilute — the two labels mean the same thing.
ABS-023 · hard · transfer · seq 18 · parallel fresh instance of seed pool[4] (seq-18 rotation: H2SO3/H2SO4 twin trap) · mcq4
A student reasons: 'H₂SO₃ must be strong — it is almost identical to H₂SO₄, which is on the list.' Which correction is right?
Membership is exact — H₂SO₃ is not on the list, so it is assumed weak. KEY
The student is right — two acids this similar must share their strength.
H₂SO₃ is strong, but only when its solution is concentrated.
Neither acid is strong — acids with two H atoms are always weak.
ABS-024 · hard · transfer · seq 19 · parallel fresh instance of seed pool[8] (seq-19 rotation: familiarity inference, Sr(OH)2; the seq-12 roster set does state Sr membership — taught recall, flagged for blind review like the seed form's A7/A12 overlap) · mcq4
Sr(OH)₂ rarely appears in household products. A student concludes it must be a weak base, 'since nobody uses it for cleaning.' Which correction is right?
Sr(OH)₂ is one of the heavier Group 2 strong bases — household familiarity is not what strength measures. KEY
The claim is right — every base that is genuinely strong shows up somewhere on supermarket cleaning shelves.
Sr(OH)₂ would be strong only if it were sold in concentrated form.
Sr(OH)₂ is the common weak base.
ABS-026 · hard · transfer · seq 20 · parallel fresh instance of seed pool[13] (seq-20 rotation: dilute-strong BASE, KOH diagram) · mcq4
The figure shows a particle diagram of a 0.0035 M KOH solution. Four dissolved units appear, and every one is split into a metal ion and a hydroxide ion. What does the diagram show?
FIGURE (particle-diagram-solution · stimulus) — panels: [{"panel": "single", "description": "a beaker outline containing only 4 dissolved units, each drawn as a separated K⁺ ion and OH⁻ ion pair, with wide empty s… · style: "clean textbook particulate view emphasizing the sparse particle count"raw spec
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The solution is dilute, and the base is strong — every dissolved unit has split. KEY
The base is weak — four particles is far too few for a strong base.
The solution is concentrated — the ions have spread across the whole beaker.
The diagram is drawn wrongly — a dilute base cannot be fully ionized.
Two different acids are dissolved, each at 4 M. Laboratory measurements report:
Solution J — 93% of its dissolved units are split into ions.
Solution K — 5% of its dissolved units are split into ions.
Two different acids are dissolved, each at 4 M. Laboratory measurements report:
Solution J — 93% of its dissolved units are split into ions.
Solution K — 5% of its dissolved units are split into ions.
(a) Classify the acid in solution J as strong or weak, citing the measurement.
(b) Classify the acid in solution K as strong or weak, citing the measurement.
(c) A third bottle holds solution L at only 0.0065 M. A particle diagram of L shows eight dissolved units, and every one of them is split into ions. A student calls L 'weak, because the beaker holds so little.' Explain the student's error and give the correct description of L.
Part a. Classify the acid in solution J as strong or weak, citing the measurement.
Model: Strong. At 4 M, 93% of J's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
Part b. Classify the acid in solution K as strong or weak, citing the measurement.
Model: Weak. Only 5% of K's dissolved units are split; nearly all stay whole, so K's acid ionizes only partially — the definition of weak. Since both solutions are 4 M, the different fractions must come from the acids themselves.
Part c. A third bottle holds solution L at only 0.0065 M. A particle diagram of L shows eight dissolved units, and every one of them is split into ions. A student calls L 'weak, because the beaker holds so little.' Explain the student's error and give the correct description of L.
Model: The student read the number of dissolved particles, which reports concentration, as if it reported strength. Eight units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here eight out of eight, complete ionization. L is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
Full model answer. (a) Strong. At 4 M, 93% of J's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
(b) Weak. Only 5% of K's dissolved units are split; nearly all stay whole, so K's acid ionizes only partially — the definition of weak. Since both solutions are 4 M, the different fractions must come from the acids themselves.
(c) The student read the number of dissolved particles, which reports concentration, as if it reported strength. Eight units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here eight out of eight, complete ionization. L is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
'Concentrated' and 'dilute' are opposite ends of the scale that reports how much is dissolved per liter. Which pair of labels sits at the ends of the second scale — the one that reports a property of the dissolved acid or base itself?
'Strong' and 'weak' — the fraction of dissolved particles that ionizes. KEY
'Bright' and 'dim' — the two readings a conductivity bulb can give in a test.
'Acid' and 'base' — the two chemical families.
'Large' and 'small' — the total amount stored in the bottle.
ABS-024 · easy · recall · seq 4 · parallel fresh instance (seq-4 rotation: whole-roster description; the NH3 mention sits in a foil about USE, not about NH3's status — seq 17's claim already states NH3's molarity scenario without relying on it) · mcq4
Which description matches the roster of common strong bases?
The Group 1 hydroxides plus the heavier Group 2 hydroxides. KEY
The Group 1 hydroxides only.
Every metal hydroxide, whatever the group.
Any base that appears in household cleaning products.
ABS-022 · medium · application · seq 5 · parallel fresh instance of seed pool[0] (seq-5 rotation: base family, nine-of-ten ratio framing) · mcq4
In one base's aqueous solution, nine out of every ten dissolved units stay whole and only one splits into ions. How is this base classified on the strength scale?
Weak KEY
Strong
Dilute
Concentrated
ABS-026 · medium · application · seq 6 · parallel fresh instance (seq-6 rotation: weak verdict, HBrO, sub-1% figure — chemically real for hypobromous acid) · mcq4
A data sheet reports that a 0.60 M solution of hypobromous acid, HBrO, is less than 1% ionized. What does this datum show?
HBrO is weak — nearly all of its dissolved molecules stay whole. KEY
HBrO is strong — any measurable ionization counts as complete.
The solution is dilute — under 1% means almost nothing is dissolved.
The datum is impossible — every acid ionizes at least half of its molecules.
ABS-024 · medium · application · seq 7 · parallel fresh instance of seed pool[6] (seq-7 rotation: Group 1 member LiOH) · mcq4
Which classification and reason fit LiOH?
A strong base — it is one of the Group 1 hydroxides on the list. KEY
A weak base — Li is the lightest listed metal, too light for complete splitting.
A strong base — any formula ending in OH is automatically strong.
A weak base — formulas with a single OH unit ionize only halfway.
ABS-023 · medium · application · seq 8 · parallel fresh instance of seed pool[5] (seq-8 rotation: pair HBr/HOCl; foils avoid H2SO3/HNO2/HF, the seq-2 foil set, and H2CO3 (seq 18)) · mcq4
Which pair puts a strong acid together with a weak acid?
HBr and HOCl KEY
HCl and HI
HCOOH and HBrO
HNO₃ and HClO₄
ABS-025 · medium · application · seq 9 · parallel fresh instance of seed pool[9] (seq-9 rotation: strong acid HNO3, 7 M -> 0.028 M) · mcq4
A 7 M solution of HNO₃ is diluted until its concentration is 0.028 M. What has changed?
The solution is now dilute, and the acid is still strong. KEY
The solution is now dilute, and the acid is now weak.
Nothing has changed, because the same amount of acid is present.
The solution is unchanged in concentration, and the acid is now weak.
ABS-022 · medium · application · seq 10 · parallel fresh instance of seed pool[2] (seq-10 rotation: HClO — partial ionization stated in the stem, so no form-E key depends on its status) · mcq4
HClO ionizes only partially when it dissolves. Which equation represents its ionization correctly?
HClO ⇌ H⁺ + ClO⁻ (double arrow) KEY
HClO → H⁺ + ClO⁻ (single arrow)
HClO ⇌ ClO⁺ + H⁻
No equation is needed — a weak acid does not ionize.
Panels R and S each show an acid solution at the same concentration, with seven dissolved units apiece. In panel R all seven units are separated ion pairs. In panel S six units are whole molecules and one is a separated ion pair. Which panel shows the strong acid?
FIGURE (particle-diagram-panels · stimulus) — panels: [{"panel": "R", "description": "a beaker with 7 dissolved units, all 7 drawn as separated H⁺ and anion pairs, every ion labeled"}, {"panel": "S", "descriptio… · style: "two side-by-side labeled beaker panels, matched particle counts, distinct particle kinds never touching"raw spec
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Panel R KEY
Panel S
Both panels
Neither panel
ABS-024 · medium · application · seq 12 · parallel fresh instance of seed pool[7] (seq-12 rotation: how-does-it-fit framing of the Mg(OH)2 boundary) · mcq4
How does Mg(OH)₂ fit the strong-base roster?
It does not — the roster's Group 2 members are only the heavier three: Ca(OH)₂, Sr(OH)₂, Ba(OH)₂. KEY
It is on the roster — every one of the Group 2 hydroxides, Mg(OH)₂ included, belongs to it.
It is on the roster — its OH ending qualifies it automatically.
It is excluded because its metal is too reactive.
ABS-025 · medium · application · seq 13 · parallel fresh instance of seed pool[10] (seq-13 rotation: concentrated strong base + dilute weak acid) · mcq4
Bottle 1 holds 10 M NaOH. Bottle 2 holds 0.032 M propanoic acid. Which statement describes the two solutions?
Bottle 1 is a concentrated strong-base solution; bottle 2 is a dilute weak-acid solution. KEY
Bottle 1 is a concentrated weak-base solution; bottle 2 is a dilute strong-acid solution.
Bottle 1's base counts as strong because so much of it is dissolved.
The two bottles cannot be compared, because one holds a base and one holds an acid.
Solution V was prepared from one of the listed strong bases; solution W holds an unidentified base. Both are aqueous solutions of equal concentration, poured to equal volumes and tested with the identical bulb apparatus at the same temperature. Solution V's bulb glows brightly; solution W's barely glows. Which statement best explains the difference?
V's base splits completely into ions, while W's splits only partially. KEY
V simply contains a larger amount of dissolved base than W does.
W's base produces no ions at all when it dissolves.
The liquid the bases are dissolved in conducts better in V than in W.
Which classification does this course assign to oxalic acid, H₂C₂O₄?
Assumed weak — it is not one of the six listed strong acids. KEY
Strong — its two H atoms double the splitting.
Strong — it resembles H₂SO₄, which is on the list.
It cannot be classified until a particle diagram of its solution has been drawn.
ABS-026 · medium · application · seq 16 · parallel fresh instance of seed pool[14] (seq-16 rotation: judge-the-objection framing, tartaric acid vs HCl) · mcq4
A student compares a tartaric acid solution against an HCl solution of matched concentration, using the same bulb setup for both and sees a much dimmer glow from the tartaric acid. A second student objects that the comparison proves nothing. Who is right, and why?
The first student — with concentrations matched, the dimmer glow can come only from a smaller fraction ionized. KEY
The second student — bulb brightness never carries strength information.
The second student — a fair test would need equal volumes of the two solutions, not equal concentrations.
The first student, but the dim glow shows the tartaric acid solution is dilute.
ABS-025 · hard · transfer · seq 17 · parallel fresh instance of seed pool[11] (seq-17 rotation: concentrated weak base NH3 called strong) · mcq4
A student writes: 'This 8.5 M NH₃ solution must contain a strong base — look how much is packed in.' Which correction fixes the claim?
The solution is concentrated, not strong — NH₃ stays the common weak base at every concentration. KEY
No correction is needed — packing that much base into every liter really does make it strong.
The claim has it backwards — bases become strong only when they are dilute.
The solution is strong AND concentrated — the two labels rise together.
ABS-023 · hard · transfer · seq 18 · parallel fresh instance of seed pool[4] (seq-18 rotation: H-count trap, H2CO3 vs HCl) · mcq4
A student argues: 'H₂CO₃ carries two H atoms but HCl carries only one, so H₂CO₃ must be the stronger acid.' Which correction is right?
Strength is list membership, not H count — HCl is one of the six, and H₂CO₃ is assumed weak. KEY
The student is right — an acid carrying more H atoms always outranks one carrying fewer.
The two acids are equally strong, because both formulas start with H.
Neither acid is strong — two-element acids never make the list.
ABS-024 · hard · transfer · seq 19 · parallel fresh instance of seed pool[8] (seq-19 rotation: gentle-product inference, KOH) · mcq4
Liquid soaps are manufactured using KOH, and the finished soaps feel gentle. A student concludes KOH must be a weak base. Which correction is right?
KOH is a Group 1 hydroxide — a strong base; how gentle a product feels is not what strength measures. KEY
The claim is right — a gentle finished product can only ever be manufactured from a weak base, never a strong one.
KOH is strong only in the concentrated form used at the factory.
KOH is not a base — it is used up when the soap is made.
ABS-026 · hard · transfer · seq 20 · parallel fresh instance of seed pool[13] (seq-20 rotation: concentrated-strong grid corner, unnamed acid) · mcq4
The figure shows a particle diagram of a 6.2 M acid solution. Eleven dissolved units appear, and every one is split into ions. What does the diagram show?
FIGURE (particle-diagram-solution · stimulus) — panels: [{"panel": "single", "description": "a beaker outline crowded with 11 dissolved units, each drawn as a separated H⁺ ion and anion pair; every ion labeled; di… · style: "clean textbook particulate view emphasizing the crowded particle count"raw spec
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The solution is concentrated, and the acid is strong — many units are dissolved, and all of them have split. KEY
The solution must be dilute — units that are fully split into ions mean the acid has been thinned far out.
The acid is strong ONLY because the solution is concentrated.
The count and the splitting contradict each other, so the diagram is wrong.
ABS-026 · hard · application · seq 21 · parallel fresh FRQ instance (seq-21 rotation: labels V/W/U, values 5 M / 92% / 2% / 0.0085 M / nine units) · frq
Two different acids are dissolved, each at 5 M. Laboratory measurements report:
Solution V — 92% of its dissolved units are split into ions.
Solution W — 2% of its dissolved units are split into ions.
Two different acids are dissolved, each at 5 M. Laboratory measurements report:
Solution V — 92% of its dissolved units are split into ions.
Solution W — 2% of its dissolved units are split into ions.
(a) Classify the acid in solution V as strong or weak, citing the measurement.
(b) Classify the acid in solution W as strong or weak, citing the measurement.
(c) A third bottle holds solution U at only 0.0085 M. A particle diagram of U shows nine dissolved units, and every one of them is split into ions. A student calls U 'weak, because the beaker is nearly empty of particles.' Explain the student's error and give the correct description of U.
Part a. Classify the acid in solution V as strong or weak, citing the measurement.
Model: Strong. At 5 M, 92% of V's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
Part b. Classify the acid in solution W as strong or weak, citing the measurement.
Model: Weak. Only 2% of W's dissolved units are split; nearly all stay whole, so W's acid ionizes only partially — the definition of weak. Since both solutions are 5 M, the different fractions must come from the acids themselves.
Part c. A third bottle holds solution U at only 0.0085 M. A particle diagram of U shows nine dissolved units, and every one of them is split into ions. A student calls U 'weak, because the beaker is nearly empty of particles.' Explain the student's error and give the correct description of U.
Model: The student read the number of dissolved particles, which reports concentration, as if it reported strength. Nine units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here nine out of nine, complete ionization. U is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
Full model answer. (a) Strong. At 5 M, 92% of V's dissolved units are split into ions — essentially every unit has ionized, and complete ionization is exactly what strong means.
(b) Weak. Only 2% of W's dissolved units are split; nearly all stay whole, so W's acid ionizes only partially — the definition of weak. Since both solutions are 5 M, the different fractions must come from the acids themselves.
(c) The student read the number of dissolved particles, which reports concentration, as if it reported strength. Nine units in the beaker means little is dissolved, so the solution is dilute. Strength is the fraction of those units that has split — here nine out of nine, complete ionization. U is a dilute solution of a strong acid: dilute and strong at the same time, with no contradiction.
End of Topic Test: The pH scale (u11-t3 · 5 forms × 22 items · 110 total)
David's notes for James:
FRQ ALLOCATION - frq_per_form = 2 (confirm the composition): the wave's calc-heavy 2-3-FRQ directive APPLIES to this scope - it carries exactly TWO multi-step calculation procedure families, and each gets one capstone FRQ. FRQ1 (seq 21) = the pH-equation lane: (a) ABS-033 pH from a decimal-form [H+] (rewrite as a power of ten, then the 5-line scaffold), (b) ABS-034 [H+] from a DIFFERENT solution's pH (full scaffold WITH the 'Make [H+] the subject' line), (c) ABS-032 explanation (why the log of a whole-number power of ten reads off the exponent, why the minus sign makes pH positive, why the course restricts the equation to 1 x 10^-n M). FRQ2 (seq 22) = the tenfold-comparison lane: (a) ABS-029 one-unit rule with direction, (b) ABS-030 count-units-then-stack-factors working (plain-sentence counting, NO formula scaffold - the lesson's own modality), (c) ABS-028 band classification of both samples. One part per lesson by design. A THIRD FRQ was considered and rejected: the remaining lanes (ABS-027/028/031 readings, ABS-035/036 indicator facts) are qualitative reading/discrimination skills better measured by the objective rows. Total 20 obj + 2 FRQ = 22 items/form; your seed file's frq_per_form=1 baseline was extended per the wave brief (prod_seeds = [], so both FRQs are unseeded). D5: min(20, 6 x 10 lessons) = 20 concurs with your target_size.
SOL-QC OVERRIDE CLASS ON THE FRQs (recorded adjudication, confirm): all 10 FRQ verdicts from the authoritative cross-vendor QC (gpt-5.6-sol) objected that the FRQs are 'not single-skill instruments' of their primary lesson. That is the deliberate blueprint design above (one part per lesson, QB-v2 sec.4 capstone shape; U9-G3 precedent) - the same verdicts judged the model answers and rubrics CORRECT. Recorded in gate_config.adjudication_notes_solqc; every other sol finding was content-fixed to zero.
COURSE POWER-OF-TEN LANE vs THE BARE-POWER NUMERIC LINT (recorded adjudication, confirm): this topic's numeric answers are exact powers of ten BY TAUGHT DESIGN - the D2 rule (ABS-032, verbatim: the equation is used only when [H+] is a whole-number power of ten) makes every [H+] answer 1 x 10^-n M, and ABS-030's counting routine makes every factor answer a stacked power of ten (its own specNotes mandate numeric entry with power-of-ten acceptedAlternates). Our deterministic validator flags bare powers of ten as sig-fig-ambiguous; the 10 affected answers (seq 8 factor entries + seq 15 [H+] entries, 5 forms) are excused ONLY under a locally ENFORCED per-slot contract: seq 8 carries integer:true exact counts with unit frame 'times' and power-of-ten acceptedAlternates; seq 15 carries sigFigs 1, decimal display (the graded value), unit M, scientific-notation acceptedAlternates, and a gradingNote citing the taught lane. Enforcement, not relief - a generic relief class stays parked pending your and David's sign-off.
pH IS UNITLESS - ENTRY-BOX UNIT FRAME (recorded adjudication, confirm): ABS-033's rule line is verbatim 'pH carries no unit - the answer is a bare number', but our numeric contract requires a non-empty answer.unit. The pH numeric rows (seq 13/14) carry the quantity-frame label 'pH' in answer.unit with a gradingNote stating it is an entry-box frame, not a physical unit - mirroring your own 'times' unit frame on the ABS-030 numeric seeds (your specNotes call 'times' a unit FRAME). Stems and model answers never attach a unit to a pH value.
TAUGHT-CONSTANT AND QUANTITY-NAME FAMILIES (recorded adjudications, disclosure): six freshness-scan families are excused by recorded, slot-enumerated adjudications enforced by the gate-local wrapper (the shared validator itself was never weakened): (1) 'hydrogen' as the taught QUANTITY NAME (hydrogen-ion concentration / hydrogen ions) - never a sample substance; avoidable uses were content-fixed (seq-10 stems now use the [H+] symbol; a 'hydrogen gas' distractor was replaced). (2) 'water' as the aqueous sample MEDIUM (pool-/stream-/well-water) and the taught pure-water-pH-7 neutral anchor - the instance-bearing qualifier differs per slot and is globally unique; your own seeds use water samples the same way. (3) 'juice' as the beverage-CATEGORY noun - the discriminating fruit qualifier (orange/kiwi/cranberry/lime/apple/grape/grapefruit/fruit-salad/rhubarb/passion-fruit/tamarind) is used exactly once each across the bank. (4) 14 = the taught scale bound + the 14-minus-n wrong-value anchor - appears only in bound wording and misconception options, never as an assessed value (pH 14 unused). (5) 100 = the taught two-unit factor constant (10 x 10). (6) 20 = the taught additive-error wrong value (2 units misread as 2 x 10), seq-9 D3 distractor only.
NOTA-PATTERN SEED DISTRACTORS REPLACED (opportunistic rule, confirm): your three ABS-028 gate seeds carry the fixed fourth option 'None of the three bands'. Per the standing NOTA ruling these were replaced with misconception-keyed contentful distractors - form A seq 2 (soft drink pH 3) and seq 5 (NaCl solution pH 7): seq-5's replacement is the scale-reach misconception ('the pH bands apply only to acids and bases, not to salt solutions'); seq-2's fourth option became a scale-does-not-apply claim after blind QC flagged the first replacement as a duplicate 'Neutral' outcome. Recorded per item in seed_placement.json.
SEED FRESHENINGS UNDER THE STRICT SEED RULING (dispositions to confirm): 18 of your 30 unique pool seeds placed on form A (demo_curated[0..2] = pool[18]/[19]/[20], deduped, both refs cited); 12 spares; 2 form-A rows authored fresh (seq 1: no recall-band ABS-027 seed exists; seq 10: third ABS-030 row). Freshenings, all in content, zero relief entries: seq 6 - the 6-vs-7 pair is the ABS-029 rule line's own example, moved to 4 vs 5 (garden soil kept); seq 7 - 'tap water' is an ABS-027 check instance and 7-to-6 is the rule pair, now aquarium water 8-to-7; seq 15 - 'household ammonia at pH 11' is verbatim in ABS-028's rule line, substance swapped to a liquid laundry-detergent solution (pH 11 kept); pool[9] (lemon juice vs black tea, factor 1000) left as a SPARE because 1000 is burned in ABS-030's worked examples. Template/idiom retemplates on seeded slots A#4/A#9/A#11 (stem phrasing only) are recorded in their seed_ref.edits. A#14 keeps your 13-decimal-places oven-cleaner seed verbatim (sole >12 value in the bank).
SEED CONTENT FIXES AT BLIND/SOL QC (confirm): A#17 (your demo-curated band-chain item) - the 'pH -9' distractor was reworded (it normalized to a duplicate of the 'pH 9 - acidic' option under the dup-option lint) and its scaffolded explanation was rewritten as prose (mcq rows carry no scaffold); A#2 - first NOTA replacement produced two options with the same 'Neutral' outcome, fourth option rebuilt as a scale-does-not-apply claim; A#22 (FRQ2) originally reused A#4's exact pH 4/9 pair - repaired to 3/9 with a fresh substance pair; A#4 key tightened (was 25+ chars longer than every distractor).
E#18 BLIND HARD-FAIL REBUILD (disclosure): the authored E-form indicator-integration item claimed colorless phenolphthalein 'rules out Basic' - wrong for mildly basic samples (the transition sits near pH 8.2). Rebuilt as a blue-litmus rule-out (blue litmus stays blue rules out Acidic), exact under BOTH the course model and real chemistry. Same lesson (ABS-036), same skill, same sample.
OTHER AUTHORED-ITEM QC FIXES (disclosure): the seq-2 'X only if Y' conditional-qualifier fourth options were swept off forms B-E (grammatical cue); B#11's 'fabric-softener solution' was chemically wrong twice over (real fabric softeners are acidic; the first replacement 'baking soda' is verbatim ABS-028 spec text) - final instance is an antacid gargle; C#15's pH-7 instance made the mandated 14-minus-n misconception produce the KEY (10^-(14-7) = 10^-7) - revalued to pH 5 (rain-barrel sample, realistically acid-tinged rainwater); C#18's 'fruit-salad juice' stem identity pre-answered its classification - now an unmarked-jug liquid; D#14's 14-minus distractor was degenerate at n=7 (equals the key) - replaced with a count-one-too-many miscue.
CAPSTONE ABS-033 = 4 ROWS TOTAL (confirm): 3 objective rows (the two numeric stem shapes at seq 13/14 + your demo-curated band-chain mcq at seq 17) + FRQ1 - one above the standard capstone 2+1, kept because all THREE of your demo_curated showcase items are ABS-033 gate items and placing all three preserves maximum seed fidelity on form A (U9-G3 4-row capstone precedent).
WITHIN-FORM EXPONENT SELF-REPEAT ON FORMS C AND E (recorded judgment call, confirm): the decimal-exponent pool for the seq-14 and FRQ1(a) slots is 8 usable values for 10 slots (exponents 1/2/4/5/12 are burned in scope worked examples; 3/6/7/8/9/10/11/13 remain), so forms C and E each reuse ONE exponent within-form (seq 14 vs FRQ1(a), different substances and different question shapes). Cross-form every decimal-form exponent stays unique. The alternative - importing a burned exponent - was rejected.
NUMBER LEDGER (disclosure): the only >12 stem/answer values in the bank are 13 (form A seq 14, your seed, sole use) and the five seq-8 factor answers 10^4/10^6/10^7/10^8/10^9 (one per form); 10^3 and 10^5 are burned in ABS-030's worked examples and never used; pH 14 is never used; pH answer values avoid 1 and 10 (bare powers); every substance string is globally unique across the 110 items (substance ledger asserted at authoring).
SAME-LADDER CROSS-ITEM CUEING (accepted class, disclosure): a 22-item single-topic pH test necessarily restates its rules - definitional rows (seq 1-3) state the rules the application rows then use, and every band value appears somewhere among the 20 rows, so a blind reviewer can always 'derive' one item from another. 49 of the 57 round-1 advisory flags were this structural class; accepted and recorded (the two FRQs' part (c) classifications overlap the seq-2 band rows on every form by the same logic).
BINDING INSTANCE RULE (course-wide, disclosure): zero fissile/weapons/dose framings; classroom-safe instances throughout (household liquids, food acids, cleaning solutions, water-quality samples). Re-swept at packaging over forms_final.json and this export body (deterministic token scan).
QC LEDGER (disclosure): deterministic validators 10/12 PASS as shipped + gate-local adjudication wrapper VERDICT PASS exit 0 (V-T7: 567 collision lines, 100% covered by the six recorded slot-enumerated families, 0 uncovered; V-T6: the 10 power-of-ten-lane slots each pass the locally enforced contract; 9/9 wrapper negative probes); blind round 1 (gpt-5.6-sol blind role + gemini, 110 items x 2) key picks 160/160, 1 hard fail (E#18, fixed), FRQ/numeric cold answers 60/60 graded match with justifications; re-blind rounds r3-r8 = 6/6, 18/18, 2/2 key picks, 0 hard fails; sol authoritative loops 1-3 = 18 -> 1 -> 0 FAILs beyond the one recorded FRQ-capstone override class (10 slots); ~95 recorded patch ops across 5 waves, all machine-logged.
FRQ delivery: your `prod` draw-on-paper class is delivered as a typed diagram-PLAN task (state kinds/recipes/counts/spacing; rubric grades the same observables). Confirm this mapping (pending from the U01-G1 round-trip).
full notes file
# u11-t3 — notes/queries from David's side (U11-G3)
1. FRQ ALLOCATION - frq_per_form = 2 (confirm the composition): the wave's calc-heavy 2-3-FRQ directive APPLIES to this scope - it carries exactly TWO multi-step calculation procedure families, and each gets one capstone FRQ. FRQ1 (seq 21) = the pH-equation lane: (a) ABS-033 pH from a decimal-form [H+] (rewrite as a power of ten, then the 5-line scaffold), (b) ABS-034 [H+] from a DIFFERENT solution's pH (full scaffold WITH the 'Make [H+] the subject' line), (c) ABS-032 explanation (why the log of a whole-number power of ten reads off the exponent, why the minus sign makes pH positive, why the course restricts the equation to 1 x 10^-n M). FRQ2 (seq 22) = the tenfold-comparison lane: (a) ABS-029 one-unit rule with direction, (b) ABS-030 count-units-then-stack-factors working (plain-sentence counting, NO formula scaffold - the lesson's own modality), (c) ABS-028 band classification of both samples. One part per lesson by design. A THIRD FRQ was considered and rejected: the remaining lanes (ABS-027/028/031 readings, ABS-035/036 indicator facts) are qualitative reading/discrimination skills better measured by the objective rows. Total 20 obj + 2 FRQ = 22 items/form; your seed file's frq_per_form=1 baseline was extended per the wave brief (prod_seeds = [], so both FRQs are unseeded). D5: min(20, 6 x 10 lessons) = 20 concurs with your target_size.
2. SOL-QC OVERRIDE CLASS ON THE FRQs (recorded adjudication, confirm): all 10 FRQ verdicts from the authoritative cross-vendor QC (gpt-5.6-sol) objected that the FRQs are 'not single-skill instruments' of their primary lesson. That is the deliberate blueprint design above (one part per lesson, QB-v2 sec.4 capstone shape; U9-G3 precedent) - the same verdicts judged the model answers and rubrics CORRECT. Recorded in gate_config.adjudication_notes_solqc; every other sol finding was content-fixed to zero.
3. COURSE POWER-OF-TEN LANE vs THE BARE-POWER NUMERIC LINT (recorded adjudication, confirm): this topic's numeric answers are exact powers of ten BY TAUGHT DESIGN - the D2 rule (ABS-032, verbatim: the equation is used only when [H+] is a whole-number power of ten) makes every [H+] answer 1 x 10^-n M, and ABS-030's counting routine makes every factor answer a stacked power of ten (its own specNotes mandate numeric entry with power-of-ten acceptedAlternates). Our deterministic validator flags bare powers of ten as sig-fig-ambiguous; the 10 affected answers (seq 8 factor entries + seq 15 [H+] entries, 5 forms) are excused ONLY under a locally ENFORCED per-slot contract: seq 8 carries integer:true exact counts with unit frame 'times' and power-of-ten acceptedAlternates; seq 15 carries sigFigs 1, decimal display (the graded value), unit M, scientific-notation acceptedAlternates, and a gradingNote citing the taught lane. Enforcement, not relief - a generic relief class stays parked pending your and David's sign-off.
4. pH IS UNITLESS - ENTRY-BOX UNIT FRAME (recorded adjudication, confirm): ABS-033's rule line is verbatim 'pH carries no unit - the answer is a bare number', but our numeric contract requires a non-empty answer.unit. The pH numeric rows (seq 13/14) carry the quantity-frame label 'pH' in answer.unit with a gradingNote stating it is an entry-box frame, not a physical unit - mirroring your own 'times' unit frame on the ABS-030 numeric seeds (your specNotes call 'times' a unit FRAME). Stems and model answers never attach a unit to a pH value.
5. TAUGHT-CONSTANT AND QUANTITY-NAME FAMILIES (recorded adjudications, disclosure): six freshness-scan families are excused by recorded, slot-enumerated adjudications enforced by the gate-local wrapper (the shared validator itself was never weakened): (1) 'hydrogen' as the taught QUANTITY NAME (hydrogen-ion concentration / hydrogen ions) - never a sample substance; avoidable uses were content-fixed (seq-10 stems now use the [H+] symbol; a 'hydrogen gas' distractor was replaced). (2) 'water' as the aqueous sample MEDIUM (pool-/stream-/well-water) and the taught pure-water-pH-7 neutral anchor - the instance-bearing qualifier differs per slot and is globally unique; your own seeds use water samples the same way. (3) 'juice' as the beverage-CATEGORY noun - the discriminating fruit qualifier (orange/kiwi/cranberry/lime/apple/grape/grapefruit/fruit-salad/rhubarb/passion-fruit/tamarind) is used exactly once each across the bank. (4) 14 = the taught scale bound + the 14-minus-n wrong-value anchor - appears only in bound wording and misconception options, never as an assessed value (pH 14 unused). (5) 100 = the taught two-unit factor constant (10 x 10). (6) 20 = the taught additive-error wrong value (2 units misread as 2 x 10), seq-9 D3 distractor only.
6. NOTA-PATTERN SEED DISTRACTORS REPLACED (opportunistic rule, confirm): your three ABS-028 gate seeds carry the fixed fourth option 'None of the three bands'. Per the standing NOTA ruling these were replaced with misconception-keyed contentful distractors - form A seq 2 (soft drink pH 3) and seq 5 (NaCl solution pH 7): seq-5's replacement is the scale-reach misconception ('the pH bands apply only to acids and bases, not to salt solutions'); seq-2's fourth option became a scale-does-not-apply claim after blind QC flagged the first replacement as a duplicate 'Neutral' outcome. Recorded per item in seed_placement.json.
7. SEED FRESHENINGS UNDER THE STRICT SEED RULING (dispositions to confirm): 18 of your 30 unique pool seeds placed on form A (demo_curated[0..2] = pool[18]/[19]/[20], deduped, both refs cited); 12 spares; 2 form-A rows authored fresh (seq 1: no recall-band ABS-027 seed exists; seq 10: third ABS-030 row). Freshenings, all in content, zero relief entries: seq 6 - the 6-vs-7 pair is the ABS-029 rule line's own example, moved to 4 vs 5 (garden soil kept); seq 7 - 'tap water' is an ABS-027 check instance and 7-to-6 is the rule pair, now aquarium water 8-to-7; seq 15 - 'household ammonia at pH 11' is verbatim in ABS-028's rule line, substance swapped to a liquid laundry-detergent solution (pH 11 kept); pool[9] (lemon juice vs black tea, factor 1000) left as a SPARE because 1000 is burned in ABS-030's worked examples. Template/idiom retemplates on seeded slots A#4/A#9/A#11 (stem phrasing only) are recorded in their seed_ref.edits. A#14 keeps your 13-decimal-places oven-cleaner seed verbatim (sole >12 value in the bank).
8. SEED CONTENT FIXES AT BLIND/SOL QC (confirm): A#17 (your demo-curated band-chain item) - the 'pH -9' distractor was reworded (it normalized to a duplicate of the 'pH 9 - acidic' option under the dup-option lint) and its scaffolded explanation was rewritten as prose (mcq rows carry no scaffold); A#2 - first NOTA replacement produced two options with the same 'Neutral' outcome, fourth option rebuilt as a scale-does-not-apply claim; A#22 (FRQ2) originally reused A#4's exact pH 4/9 pair - repaired to 3/9 with a fresh substance pair; A#4 key tightened (was 25+ chars longer than every distractor).
9. E#18 BLIND HARD-FAIL REBUILD (disclosure): the authored E-form indicator-integration item claimed colorless phenolphthalein 'rules out Basic' - wrong for mildly basic samples (the transition sits near pH 8.2). Rebuilt as a blue-litmus rule-out (blue litmus stays blue rules out Acidic), exact under BOTH the course model and real chemistry. Same lesson (ABS-036), same skill, same sample.
10. OTHER AUTHORED-ITEM QC FIXES (disclosure): the seq-2 'X only if Y' conditional-qualifier fourth options were swept off forms B-E (grammatical cue); B#11's 'fabric-softener solution' was chemically wrong twice over (real fabric softeners are acidic; the first replacement 'baking soda' is verbatim ABS-028 spec text) - final instance is an antacid gargle; C#15's pH-7 instance made the mandated 14-minus-n misconception produce the KEY (10^-(14-7) = 10^-7) - revalued to pH 5 (rain-barrel sample, realistically acid-tinged rainwater); C#18's 'fruit-salad juice' stem identity pre-answered its classification - now an unmarked-jug liquid; D#14's 14-minus distractor was degenerate at n=7 (equals the key) - replaced with a count-one-too-many miscue.
11. CAPSTONE ABS-033 = 4 ROWS TOTAL (confirm): 3 objective rows (the two numeric stem shapes at seq 13/14 + your demo-curated band-chain mcq at seq 17) + FRQ1 - one above the standard capstone 2+1, kept because all THREE of your demo_curated showcase items are ABS-033 gate items and placing all three preserves maximum seed fidelity on form A (U9-G3 4-row capstone precedent).
12. WITHIN-FORM EXPONENT SELF-REPEAT ON FORMS C AND E (recorded judgment call, confirm): the decimal-exponent pool for the seq-14 and FRQ1(a) slots is 8 usable values for 10 slots (exponents 1/2/4/5/12 are burned in scope worked examples; 3/6/7/8/9/10/11/13 remain), so forms C and E each reuse ONE exponent within-form (seq 14 vs FRQ1(a), different substances and different question shapes). Cross-form every decimal-form exponent stays unique. The alternative - importing a burned exponent - was rejected.
13. NUMBER LEDGER (disclosure): the only >12 stem/answer values in the bank are 13 (form A seq 14, your seed, sole use) and the five seq-8 factor answers 10^4/10^6/10^7/10^8/10^9 (one per form); 10^3 and 10^5 are burned in ABS-030's worked examples and never used; pH 14 is never used; pH answer values avoid 1 and 10 (bare powers); every substance string is globally unique across the 110 items (substance ledger asserted at authoring).
14. SAME-LADDER CROSS-ITEM CUEING (accepted class, disclosure): a 22-item single-topic pH test necessarily restates its rules - definitional rows (seq 1-3) state the rules the application rows then use, and every band value appears somewhere among the 20 rows, so a blind reviewer can always 'derive' one item from another. 49 of the 57 round-1 advisory flags were this structural class; accepted and recorded (the two FRQs' part (c) classifications overlap the seq-2 band rows on every form by the same logic).
15. BINDING INSTANCE RULE (course-wide, disclosure): zero fissile/weapons/dose framings; classroom-safe instances throughout (household liquids, food acids, cleaning solutions, water-quality samples). Re-swept at packaging over forms_final.json and this export body (deterministic token scan).
16. QC LEDGER (disclosure): deterministic validators 10/12 PASS as shipped + gate-local adjudication wrapper VERDICT PASS exit 0 (V-T7: 567 collision lines, 100% covered by the six recorded slot-enumerated families, 0 uncovered; V-T6: the 10 power-of-ten-lane slots each pass the locally enforced contract; 9/9 wrapper negative probes); blind round 1 (gpt-5.6-sol blind role + gemini, 110 items x 2) key picks 160/160, 1 hard fail (E#18, fixed), FRQ/numeric cold answers 60/60 graded match with justifications; re-blind rounds r3-r8 = 6/6, 18/18, 2/2 key picks, 0 hard fails; sol authoritative loops 1-3 = 18 -> 1 -> 0 FAILs beyond the one recorded FRQ-capstone override class (10 slots); ~95 recorded patch ops across 5 waves, all machine-logged.
An orange juice sample has pH 4, and an egg-white sample has pH 9. Comparing the two, which conclusion is correct?
The orange juice has a higher [H⁺] than the egg white. KEY
The egg white has a higher [H⁺], because 9 is the larger number.
The orange juice has a lower [H⁺], because 4 is the smaller number.
Neither has any H⁺, because both pH values sit inside the 0-to-14 range.
ABS-028 · medium · application · seq 5 · seed:U11-G3/pool[5] (ABS-028 gate) — one distractor replaced (recorded) · mcq4
A sodium chloride solution measures pH 7 exactly. A student classifies it as basic 'because sodium hydroxide contains sodium, and this solution contains sodium too'. Which classification is correct?
Neutral KEY
Basic
Acidic
Impossible to classify — the pH bands apply only to acids and bases, not to salt solutions
A soft drink has pH 3, and a glass of pure water has pH 7. How many times greater is the [H⁺] of the soft drink than that of the glass of pure water?
Answer: 10000 times KEY
also accepted: 10,000, 1 x 10^4, ten thousand
wrongValueDiagnostics
[
{
"value": 4,
"misconception": "you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten",
"feedback": "This answer is wrong — you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten."
},
{
"value": 40,
"misconception": "you multiplied the unit count by ten instead of stacking a factor of ten per unit",
"feedback": "This answer is wrong — you multiplied the unit count by ten instead of stacking a factor of ten per unit."
},
{
"value": 1000,
"misconception": "you stopped a factor of ten short — count all 4 units between 3 and 7",
"feedback": "This answer is wrong — you stopped a factor of ten short — count all 4 units between 3 and 7."
}
]
feedback
{
"keyExplanation": "Count the units between the two pH values: 7 − 3 = 4 units. Each unit is a factor of ten: 10 × 10 × 10 × 10 = 10000. The lower pH marks the greater [H⁺], so the factor is 10000."
}
A cola sample is measured to have [H⁺] = 1 × 10⁻³ M. What is its pH? Give the pH as a whole number.
Answer: 3 pH KEY
wrongValueDiagnostics
[
{
"value": -3,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −3 to 3",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −3 to 3."
},
{
"value": 11,
"misconception": "you subtracted the exponent from 14 — no such step exists in this calculation",
"feedback": "This answer is wrong — you subtracted the exponent from 14 — no such step exists in this calculation."
},
{
"value": 0.001,
"misconception": "you gave the concentration back instead of the pH",
"feedback": "This answer is wrong — you gave the concentration back instead of the pH."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 1 × 10⁻³ M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻³) = −(−3) pH = 3"
}
An oven-cleaner solution has [H⁺] = 0.0000000000001 M — thirteen decimal places. What is its pH? Give the pH as a whole number.
Answer: 13 pH KEY
wrongValueDiagnostics
[
{
"value": 12,
"misconception": "you miscounted the decimal places — thirteen places means 1 × 10⁻¹³ M",
"feedback": "This answer is wrong — you miscounted the decimal places — thirteen places means 1 × 10⁻¹³ M."
},
{
"value": -13,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −13 to 13",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −13 to 13."
},
{
"value": 1,
"misconception": "you subtracted the exponent from 14 — no such step exists in this calculation",
"feedback": "This answer is wrong — you subtracted the exponent from 14 — no such step exists in this calculation."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 0.0000000000001 M Rewrite as a power of ten: [H⁺] = 1 × 10⁻¹³ M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻¹³) = −(−13) pH = 13"
}
A liquid laundry-detergent solution measures pH 11. What is its [H⁺]? Give your answer in M, to 1 significant figure.
Answer: 1e-11 M KEY
also accepted: 1 x 10^-11, 1e-11, 10^-11
wrongValueDiagnostics
[
{
"value": 100000000000.0,
"misconception": "you dropped the minus sign in the exponent — the pH enters as MINUS the pH",
"feedback": "This answer is wrong — you dropped the minus sign in the exponent — the pH enters as MINUS the pH."
},
{
"value": 0.001,
"misconception": "you subtracted the pH from 14 first — no such step exists in this relationship",
"feedback": "This answer is wrong — you subtracted the pH from 14 first — no such step exists in this relationship."
},
{
"value": 11.0,
"misconception": "you gave the pH itself back as a concentration — the pH must move into the exponent",
"feedback": "This answer is wrong — you gave the pH itself back as a concentration — the pH must move into the exponent."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: pH = 11 Write down the equation: pH = −log[H⁺] Make [H⁺] the subject: [H⁺] = 1 × 10⁻ᵖᴴ Substitute in the values, and calculate: [H⁺] = 1 × 10⁻¹¹ [H⁺] = 1 × 10⁻¹¹ M"
}
A hand-soap solution has [H⁺] = 1 × 10⁻⁹ M. What is its pH, and which band is it in?
pH 9 — basic KEY
pH 9 — acidic
pH −9 — a negative pH, past the acidic end of the scale
pH 5 — acidic
ABS-036 · hard · transfer · seq 18 · seed:U11-G3/pool[29] (ABS-036 gate) — verbatim (field mapping only) · mcq4
Three tests are run on the same pond-water sample: blue litmus stays blue, red litmus stays red, and phenolphthalein stays colorless. What is the sample?
Near-neutral KEY
Acidic
Basic
It cannot be judged from these results
ABS-032 · hard · transfer · seq 19 · seed:U11-G3/pool[17] (ABS-032 gate) — verbatim (field mapping only) · mcq4
Why does this course use the pH equation only for concentrations like 1 × 10⁻⁶ M, and not for ones like 4.7 × 10⁻⁶ M?
For a whole-number power of ten the log is just the exponent — anything else needs a calculator logarithm. KEY
Because concentrations that sit between powers of ten, like 4.7 × 10⁻⁶ M, cannot occur in real solutions.
Because the pH equation is only approximately true for concentrations that are not powers of ten.
Because every pH value must come out between 0 and 14 on the scale.
ABS-031 · hard · transfer · seq 20 · seed:U11-G3/pool[14] (ABS-031 gate) — verbatim (field mapping only) · mcq4
A student writes: 'An acidic solution contains only H⁺ ions — the OH⁻ ions appear once the solution turns basic.' Which correction fixes the claim?
Both ions are present at every pH — acidic just means [H⁺] is the greater of the two. KEY
No correction is needed — OH⁻ cannot survive in an acidic solution.
The claim only has the ions swapped — acidic solutions contain only OH⁻.
The claim is right about acids but wrong about bases — basic solutions contain both ions.
ABS-033 · medium · application · seq 21 · authored (UNSEEDED — prod_seeds = []; fresh substance pair + fresh exponents per form; parts map ABS-033/ABS-034/ABS-032) · frq
A water-quality bench holds two liquids: a fruit-canning syrup with [H⁺] = 0.000001 M (six decimal places), and a whitewash solution that measures pH 12.
A water-quality bench holds two liquids: a fruit-canning syrup with [H⁺] = 0.000001 M (six decimal places), and a whitewash solution that measures pH 12.
(a) Calculate the pH of the fruit-canning syrup. Show every step of your working, including the rewrite of the concentration as a power of ten.
(b) Calculate the [H⁺] of the whitewash solution, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
(c) Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Part a. Calculate the pH of the fruit-canning syrup. Show every step of your working, including the rewrite of the concentration as a power of ten.
Model: Values: [H+] = 0.000001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 6, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -6, and the minus sign flips it: pH = -(-6)
pH = 6
Part b. Calculate the [H⁺] of the whitewash solution, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
Model: Values: pH = 12
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 12
[H+] = 0.000000000001 M
Part c. Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Model: When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
Full model answer. (a) Values: [H+] = 0.000001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 6, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -6, and the minus sign flips it: pH = -(-6)
pH = 6
(b) Values: pH = 12
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 12
[H+] = 0.000000000001 M
(c) When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
ABS-030 · medium · application · seq 22 · authored (UNSEEDED — prod_seeds = []; fresh sample pair per form; parts map ABS-029/ABS-030/ABS-028; plain-sentence counting working per ABS-030 specNotes — no formula scaffold) · frq
A kitchen-chemistry station compares two liquids: a jar of sauerkraut at pH 3 and a mop-bucket cleaning solution at pH 9.
A kitchen-chemistry station compares two liquids: a jar of sauerkraut at pH 3 and a mop-bucket cleaning solution at pH 9.
(a) State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
(b) How many times greater is the [H+] of the jar of sauerkraut than that of the mop-bucket cleaning solution? Show your working: count the pH units between the two liquids, then build the factor.
(c) Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Part a. State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
Model: Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
Part b. How many times greater is the [H+] of the jar of sauerkraut than that of the mop-bucket cleaning solution? Show your working: count the pH units between the two liquids, then build the factor.
Model: Count the units between the two pH values: 9 − 3 = 6 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 = 1,000,000.
The jar of sauerkraut has the lower pH, so it is the one with the greater [H+].
The jar of sauerkraut has 1,000,000 times the [H+] of the mop-bucket cleaning solution.
Part c. Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Model: Compare each pH with 7. The jar of sauerkraut measures pH 3, which is below 7, so it is acidic. The mop-bucket cleaning solution measures pH 9, which is above 7, so it is basic.
Full model answer. (a) Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
(b) Count the units between the two pH values: 9 − 3 = 6 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 = 1,000,000.
The jar of sauerkraut has the lower pH, so it is the one with the greater [H+].
The jar of sauerkraut has 1,000,000 times the [H+] of the mop-bucket cleaning solution.
(c) Compare each pH with 7. The jar of sauerkraut measures pH 3, which is below 7, so it is acidic. The mop-bucket cleaning solution measures pH 9, which is above 7, so it is basic.
A few drops of phenolphthalein are added to a basic solution. What color does the mixture show?
Pink KEY
Colorless
Green
Red
ABS-027 · medium · application · seq 4 · authored (fresh instance, parallel to the row-4 seed skill) · mcq4
A kiwi-juice sample has pH 3, and a dishwasher rinse-water sample comes out at pH 10. Comparing the two, which conclusion is correct?
The kiwi juice has a higher [H⁺] than the rinse water. KEY
The rinse water has a higher [H⁺], because 10 is the larger number.
The kiwi juice has a lower [H⁺], because 3 is the smaller number.
The two have equal [H⁺] — pH measures how corrosive a liquid is, not the H⁺ concentration
ABS-028 · medium · application · seq 5 · authored (fresh instance, parallel to the row-5 seed skill) · mcq4
A glucose solution measures pH 7 exactly. A student classifies it as acidic 'because glucose comes from fruit, and fruit is acidic'. Which classification is correct?
Neutral KEY
Acidic
Basic
Impossible to classify — glucose solutions are not on the pH scale
ABS-029 · medium · application · seq 6 · authored (fresh instance, parallel to the row-6 seed skill) · mcq4
One kombucha brew reads pH 2 and a second reads pH 3. Which statement compares their hydrogen-ion concentrations correctly?
The pH 2 sample has ten times the [H⁺] of the pH 3 sample. KEY
The pH 2 sample has one more unit of [H⁺] than the pH 3 sample.
The pH 3 sample has ten times the [H⁺] of the pH 2 sample.
The two differ by only a few percent, since 2 is close to 3.
ABS-029 · medium · application · seq 7 · authored (fresh instance, parallel to the row-7 seed skill) · mcq4
A base stirred into a craft-dye bath makes its [H⁺] ten times LOWER. The bath started at pH 11. What is its pH now?
pH 12 KEY
pH 10
pH 110
Still pH 11, because the change in concentration was only a factor of ten.
ABS-030 · medium · application · seq 8 · authored (fresh instance, parallel to the row-8 seed skill) · numeric
A cranberry juice has pH 2, and a stream-water sample shows pH 8. How many times greater is the [H⁺] of the cranberry juice than that of the stream-water sample?
Answer: 1000000 times KEY
also accepted: 1,000,000, 1 x 10^6, one million
wrongValueDiagnostics
[
{
"value": 6,
"misconception": "you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten",
"feedback": "This answer is wrong — you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten."
},
{
"value": 60,
"misconception": "you multiplied the unit count by ten instead of stacking a factor of ten per unit",
"feedback": "This answer is wrong — you multiplied the unit count by ten instead of stacking a factor of ten per unit."
},
{
"value": 100000,
"misconception": "you stopped a factor of ten short — count all 6 units between 2 and 8",
"feedback": "This answer is wrong — you stopped a factor of ten short — count all 6 units between 2 and 8."
}
]
feedback
{
"keyExplanation": "Count the units between the two pH values: 8 − 2 = 6 units. Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 = 1000000. The lower pH marks the greater [H⁺], so the factor is 1000000."
}
ABS-030 · medium · application · seq 9 · authored (fresh instance, parallel to the row-9 seed skill; 100 = taught constant, gate_config) · mcq4
A dish-soap solution has pH 8 and a bar-soap solution has pH 10. Which comparison of the two hydrogen-ion concentrations is correct?
The dish-soap solution has 100 times the [H⁺] of the bar-soap solution. KEY
The bar-soap solution has 100 times the [H⁺] of the dish-soap solution.
The dish-soap solution has 2 times the [H⁺] of the bar-soap solution.
The dish-soap solution has 20 times the [H⁺] of the bar-soap solution.
ABS-030 · medium · application · seq 10 · authored (fresh row — third ABS-030 slot per blueprint; factor-to-pH framing; 100 = taught constant, gate_config) · mcq4
Sample J has 100 times the [H⁺] of sample K. Sample K's reading is pH 9. What pH does sample J show?
pH 7 — two units DOWN the scale, because more H⁺ means lower pH. KEY
pH 11 — two units UP the scale, because more H⁺ means higher pH.
pH 8 — one unit down, because a factor of 100 is a single pH step.
pH 9 — unchanged, because concentration factors do not move the pH.
ABS-031 · medium · application · seq 11 · authored (fresh instance, parallel to the row-11 seed skill: band <-> ion-excess pattern) · mcq4
An antacid gargle has pH 9. How do its ion concentrations compare?
Its [OH⁻] is greater than its [H⁺]. KEY
Its [H⁺] is greater than its [OH⁻].
Its [H⁺] and [OH⁻] are equal.
It contains OH⁻ ions but no H⁺ ions at all.
ABS-032 · medium · application · seq 12 · authored (fresh value, parallel to the row-12 seed skill: exponent shortcut + sign flip) · mcq4
A solution has [H⁺] = 1 × 10⁻⁷ M. Which statement applies the definition of pH correctly?
The pH is 7, because the minus sign in pH = −log[H⁺] flips the exponent's −7. KEY
The pH is −7, because the log of 1 × 10⁻⁷ is −7.
The pH is 7, because 14 − 7 = 7.
The pH cannot be found, because logs need a calculator.
ABS-033 · medium · application · seq 13 · authored (fresh instance, parallel to the row-13 seed skill) · numeric
A glass of milk is measured to have [H⁺] = 1 × 10⁻⁶ M. What is its pH? Give the pH as a whole number.
Answer: 6 pH KEY
wrongValueDiagnostics
[
{
"value": -6,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −6 to 6",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −6 to 6."
},
{
"value": 8,
"misconception": "you subtracted the exponent from 14 — no such step exists in this calculation",
"feedback": "This answer is wrong — you subtracted the exponent from 14 — no such step exists in this calculation."
},
{
"value": 1e-06,
"misconception": "you gave the concentration back instead of the pH",
"feedback": "This answer is wrong — you gave the concentration back instead of the pH."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 1 × 10⁻⁶ M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻⁶) = −(−6) pH = 6"
}
ABS-033 · medium · application · seq 14 · authored (fresh instance, parallel to the row-14 seed skill) · numeric
A cement-wash water sample has [H⁺] = 0.00000000001 M — eleven decimal places. What is its pH? Give the pH as a whole number.
Answer: 11 pH KEY
wrongValueDiagnostics
[
{
"value": 10,
"misconception": "you miscounted the decimal places — eleven places means 1 × 10⁻¹¹ M",
"feedback": "This answer is wrong — you miscounted the decimal places — eleven places means 1 × 10⁻¹¹ M."
},
{
"value": -11,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −11 to 11",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −11 to 11."
},
{
"value": 3,
"misconception": "you subtracted the exponent from 14 — no such step exists in this calculation",
"feedback": "This answer is wrong — you subtracted the exponent from 14 — no such step exists in this calculation."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 0.00000000001 M Rewrite as a power of ten: [H⁺] = 1 × 10⁻¹¹ M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻¹¹) = −(−11) pH = 11"
}
ABS-034 · medium · application · seq 15 · authored (fresh instance, parallel to the row-15 seed skill) · numeric
A lime-juice sample measures pH 2. What is its [H⁺]? Give your answer in M, to 1 significant figure.
Answer: 0.01 M KEY
also accepted: 1 x 10^-2, 1e-2, 10^-2
wrongValueDiagnostics
[
{
"value": 100.0,
"misconception": "you dropped the minus sign in the exponent — the pH enters as MINUS the pH",
"feedback": "This answer is wrong — you dropped the minus sign in the exponent — the pH enters as MINUS the pH."
},
{
"value": 1e-12,
"misconception": "you subtracted the pH from 14 first — no such step exists in this relationship",
"feedback": "This answer is wrong — you subtracted the pH from 14 first — no such step exists in this relationship."
},
{
"value": 2.0,
"misconception": "you gave the pH itself back as a concentration — the pH must move into the exponent",
"feedback": "This answer is wrong — you gave the pH itself back as a concentration — the pH must move into the exponent."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: pH = 2 Write down the equation: pH = −log[H⁺] Make [H⁺] the subject: [H⁺] = 1 × 10⁻ᵖᴴ Substitute in the values, and calculate: [H⁺] = 1 × 10⁻² [H⁺] = 1 × 10⁻² M"
}
ABS-034 · medium · application · seq 16 · authored (fresh instance, parallel to the row-16 seed skill) · mcq4
A plaster-mixing water sample measures pH 12. Which [H⁺] matches that reading?
1 × 10⁻¹² M KEY
1 × 10¹² M
12 M
1 × 10⁻² M
ABS-033 · medium · application · seq 17 · authored (fresh instance, parallel to the row-17 seed skill: capstone chain into the bands) · mcq4
An apple-juice sample has [H⁺] = 1 × 10⁻⁴ M. What is its pH, and which band is it in?
pH 4 — acidic KEY
pH 4 — basic
pH −4 — a negative pH, past the acidic end of the scale
pH 10 — basic
ABS-036 · hard · transfer · seq 18 · authored (fresh instance + fresh result set, parallel to the row-18 seed skill: integrate indicator results) · mcq4
Two tests are run on a mystery cleaning solution from an unlabeled spray bottle: red litmus paper turns blue, and phenolphthalein turns pink. What is the solution?
Basic KEY
Acidic
Near-neutral
The two results contradict each other, so no verdict is possible
ABS-032 · hard · transfer · seq 19 · authored (fresh framing, parallel to the row-19 seed skill: the D2 validity condition) · mcq4
A student is told a solution has [H⁺] = 3.6 × 10⁻⁵ M, reads the exponent, and reports pH 5. What is wrong with the method?
The shortcut needs [H⁺] written as 1 × 10⁻ⁿ M — 3.6 × 10⁻⁵ sits between powers of ten. KEY
Nothing is wrong — the exponent is −5, so the pH of the solution is exactly 5.
pH = −log[H⁺] itself stops being true for concentrations like 3.6 × 10⁻⁵ M.
A pH of 5 is impossible for a real solution, so the answer must be recomputed.
ABS-031 · hard · transfer · seq 20 · authored (fresh claim, parallel to the row-20 seed skill: all-or-nothing misconception repair) · mcq4
A student writes: 'A basic solution contains only OH⁻ ions — its H⁺ ions appear only if the solution turns acidic.' Which correction fixes the claim?
Both ions are present at every pH — basic just means [OH⁻] is the greater of the two. KEY
No correction is needed — H⁺ cannot survive in a basic solution.
The claim only has the ions swapped — basic solutions contain only H⁺.
The claim is right about bases but wrong about acids — acidic solutions contain both ions.
ABS-033 · medium · application · seq 21 · authored (UNSEEDED — prod_seeds = []; fresh substance pair + fresh exponents per form; parts map ABS-033/ABS-034/ABS-032) · frq
A water-quality bench holds two liquids: a laundry rinse water sample with [H⁺] = 0.000000001 M (nine decimal places), and a cottage-cheese whey sample that measures pH 5.
A water-quality bench holds two liquids: a laundry rinse water sample with [H⁺] = 0.000000001 M (nine decimal places), and a cottage-cheese whey sample that measures pH 5.
(a) Calculate the pH of the laundry rinse water sample. Show every step of your working, including the rewrite of the concentration as a power of ten.
(b) Calculate the [H⁺] of the cottage-cheese whey sample, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
(c) Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Part a. Calculate the pH of the laundry rinse water sample. Show every step of your working, including the rewrite of the concentration as a power of ten.
Model: Values: [H+] = 0.000000001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 9, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -9, and the minus sign flips it: pH = -(-9)
pH = 9
Part b. Calculate the [H⁺] of the cottage-cheese whey sample, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
Model: Values: pH = 5
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 5
[H+] = 0.00001 M
Part c. Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Model: When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
Full model answer. (a) Values: [H+] = 0.000000001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 9, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -9, and the minus sign flips it: pH = -(-9)
pH = 9
(b) Values: pH = 5
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 5
[H+] = 0.00001 M
(c) When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
ABS-030 · medium · application · seq 22 · authored (UNSEEDED — prod_seeds = []; fresh sample pair per form; parts map ABS-029/ABS-030/ABS-028; plain-sentence counting working per ABS-030 specNotes — no formula scaffold) · frq
A kitchen-chemistry station compares two liquids: a chamomile-tea sample at pH 5 and a bath-salts solution at pH 9.
A kitchen-chemistry station compares two liquids: a chamomile-tea sample at pH 5 and a bath-salts solution at pH 9.
(a) State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
(b) How many times greater is the [H+] of the chamomile-tea sample than that of the bath-salts solution? Show your working: count the pH units between the two liquids, then build the factor.
(c) Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Part a. State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
Model: Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
Part b. How many times greater is the [H+] of the chamomile-tea sample than that of the bath-salts solution? Show your working: count the pH units between the two liquids, then build the factor.
Model: Count the units between the two pH values: 9 − 5 = 4 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 = 10,000.
The chamomile-tea sample has the lower pH, so it is the one with the greater [H+].
The chamomile-tea sample has 10,000 times the [H+] of the bath-salts solution.
Part c. Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Model: Compare each pH with 7. The chamomile-tea sample measures pH 5, which is below 7, so it is acidic. The bath-salts solution measures pH 9, which is above 7, so it is basic.
Full model answer. (a) Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
(b) Count the units between the two pH values: 9 − 5 = 4 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 = 10,000.
The chamomile-tea sample has the lower pH, so it is the one with the greater [H+].
The chamomile-tea sample has 10,000 times the [H+] of the bath-salts solution.
(c) Compare each pH with 7. The chamomile-tea sample measures pH 5, which is below 7, so it is acidic. The bath-salts solution measures pH 9, which is above 7, so it is basic.
Universal indicator is added to a weakly basic solution with pH 9. What color does the mixture show?
Blue KEY
Purple
Green
Pink
ABS-027 · medium · application · seq 4 · authored (fresh instance, parallel to the row-4 seed skill) · mcq4
A salad-dressing sample has pH 3, and a marble-polishing slurry has pH 9. Comparing the two, which conclusion is correct?
The salad dressing has a higher [H⁺] than the slurry. KEY
The slurry has a higher [H⁺], because 9 is the larger number.
The salad dressing has a lower [H⁺], because 3 is the smaller number.
Neither contains H⁺ ions, because neither pH is 0.
ABS-028 · medium · application · seq 5 · authored (fresh instance, parallel to the row-5 seed skill) · mcq4
A bottled mineral water tests at pH 6. A student classifies it as neutral 'because bottled waters are always neutral'. Which classification is correct?
Acidic KEY
Neutral
Basic
Neutral, because 6 rounds to 7
ABS-029 · medium · application · seq 6 · authored (fresh instance, parallel to the row-6 seed skill) · mcq4
One hot-tub sample reads pH 7 and another reads pH 8. Which statement compares their hydrogen-ion concentrations correctly?
The pH 7 sample has ten times the [H⁺] of the pH 8 sample. KEY
The pH 7 sample has one more unit of [H⁺] than the pH 8 sample.
The pH 8 sample has ten times the [H⁺] of the pH 7 sample.
The two differ by only a few percent, since 7 is close to 8.
ABS-029 · medium · application · seq 7 · authored (fresh instance, parallel to the row-7 seed skill) · mcq4
Acid dripped into a soaking bath multiplies its [H⁺] by ten. The bath started at pH 9. What is its pH now?
pH 8 KEY
pH 10
pH 90
Still pH 9, because the change in concentration was only a factor of ten.
ABS-030 · medium · application · seq 8 · authored (fresh instance, parallel to the row-8 seed skill) · numeric
A grapefruit juice has pH 3, and a washing-soda bath has pH 10. How many times greater is the [H⁺] of the grapefruit juice than that of the washing-soda bath?
Answer: 10000000 times KEY
also accepted: 10,000,000, 1 x 10^7, ten million
wrongValueDiagnostics
[
{
"value": 7,
"misconception": "you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten",
"feedback": "This answer is wrong — you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten."
},
{
"value": 70,
"misconception": "you multiplied the unit count by ten instead of stacking a factor of ten per unit",
"feedback": "This answer is wrong — you multiplied the unit count by ten instead of stacking a factor of ten per unit."
},
{
"value": 1000000,
"misconception": "you stopped a factor of ten short — count all 7 units between 3 and 10",
"feedback": "This answer is wrong — you stopped a factor of ten short — count all 7 units between 3 and 10."
}
]
feedback
{
"keyExplanation": "Count the units between the two pH values: 10 − 3 = 7 units. Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 × 10 = 10000000. The lower pH marks the greater [H⁺], so the factor is 10000000."
}
ABS-030 · medium · application · seq 9 · authored (fresh instance, parallel to the row-9 seed skill; 100 = taught constant, gate_config) · mcq4
An energy drink measures pH 3 and a buttermilk sample reads pH 5. Which comparison of the two hydrogen-ion concentrations is correct?
The energy drink has 100 times the [H⁺] of the buttermilk sample. KEY
The buttermilk has 100 times the [H⁺] of the energy drink.
The energy drink has 2 times the [H⁺] of the buttermilk sample.
The energy drink has 20 times the [H⁺] of the buttermilk sample.
ABS-030 · medium · application · seq 10 · authored (fresh row — third ABS-030 slot per blueprint; factor-to-pH framing; 100 = taught constant, gate_config) · mcq4
Sample L has 100 times the [H⁺] of sample M. Sample M's reading is pH 5. What pH does sample L show?
pH 3 — two units DOWN the scale, because more H⁺ means lower pH. KEY
pH 7 — two units UP the scale, because more H⁺ means higher pH.
pH 4 — one unit down, because a factor of 100 is a single pH step.
pH 5 — unchanged, because concentration factors do not move the pH.
ABS-031 · medium · application · seq 11 · authored (fresh instance, parallel to the row-11 seed skill: band <-> ion-excess pattern) · mcq4
A laboratory solution is found to have [H⁺] greater than [OH⁻]. Classify the solution.
Acidic KEY
Basic
Neutral
Impossible to classify from ion concentrations alone
ABS-032 · medium · application · seq 12 · authored (fresh value, parallel to the row-12 seed skill: exponent shortcut + sign flip) · mcq4
A solution has [H⁺] = 1 × 10⁻¹⁰ M. Which statement applies the definition of pH correctly?
The pH is 10, because the minus sign in pH = −log[H⁺] flips the exponent's −10. KEY
The pH is −10, because the log of 1 × 10⁻¹⁰ is −10.
The pH is 4, because 14 − 10 = 4.
The pH cannot be found, because logs need a calculator.
ABS-033 · medium · application · seq 13 · authored (fresh instance, parallel to the row-13 seed skill) · numeric
A sports-drink sample is measured to have [H⁺] = 1 × 10⁻⁴ M. What is its pH? Give the pH as a whole number.
Answer: 4 pH KEY
wrongValueDiagnostics
[
{
"value": -4,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −4 to 4",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −4 to 4."
},
{
"value": 10,
"misconception": "you subtracted the exponent from 14 — no such step exists in this calculation",
"feedback": "This answer is wrong — you subtracted the exponent from 14 — no such step exists in this calculation."
},
{
"value": 0.0001,
"misconception": "you gave the concentration back instead of the pH",
"feedback": "This answer is wrong — you gave the concentration back instead of the pH."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 1 × 10⁻⁴ M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻⁴) = −(−4) pH = 4"
}
ABS-033 · medium · application · seq 14 · authored (fresh instance, parallel to the row-14 seed skill) · numeric
A seawater sample has [H⁺] = 0.00000001 M — eight decimal places. What is its pH? Give the pH as a whole number.
Answer: 8 pH KEY
wrongValueDiagnostics
[
{
"value": 7,
"misconception": "you miscounted the decimal places — eight places means 1 × 10⁻⁸ M",
"feedback": "This answer is wrong — you miscounted the decimal places — eight places means 1 × 10⁻⁸ M."
},
{
"value": -8,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −8 to 8",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −8 to 8."
},
{
"value": 6,
"misconception": "you subtracted the exponent from 14 — no such step exists in this calculation",
"feedback": "This answer is wrong — you subtracted the exponent from 14 — no such step exists in this calculation."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 0.00000001 M Rewrite as a power of ten: [H⁺] = 1 × 10⁻⁸ M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻⁸) = −(−8) pH = 8"
}
ABS-034 · medium · application · seq 15 · authored (fresh instance, parallel to the row-15 seed skill) · numeric
A rain-barrel sample reads pH 5. What is its [H⁺]? Give your answer in M, to 1 significant figure.
Answer: 1e-05 M KEY
also accepted: 1 x 10^-5, 1e-5, 10^-5
wrongValueDiagnostics
[
{
"value": 100000,
"misconception": "you dropped the minus sign in the exponent — the pH enters as MINUS the pH",
"feedback": "This answer is wrong — you dropped the minus sign in the exponent — the pH enters as MINUS the pH."
},
{
"value": 1e-09,
"misconception": "you subtracted the pH from 14 first — no such step exists in this relationship",
"feedback": "This answer is wrong — you subtracted the pH from 14 first — no such step exists in this relationship."
},
{
"value": 5,
"misconception": "you gave the pH itself back as a concentration — the pH must move into the exponent",
"feedback": "This answer is wrong — you gave the pH itself back as a concentration — the pH must move into the exponent."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: pH = 5 Write down the equation: pH = −log[H⁺] Make [H⁺] the subject: [H⁺] = 1 × 10⁻ᵖᴴ M Substitute in the values, and calculate: [H⁺] = 1 × 10⁻⁵ M = 0.00001 M"
}
ABS-034 · medium · application · seq 16 · authored (fresh instance, parallel to the row-16 seed skill) · mcq4
An oat-flour slurry measures pH 6. Which [H⁺] matches that reading?
1 × 10⁻⁶ M KEY
1 × 10⁶ M
6 M
1 × 10⁻⁸ M
ABS-033 · medium · application · seq 17 · authored (fresh instance, parallel to the row-17 seed skill: capstone chain into the bands) · mcq4
An all-purpose spray cleaner has [H⁺] = 1 × 10⁻¹¹ M. What is its pH, and which band is it in?
pH 11 — basic KEY
pH 11 — acidic
pH −11 — a negative pH, past the acidic end of the scale
pH 3 — acidic
ABS-036 · hard · transfer · seq 18 · authored (fresh instance + fresh result set, parallel to the row-18 seed skill: integrate indicator results) · mcq4
Three tests are run on a liquid from an unmarked jug: blue litmus paper turns red, red litmus paper stays red, and phenolphthalein stays colorless. What is the liquid?
Acidic KEY
Basic
Near-neutral
It cannot be judged — the three results contradict one another
ABS-032 · hard · transfer · seq 19 · authored (fresh framing, parallel to the row-19 seed skill: the D2 validity condition) · mcq4
This course's pH calculation lane can handle exactly one of these hydrogen-ion concentrations. Which one?
1 × 10⁻¹⁰ M KEY
2.5 × 10⁻⁴ M
7.1 × 10⁻⁹ M
5 × 10⁻³ M
ABS-031 · hard · transfer · seq 20 · authored (fresh claim, parallel to the row-20 seed skill: all-or-nothing misconception repair) · mcq4
A student writes: 'At pH 7 a solution is neutral, so it contains no H⁺ ions and no OH⁻ ions at all.' Which correction fixes the claim?
A neutral solution contains BOTH ions — neutral means the two concentrations are exactly equal, not absent. KEY
No correction is needed — a neutral solution really does contain no ions of either kind.
Only the H⁺ part is wrong — a neutral solution contains H⁺ but no OH⁻.
Only the OH⁻ part is wrong — a neutral solution contains OH⁻ but no H⁺.
ABS-033 · medium · application · seq 21 · authored (UNSEEDED — prod_seeds = []; fresh substance pair + fresh exponents per form; parts map ABS-033/ABS-034/ABS-032) · frq
A water-quality bench holds two liquids: a brackish-pond sample with [H⁺] = 0.00000001 M (eight decimal places), and a rhubarb-juice sample that measures pH 2.
A water-quality bench holds two liquids: a brackish-pond sample with [H⁺] = 0.00000001 M (eight decimal places), and a rhubarb-juice sample that measures pH 2.
(a) Calculate the pH of the brackish-pond sample. Show every step of your working, including the rewrite of the concentration as a power of ten.
(b) Calculate the [H⁺] of the rhubarb-juice sample, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
(c) Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Part a. Calculate the pH of the brackish-pond sample. Show every step of your working, including the rewrite of the concentration as a power of ten.
Model: Values: [H+] = 0.00000001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 8, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -8, and the minus sign flips it: pH = -(-8)
pH = 8
Part b. Calculate the [H⁺] of the rhubarb-juice sample, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
Model: Values: pH = 2
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 2
[H+] = 0.01 M
Part c. Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Model: When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
Full model answer. (a) Values: [H+] = 0.00000001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 8, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -8, and the minus sign flips it: pH = -(-8)
pH = 8
(b) Values: pH = 2
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 2
[H+] = 0.01 M
(c) When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
ABS-030 · medium · application · seq 22 · authored (UNSEEDED — prod_seeds = []; fresh sample pair per form; parts map ABS-029/ABS-030/ABS-028; plain-sentence counting working per ABS-030 specNotes — no formula scaffold) · frq
A kitchen-chemistry station compares two liquids: a sour-plum sauce at pH 3 and a mortar-mixing slurry at pH 11.
A kitchen-chemistry station compares two liquids: a sour-plum sauce at pH 3 and a mortar-mixing slurry at pH 11.
(a) State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
(b) How many times greater is the [H+] of the sour-plum sauce than that of the mortar-mixing slurry? Show your working: count the pH units between the two liquids, then build the factor.
(c) Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Part a. State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
Model: Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
Part b. How many times greater is the [H+] of the sour-plum sauce than that of the mortar-mixing slurry? Show your working: count the pH units between the two liquids, then build the factor.
Model: Count the units between the two pH values: 11 − 3 = 8 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 × 10 × 10 = 100,000,000.
The sour-plum sauce has the lower pH, so it is the one with the greater [H+].
The sour-plum sauce has 100,000,000 times the [H+] of the mortar-mixing slurry.
Part c. Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Model: Compare each pH with 7. The sour-plum sauce measures pH 3, which is below 7, so it is acidic. The mortar-mixing slurry measures pH 11, which is above 7, so it is basic.
Full model answer. (a) Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
(b) Count the units between the two pH values: 11 − 3 = 8 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 × 10 × 10 = 100,000,000.
The sour-plum sauce has the lower pH, so it is the one with the greater [H+].
The sour-plum sauce has 100,000,000 times the [H+] of the mortar-mixing slurry.
(c) Compare each pH with 7. The sour-plum sauce measures pH 3, which is below 7, so it is acidic. The mortar-mixing slurry measures pH 11, which is above 7, so it is basic.
A few drops of phenolphthalein are added to an acidic solution. What color does the mixture show?
Colorless KEY
Pink
Red
Yellow
ABS-027 · medium · application · seq 4 · authored (fresh instance, parallel to the row-4 seed skill) · mcq4
A passion-fruit juice sample has pH 3, and a stain-remover soak has pH 10. Comparing the two, which conclusion is correct?
The passion-fruit juice has a higher [H⁺] than the stain-remover soak. KEY
The stain-remover soak has a higher [H⁺], because 10 is the larger number.
The passion-fruit juice has a lower [H⁺], because 3 is the smaller number.
The comparison cannot be made without knowing both volumes.
ABS-028 · medium · application · seq 5 · authored (fresh instance, parallel to the row-5 seed skill) · mcq4
A mouthwash reads pH 8 on a test strip. A student classifies it as acidic 'because mouthwash stings, and stinging means acid'. Which classification is correct?
Basic KEY
Acidic
Neutral
Impossible to classify — a sensation cannot be put on the pH scale
ABS-029 · medium · application · seq 6 · authored (fresh instance, parallel to the row-6 seed skill) · mcq4
One bird-fountain water sample reads pH 9 and another reads pH 10. Which statement compares their hydrogen-ion concentrations correctly?
The pH 9 sample has ten times the [H⁺] of the pH 10 sample. KEY
The pH 9 sample has one more unit of [H⁺] than the pH 10 sample.
The pH 10 sample has ten times the [H⁺] of the pH 9 sample.
The two differ by only a few percent, since 9 is close to 10.
ABS-029 · medium · application · seq 7 · authored (fresh instance, parallel to the row-7 seed skill) · mcq4
A treatment tank brings a glass-etching rinse's [H⁺] down to one tenth of what it was. The rinse started at pH 1. What is its pH now?
pH 2 KEY
pH 0
pH 10
Still pH 1, because the change in concentration was only a factor of ten.
ABS-030 · medium · application · seq 8 · authored (fresh instance, parallel to the row-8 seed skill) · numeric
A descaling solution has pH 2, and a borax solution has pH 10. How many times greater is the [H⁺] of the descaling solution than that of the borax solution?
Answer: 100000000 times KEY
also accepted: 100,000,000, 1 x 10^8, one hundred million
wrongValueDiagnostics
[
{
"value": 8,
"misconception": "you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten",
"feedback": "This answer is wrong — you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten."
},
{
"value": 80,
"misconception": "you multiplied the unit count by ten instead of stacking a factor of ten per unit",
"feedback": "This answer is wrong — you multiplied the unit count by ten instead of stacking a factor of ten per unit."
},
{
"value": 10000000,
"misconception": "you stopped a factor of ten short — count all 8 units between 2 and 10",
"feedback": "This answer is wrong — you stopped a factor of ten short — count all 8 units between 2 and 10."
}
]
feedback
{
"keyExplanation": "Count the units between the two pH values: 10 − 2 = 8 units. Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 × 10 × 10 = 100000000. The lower pH marks the greater [H⁺], so the factor is 100000000."
}
ABS-030 · medium · application · seq 9 · authored (fresh instance, parallel to the row-9 seed skill; 100 = taught constant, gate_config) · mcq4
A glass of root beer has pH 5 and a well-water sample reads pH 7. Which comparison of the two hydrogen-ion concentrations is correct?
The root beer has 100 times the [H⁺] of the well water. KEY
The well water has 100 times the [H⁺] of the root beer.
The root beer has 2 times the [H⁺] of the well water.
The root beer has 20 times the [H⁺] of the well water.
ABS-030 · medium · application · seq 10 · authored (fresh row — third ABS-030 slot per blueprint; factor-to-pH framing; 100 = taught constant, gate_config) · mcq4
Sample P has 100 times the [H⁺] of sample Q. Sample Q's reading is pH 11. What pH does sample P show?
pH 9 — two units DOWN the scale, because more H⁺ means lower pH. KEY
pH 13 — two units UP the scale, because more H⁺ means higher pH.
pH 10 — one unit down, because a factor of 100 is a single pH step.
pH 11 — unchanged, because concentration factors do not move the pH.
ABS-031 · medium · application · seq 11 · authored (fresh instance, parallel to the row-11 seed skill: band <-> ion-excess pattern) · mcq4
A facial-toner sample has pH 5. How do its ion concentrations compare?
Its [H⁺] is greater than its [OH⁻]. KEY
Its [OH⁻] is greater than its [H⁺].
Its [H⁺] and [OH⁻] are equal.
It contains H⁺ ions but no OH⁻ ions at all.
ABS-032 · medium · application · seq 12 · authored (fresh value, parallel to the row-12 seed skill: exponent shortcut + sign flip) · mcq4
A solution has [H⁺] = 1 × 10⁻⁸ M. Which statement applies the definition of pH correctly?
The pH is 8, because the minus sign in pH = −log[H⁺] flips the exponent's −8. KEY
The pH is −8, because the log of 1 × 10⁻⁸ is −8.
The pH is 6, because 14 − 8 = 6.
The pH cannot be found, because logs need a calculator.
ABS-033 · medium · application · seq 13 · authored (fresh instance, parallel to the row-13 seed skill) · numeric
A laundry-bleach solution is measured to have [H⁺] = 1 × 10⁻¹² M. What is its pH? Give the pH as a whole number.
Answer: 12 pH KEY
wrongValueDiagnostics
[
{
"value": -12,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −12 to 12",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −12 to 12."
},
{
"value": 2,
"misconception": "you subtracted the exponent from 14 — no such step exists in this calculation",
"feedback": "This answer is wrong — you subtracted the exponent from 14 — no such step exists in this calculation."
},
{
"value": 1e-12,
"misconception": "you gave the concentration back instead of the pH",
"feedback": "This answer is wrong — you gave the concentration back instead of the pH."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 1 × 10⁻¹² M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻¹²) = −(−12) pH = 12"
}
ABS-033 · medium · application · seq 14 · authored (fresh instance, parallel to the row-14 seed skill) · numeric
A contact-lens saline sample has [H⁺] = 0.0000001 M — seven decimal places. What is its pH? Give the pH as a whole number.
Answer: 7 pH KEY
wrongValueDiagnostics
[
{
"value": 6,
"misconception": "you miscounted the decimal places — seven places means 1 × 10⁻⁷ M",
"feedback": "This answer is wrong — you miscounted the decimal places — seven places means 1 × 10⁻⁷ M."
},
{
"value": -7,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −7 to 7",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −7 to 7."
},
{
"value": 8,
"misconception": "you counted one decimal place too many — the concentration has seven places, so the exponent is −7",
"feedback": "This answer is wrong — you counted one decimal place too many — the concentration has seven places, so the exponent is −7."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 0.0000001 M Rewrite as a power of ten: [H⁺] = 1 × 10⁻⁷ M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻⁷) = −(−7) pH = 7"
}
ABS-034 · medium · application · seq 15 · authored (fresh instance, parallel to the row-15 seed skill) · numeric
A titration-practical solution T measures pH 9. What is its [H⁺]? Give your answer in M, to 1 significant figure.
Answer: 1e-09 M KEY
also accepted: 1 x 10^-9, 1e-9, 10^-9
wrongValueDiagnostics
[
{
"value": 1000000000.0,
"misconception": "you dropped the minus sign in the exponent — the pH enters as MINUS the pH",
"feedback": "This answer is wrong — you dropped the minus sign in the exponent — the pH enters as MINUS the pH."
},
{
"value": 1e-05,
"misconception": "you subtracted the pH from 14 first — no such step exists in this relationship",
"feedback": "This answer is wrong — you subtracted the pH from 14 first — no such step exists in this relationship."
},
{
"value": 9.0,
"misconception": "you gave the pH itself back as a concentration — the pH must move into the exponent",
"feedback": "This answer is wrong — you gave the pH itself back as a concentration — the pH must move into the exponent."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: pH = 9 Write down the equation: pH = −log[H⁺] Make [H⁺] the subject: [H⁺] = 1 × 10⁻ᵖᴴ Substitute in the values, and calculate: [H⁺] = 1 × 10⁻⁹ [H⁺] = 1 × 10⁻⁹ M"
}
ABS-034 · medium · application · seq 16 · authored (fresh instance, parallel to the row-16 seed skill) · mcq4
A yogurt-drink sample measures pH 5. Which [H⁺] matches that reading?
1 × 10⁻⁵ M KEY
1 × 10⁵ M
5 M
1 × 10⁻⁹ M
ABS-033 · medium · application · seq 17 · authored (fresh instance, parallel to the row-17 seed skill: capstone chain into the bands) · mcq4
A fruit-punch sample has [H⁺] = 1 × 10⁻³ M. What is its pH, and which band is it in?
pH 3 — acidic KEY
pH 3 — basic
pH −3 — a negative pH, past the acidic end of the scale
pH 11 — basic
ABS-036 · hard · transfer · seq 18 · authored (fresh instance + fresh result set, parallel to the row-18 seed skill: integrate indicator results) · mcq4
Two tests are run on a dehumidifier-tank water sample: blue litmus paper stays blue, and red litmus paper stays red. What is the sample?
Near-neutral KEY
Acidic
Basic
Nothing can be said until a phenolphthalein test is run
ABS-032 · hard · transfer · seq 19 · authored (fresh framing, parallel to the row-19 seed skill: the D2 validity condition) · mcq4
A student claims: 'pH = −log[H⁺] is only approximately true when the concentration is not a whole-number power of ten.' Which correction is right?
The definition is exact everywhere — the restriction just marks what this course can compute without a calculator. KEY
Nothing needs correcting — between whole-number powers of ten the equation really is only an estimate.
It is backwards — the equation is approximate for whole-number powers and exact everywhere else.
The equation is exact only for basic solutions, whatever the hydrogen-ion concentration.
ABS-031 · hard · transfer · seq 20 · authored (fresh claim, parallel to the row-20 seed skill: all-or-nothing misconception repair) · mcq4
A student writes: 'Adding acid to a solution removes every OH⁻ ion from it.' Which correction fixes the claim?
Adding acid makes [OH⁻] FALL as [H⁺] rises — the two trade off, but the OH⁻ never reaches zero. KEY
No correction is needed — acid and OH⁻ cannot exist in the same solution.
The claim has the direction wrong — adding acid makes the [OH⁻] rise.
The claim confuses the ions — adding acid removes every H⁺ instead.
ABS-033 · medium · application · seq 21 · authored (UNSEEDED — prod_seeds = []; fresh substance pair + fresh exponents per form; parts map ABS-033/ABS-034/ABS-032) · frq
A water-quality bench holds two liquids: a washing-powder solution with [H⁺] = 0.0000000001 M (ten decimal places), and a paint-stripping wash that measures pH 11.
A water-quality bench holds two liquids: a washing-powder solution with [H⁺] = 0.0000000001 M (ten decimal places), and a paint-stripping wash that measures pH 11.
(a) Calculate the pH of the washing-powder solution. Show every step of your working, including the rewrite of the concentration as a power of ten.
(b) Calculate the [H⁺] of the paint-stripping wash, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
(c) Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Part a. Calculate the pH of the washing-powder solution. Show every step of your working, including the rewrite of the concentration as a power of ten.
Model: Values: [H+] = 0.0000000001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 10, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -10, and the minus sign flips it: pH = -(-10)
pH = 10
Part b. Calculate the [H⁺] of the paint-stripping wash, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
Model: Values: pH = 11
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 11
[H+] = 0.00000000001 M
Part c. Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Model: When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
Full model answer. (a) Values: [H+] = 0.0000000001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 10, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -10, and the minus sign flips it: pH = -(-10)
pH = 10
(b) Values: pH = 11
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 11
[H+] = 0.00000000001 M
(c) When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
ABS-030 · medium · application · seq 22 · authored (UNSEEDED — prod_seeds = []; fresh sample pair per form; parts map ABS-029/ABS-030/ABS-028; plain-sentence counting working per ABS-030 specNotes — no formula scaffold) · frq
A kitchen-chemistry station compares two liquids: a kefir sample at pH 4 and a birdbath sample at pH 8.
A kitchen-chemistry station compares two liquids: a kefir sample at pH 4 and a birdbath sample at pH 8.
(a) State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
(b) How many times greater is the [H+] of the kefir sample than that of the birdbath sample? Show your working: count the pH units between the two liquids, then build the factor.
(c) Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Part a. State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
Model: Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
Part b. How many times greater is the [H+] of the kefir sample than that of the birdbath sample? Show your working: count the pH units between the two liquids, then build the factor.
Model: Count the units between the two pH values: 8 − 4 = 4 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 = 10,000.
The kefir sample has the lower pH, so it is the one with the greater [H+].
The kefir sample has 10,000 times the [H+] of the birdbath sample.
Part c. Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Model: Compare each pH with 7. The kefir sample measures pH 4, which is below 7, so it is acidic. The birdbath sample measures pH 8, which is above 7, so it is basic.
Full model answer. (a) Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
(b) Count the units between the two pH values: 8 − 4 = 4 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 = 10,000.
The kefir sample has the lower pH, so it is the one with the greater [H+].
The kefir sample has 10,000 times the [H+] of the birdbath sample.
(c) Compare each pH with 7. The kefir sample measures pH 4, which is below 7, so it is acidic. The birdbath sample measures pH 8, which is above 7, so it is basic.
Universal indicator is added to a weakly acidic solution with pH 5. What color does the mixture show?
Yellow KEY
Orange
Green
Blue
ABS-027 · medium · application · seq 4 · authored (fresh instance, parallel to the row-4 seed skill) · mcq4
A tamarind-juice sample has pH 2, and a ceramic-tile cleaner has pH 11. Comparing the two, which conclusion is correct?
The tamarind juice has a higher [H⁺] than the tile cleaner. KEY
The tile cleaner has a higher [H⁺], because 11 is the larger number.
The tamarind juice has a lower [H⁺], because 2 is the smaller number.
The two have equal [H⁺], because 2 and 11 are both on the 0-to-14 scale.
ABS-028 · medium · application · seq 5 · authored (fresh instance, parallel to the row-5 seed skill) · mcq4
An electrolyte-tablet solution measures pH 7 exactly. A student classifies it as basic 'because electrolytes are salts, and salts are always basic'. Which classification is correct?
Neutral KEY
Basic
Acidic
Impossible to classify — tablet solutions are mixtures, and mixtures have no pH
ABS-029 · medium · application · seq 6 · authored (fresh instance, parallel to the row-6 seed skill) · mcq4
One mop bucket reads pH 10 and another reads pH 11. Which statement compares their hydrogen-ion concentrations correctly?
The pH 10 sample has ten times the [H⁺] of the pH 11 sample. KEY
The pH 10 sample has one more unit of [H⁺] than the pH 11 sample.
The pH 11 sample has ten times the [H⁺] of the pH 10 sample.
The two differ by only a few percent, since 10 is close to 11.
ABS-029 · medium · application · seq 7 · authored (fresh instance, parallel to the row-7 seed skill) · mcq4
Acid carried in on unwashed parts multiplies a workshop rinse water's [H⁺] by ten. The rinse water started at pH 5. What is its pH now?
pH 4 KEY
pH 6
pH 50
Still pH 5, because the change in concentration was only a factor of ten.
ABS-030 · medium · application · seq 8 · authored (fresh instance, parallel to the row-8 seed skill) · numeric
A car-battery acid sample has pH 1, and a liquid-antacid suspension has pH 10. How many times greater is the [H⁺] of the car-battery acid than that of the liquid-antacid suspension?
Answer: 1000000000 times KEY
also accepted: 1,000,000,000, 1 x 10^9, one billion
wrongValueDiagnostics
[
{
"value": 9,
"misconception": "you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten",
"feedback": "This answer is wrong — you gave the number of pH units instead of the factor — each unit multiplies the [H⁺] by ten."
},
{
"value": 90,
"misconception": "you multiplied the unit count by ten instead of stacking a factor of ten per unit",
"feedback": "This answer is wrong — you multiplied the unit count by ten instead of stacking a factor of ten per unit."
},
{
"value": 100000000,
"misconception": "you stopped a factor of ten short — count all 9 units between 1 and 10",
"feedback": "This answer is wrong — you stopped a factor of ten short — count all 9 units between 1 and 10."
}
]
feedback
{
"keyExplanation": "Count the units between the two pH values: 10 − 1 = 9 units. Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 × 10 × 10 × 10 = 1000000000. The lower pH marks the greater [H⁺], so the factor is 1000000000."
}
ABS-030 · medium · application · seq 9 · authored (fresh instance, parallel to the row-9 seed skill; 100 = taught constant, gate_config) · mcq4
A floor-cleaner concentrate has pH 12 and an enzyme presoak solution has pH 10. Which comparison of the two hydrogen-ion concentrations is correct?
The enzyme presoak solution has 100 times the [H⁺] of the floor-cleaner concentrate. KEY
The floor-cleaner concentrate has 100 times the [H⁺] of the enzyme presoak solution.
The enzyme presoak solution has 2 times the [H⁺] of the floor-cleaner concentrate.
The enzyme presoak solution has 20 times the [H⁺] of the floor-cleaner concentrate.
ABS-030 · medium · application · seq 10 · authored (fresh row — third ABS-030 slot per blueprint; factor-to-pH framing; 100 = taught constant, gate_config) · mcq4
Sample X has 100 times the [H⁺] of sample Y. Sample Y's reading is pH 8. What pH does sample X show?
pH 6 — two units DOWN the scale, because more H⁺ means lower pH. KEY
pH 10 — two units UP the scale, because more H⁺ means higher pH.
pH 7 — one unit down, because a factor of 100 is a single pH step.
pH 8 — unchanged, because concentration factors do not move the pH.
ABS-031 · medium · application · seq 11 · authored (fresh instance, parallel to the row-11 seed skill: band <-> ion-excess pattern) · mcq4
A buffer-training solution reads exactly pH 7. How do its ion concentrations compare?
Its [H⁺] and [OH⁻] are exactly equal. KEY
Its [H⁺] is greater than its [OH⁻].
Its [OH⁻] is greater than its [H⁺].
It contains neither H⁺ nor OH⁻ ions.
ABS-032 · medium · application · seq 12 · authored (fresh value, parallel to the row-12 seed skill: exponent shortcut + sign flip) · mcq4
A solution has [H⁺] = 1 × 10⁻⁵ M. Which statement applies the definition of pH correctly?
The pH is 5, because the minus sign in pH = −log[H⁺] flips the exponent's −5. KEY
The pH is −5, because the log of 1 × 10⁻⁵ is −5.
The pH is 9, because 14 − 5 = 9.
The pH cannot be found, because logs need a calculator.
ABS-033 · medium · application · seq 13 · authored (fresh instance, parallel to the row-13 seed skill) · numeric
A toothpaste-and-water slurry is measured to have [H⁺] = 1 × 10⁻⁹ M. What is its pH? Give the pH as a whole number.
Answer: 9 pH KEY
wrongValueDiagnostics
[
{
"value": -9,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −9 to 9",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −9 to 9."
},
{
"value": 5,
"misconception": "you subtracted the exponent from 14 — no such step exists in this calculation",
"feedback": "This answer is wrong — you subtracted the exponent from 14 — no such step exists in this calculation."
},
{
"value": 1e-09,
"misconception": "you gave the concentration back instead of the pH",
"feedback": "This answer is wrong — you gave the concentration back instead of the pH."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 1 × 10⁻⁹ M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻⁹) = −(−9) pH = 9"
}
ABS-033 · medium · application · seq 14 · authored (fresh instance, parallel to the row-14 seed skill) · numeric
A citrus-degreaser solution has [H⁺] = 0.001 M — three decimal places. What is its pH? Give the pH as a whole number.
Answer: 3 pH KEY
wrongValueDiagnostics
[
{
"value": 2,
"misconception": "you miscounted the decimal places — three places means 1 × 10⁻³ M",
"feedback": "This answer is wrong — you miscounted the decimal places — three places means 1 × 10⁻³ M."
},
{
"value": -3,
"misconception": "you kept the exponent's minus sign — the equation's minus flips −3 to 3",
"feedback": "This answer is wrong — you kept the exponent's minus sign — the equation's minus flips −3 to 3."
},
{
"value": 11,
"misconception": "you subtracted the exponent from 14 — no such step exists in this calculation",
"feedback": "This answer is wrong — you subtracted the exponent from 14 — no such step exists in this calculation."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: [H⁺] = 0.001 M Rewrite as a power of ten: [H⁺] = 1 × 10⁻³ M Write down the equation: pH = −log[H⁺] Substitute in the values, and calculate: pH = −log(1 × 10⁻³) = −(−3) pH = 3"
}
ABS-034 · medium · application · seq 15 · authored (fresh instance, parallel to the row-15 seed skill) · numeric
A fish-tank water sample measures pH 6. What is its [H⁺]? Give your answer in M, to 1 significant figure.
Answer: 1e-06 M KEY
also accepted: 1 x 10^-6, 1e-6, 10^-6
wrongValueDiagnostics
[
{
"value": 1000000.0,
"misconception": "you dropped the minus sign in the exponent — the pH enters as MINUS the pH",
"feedback": "This answer is wrong — you dropped the minus sign in the exponent — the pH enters as MINUS the pH."
},
{
"value": 1e-08,
"misconception": "you subtracted the pH from 14 first — no such step exists in this relationship",
"feedback": "This answer is wrong — you subtracted the pH from 14 first — no such step exists in this relationship."
},
{
"value": 6.0,
"misconception": "you gave the pH itself back as a concentration — the pH must move into the exponent",
"feedback": "This answer is wrong — you gave the pH itself back as a concentration — the pH must move into the exponent."
}
]
feedback
{
"keyExplanation": "Write down the values in the question: pH = 6 Write down the equation: pH = −log[H⁺] Make [H⁺] the subject: [H⁺] = 1 × 10⁻ᵖᴴ Substitute in the values, and calculate: [H⁺] = 1 × 10⁻⁶ [H⁺] = 1 × 10⁻⁶ M"
}
ABS-034 · medium · application · seq 16 · authored (fresh instance, parallel to the row-16 seed skill) · mcq4
A glass-cleaner spray measures pH 11. Which [H⁺] matches that reading?
1 × 10⁻¹¹ M KEY
1 × 10¹¹ M
11 M
1 × 10⁻³ M
ABS-033 · medium · application · seq 17 · authored (fresh instance, parallel to the row-17 seed skill: capstone chain into the bands) · mcq4
A wallpaper-stripper solution has [H⁺] = 1 × 10⁻¹² M. What is its pH, and which band is it in?
pH 12 — basic KEY
pH 12 — acidic
pH −12 — a negative pH, past the acidic end of the scale
pH 2 — acidic
ABS-036 · hard · transfer · seq 18 · authored (fresh instance + fresh result set, parallel to the row-18 seed skill: integrate indicator results) · mcq4
Blue litmus paper is dipped into a sink-rinse water sample, and the paper keeps its blue color. Which single description of the sample is ruled out by this result?
Acidic KEY
Basic
Near-neutral
Nothing is ruled out — a no-change result carries no information
ABS-032 · hard · transfer · seq 19 · authored (fresh framing, parallel to the row-19 seed skill: the D2 validity condition) · mcq4
In this course, every pH-calculation problem writes the concentration as 1 × 10⁻ⁿ M. What does that form guarantee?
That the log is simply the exponent −n, so the pH can be read off without a calculator. KEY
That the solution must be acidic, because the exponent in the concentration is negative.
That the calculated pH will come out negative, matching the negative exponent.
That the concentration is too small to have any chemical effect on the solution.
ABS-031 · hard · transfer · seq 20 · authored (fresh claim, parallel to the row-20 seed skill: all-or-nothing misconception repair) · mcq4
A laboratory test shows a solution has [OH⁻] greater than [H⁺]. A student concludes the test proves the solution contains no H⁺ at all. Which correction fixes the conclusion?
The test shows an OH⁻ excess, not an H⁺ absence — a basic solution still contains some H⁺. KEY
No correction is needed — an OH⁻ excess can only happen when the H⁺ is completely gone.
The conclusion is wrong only because the test must have misread the ions.
The conclusion should be the reverse — the solution contains no OH⁻ instead.
ABS-033 · medium · application · seq 21 · authored (UNSEEDED — prod_seeds = []; fresh substance pair + fresh exponents per form; parts map ABS-033/ABS-034/ABS-032) · frq
A water-quality bench holds two liquids: a mixed fruit-wash bath with [H⁺] = 0.001 M (three decimal places), and an egg-poaching water sample that measures pH 8.
A water-quality bench holds two liquids: a mixed fruit-wash bath with [H⁺] = 0.001 M (three decimal places), and an egg-poaching water sample that measures pH 8.
(a) Calculate the pH of the mixed fruit-wash bath. Show every step of your working, including the rewrite of the concentration as a power of ten.
(b) Calculate the [H⁺] of the egg-poaching water sample, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
(c) Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Part a. Calculate the pH of the mixed fruit-wash bath. Show every step of your working, including the rewrite of the concentration as a power of ten.
Model: Values: [H+] = 0.001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 3, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -3, and the minus sign flips it: pH = -(-3)
pH = 3
Part b. Calculate the [H⁺] of the egg-poaching water sample, in M. Show every step of your working, including the step where you make [H⁺] the subject of the equation.
Model: Values: pH = 8
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 8
[H+] = 0.00000001 M
Part c. Both calculations used the same equation, pH = −log[H+]. Explain in words why the log in this course can always be read straight off the exponent, what the equation's minus sign does to that exponent, and why this course only uses the equation when the concentration is a whole-number power of ten (written 1 × 10⁻ⁿ M).
Write your answers in plain numbers and words; you may type powers of ten in plain keyboard notation, and no special symbols are needed.
Model: When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
Full model answer. (a) Values: [H+] = 0.001 M
Rewrite as a power of ten: [H+] = 1 times 10 to the minus 3, in M
Equation: pH = -log[H+]
Substitute and calculate: the log is -3, and the minus sign flips it: pH = -(-3)
pH = 3
(b) Values: pH = 8
Equation: pH = -log[H+]
Make [H+] the subject: [H+] = 10 to the power of minus the pH
Substitute and calculate: [H+] = 1 times 10 to the minus 8
[H+] = 0.00000001 M
(c) When a concentration is a whole-number power of ten, written as 1 times ten to the minus n in M, its log is simply the exponent, minus n — no calculator is needed. The minus sign in pH = -log[H+] then flips that to plus n, which is why pH values come out positive. The course restricts the equation to concentrations of this form because for any value between powers of ten the log is no longer just the exponent and would need a calculator logarithm — a tool for a later course.
ABS-030 · medium · application · seq 22 · authored (UNSEEDED — prod_seeds = []; fresh sample pair per form; parts map ABS-029/ABS-030/ABS-028; plain-sentence counting working per ABS-030 specNotes — no formula scaffold) · frq
A kitchen-chemistry station compares two liquids: a miso-soup broth at pH 5 and an oven-rack soak solution at pH 11.
A kitchen-chemistry station compares two liquids: a miso-soup broth at pH 5 and an oven-rack soak solution at pH 11.
(a) State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
(b) How many times greater is the [H+] of the miso-soup broth than that of the oven-rack soak solution? Show your working: count the pH units between the two liquids, then build the factor.
(c) Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Part a. State the rule that connects a change of one pH unit to the change in hydrogen-ion concentration, including which direction the concentration moves as pH goes up.
Model: Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
Part b. How many times greater is the [H+] of the miso-soup broth than that of the oven-rack soak solution? Show your working: count the pH units between the two liquids, then build the factor.
Model: Count the units between the two pH values: 11 − 5 = 6 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 = 1,000,000.
The miso-soup broth has the lower pH, so it is the one with the greater [H+].
The miso-soup broth has 1,000,000 times the [H+] of the oven-rack soak solution.
Part c. Classify each of the two liquids as acidic, neutral, or basic, and give the reason for each classification.
Write your answers in plain numbers and words; no special symbols are needed.
Model: Compare each pH with 7. The miso-soup broth measures pH 5, which is below 7, so it is acidic. The oven-rack soak solution measures pH 11, which is above 7, so it is basic.
Full model answer. (a) Each change of one pH unit means a tenfold change in the hydrogen-ion concentration. The scale runs in reverse: step UP one pH unit and the [H+] becomes ten times lower; step DOWN one unit and it becomes ten times higher. So the lower-pH liquid always has the higher [H+].
(b) Count the units between the two pH values: 11 − 5 = 6 units.
Each unit is a factor of ten: 10 × 10 × 10 × 10 × 10 × 10 = 1,000,000.
The miso-soup broth has the lower pH, so it is the one with the greater [H+].
The miso-soup broth has 1,000,000 times the [H+] of the oven-rack soak solution.
(c) Compare each pH with 7. The miso-soup broth measures pH 5, which is below 7, so it is acidic. The oven-rack soak solution measures pH 11, which is above 7, so it is basic.
End of Topic Test: Neutralization and titration (u11-t4 · 5 forms × 22 items · 110 total)
David's notes for James:
FRQ ALLOCATION - frq_per_form = 2 (confirm the composition): the wave's calc-heavy 2-FRQ directive APPLIES to this scope - it carries exactly TWO production capstones, and each gets one FRQ. FRQ1 (seq 21) = the ABS-040 equation-writing production: (a) predict both products including the salt's formula via criss-cross, (b) unbalanced first write then the balanced equation with H+/OH- pair-counting reasoning (coefficients only, never a subscript), (c) atom check both sides. Form A carries your gate production seed pool[11] (HNO3 + Sr(OH)2, = demo_curated[2]); B-E rotate the case within the seq-21 family (HCl+Sr(OH)2 / HI+Sr(OH)2 / HI+KOH 1:1 / HNO3+Sr(OH)2 fresh context). FRQ2 (seq 22, authored - prod_seeds has no usable FRQ seed) = the ABS-045 titration-calculation routine: (a) titration equation + why it applies to this pair + Make-the-unknown-the-subject rearrangement, (b) substitute and calculate with unit (5-line-scaffold model answer), (c) the ABS-045 rule-8 sanity check (smaller volume means more concentrated) stated and applied; unknown direction rotates acid/base across forms (D8). Why not 3: the scope has exactly ONE formula (the titration equation; ABS-044's own extraNotes ban numeric solving) and ABS-043's qualitative comparison is the calculation's built-in sanity check - a third FRQ would double-sample one formula family. Total 20 obj + 2 FRQ = 22 items/form; your seed file's frq_per_form=1 baseline was extended per the wave brief. D5: min(20, 6 x 9 lessons) = 20 concurs with your target_size.
CLOSED-REGISTER ADJUDICATION (recorded, slot-enumerated - confirm): this gate's instance vocabulary IS the taught register (acids HCl/HBr/HI/HNO3/H2SO4; bases NaOH/KOH/LiOH + NH3 + Ca/Ba/Sr(OH)2), and every 1:1 monoprotic/MOH pair is named somewhere in the 9-lesson corpus - token-level cross-slot exclusivity for acid/base NAMES is structurally unsatisfiable. Authoring therefore enforces PAIR-level home-seq exclusivity (one acid-base pair per seq family, machine-asserted at assembly) plus fully-armed bank-unique numeric values, and FIVE material families are excused by recorded, rationaled, slot-enumerated adjudications enforced by the gate-local wrapper (the shared validator itself was never weakened): (1) register-salt, 29 slots - 'salt' is the assessed concept itself ('neutralization produces water and A SALT' cannot be stated or tested without it; the 'table salt, NaCl' instance appears only at its home seq 17 where your spec designates it); (2) register-water, 13 slots - neutralization's invariant product (the seq-3 ask IS which ions form the water; seq-18's given mixture contains the water; the seq-17/18 within-form adjacency is two consecutive-lesson register rows and telegraphs no key); (3) register-sodium, 20 slots - only 'sodium' of the three taught monoprotic bases sits in the MATERIALS lexicon; NaOH pairs are distinct per family (HNO3+NaOH seq 7, HI+NaOH seq 14 = your p19 pair, H2SO4+NaOH seq 20 spec-mandated, HBr+NaOH seq 22) and the gratuitous seq-18 sodium foil was content-purged to potassium hydroxide BEFORE the family was recorded; (4) case-calcium, 5 slots - the single homed M(OH)2 criss-cross family at seq 5 (Ca 5 / Ba 13 / Sr 21 per the home-pair ledger); (5) case-ammonia, 5 slots - your p12 seed case kept 1:1 at seq 2. Non-material carrier vocab recorded per family. HCl+NaOH is RESERVED to the register (037/038 article instance, 042 hook, 045 WE1) - no item uses the pair.
SPEC-MANDATED INSTANCE (confirm): seq 20 keeps H2SO4 + NaOH in every form - your ABS-044 specNotes designate this exact pair as the 1:2 validity non-example for the titration equation (leaning on ABS-040's taught coefficients). It is also ABS-040's article instance; covered by the register-sodium family.
GIVEN-EQUATION FAMILY (confirm): seq 1 keeps the seed's H2SO4 + 2KOH -> K2SO4 + 2H2O equation in every form (the equation ARRIVES balanced per 037 extraNotes and is READ, not produced; forms rotate the framing around the same identify-the-salt case). H2SO4/KOH is also the 040 in-lesson fluency-production instance - same-seq family only, recorded WARN class.
R14 COVERAGE GAP (disclosure): the 1:2 coefficient case (diprotic acid) has NO production slot in this gate - every H2SO4 pair is homed to an objective seq under pair-exclusivity (seqs 1 given-balanced, 11 salt-formula mcq, 20 validity non-example), so 1:2 is assessed receptively three times but never produced; the FRQ-21 family covers 2:1 (forms A/B/C/E) and 1:1 (form D). If you want a produced 1:2 equation, it would need a swap of the seq-21 family case against the home-pair ledger - flagging rather than deciding.
FRQ NOTATION CONTRACT (recorded adjudication, confirm): FRQ prompts carry Unicode notation (student-visible); FRQ model answers and rubrics describe TYPED student work in the plain-digit ASCII register (typed answers must never require sub/superscripts), with charges written H(+)/OH(-)/Sr(2+). The unbalanced first write is shown with EXPLICIT 1-coefficients (1HNO3 + 1Sr(OH)2 -> 1Sr(NO3)2 + 1H2O) - pedagogically the first write IS the all-coefficients-1 form - and the model notes that 1s are left unwritten in the final balanced answer. Form D's 1:1 case states the first write is already balanced. The seq-22 calculation model uses Values/Substitution/Result lines with exactly one 'Make X the subject' stage-marker.
NUMERIC PRECISION RULING (sol-QC loops 1+2 convergence - confirm, and note the platform caveat): every given in the seq-12/15 slots carries 3 significant figures, so the stems ANNOUNCE 'Give your answer to 3 significant figures' and the contract enforces it - display = the 3-sf spelling (e.g. 0.280, 0.130), sigFigs 3, tolerance 0.0005, and the 2-sf spelling is NOT an accepted alternate. PLATFORM CAVEAT FOR YOU: numeric tolerance grading cannot see trailing zeros - a student typing 0.28 is numerically inside tolerance even though the announced precision asks for 0.280; the gradingNote records this, and enforcement of the trailing zero is renderer-dependent. All answer values are exact divisions, never bare powers of ten, no ambiguous trailing zeros; every number token is bank-unique across the 110 items and excludes your corpus register values (0.100/0.150/0.400 M etc.).
TYPED-EQUATION CONTRACT AT SEQ 7 (sol-QC catches, confirm): the doubled equation 2HNO3 + 2NaOH -> 2NaNO3 + 2H2O is balanced, so rejecting it requires an explicit instruction - the stems now ask for 'the smallest whole-number coefficients'; and a student may type the reactants/products in either order, so the accepted-alternates enumerate all 8 order/notation spellings (reactant-order x product-order x Unicode/ASCII digits and arrow). The seq-5 salt-formula text slots accept the plain-digit spelling (CaI2) alongside the Unicode display form.
SEED DISPOSITIONS UNDER THE STRICT SEED RULING (confirm): pool 27 (= 9 lessons x 3 gate items; your demo_curated[0..5] dedup to pool[9,10,11,24,25,26], both refs cited). 20 objective placements on form A + the FRQ-21 seed = 21 of 22 form-A items seed-derived; 6 spares, each with a recorded why. prod_seeds[0] is byte-identical to the ABS-040 in-lesson fluency production (student-seen) - spares-only, never a test item; the FRQ seed is the GATE production pool[11]. 12 of 20 placements carried must_freshen_instance, all resolved in content: p24 (seq 12) pair HCl+KOH kept but ALL values re-picked (0.150 M = your ABS-045 WE1; 10.0/40.0 corpus volumes); p25 (seq 15) re-valued (its 0.100 M answer is a bare power of ten under our armed numeric lint) AND re-paired HBr+LiOH (its HI/NaOH pair is homed at seq 14); p26 left as a SPARE (0.400 M + 60.0/45.0 are corpus tokens; its HBr pair redeployed at seq 15); seq 5 re-paired from H2SO4/KOH to the Ca(OH)2 2:1 family; seq 7 re-paired to HNO3+NaOH (the seed equation HI + LiOH -> LiI + H2O appears verbatim in your 037 f2); seq 16 re-cased to the EQUAL-volumes outcome (completes the acid/base/equal key spread your 043 specNotes demand) and re-paired HNO3+KOH; seq 18 ions re-picked Li+/NO3- (the seed's K+/Cl- collides with 038 gate3's own instance); seq 2/6/10/14 volumes re-picked bank-unique. NOTA/AOTA scan over all 27 seeds: ZERO hits - no replacements needed.
SEED-TEXT EDIT AT SEQ 4 (recorded in seed_ref.edits, confirm): blind review caught a family style tell - the spec-verbatim key was the only option NOT starting 'The indicator ...', an odd-one-out giveaway. The key was rephrased on ALL FIVE forms (parallel option style, distinct wording per form, same taught content: the endpoint needs a visible signal because both solutions can be colorless). Also C#4's stem overstatement ('would fail') was reframed and its key trimmed of a 'colorless' echo + length cue.
BLIND-REVIEW ACCEPT-CLASSES (recorded dismissals, disclosure): round-1 reviewers raised 54 advisory flags, ~40 of them same-ladder cross-item cueing - the blueprint places 2-3 rows per calc lesson (ABS-043 at seqs 6/14/16, ABS-044 at 8/10/20, ABS-045 at 12/15/22, ABS-040 at 7/13/21), and definitional rows necessarily restate rules the application rows then use, so a blind reader can 'derive' one item from another; this is blueprint-inherent for a single-topic test. Other recorded classes: seq-8/10 missing-variable structure IS the ABS-044 skill; titration stems must state the knowns (givens-eliminate); seq-17/19 qualified keys vs categorical misconception distractors (deterministic longest-key arbiter passes); B#20/E#20 course-authority (the equation is licensed only for 1:1 pairs); D#19 strength-vs-concentration fence = the taught ABS-041/ABS-025 boundary.
NUMBER LEDGER (disclosure): every number token in the bank is unique across all 110 items; molarity/volume pools exclude ALL corpus register values (0.100/0.150/0.200/0.250/0.300/0.400/0.500/0.600 M; 5/8/10/12/15/16/20/24/25/30/35/36/40/45/48/50/60/75 mL); every keyed value divides exactly; volume ratios in the qualitative ABS-043 rows are exact (a stated 'one seventh' wording error at 13.0/91.0 was caught and fixed at stage 3).
BINDING INSTANCE RULE (course-wide, disclosure): zero uranium/plutonium/enrichment/reactor/weapons framings; classroom-safe instances throughout (cleaning products, fertilizer solution, quality-control and water samples). Re-swept at packaging over forms_final.json and this export body (deterministic token scan).
QC LEDGER (disclosure): deterministic validators 11/12 PASS as shipped + gate-local adjudication wrapper VERDICT PASS exit 0 (V-T7: 597 collision lines, 100% covered by the five recorded slot-enumerated families, 0 uncovered, parity guard MATCH; V-T6 FULLY ARMED over the 10 live numeric items, zero excusals; stage-3 content purges landed BEFORE any adjudication was recorded); blind round 1 (gpt-5.6-sol blind role + gemini, 110 items x 2) key picks 160/160, hard fails 0, FRQ/numeric/text cold answers 30 slots x 2 reviewers = 60/60 graded match with justifications; re-blind rounds r3-r10 = 10/10, 2/2, 0/0, 6/6 key picks, 0 hard fails, keyless re-grades 30/30 + 20/20 + 4/4 all match; sol authoritative loops 1-4 = 17 -> 11 -> 0 -> 0 FAIL, terminal 110/110 pass with ZERO recorded override classes; all patch waves machine-logged.
FRQ delivery: your `prod` draw-on-paper class is delivered as a typed diagram-PLAN task (state kinds/recipes/counts/spacing; rubric grades the same observables). Confirm this mapping (pending from the U01-G1 round-trip).
full notes file
# u11-t4 — notes/queries from David's side (U11-G4)
1. FRQ ALLOCATION - frq_per_form = 2 (confirm the composition): the wave's calc-heavy 2-FRQ directive APPLIES to this scope - it carries exactly TWO production capstones, and each gets one FRQ. FRQ1 (seq 21) = the ABS-040 equation-writing production: (a) predict both products including the salt's formula via criss-cross, (b) unbalanced first write then the balanced equation with H+/OH- pair-counting reasoning (coefficients only, never a subscript), (c) atom check both sides. Form A carries your gate production seed pool[11] (HNO3 + Sr(OH)2, = demo_curated[2]); B-E rotate the case within the seq-21 family (HCl+Sr(OH)2 / HI+Sr(OH)2 / HI+KOH 1:1 / HNO3+Sr(OH)2 fresh context). FRQ2 (seq 22, authored - prod_seeds has no usable FRQ seed) = the ABS-045 titration-calculation routine: (a) titration equation + why it applies to this pair + Make-the-unknown-the-subject rearrangement, (b) substitute and calculate with unit (5-line-scaffold model answer), (c) the ABS-045 rule-8 sanity check (smaller volume means more concentrated) stated and applied; unknown direction rotates acid/base across forms (D8). Why not 3: the scope has exactly ONE formula (the titration equation; ABS-044's own extraNotes ban numeric solving) and ABS-043's qualitative comparison is the calculation's built-in sanity check - a third FRQ would double-sample one formula family. Total 20 obj + 2 FRQ = 22 items/form; your seed file's frq_per_form=1 baseline was extended per the wave brief. D5: min(20, 6 x 9 lessons) = 20 concurs with your target_size.
2. CLOSED-REGISTER ADJUDICATION (recorded, slot-enumerated - confirm): this gate's instance vocabulary IS the taught register (acids HCl/HBr/HI/HNO3/H2SO4; bases NaOH/KOH/LiOH + NH3 + Ca/Ba/Sr(OH)2), and every 1:1 monoprotic/MOH pair is named somewhere in the 9-lesson corpus - token-level cross-slot exclusivity for acid/base NAMES is structurally unsatisfiable. Authoring therefore enforces PAIR-level home-seq exclusivity (one acid-base pair per seq family, machine-asserted at assembly) plus fully-armed bank-unique numeric values, and FIVE material families are excused by recorded, rationaled, slot-enumerated adjudications enforced by the gate-local wrapper (the shared validator itself was never weakened): (1) register-salt, 29 slots - 'salt' is the assessed concept itself ('neutralization produces water and A SALT' cannot be stated or tested without it; the 'table salt, NaCl' instance appears only at its home seq 17 where your spec designates it); (2) register-water, 13 slots - neutralization's invariant product (the seq-3 ask IS which ions form the water; seq-18's given mixture contains the water; the seq-17/18 within-form adjacency is two consecutive-lesson register rows and telegraphs no key); (3) register-sodium, 20 slots - only 'sodium' of the three taught monoprotic bases sits in the MATERIALS lexicon; NaOH pairs are distinct per family (HNO3+NaOH seq 7, HI+NaOH seq 14 = your p19 pair, H2SO4+NaOH seq 20 spec-mandated, HBr+NaOH seq 22) and the gratuitous seq-18 sodium foil was content-purged to potassium hydroxide BEFORE the family was recorded; (4) case-calcium, 5 slots - the single homed M(OH)2 criss-cross family at seq 5 (Ca 5 / Ba 13 / Sr 21 per the home-pair ledger); (5) case-ammonia, 5 slots - your p12 seed case kept 1:1 at seq 2. Non-material carrier vocab recorded per family. HCl+NaOH is RESERVED to the register (037/038 article instance, 042 hook, 045 WE1) - no item uses the pair.
3. SPEC-MANDATED INSTANCE (confirm): seq 20 keeps H2SO4 + NaOH in every form - your ABS-044 specNotes designate this exact pair as the 1:2 validity non-example for the titration equation (leaning on ABS-040's taught coefficients). It is also ABS-040's article instance; covered by the register-sodium family.
4. GIVEN-EQUATION FAMILY (confirm): seq 1 keeps the seed's H2SO4 + 2KOH -> K2SO4 + 2H2O equation in every form (the equation ARRIVES balanced per 037 extraNotes and is READ, not produced; forms rotate the framing around the same identify-the-salt case). H2SO4/KOH is also the 040 in-lesson fluency-production instance - same-seq family only, recorded WARN class.
5. R14 COVERAGE GAP (disclosure): the 1:2 coefficient case (diprotic acid) has NO production slot in this gate - every H2SO4 pair is homed to an objective seq under pair-exclusivity (seqs 1 given-balanced, 11 salt-formula mcq, 20 validity non-example), so 1:2 is assessed receptively three times but never produced; the FRQ-21 family covers 2:1 (forms A/B/C/E) and 1:1 (form D). If you want a produced 1:2 equation, it would need a swap of the seq-21 family case against the home-pair ledger - flagging rather than deciding.
6. FRQ NOTATION CONTRACT (recorded adjudication, confirm): FRQ prompts carry Unicode notation (student-visible); FRQ model answers and rubrics describe TYPED student work in the plain-digit ASCII register (typed answers must never require sub/superscripts), with charges written H(+)/OH(-)/Sr(2+). The unbalanced first write is shown with EXPLICIT 1-coefficients (1HNO3 + 1Sr(OH)2 -> 1Sr(NO3)2 + 1H2O) - pedagogically the first write IS the all-coefficients-1 form - and the model notes that 1s are left unwritten in the final balanced answer. Form D's 1:1 case states the first write is already balanced. The seq-22 calculation model uses Values/Substitution/Result lines with exactly one 'Make X the subject' stage-marker.
7. NUMERIC PRECISION RULING (sol-QC loops 1+2 convergence - confirm, and note the platform caveat): every given in the seq-12/15 slots carries 3 significant figures, so the stems ANNOUNCE 'Give your answer to 3 significant figures' and the contract enforces it - display = the 3-sf spelling (e.g. 0.280, 0.130), sigFigs 3, tolerance 0.0005, and the 2-sf spelling is NOT an accepted alternate. PLATFORM CAVEAT FOR YOU: numeric tolerance grading cannot see trailing zeros - a student typing 0.28 is numerically inside tolerance even though the announced precision asks for 0.280; the gradingNote records this, and enforcement of the trailing zero is renderer-dependent. All answer values are exact divisions, never bare powers of ten, no ambiguous trailing zeros; every number token is bank-unique across the 110 items and excludes your corpus register values (0.100/0.150/0.400 M etc.).
8. TYPED-EQUATION CONTRACT AT SEQ 7 (sol-QC catches, confirm): the doubled equation 2HNO3 + 2NaOH -> 2NaNO3 + 2H2O is balanced, so rejecting it requires an explicit instruction - the stems now ask for 'the smallest whole-number coefficients'; and a student may type the reactants/products in either order, so the accepted-alternates enumerate all 8 order/notation spellings (reactant-order x product-order x Unicode/ASCII digits and arrow). The seq-5 salt-formula text slots accept the plain-digit spelling (CaI2) alongside the Unicode display form.
9. SEED DISPOSITIONS UNDER THE STRICT SEED RULING (confirm): pool 27 (= 9 lessons x 3 gate items; your demo_curated[0..5] dedup to pool[9,10,11,24,25,26], both refs cited). 20 objective placements on form A + the FRQ-21 seed = 21 of 22 form-A items seed-derived; 6 spares, each with a recorded why. prod_seeds[0] is byte-identical to the ABS-040 in-lesson fluency production (student-seen) - spares-only, never a test item; the FRQ seed is the GATE production pool[11]. 12 of 20 placements carried must_freshen_instance, all resolved in content: p24 (seq 12) pair HCl+KOH kept but ALL values re-picked (0.150 M = your ABS-045 WE1; 10.0/40.0 corpus volumes); p25 (seq 15) re-valued (its 0.100 M answer is a bare power of ten under our armed numeric lint) AND re-paired HBr+LiOH (its HI/NaOH pair is homed at seq 14); p26 left as a SPARE (0.400 M + 60.0/45.0 are corpus tokens; its HBr pair redeployed at seq 15); seq 5 re-paired from H2SO4/KOH to the Ca(OH)2 2:1 family; seq 7 re-paired to HNO3+NaOH (the seed equation HI + LiOH -> LiI + H2O appears verbatim in your 037 f2); seq 16 re-cased to the EQUAL-volumes outcome (completes the acid/base/equal key spread your 043 specNotes demand) and re-paired HNO3+KOH; seq 18 ions re-picked Li+/NO3- (the seed's K+/Cl- collides with 038 gate3's own instance); seq 2/6/10/14 volumes re-picked bank-unique. NOTA/AOTA scan over all 27 seeds: ZERO hits - no replacements needed.
10. SEED-TEXT EDIT AT SEQ 4 (recorded in seed_ref.edits, confirm): blind review caught a family style tell - the spec-verbatim key was the only option NOT starting 'The indicator ...', an odd-one-out giveaway. The key was rephrased on ALL FIVE forms (parallel option style, distinct wording per form, same taught content: the endpoint needs a visible signal because both solutions can be colorless). Also C#4's stem overstatement ('would fail') was reframed and its key trimmed of a 'colorless' echo + length cue.
11. BLIND-REVIEW ACCEPT-CLASSES (recorded dismissals, disclosure): round-1 reviewers raised 54 advisory flags, ~40 of them same-ladder cross-item cueing - the blueprint places 2-3 rows per calc lesson (ABS-043 at seqs 6/14/16, ABS-044 at 8/10/20, ABS-045 at 12/15/22, ABS-040 at 7/13/21), and definitional rows necessarily restate rules the application rows then use, so a blind reader can 'derive' one item from another; this is blueprint-inherent for a single-topic test. Other recorded classes: seq-8/10 missing-variable structure IS the ABS-044 skill; titration stems must state the knowns (givens-eliminate); seq-17/19 qualified keys vs categorical misconception distractors (deterministic longest-key arbiter passes); B#20/E#20 course-authority (the equation is licensed only for 1:1 pairs); D#19 strength-vs-concentration fence = the taught ABS-041/ABS-025 boundary.
12. NUMBER LEDGER (disclosure): every number token in the bank is unique across all 110 items; molarity/volume pools exclude ALL corpus register values (0.100/0.150/0.200/0.250/0.300/0.400/0.500/0.600 M; 5/8/10/12/15/16/20/24/25/30/35/36/40/45/48/50/60/75 mL); every keyed value divides exactly; volume ratios in the qualitative ABS-043 rows are exact (a stated 'one seventh' wording error at 13.0/91.0 was caught and fixed at stage 3).
13. BINDING INSTANCE RULE (course-wide, disclosure): zero uranium/plutonium/enrichment/reactor/weapons framings; classroom-safe instances throughout (cleaning products, fertilizer solution, quality-control and water samples). Re-swept at packaging over forms_final.json and this export body (deterministic token scan).
14. QC LEDGER (disclosure): deterministic validators 11/12 PASS as shipped + gate-local adjudication wrapper VERDICT PASS exit 0 (V-T7: 597 collision lines, 100% covered by the five recorded slot-enumerated families, 0 uncovered, parity guard MATCH; V-T6 FULLY ARMED over the 10 live numeric items, zero excusals; stage-3 content purges landed BEFORE any adjudication was recorded); blind round 1 (gpt-5.6-sol blind role + gemini, 110 items x 2) key picks 160/160, hard fails 0, FRQ/numeric/text cold answers 30 slots x 2 reviewers = 60/60 graded match with justifications; re-blind rounds r3-r10 = 10/10, 2/2, 0/0, 6/6 key picks, 0 hard fails, keyless re-grades 30/30 + 20/20 + 4/4 all match; sol authoritative loops 1-4 = 17 -> 11 -> 0 -> 0 FAIL, terminal 110/110 pass with ZERO recorded override classes; all patch waves machine-logged.
A window cleaner contains ammonia. A chemist titrates a 73.0 mL sample of the cleaner with hydrobromic acid whose concentration is already known, until the two have exactly reacted. Which quantity does the titration reveal?
The concentration of the ammonia in the cleaner KEY
Why does a titration need an indicator in the flask at all?
The indicator gives the endpoint a visible signal — both solutions can be colorless KEY
The indicator makes the acid and the base react faster once mixed
The indicator neutralizes any acid still left over at the end of the titration
The indicator marks the level of solution on the flask so volumes can be read
ABS-039 · medium · application · seq 5 · seed:pool[6] task shape (salt-formula text entry) — re-paired to the Ca(OH)₂ 2:1 family per seed_placement (seed's H₂SO₄/KOH = seq-1 home + 040 fluency-prod corpus) · text
Hydroiodic acid, HI, reacts with calcium hydroxide, Ca(OH)₂. Write the formula of the salt formed.
Answer: CaI₂ KEY
also accepted: CaI2
wrongValueDiagnostics
[
{
"value": "CaH₂",
"misconception": "you paired the metal with the acid's hydrogen — the salt takes the acid's NEGATIVE ion, I⁻",
"feedback": null
},
{
"value": "CaI",
"misconception": "you ignored the charges — one 1− iodide cannot balance a 2+ calcium; calcium's 2 must cross to the iodide",
"feedback": null
},
{
"value": "Ca₂I",
"misconception": "you criss-crossed in reverse — calcium's 2 becomes the IODIDE's subscript, not calcium's own",
"feedback": null
}
]
feedback
{
"keyExplanation": "The acid's negative ion: HI gives I⁻. The base's metal ion: Ca(OH)₂ gives Ca²⁺. Criss-cross the charges: calcium's 2 crosses to the iodide, giving CaI₂. Water forms alongside it."
}
Neutralizing a 54.0 mL sample of hydrobromic acid took just 18.0 mL of potassium hydroxide solution at the endpoint; the two react one-to-one. Which is more concentrated?
The potassium hydroxide solution KEY
The hydrobromic acid
The two are equally concentrated
It cannot be judged from the volumes
ABS-040 · medium · application · seq 7 · seed:pool[9] task shape (1:1 balanced-equation text entry) — re-paired HNO₃+NaOH per seed_placement (seed's HI + LiOH equation appears verbatim in 037 fluency corpus; HI/LiOH homed at seq 3) · text
Write the balanced chemical equation, using the smallest whole-number coefficients, for nitric acid, HNO₃, reacting with sodium hydroxide, NaOH.
[
{
"value": "HNO₃ + NaOH → NaNO₃ + H₂",
"misconception": "you released hydrogen gas — with a base, the acid's hydrogen ends up in water, not H₂",
"feedback": null
},
{
"value": "HNO₃ + NaOH → NaNO₃",
"misconception": "you dropped the water — the acid's H⁺ and the base's OH⁻ pair up and must appear as the product H₂O",
"feedback": null
},
{
"value": "2HNO₃ + 2NaOH → 2NaNO₃ + 2H₂O",
"misconception": "your equation is balanced, but not written in the smallest whole-number coefficients — every coefficient here can be divided by two",
"feedback": null
}
]
feedback
{
"keyExplanation": "Products: the salt NaNO₃ and water. Count the pairs: one H⁺ from HNO₃, one OH⁻ from NaOH — the counts match, so no coefficients are needed. HNO₃ + NaOH → NaNO₃ + H₂O. Check: 2 H, 1 N, 4 O, 1 Na on each side."
}
A flask holds lithium hydroxide solution with a few drops of phenolphthalein, so it starts out pink. Hydrochloric acid is added slowly from the tube. What does the student observe at the endpoint?
The pink color disappears and does not come back KEY
The pink color deepens sharply
The solution turns from pink to blue
Nothing is observed, because phenolphthalein only works when base is added to acid
ABS-044 · medium · application · seq 10 · seed:pool[23]/spec 044 gate3 — design kept; the 20.0 mL / 0.0300 L pair re-picked bank-unique · mcq4
A titration's data sheet lists V(acid) = 52.0 mL and V(base) = 0.0790 L. Before these values go into M(acid) × V(acid) = M(base) × V(base), what must be done?
Express both volumes in the same unit KEY
Nothing — the equation works with any mix of volume units
Convert both volumes into moles first
Convert the two molarities into grams
ABS-039 · medium · application · seq 11 · seed:pool[8]/spec 039 gate3 — kept VERBATIM (permutational distractor set fixed by the spec) · mcq4
Which salt forms when sulfuric acid, H₂SO₄, neutralizes lithium hydroxide, LiOH?
Li₂SO₄ KEY
LiSO₄
Li(SO₄)₂
Li₂(SO₄)₂
ABS-045 · medium · application · seq 12 · seed:pool[24]/spec 045 gate1 — pair HCl/KOH + acid-unknown direction kept; ALL values re-picked (0.150 M = 045 WE1 corpus; 10.0/40.0 corpus volumes; bank-unique) · numeric
A 42.0 mL sample of hydrochloric acid reaches the endpoint after 84.0 mL of 0.140 M potassium hydroxide solution has been added; the two react one-to-one. What is the molarity of the acid, in M? Give your answer to 3 significant figures.
Answer: 0.28 M KEY
wrongValueDiagnostics
[
{
"value": 0.07,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.14,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 11.8,
"misconception": "you multiplied the known side but never divided by the acid's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(acid) = 42.0 mL\nM(base) = 0.140 M\nV(base) = 84.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(acid) the subject:\nM(acid) = M(base) × V(base) ÷ V(acid)\nSubstitute in the values, and calculate:\nM(acid) = 0.140 × 84.0 ÷ 42.0\nM(acid) = 0.280 M\nSanity check: the acid needed half the base's volume, so it comes out twice as concentrated — 0.280 M against 0.140 M passes."
}
ABS-040 · medium · application · seq 13 · seed:pool[10]/spec 040 gate2 — kept VERBATIM (Ba(OH)₂ token in 040's own fluency recorded as WARN class) · mcq4
Hydrobromic acid reacts with barium hydroxide. Which is the correctly balanced equation?
Reaching the endpoint took 82.0 mL of sodium hydroxide solution for a 41.0 mL sample of hydroiodic acid; the two react one-to-one. A student concludes the base is the more concentrated 'because more of it took part'. Which is actually more concentrated?
The hydroiodic acid KEY
The sodium hydroxide solution
The two are equally concentrated
It cannot be judged from the volumes
ABS-045 · hard · application · seq 15 · seed:pool[25]/spec 045 gate2 — base-unknown direction kept; RE-PAIRED HBr+LiOH (seed HI/NaOH homed at seq 14) and RE-VALUED (seed answer 0.100 M = bare power of ten, armed V-T6) · numeric
An 81.0 mL sample of lithium hydroxide solution is neutralized at the endpoint by 27.0 mL of 0.390 M hydrobromic acid; the two react one-to-one. What is the molarity of the base, in M? Give your answer to 3 significant figures.
Answer: 0.13 M KEY
wrongValueDiagnostics
[
{
"value": 1.17,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.39,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 10.5,
"misconception": "you multiplied the known side but never divided by the base's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(base) = 81.0 mL\nM(acid) = 0.390 M\nV(acid) = 27.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(base) the subject:\nM(base) = M(acid) × V(acid) ÷ V(base)\nSubstitute in the values, and calculate:\nM(base) = 0.390 × 27.0 ÷ 81.0\nM(base) = 0.130 M\nSanity check: the base needed three times the acid's volume, so it comes out a third as concentrated — 0.130 M against 0.390 M passes."
}
ABS-043 · hard · application · seq 16 · seed:pool[20] distractor design (needs-numbers variant) — outcome re-cased to EQUAL volumes (completes the acid/base/equal key spread across seqs 6/14/16); pair re-picked HNO₃+KOH per seed_placement · mcq4
A 39.0 mL sample of nitric acid reaches the endpoint after exactly 39.0 mL of potassium hydroxide solution has been added; the two react one-to-one. Which is more concentrated?
Neither — the two are equally concentrated KEY
The nitric acid
The potassium hydroxide solution
It cannot be judged without knowing at least one molarity
ABS-037 · hard · transfer · seq 17 · seed:pool[2]/spec 037 gate3 — claim design kept; explanation re-written instance-light (seed named HCl/NaOH + KNO₃/CaBr₂) · mcq4
A student says: 'Neutralization always produces table salt, NaCl.' Which correction is right?
Every neutralization produces a salt, but which salt depends on the acid and base used. KEY
The claim is right — in chemistry, the word salt means NaCl and nothing else.
The claim is wrong because many neutralizations produce only water and no salt at all.
The claim is wrong because neutralization produces no salt — salts come only from mines and seawater.
ABS-038 · hard · transfer · seq 18 · seed:pool[5]/spec 038 gate3 — reverse-identification design kept; ions re-picked Li⁺/NO₃⁻ per seed_placement (seed's HCl/KOH pair homed at seq 12) · mcq4
After a neutralization ran exactly to completion, the mixture contains only water molecules, Li⁺ ions, and NO₃⁻ ions. Which acid and base were mixed?
Nitric acid and lithium hydroxide KEY
Nitric acid and potassium hydroxide
Hydrochloric acid and lithium hydroxide
Lithium nitrate and water
ABS-041 · hard · transfer · seq 19 · seed:pool[14]/spec 041 gate3 — kept VERBATIM (ABS-025 boundary retrieval) · mcq4
A student says: 'A titration will tell us whether this acid is strong or weak.' Which correction is right?
A titration finds the acid's concentration — strength is a different property KEY
The student is right — the more concentrated an acid, the stronger it is
The student is almost right — a titration finds strength, but only for bases
The student is wrong because a titration measures nothing about the acid at all
ABS-044 · hard · transfer · seq 20 · seed:pool[22]/spec 044 gate2 — kept VERBATIM (spec-MANDATED H₂SO₄/NaOH non-example) · mcq4
A student wants to apply M(acid) × V(acid) = M(base) × V(base) to a titration of sulfuric acid, H₂SO₄, with sodium hydroxide, NaOH. Is that allowed?
No — H₂SO₄ and NaOH react one-to-two, not one-to-one KEY
Yes — the equation applies to every acid–base titration
Yes — because both solutions are strong, the equation applies
No — because sulfuric acid is too concentrated for titrations
ABS-040 · medium · application · seq 21 · seed:pool[11]/spec 040 gate production (demo_curated[2]) — model answer + checklist recast as parts (a)-(c) with rubric; model/rubric in the plain-digit TYPED register (V-T12) · frq
On paper, work out the balanced chemical equation for nitric acid, HNO₃, reacting with strontium hydroxide, Sr(OH)₂.
On paper, work out the balanced chemical equation for nitric acid, HNO₃, reacting with strontium hydroxide, Sr(OH)₂.
(a) Give both products of the neutralization, including the salt's formula.
(b) Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
(c) Check your balanced equation by counting each element's atoms on both sides.
Part a. Give both products of the neutralization, including the salt's formula.
Model: Products: the salt Sr(NO3)2 (Sr(2+) criss-crossed with NO3(1-) — the nitrate keeps its parentheses) and water.
Part b. Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
Model: First write, products once each (all coefficients 1): 1HNO3 + 1Sr(OH)2 -> 1Sr(NO3)2 + 1H2O. Count the pairs: each HNO3 gives one H(+) but Sr(OH)2 gives two OH(-), so two HNO3 are needed and the pairs make 2H2O. Balanced (coefficients of 1 left unwritten): 2HNO3 + Sr(OH)2 -> Sr(NO3)2 + 2H2O.
Part c. Check your balanced equation by counting each element's atoms on both sides.
Model: Check: 4 H, 2 N, 8 O, and 1 Sr on each side.
Full model answer. (a) Products: the salt Sr(NO3)2 (Sr(2+) criss-crossed with NO3(1-) — the nitrate keeps its parentheses) and water.
(b) First write, products once each (all coefficients 1): 1HNO3 + 1Sr(OH)2 -> 1Sr(NO3)2 + 1H2O. Count the pairs: each HNO3 gives one H(+) but Sr(OH)2 gives two OH(-), so two HNO3 are needed and the pairs make 2H2O. Balanced (coefficients of 1 left unwritten): 2HNO3 + Sr(OH)2 -> Sr(NO3)2 + 2H2O.
(c) Check: 4 H, 2 N, 8 O, and 1 Sr on each side.
ABS-045 · hard · application · seq 22 · authored calculation FRQ (ABS-045 R15 routine; 045 has no production seed — frq_prod_seeded=false; pair HBr+NaOH per home-pair ledger, values bank-unique; unknown direction rotates acid; model keeps ONE scaffold stage-marker — 'the subject' — per the wave V-T9 canon) · frq
A 33.0 mL portion of hydrobromic acid is titrated with sodium hydroxide solution of known concentration, 0.410 M. The endpoint arrives after 66.0 mL of the known solution has been delivered; the two react one-to-one.
A 33.0 mL portion of hydrobromic acid is titrated with sodium hydroxide solution of known concentration, 0.410 M. The endpoint arrives after 66.0 mL of the known solution has been delivered; the two react one-to-one.
(a) Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(acid) the subject.
(b) Substitute the values and calculate M(acid). Give the result with its unit, to 3 significant figures.
(c) Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Part a. Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(acid) the subject.
Model: The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(acid) the subject: M(acid) = M(base) × V(base) ÷ V(acid).
Part b. Substitute the values and calculate M(acid). Give the result with its unit, to 3 significant figures.
Part c. Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Model: Sanity check: the solution that needed the smaller volume must come out more concentrated — the acid needed 33.0 mL against the base's 66.0 mL — half the volume — so it should come out twice as concentrated: 0.820 M against 0.410 M passes.
Full model answer. (a) The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(acid) the subject: M(acid) = M(base) × V(base) ÷ V(acid).
(b) Values: V(acid) = 33.0 mL, M(base) = 0.410 M, V(base) = 66.0 mL.
Substitution: M(acid) = 0.410 × 66.0 ÷ 33.0
Result: M(acid) = 0.820 M
(c) Sanity check: the solution that needed the smaller volume must come out more concentrated — the acid needed 33.0 mL against the base's 66.0 mL — half the volume — so it should come out twice as concentrated: 0.820 M against 0.410 M passes.
A floor cleaner contains ammonia. A chemist titrates an 85.0 mL sample of the cleaner with hydrobromic acid whose concentration is already known, until the two have exactly reacted. Which quantity does the titration reveal?
The concentration of the ammonia in the cleaner KEY
The concentration of the hydrobromic acid
The volume of the 85.0 mL sample
The pH of the cleaner
ABS-038 · easy · application · seq 3 · authored parallel of pool[3] (ask rotated within the mechanism-bookkeeping case) · mcq4
Hydroiodic acid solution (H⁺ and I⁻ ions) neutralizes lithium hydroxide solution (Li⁺ and OH⁻ ions). Which two ions combine to form the water?
H⁺ and OH⁻ KEY
Li⁺ and I⁻
H⁺ and I⁻
Li⁺ and OH⁻
ABS-042 · easy · recall · seq 4 · authored parallel of pool[16] (stem reworded; same misconception trio) · mcq4
A few drops of indicator are added to the flask before a titration begins. What job do they do?
The indicator supplies a visible endpoint signal that two colorless solutions cannot KEY
The indicator makes the acid and the base react faster once mixed
The indicator neutralizes any acid still left over at the end of the titration
The indicator marks the level of solution on the flask so volumes can be read
ABS-039 · medium · application · seq 5 · authored parallel of pool[6] (Ca(OH)₂ family rotation) · text
Nitric acid, HNO₃, reacts with calcium hydroxide, Ca(OH)₂. Write the formula of the salt formed.
Answer: Ca(NO₃)₂ KEY
also accepted: Ca(NO3)2
wrongValueDiagnostics
[
{
"value": "CaNO₃",
"misconception": "you ignored the charges — one 1− nitrate cannot balance a 2+ calcium; calcium's 2 must cross to the nitrate",
"feedback": null
},
{
"value": "Ca₂NO₃",
"misconception": "you criss-crossed in reverse — calcium's 2 belongs on the nitrate group, outside its parentheses, not on calcium itself",
"feedback": null
},
{
"value": "CaN₂O₆",
"misconception": "you multiplied out the atoms — the nitrate ion stays whole, in parentheses, with its subscript outside",
"feedback": null
}
]
feedback
{
"keyExplanation": "The acid's negative ion: HNO₃ gives NO₃⁻. The base's metal ion: Ca(OH)₂ gives Ca²⁺. Criss-cross the charges: calcium's 2 crosses to the nitrate, which keeps its parentheses, giving Ca(NO₃)₂. Water forms alongside it."
}
ABS-043 · medium · application · seq 6 · authored parallel of pool[18] (fresh volumes, same case) · mcq4
A 93.0 mL sample of hydrobromic acid reaches the endpoint after only 31.0 mL of potassium hydroxide solution has been added; the two react one-to-one. Which is more concentrated?
The potassium hydroxide solution KEY
The hydrobromic acid
The two are equally concentrated
It cannot be judged from the volumes
ABS-040 · medium · application · seq 7 · authored parallel of pool[9] (same equation family, reframed stem) · text
Nitric acid, HNO₃, neutralizes sodium hydroxide, NaOH. Write the balanced chemical equation for the reaction, using the smallest whole-number coefficients.
[
{
"value": "HNO₃ + NaOH → NaNO₃ + H₂",
"misconception": "you released hydrogen gas — with a base, the acid's hydrogen ends up in water, not H₂",
"feedback": null
},
{
"value": "HNO₃ + NaOH → NaNO₃",
"misconception": "you dropped the water — the acid's H⁺ and the base's OH⁻ pair up and must appear as the product H₂O",
"feedback": null
},
{
"value": "2HNO₃ + 2NaOH → 2NaNO₃ + 2H₂O",
"misconception": "your equation is balanced, but not written in the smallest whole-number coefficients — every coefficient here can be divided by two",
"feedback": null
}
]
feedback
{
"keyExplanation": "Products: the salt NaNO₃ and water. Count the pairs: one H⁺ from HNO₃, one OH⁻ from NaOH — the counts match, so no coefficients are needed. HNO₃ + NaOH → NaNO₃ + H₂O. Check: 2 H, 1 N, 4 O, 1 Na on each side."
}
ABS-044 · medium · application · seq 8 · authored parallel of pool[21] (recorded-quantities set rotated) · mcq4
In a one-to-one titration, a student has recorded M(acid), V(acid), and V(base). Which quantity can now be found with the titration equation?
M(base) KEY
The acid's pH
Whether the acid is strong or weak
Nothing — all four quantities must already be known
ABS-042 · medium · application · seq 9 · authored parallel of pool[15] (ask rotated; flash-then-fade detail never tested per 042 extraNotes) · mcq4
A flask holds lithium hydroxide solution with a few drops of phenolphthalein, so it starts out pink. Hydrochloric acid is added slowly from the tube. When should the additions stop?
When the pink disappears and does not come back, even as the contents are mixed KEY
When the pink has deepened as far as it will go
When all of the acid in the tube has been delivered
As soon as the first drop of acid has landed in the flask
ABS-044 · medium · application · seq 10 · authored parallel of pool[23] (fresh mL/L pair) · mcq4
A student's titration notes record V(acid) = 68.0 mL and V(base) = 0.0510 L. What must happen before these values can be used in M(acid) × V(acid) = M(base) × V(base)?
Express both volumes in the same unit KEY
Nothing — the equation works with any mix of volume units
Convert both volumes into moles first
Convert the two molarities into grams
ABS-039 · medium · application · seq 11 · authored parallel of pool[8] (stem reworded; spec's permutational distractor set kept) · mcq4
Sulfuric acid, H₂SO₄, reacts with lithium hydroxide, LiOH. Which is the salt produced?
Li₂SO₄ KEY
LiSO₄
Li(SO₄)₂
Li₂(SO₄)₂
ABS-045 · medium · application · seq 12 · authored parallel of pool[24] (fresh values, same routine) · numeric
A 78.0 mL sample of hydrochloric acid is neutralized at the endpoint by 26.0 mL of 0.660 M potassium hydroxide solution; the two react one-to-one. What is the molarity of the acid, in M? Give your answer to 3 significant figures.
Answer: 0.22 M KEY
wrongValueDiagnostics
[
{
"value": 1.98,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.66,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 17.2,
"misconception": "you multiplied the known side but never divided by the acid's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(acid) = 78.0 mL\nM(base) = 0.660 M\nV(base) = 26.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(acid) the subject:\nM(acid) = M(base) × V(base) ÷ V(acid)\nSubstitute in the values, and calculate:\nM(acid) = 0.660 × 26.0 ÷ 78.0\nM(acid) = 0.220 M\nSanity check: the acid needed three times the base's volume, so it comes out a third as concentrated — 0.220 M against 0.660 M passes."
}
ABS-040 · medium · application · seq 13 · authored parallel of pool[10] (stem reframed; same equation family + distractor set) · mcq4
Hydrobromic acid neutralizes barium hydroxide. Which equation is correctly balanced?
2HBr + Ba(OH)₂ → BaBr₂ + 2H₂O KEY
HBr + Ba(OH)₂ → BaBr₂ + H₂O
2HBr + Ba(OH)₂ → Ba₂Br + 2H₂O
2HBr + Ba(OH)₂ → BaBr₂ + 2H₂
ABS-043 · medium · application · seq 14 · authored parallel of pool[19] (fresh volumes + hunch wording) · mcq4
Reaching the endpoint took 98.0 mL of sodium hydroxide solution for a 49.0 mL sample of hydroiodic acid; the two react one-to-one. A student reasons: 'more base was used, so the base must be the stronger solution here — the more concentrated one.' Which is actually more concentrated?
The hydroiodic acid KEY
The sodium hydroxide solution
The two are equally concentrated
It cannot be judged from the volumes
ABS-045 · hard · application · seq 15 · authored parallel of pool[25] (fresh values, same routine) · numeric
A 17.0 mL sample of lithium hydroxide solution reaches the endpoint once 34.0 mL of 0.230 M hydrobromic acid has gone in; the two react one-to-one. What is the molarity of the base, in M? Give your answer to 3 significant figures.
Answer: 0.46 M KEY
wrongValueDiagnostics
[
{
"value": 0.115,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.23,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 7.82,
"misconception": "you multiplied the known side but never divided by the base's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(base) = 17.0 mL\nM(acid) = 0.230 M\nV(acid) = 34.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(base) the subject:\nM(base) = M(acid) × V(acid) ÷ V(base)\nSubstitute in the values, and calculate:\nM(base) = 0.230 × 34.0 ÷ 17.0\nM(base) = 0.460 M\nSanity check: the base needed half the acid's volume, so it comes out twice as concentrated — 0.460 M against 0.230 M passes."
}
ABS-043 · hard · application · seq 16 · authored parallel of pool[20] (fresh equal volumes) · mcq4
Neutralizing a 46.0 mL sample of nitric acid took exactly 46.0 mL of potassium hydroxide solution at the endpoint; the two react one-to-one. Which is more concentrated?
Neither — the two are equally concentrated KEY
The nitric acid
The potassium hydroxide solution
It cannot be judged without knowing at least one molarity
ABS-037 · hard · transfer · seq 17 · authored parallel of pool[2] (claimant/context rotated) · mcq4
A lab partner insists: 'whatever acid and base you mix, the salt you get is table salt, NaCl.' Which correction is right?
Every neutralization produces a salt, but which salt depends on the acid and base used. KEY
The claim is right — in chemistry, the word salt means NaCl and nothing else.
The claim is wrong because many neutralizations produce only water and no salt at all.
The claim is wrong because neutralization produces no salt — salts come only from mines and seawater.
ABS-038 · hard · transfer · seq 18 · authored parallel of pool[5] (stem reworded; same reverse design) · mcq4
A completed neutralization leaves nothing in the flask but water molecules, Li⁺ ions, and NO₃⁻ ions. Which acid and base reacted?
Nitric acid and lithium hydroxide KEY
Nitric acid and potassium hydroxide
Hydrochloric acid and lithium hydroxide
Lithium nitrate and water
ABS-041 · hard · transfer · seq 19 · authored parallel of pool[14] (claim wording rotated) · mcq4
A student proposes: 'let's titrate this acid to find out how strong it is.' Which correction is right?
A titration finds the acid's concentration — strength is a different property KEY
The student is right — the more concentrated an acid, the stronger it is
The student is almost right — a titration finds strength, but only for bases
The student is wrong because a titration measures nothing about the acid at all
ABS-044 · hard · transfer · seq 20 · authored parallel of pool[22] (ask rotated; spec-mandated instance kept per A-U11G4-4) · mcq4
Why can the titration equation M(acid) × V(acid) = M(base) × V(base) NOT be used for a titration of sulfuric acid, H₂SO₄, with sodium hydroxide, NaOH?
H₂SO₄ and NaOH react one-to-two, so the two mole counts at the endpoint are unequal KEY
It can be used — the equation applies to every acid–base titration
Because sulfuric acid is too concentrated for titrations
Because the equation only works when the acid sits in the flask
ABS-040 · medium · application · seq 21 · authored parallel of pool[11] (seq-21 case family rotation: HCl + Sr(OH)₂) · frq
On paper, work out the balanced chemical equation for hydrochloric acid, HCl, reacting with strontium hydroxide, Sr(OH)₂.
On paper, work out the balanced chemical equation for hydrochloric acid, HCl, reacting with strontium hydroxide, Sr(OH)₂.
(a) Give both products of the neutralization, including the salt's formula.
(b) Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
(c) Check your balanced equation by counting each element's atoms on both sides.
Part a. Give both products of the neutralization, including the salt's formula.
Model: Products: the salt SrCl2 (Sr(2+) criss-crossed with Cl(1-) — strontium's 2 crosses to the chloride) and water.
Part b. Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
Model: First write, products once each (all coefficients 1): 1HCl + 1Sr(OH)2 -> 1SrCl2 + 1H2O. Count the pairs: each HCl gives one H(+) but Sr(OH)2 gives two OH(-), so two HCl are needed and the pairs make 2H2O. Balanced (coefficients of 1 left unwritten): 2HCl + Sr(OH)2 -> SrCl2 + 2H2O.
Part c. Check your balanced equation by counting each element's atoms on both sides.
Model: Check: 4 H, 2 Cl, 2 O, and 1 Sr on each side.
Full model answer. (a) Products: the salt SrCl2 (Sr(2+) criss-crossed with Cl(1-) — strontium's 2 crosses to the chloride) and water.
(b) First write, products once each (all coefficients 1): 1HCl + 1Sr(OH)2 -> 1SrCl2 + 1H2O. Count the pairs: each HCl gives one H(+) but Sr(OH)2 gives two OH(-), so two HCl are needed and the pairs make 2H2O. Balanced (coefficients of 1 left unwritten): 2HCl + Sr(OH)2 -> SrCl2 + 2H2O.
(c) Check: 4 H, 2 Cl, 2 O, and 1 Sr on each side.
ABS-045 · hard · application · seq 22 · authored calculation FRQ (ABS-045 R15 routine; 045 has no production seed — frq_prod_seeded=false; pair HBr+NaOH per home-pair ledger, values bank-unique; unknown direction rotates base; model keeps ONE scaffold stage-marker — 'the subject' — per the wave V-T9 canon) · frq
A 56.0 mL portion of sodium hydroxide solution is titrated with hydrobromic acid of known concentration, 0.640 M. The endpoint arrives after 14.0 mL of the known solution has been delivered; the two react one-to-one.
A 56.0 mL portion of sodium hydroxide solution is titrated with hydrobromic acid of known concentration, 0.640 M. The endpoint arrives after 14.0 mL of the known solution has been delivered; the two react one-to-one.
(a) Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(base) the subject.
(b) Substitute the values and calculate M(base). Give the result with its unit, to 3 significant figures.
(c) Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Part a. Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(base) the subject.
Model: The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(base) the subject: M(base) = M(acid) × V(acid) ÷ V(base).
Part b. Substitute the values and calculate M(base). Give the result with its unit, to 3 significant figures.
Part c. Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Model: Sanity check: the solution that needed the smaller volume must come out more concentrated — the base needed 56.0 mL against the acid's 14.0 mL — four times the volume — so it should come out a quarter as concentrated: 0.160 M against 0.640 M passes.
Full model answer. (a) The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(base) the subject: M(base) = M(acid) × V(acid) ÷ V(base).
(b) Values: V(base) = 56.0 mL, M(acid) = 0.640 M, V(acid) = 14.0 mL.
Substitution: M(base) = 0.640 × 14.0 ÷ 56.0
Result: M(base) = 0.160 M
(c) Sanity check: the solution that needed the smaller volume must come out more concentrated — the base needed 56.0 mL against the acid's 14.0 mL — four times the volume — so it should come out a quarter as concentrated: 0.160 M against 0.640 M passes.
A greenhouse fertilizer solution contains ammonia. A chemist titrates an 87.0 mL sample of the fertilizer solution with hydrobromic acid whose concentration is already known, until the two have exactly reacted. Which quantity does the titration reveal?
The concentration of the ammonia in the fertilizer solution KEY
The concentration of the hydrobromic acid
The volume of the 87.0 mL sample
The pH of the fertilizer solution
ABS-038 · easy · application · seq 3 · authored parallel of pool[3] (ask rotated within the mechanism-bookkeeping case) · mcq4
After hydroiodic acid solution has exactly neutralized lithium hydroxide solution, which two ions remain dissolved as the salt?
Li⁺ and I⁻ KEY
H⁺ and OH⁻
Li⁺ and OH⁻
H⁺ and I⁻
ABS-042 · easy · recall · seq 4 · authored parallel of pool[16] (stem reworded; same misconception trio) · mcq4
A student sets up a titration but forgets to add the indicator drops. What job will go missing?
The indicator provides the visible signal that marks the endpoint KEY
The indicator makes the acid and the base react faster once mixed
The indicator neutralizes any acid still left over at the end of the titration
The indicator marks the level of solution on the flask so volumes can be read
ABS-039 · medium · application · seq 5 · authored parallel of pool[6] (Ca(OH)₂ family rotation) · text
A student mixes hydroiodic acid, HI, with calcium hydroxide solution, Ca(OH)₂. Write the formula of the salt these two produce.
Answer: CaI₂ KEY
also accepted: CaI2
wrongValueDiagnostics
[
{
"value": "CaH₂",
"misconception": "you paired the metal with the acid's hydrogen — the salt takes the acid's NEGATIVE ion, I⁻",
"feedback": null
},
{
"value": "CaI",
"misconception": "you ignored the charges — one 1− iodide cannot balance a 2+ calcium; calcium's 2 must cross to the iodide",
"feedback": null
},
{
"value": "Ca₂I",
"misconception": "you criss-crossed in reverse — calcium's 2 becomes the IODIDE's subscript, not calcium's own",
"feedback": null
}
]
feedback
{
"keyExplanation": "The acid's negative ion: HI gives I⁻. The base's metal ion: Ca(OH)₂ gives Ca²⁺. Criss-cross the charges: calcium's 2 crosses to the iodide, giving CaI₂. Water forms alongside it."
}
ABS-043 · medium · application · seq 6 · authored parallel of pool[18] (fresh volumes, same case) · mcq4
At the endpoint, a 76.0 mL sample of hydrobromic acid has been neutralized by 38.0 mL of potassium hydroxide solution; the two react one-to-one. Which is more concentrated?
The potassium hydroxide solution KEY
The hydrobromic acid
The two are equally concentrated
It cannot be judged from the volumes
ABS-040 · medium · application · seq 7 · authored parallel of pool[9] (same equation family, reframed stem) · text
Write the balanced chemical equation, using the smallest whole-number coefficients, for the neutralization of sodium hydroxide, NaOH, by nitric acid, HNO₃.
[
{
"value": "HNO₃ + NaOH → NaNO₃ + H₂",
"misconception": "you released hydrogen gas — with a base, the acid's hydrogen ends up in water, not H₂",
"feedback": null
},
{
"value": "HNO₃ + NaOH → NaNO₃",
"misconception": "you dropped the water — the acid's H⁺ and the base's OH⁻ pair up and must appear as the product H₂O",
"feedback": null
},
{
"value": "2HNO₃ + 2NaOH → 2NaNO₃ + 2H₂O",
"misconception": "your equation is balanced, but not written in the smallest whole-number coefficients — every coefficient here can be divided by two",
"feedback": null
}
]
feedback
{
"keyExplanation": "Products: the salt NaNO₃ and water. Count the pairs: one H⁺ from HNO₃, one OH⁻ from NaOH — the counts match, so no coefficients are needed. HNO₃ + NaOH → NaNO₃ + H₂O. Check: 2 H, 1 N, 4 O, 1 Na on each side."
}
ABS-044 · medium · application · seq 8 · authored parallel of pool[21] (recorded-quantities set rotated) · mcq4
A data sheet from a one-to-one titration lists values for M(base), V(base), and V(acid). Which quantity can the titration equation deliver?
M(acid) KEY
The acid's pH
Whether the acid is strong or weak
Nothing — all four quantities must already be known
ABS-042 · medium · application · seq 9 · authored parallel of pool[15] (ask rotated; flash-then-fade detail never tested per 042 extraNotes) · mcq4
A flask holds lithium hydroxide solution with a few drops of phenolphthalein, so it starts out pink. Hydrochloric acid is added slowly from the tube. What does the endpoint look like in this flask?
The pink color disappears and does not come back KEY
The pink color deepens sharply
The solution turns from pink to blue
Nothing is observed, because phenolphthalein only works when base is added to acid
ABS-044 · medium · application · seq 10 · authored parallel of pool[23] (fresh mL/L pair) · mcq4
Recorded from a titration: V(acid) = 83.0 mL, V(base) = 0.0590 L. Before substituting into M(acid) × V(acid) = M(base) × V(base), what is required?
Express both volumes in the same unit KEY
Nothing — the equation works with any mix of volume units
Convert both volumes into moles first
Convert the two molarities into grams
ABS-039 · medium · application · seq 11 · authored parallel of pool[8] (stem reworded; spec's permutational distractor set kept) · mcq4
When lithium hydroxide, LiOH, is neutralized by sulfuric acid, H₂SO₄, which salt forms?
Li₂SO₄ KEY
LiSO₄
Li(SO₄)₂
Li₂(SO₄)₂
ABS-045 · medium · application · seq 12 · authored parallel of pool[24] (fresh values, same routine) · numeric
Titrating a 19.0 mL sample of hydrochloric acid to the endpoint takes 57.0 mL of 0.180 M potassium hydroxide solution; the two react one-to-one. What is the molarity of the acid, in M? Give your answer to 3 significant figures.
Answer: 0.54 M KEY
wrongValueDiagnostics
[
{
"value": 0.06,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.18,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 10.3,
"misconception": "you multiplied the known side but never divided by the acid's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(acid) = 19.0 mL\nM(base) = 0.180 M\nV(base) = 57.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(acid) the subject:\nM(acid) = M(base) × V(base) ÷ V(acid)\nSubstitute in the values, and calculate:\nM(acid) = 0.180 × 57.0 ÷ 19.0\nM(acid) = 0.540 M\nSanity check: the acid needed a third of the base's volume, so it comes out three times as concentrated — 0.540 M against 0.180 M passes."
}
ABS-040 · medium · application · seq 13 · authored parallel of pool[10] (stem reframed; same equation family + distractor set) · mcq4
A student writes four candidate equations for hydrobromic acid reacting with barium hydroxide. Which one is correct?
2HBr + Ba(OH)₂ → BaBr₂ + 2H₂O KEY
HBr + Ba(OH)₂ → BaBr₂ + H₂O
2HBr + Ba(OH)₂ → Ba₂Br + 2H₂O
2HBr + Ba(OH)₂ → BaBr₂ + 2H₂
ABS-043 · medium · application · seq 14 · authored parallel of pool[19] (fresh volumes + hunch wording) · mcq4
Reaching the endpoint took 21.0 mL of sodium hydroxide solution for a 7.0 mL sample of hydroiodic acid; the two react one-to-one. A student argues the base 'did most of the work, so it must be the more concentrated solution.' Which is actually more concentrated?
The hydroiodic acid KEY
The sodium hydroxide solution
The two are equally concentrated
It cannot be judged from the volumes
ABS-045 · hard · application · seq 15 · authored parallel of pool[25] (fresh values, same routine) · numeric
Titrating a 32.0 mL sample of lithium hydroxide solution to the endpoint takes 64.0 mL of 0.210 M hydrobromic acid; the two react one-to-one. What is the molarity of the base, in M? Give your answer to 3 significant figures.
Answer: 0.42 M KEY
wrongValueDiagnostics
[
{
"value": 0.105,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.21,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 13.4,
"misconception": "you multiplied the known side but never divided by the base's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(base) = 32.0 mL\nM(acid) = 0.210 M\nV(acid) = 64.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(base) the subject:\nM(base) = M(acid) × V(acid) ÷ V(base)\nSubstitute in the values, and calculate:\nM(base) = 0.210 × 64.0 ÷ 32.0\nM(base) = 0.420 M\nSanity check: the base needed half the acid's volume, so it comes out twice as concentrated — 0.420 M against 0.210 M passes."
}
ABS-043 · hard · application · seq 16 · authored parallel of pool[20] (fresh equal volumes) · mcq4
At the endpoint, a 53.0 mL sample of nitric acid has been neutralized by exactly 53.0 mL of potassium hydroxide solution; the two react one-to-one. Which is more concentrated?
Neither — the two are equally concentrated KEY
The nitric acid
The potassium hydroxide solution
It cannot be judged without knowing at least one molarity
ABS-037 · hard · transfer · seq 17 · authored parallel of pool[2] (claimant/context rotated) · mcq4
A classmate's notes read: 'the salt in a neutralization is always NaCl.' Which correction is right?
Every neutralization produces a salt, but which salt depends on the acid and base used. KEY
The claim is right — in chemistry, the word salt means NaCl and nothing else.
The claim is wrong because many neutralizations produce only water and no salt at all.
The claim is wrong because neutralization produces no salt — salts come only from mines and seawater.
ABS-038 · hard · transfer · seq 18 · authored parallel of pool[5] (stem reworded; same reverse design) · mcq4
When a neutralization finished exactly, the only particles left were H₂O molecules, Li⁺ ions, and NO₃⁻ ions. Which acid and base were combined?
Nitric acid and lithium hydroxide KEY
Nitric acid and potassium hydroxide
Hydrochloric acid and lithium hydroxide
Lithium nitrate and water
ABS-041 · hard · transfer · seq 19 · authored parallel of pool[14] (claim wording rotated) · mcq4
A lab notebook entry reads: 'titration result will show if the acid is strong or weak.' Which correction is right?
A titration finds the acid's concentration — strength is a different property KEY
The student is right — the more concentrated an acid, the stronger it is
The student is almost right — a titration finds strength, but only for bases
The student is wrong because a titration measures nothing about the acid at all
ABS-044 · hard · transfer · seq 20 · authored parallel of pool[22] (ask rotated; spec-mandated instance kept per A-U11G4-4) · mcq4
A student applies M(acid) × V(acid) = M(base) × V(base) to a titration of sulfuric acid, H₂SO₄, with sodium hydroxide, NaOH. What is wrong with the plan?
The pair reacts one-to-two, so the equation's one-to-one condition fails KEY
Nothing — the equation applies to every acid–base titration
Sulfuric acid cannot be titrated at all
The equation requires a weak acid, and sulfuric acid is strong
ABS-040 · medium · application · seq 21 · authored parallel of pool[11] (seq-21 case family rotation: HI + Sr(OH)₂) · frq
On paper, work out the balanced chemical equation for hydroiodic acid, HI, reacting with strontium hydroxide, Sr(OH)₂.
On paper, work out the balanced chemical equation for hydroiodic acid, HI, reacting with strontium hydroxide, Sr(OH)₂.
(a) Give both products of the neutralization, including the salt's formula.
(b) Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
(c) Check your balanced equation by counting each element's atoms on both sides.
Part a. Give both products of the neutralization, including the salt's formula.
Model: Products: the salt SrI2 (Sr(2+) criss-crossed with I(1-) — strontium's 2 crosses to the iodide) and water.
Part b. Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
Model: First write, products once each (all coefficients 1): 1HI + 1Sr(OH)2 -> 1SrI2 + 1H2O. Count the pairs: each HI gives one H(+) but Sr(OH)2 gives two OH(-), so two HI are needed and the pairs make 2H2O. Balanced (coefficients of 1 left unwritten): 2HI + Sr(OH)2 -> SrI2 + 2H2O.
Part c. Check your balanced equation by counting each element's atoms on both sides.
Model: Check: 4 H, 2 I, 2 O, and 1 Sr on each side.
Full model answer. (a) Products: the salt SrI2 (Sr(2+) criss-crossed with I(1-) — strontium's 2 crosses to the iodide) and water.
(b) First write, products once each (all coefficients 1): 1HI + 1Sr(OH)2 -> 1SrI2 + 1H2O. Count the pairs: each HI gives one H(+) but Sr(OH)2 gives two OH(-), so two HI are needed and the pairs make 2H2O. Balanced (coefficients of 1 left unwritten): 2HI + Sr(OH)2 -> SrI2 + 2H2O.
(c) Check: 4 H, 2 I, 2 O, and 1 Sr on each side.
ABS-045 · hard · application · seq 22 · authored calculation FRQ (ABS-045 R15 routine; 045 has no production seed — frq_prod_seeded=false; pair HBr+NaOH per home-pair ledger, values bank-unique; unknown direction rotates acid; model keeps ONE scaffold stage-marker — 'the subject' — per the wave V-T9 canon) · frq
A 43.0 mL portion of hydrobromic acid is titrated with sodium hydroxide solution of known concentration, 0.290 M. The endpoint arrives after 86.0 mL of the known solution has been delivered; the two react one-to-one.
A 43.0 mL portion of hydrobromic acid is titrated with sodium hydroxide solution of known concentration, 0.290 M. The endpoint arrives after 86.0 mL of the known solution has been delivered; the two react one-to-one.
(a) Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(acid) the subject.
(b) Substitute the values and calculate M(acid). Give the result with its unit, to 3 significant figures.
(c) Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Part a. Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(acid) the subject.
Model: The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(acid) the subject: M(acid) = M(base) × V(base) ÷ V(acid).
Part b. Substitute the values and calculate M(acid). Give the result with its unit, to 3 significant figures.
Part c. Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Model: Sanity check: the solution that needed the smaller volume must come out more concentrated — the acid needed 43.0 mL against the base's 86.0 mL — half the volume — so it should come out twice as concentrated: 0.580 M against 0.290 M passes.
Full model answer. (a) The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(acid) the subject: M(acid) = M(base) × V(base) ÷ V(acid).
(b) Values: V(acid) = 43.0 mL, M(base) = 0.290 M, V(base) = 86.0 mL.
Substitution: M(acid) = 0.290 × 86.0 ÷ 43.0
Result: M(acid) = 0.580 M
(c) Sanity check: the solution that needed the smaller volume must come out more concentrated — the acid needed 43.0 mL against the base's 86.0 mL — half the volume — so it should come out twice as concentrated: 0.580 M against 0.290 M passes.
A metal-cleaning bath contains ammonia. A chemist titrates a 95.0 mL sample of the bath solution with hydrobromic acid whose concentration is already known, until the two have exactly reacted. Which quantity does the titration reveal?
The concentration of the ammonia in the bath solution KEY
The concentration of the hydrobromic acid
The volume of the 95.0 mL sample
The pH of the bath solution
ABS-038 · easy · application · seq 3 · authored parallel of pool[3] (ask rotated within the mechanism-bookkeeping case) · mcq4
When hydroiodic acid solution neutralizes lithium hydroxide solution, which ions are removed from the solution by being locked into water molecules?
H⁺ and OH⁻ KEY
Li⁺ and I⁻
H⁺ and I⁻
Li⁺ and OH⁻
ABS-042 · easy · recall · seq 4 · authored parallel of pool[16] (stem reworded; same misconception trio) · mcq4
What does the indicator supply that the acid and base solutions themselves do not?
The indicator adds a visible endpoint signal — the acid and base can both be colorless KEY
The indicator makes the acid and the base react faster once mixed
The indicator neutralizes any acid still left over at the end of the titration
The indicator marks the level of solution on the flask so volumes can be read
ABS-039 · medium · application · seq 5 · authored parallel of pool[6] (Ca(OH)₂ family rotation) · text
When nitric acid, HNO₃, neutralizes calcium hydroxide, Ca(OH)₂, a salt and water form. Write the salt's formula.
Answer: Ca(NO₃)₂ KEY
also accepted: Ca(NO3)2
wrongValueDiagnostics
[
{
"value": "CaNO₃",
"misconception": "you ignored the charges — one 1− nitrate cannot balance a 2+ calcium; calcium's 2 must cross to the nitrate",
"feedback": null
},
{
"value": "Ca₂NO₃",
"misconception": "you criss-crossed in reverse — calcium's 2 belongs on the nitrate group, outside its parentheses, not on calcium itself",
"feedback": null
},
{
"value": "CaN₂O₆",
"misconception": "you multiplied out the atoms — the nitrate ion stays whole, in parentheses, with its subscript outside",
"feedback": null
}
]
feedback
{
"keyExplanation": "The acid's negative ion: HNO₃ gives NO₃⁻. The base's metal ion: Ca(OH)₂ gives Ca²⁺. Criss-cross the charges: calcium's 2 crosses to the nitrate, which keeps its parentheses, giving Ca(NO₃)₂. Water forms alongside it."
}
ABS-043 · medium · application · seq 6 · authored parallel of pool[18] (fresh volumes, same case) · mcq4
Titrating a 91.0 mL sample of hydrobromic acid to the endpoint used only 13.0 mL of potassium hydroxide solution; the two react one-to-one. Which is more concentrated?
The potassium hydroxide solution KEY
The hydrobromic acid
The two are equally concentrated
It cannot be judged from the volumes
ABS-040 · medium · application · seq 7 · authored parallel of pool[9] (same equation family, reframed stem) · text
A flask of sodium hydroxide, NaOH, is exactly neutralized by nitric acid, HNO₃. Write the balanced chemical equation, using the smallest whole-number coefficients.
[
{
"value": "HNO₃ + NaOH → NaNO₃ + H₂",
"misconception": "you released hydrogen gas — with a base, the acid's hydrogen ends up in water, not H₂",
"feedback": null
},
{
"value": "HNO₃ + NaOH → NaNO₃",
"misconception": "you dropped the water — the acid's H⁺ and the base's OH⁻ pair up and must appear as the product H₂O",
"feedback": null
},
{
"value": "2HNO₃ + 2NaOH → 2NaNO₃ + 2H₂O",
"misconception": "your equation is balanced, but not written in the smallest whole-number coefficients — every coefficient here can be divided by two",
"feedback": null
}
]
feedback
{
"keyExplanation": "Products: the salt NaNO₃ and water. Count the pairs: one H⁺ from HNO₃, one OH⁻ from NaOH — the counts match, so no coefficients are needed. HNO₃ + NaOH → NaNO₃ + H₂O. Check: 2 H, 1 N, 4 O, 1 Na on each side."
}
ABS-044 · medium · application · seq 8 · authored parallel of pool[21] (recorded-quantities set rotated) · mcq4
A one-to-one titration's records show M(acid), V(acid), and V(base). Which quantity can the titration equation deliver?
M(base) KEY
The acid's pH
Whether the acid is strong or weak
Nothing — all four quantities must already be known
ABS-042 · medium · application · seq 9 · authored parallel of pool[15] (ask rotated; flash-then-fade detail never tested per 042 extraNotes) · mcq4
A flask holds lithium hydroxide solution with a few drops of phenolphthalein, so it starts out pink. Hydrochloric acid is added slowly from the tube. How does the student know when to stop adding acid?
When the pink disappears and does not come back, even as the contents are mixed KEY
When the pink has deepened as far as it will go
When all of the acid in the tube has been delivered
As soon as the first drop of acid has landed in the flask
ABS-044 · medium · application · seq 10 · authored parallel of pool[23] (fresh mL/L pair) · mcq4
A lab report gives V(acid) = 71.0 mL and V(base) = 0.0650 L. What must be done before these two volumes go into the titration equation?
Express both volumes in the same unit KEY
Nothing — the equation works with any mix of volume units
Convert both volumes into moles first
Convert the two molarities into grams
ABS-039 · medium · application · seq 11 · authored parallel of pool[8] (stem reworded; spec's permutational distractor set kept) · mcq4
A neutralization mixes sulfuric acid, H₂SO₄, with lithium hydroxide, LiOH. Which formula shows the salt?
Li₂SO₄ KEY
LiSO₄
Li(SO₄)₂
Li₂(SO₄)₂
ABS-045 · medium · application · seq 12 · authored parallel of pool[24] (fresh values, same routine) · numeric
The endpoint of a titration arrives after a 55.0 mL sample of hydrochloric acid has taken up 44.0 mL of 0.450 M potassium hydroxide solution; the two react one-to-one. What is the molarity of the acid, in M? Give your answer to 3 significant figures.
Answer: 0.36 M KEY
wrongValueDiagnostics
[
{
"value": 0.563,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.45,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 19.8,
"misconception": "you multiplied the known side but never divided by the acid's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(acid) = 55.0 mL\nM(base) = 0.450 M\nV(base) = 44.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(acid) the subject:\nM(acid) = M(base) × V(base) ÷ V(acid)\nSubstitute in the values, and calculate:\nM(acid) = 0.450 × 44.0 ÷ 55.0\nM(acid) = 0.360 M\nSanity check: the acid needed more volume than the base, so it comes out less concentrated — 0.360 M against 0.450 M passes."
}
ABS-040 · medium · application · seq 13 · authored parallel of pool[10] (stem reframed; same equation family + distractor set) · mcq4
Which equation correctly shows hydrobromic acid reacting with barium hydroxide — right salt AND balanced?
2HBr + Ba(OH)₂ → BaBr₂ + 2H₂O KEY
HBr + Ba(OH)₂ → BaBr₂ + H₂O
2HBr + Ba(OH)₂ → Ba₂Br + 2H₂O
2HBr + Ba(OH)₂ → BaBr₂ + 2H₂
ABS-043 · medium · application · seq 14 · authored parallel of pool[19] (fresh volumes + hunch wording) · mcq4
Reaching the endpoint took 77.0 mL of sodium hydroxide solution for an 11.0 mL sample of hydroiodic acid; the two react one-to-one. A student writes: 'the base contributed the bigger volume, so the base is the more concentrated.' Which is actually more concentrated?
The hydroiodic acid KEY
The sodium hydroxide solution
The two are equally concentrated
It cannot be judged from the volumes
ABS-045 · hard · application · seq 15 · authored parallel of pool[25] (fresh values, same routine) · numeric
The endpoint arrives when an 88.0 mL sample of lithium hydroxide solution has taken up 22.0 mL of 0.760 M hydrobromic acid; the two react one-to-one. What is the molarity of the base, in M? Give your answer to 3 significant figures.
Answer: 0.19 M KEY
wrongValueDiagnostics
[
{
"value": 3.04,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.76,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 16.7,
"misconception": "you multiplied the known side but never divided by the base's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(base) = 88.0 mL\nM(acid) = 0.760 M\nV(acid) = 22.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(base) the subject:\nM(base) = M(acid) × V(acid) ÷ V(base)\nSubstitute in the values, and calculate:\nM(base) = 0.760 × 22.0 ÷ 88.0\nM(base) = 0.190 M\nSanity check: the base needed four times the acid's volume, so it comes out a quarter as concentrated — 0.190 M against 0.760 M passes."
}
ABS-043 · hard · application · seq 16 · authored parallel of pool[20] (fresh equal volumes) · mcq4
A titration of a 61.0 mL nitric acid sample reaches its endpoint at exactly 61.0 mL of potassium hydroxide solution delivered; the two react one-to-one. Which is more concentrated?
Neither — the two are equally concentrated KEY
The nitric acid
The potassium hydroxide solution
It cannot be judged without knowing at least one molarity
ABS-037 · hard · transfer · seq 17 · authored parallel of pool[2] (claimant/context rotated) · mcq4
During a review session a student claims: 'every acid–metal hydroxide neutralization makes NaCl — that is what salt means.' Which correction is right?
Every neutralization produces a salt, but which salt depends on the acid and base used. KEY
The claim is right — in chemistry, the word salt means NaCl and nothing else.
The claim is wrong because many neutralizations produce only water and no salt at all.
The claim is wrong because neutralization produces no salt — salts come only from mines and seawater.
ABS-038 · hard · transfer · seq 18 · authored parallel of pool[5] (stem reworded; same reverse design) · mcq4
Analysis of a mixture after an exact neutralization finds only water, Li⁺ ions, and NO₃⁻ ions. Which two solutions were mixed?
Nitric acid and lithium hydroxide KEY
Nitric acid and potassium hydroxide
Hydrochloric acid and lithium hydroxide
Lithium nitrate and water
ABS-041 · hard · transfer · seq 19 · authored parallel of pool[14] (claim wording rotated) · mcq4
Planning an experiment, a student writes: 'the titration will measure the acid's strength.' Which correction is right?
A titration finds the acid's concentration — strength is a different property KEY
The student is right — the more concentrated an acid, the stronger it is
The student is almost right — a titration finds strength, but only for bases
The student is wrong because a titration measures nothing about the acid at all
ABS-044 · hard · transfer · seq 20 · authored parallel of pool[22] (ask rotated; spec-mandated instance kept per A-U11G4-4) · mcq4
Which condition for using the titration equation M(acid) × V(acid) = M(base) × V(base) does a titration of sulfuric acid, H₂SO₄, with sodium hydroxide, NaOH, fail?
The acid and the base must react one-to-one — this pair reacts one-to-two KEY
The two volumes must be equal — and these differ
The acid must sit in the flask — and here it is in the tube
Both solutions must be weak — and both of these are strong
ABS-040 · medium · application · seq 21 · authored parallel of pool[11] (seq-21 case family rotation: HI + KOH) · frq
On paper, work out the balanced chemical equation for hydroiodic acid, HI, reacting with potassium hydroxide, KOH.
On paper, work out the balanced chemical equation for hydroiodic acid, HI, reacting with potassium hydroxide, KOH.
(a) Give both products of the neutralization, including the salt's formula.
(b) Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
(c) Check your balanced equation by counting each element's atoms on both sides.
Part a. Give both products of the neutralization, including the salt's formula.
Model: Products: the salt KI (K(+) paired one-to-one with I(1-) — equal charge numbers, so no subscripts) and water.
Part b. Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
Model: First write, products once each (all coefficients 1): 1HI + 1KOH -> 1KI + 1H2O. Count the pairs: one HI gives one H(+) and one KOH gives one OH(-) — the counts already match, so no coefficient needs changing. The first write is already balanced; coefficients of 1 are left unwritten in the final answer.
Part c. Check your balanced equation by counting each element's atoms on both sides.
Model: Check: 2 H, 1 I, 1 K, and 1 O on each side.
Full model answer. (a) Products: the salt KI (K(+) paired one-to-one with I(1-) — equal charge numbers, so no subscripts) and water.
(b) First write, products once each (all coefficients 1): 1HI + 1KOH -> 1KI + 1H2O. Count the pairs: one HI gives one H(+) and one KOH gives one OH(-) — the counts already match, so no coefficient needs changing. The first write is already balanced; coefficients of 1 are left unwritten in the final answer.
(c) Check: 2 H, 1 I, 1 K, and 1 O on each side.
ABS-045 · hard · application · seq 22 · authored calculation FRQ (ABS-045 R15 routine; 045 has no production seed — frq_prod_seeded=false; pair HBr+NaOH per home-pair ledger, values bank-unique; unknown direction rotates base; model keeps ONE scaffold stage-marker — 'the subject' — per the wave V-T9 canon) · frq
A 37.0 mL portion of sodium hydroxide solution is titrated with hydrobromic acid of known concentration, 0.470 M. The endpoint arrives after 74.0 mL of the known solution has been delivered; the two react one-to-one.
A 37.0 mL portion of sodium hydroxide solution is titrated with hydrobromic acid of known concentration, 0.470 M. The endpoint arrives after 74.0 mL of the known solution has been delivered; the two react one-to-one.
(a) Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(base) the subject.
(b) Substitute the values and calculate M(base). Give the result with its unit, to 3 significant figures.
(c) Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Part a. Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(base) the subject.
Model: The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(base) the subject: M(base) = M(acid) × V(acid) ÷ V(base).
Part b. Substitute the values and calculate M(base). Give the result with its unit, to 3 significant figures.
Part c. Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Model: Sanity check: the solution that needed the smaller volume must come out more concentrated — the base needed 37.0 mL against the acid's 74.0 mL — half the volume — so it should come out twice as concentrated: 0.940 M against 0.470 M passes.
Full model answer. (a) The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(base) the subject: M(base) = M(acid) × V(acid) ÷ V(base).
(b) Values: V(base) = 37.0 mL, M(acid) = 0.470 M, V(acid) = 74.0 mL.
Substitution: M(base) = 0.470 × 74.0 ÷ 37.0
Result: M(base) = 0.940 M
(c) Sanity check: the solution that needed the smaller volume must come out more concentrated — the base needed 37.0 mL against the acid's 74.0 mL — half the volume — so it should come out twice as concentrated: 0.940 M against 0.470 M passes.
A laboratory stock solution contains ammonia. A chemist titrates a 69.0 mL sample of the stock solution with hydrobromic acid whose concentration is already known, until the two have exactly reacted. Which quantity does the titration reveal?
The concentration of the ammonia in the stock solution KEY
The concentration of the hydrobromic acid
The volume of the 69.0 mL sample
The pH of the stock solution
ABS-038 · easy · application · seq 3 · authored parallel of pool[3] (ask rotated within the mechanism-bookkeeping case) · mcq4
The salt formed when hydroiodic acid neutralizes lithium hydroxide is built from which pair of ions?
Li⁺ and I⁻ KEY
H⁺ and OH⁻
Li⁺ and OH⁻
H⁺ and I⁻
ABS-042 · easy · recall · seq 4 · authored parallel of pool[16] (stem reworded; same misconception trio) · mcq4
A student asks why the flask solution needs indicator drops before the titration starts. What is the reason?
The indicator makes the endpoint visible — the two solutions on their own can be colorless KEY
The indicator makes the acid and the base react faster once mixed
The indicator neutralizes any acid still left over at the end of the titration
The indicator marks the level of solution on the flask so volumes can be read
ABS-039 · medium · application · seq 5 · authored parallel of pool[6] (Ca(OH)₂ family rotation) · text
Predict the salt: hydroiodic acid, HI, neutralizes calcium hydroxide, Ca(OH)₂. Write the salt's formula.
Answer: CaI₂ KEY
also accepted: CaI2
wrongValueDiagnostics
[
{
"value": "CaH₂",
"misconception": "you paired the metal with the acid's hydrogen — the salt takes the acid's NEGATIVE ion, I⁻",
"feedback": null
},
{
"value": "CaI",
"misconception": "you ignored the charges — one 1− iodide cannot balance a 2+ calcium; calcium's 2 must cross to the iodide",
"feedback": null
},
{
"value": "Ca₂I",
"misconception": "you criss-crossed in reverse — calcium's 2 becomes the IODIDE's subscript, not calcium's own",
"feedback": null
}
]
feedback
{
"keyExplanation": "The acid's negative ion: HI gives I⁻. The base's metal ion: Ca(OH)₂ gives Ca²⁺. Criss-cross the charges: calcium's 2 crosses to the iodide, giving CaI₂. Water forms alongside it."
}
ABS-043 · medium · application · seq 6 · authored parallel of pool[18] (fresh volumes, same case) · mcq4
A titration of a 72.0 mL hydrobromic acid sample needs just 9.0 mL of potassium hydroxide solution to reach the endpoint; the two react one-to-one. Which is more concentrated?
The potassium hydroxide solution KEY
The hydrobromic acid
The two are equally concentrated
It cannot be judged from the volumes
ABS-040 · medium · application · seq 7 · authored parallel of pool[9] (same equation family, reframed stem) · text
Write the balanced chemical equation, using the smallest whole-number coefficients: nitric acid, HNO₃, reacts with sodium hydroxide, NaOH.
[
{
"value": "HNO₃ + NaOH → NaNO₃ + H₂",
"misconception": "you released hydrogen gas — with a base, the acid's hydrogen ends up in water, not H₂",
"feedback": null
},
{
"value": "HNO₃ + NaOH → NaNO₃",
"misconception": "you dropped the water — the acid's H⁺ and the base's OH⁻ pair up and must appear as the product H₂O",
"feedback": null
},
{
"value": "2HNO₃ + 2NaOH → 2NaNO₃ + 2H₂O",
"misconception": "your equation is balanced, but not written in the smallest whole-number coefficients — every coefficient here can be divided by two",
"feedback": null
}
]
feedback
{
"keyExplanation": "Products: the salt NaNO₃ and water. Count the pairs: one H⁺ from HNO₃, one OH⁻ from NaOH — the counts match, so no coefficients are needed. HNO₃ + NaOH → NaNO₃ + H₂O. Check: 2 H, 1 N, 4 O, 1 Na on each side."
}
ABS-044 · medium · application · seq 8 · authored parallel of pool[21] (recorded-quantities set rotated) · mcq4
Three quantities from a one-to-one titration are known: M(base), V(base), and V(acid). Which quantity does the titration equation give?
M(acid) KEY
The acid's pH
Whether the acid is strong or weak
Nothing — all four quantities must already be known
ABS-042 · medium · application · seq 9 · authored parallel of pool[15] (ask rotated; flash-then-fade detail never tested per 042 extraNotes) · mcq4
A flask holds lithium hydroxide solution with a few drops of phenolphthalein, so it starts out pink. Hydrochloric acid is added slowly from the tube. Which observation tells the student the endpoint has arrived?
The pink color disappears and does not come back KEY
The pink color deepens sharply
The solution turns from pink to blue
Nothing is observed, because phenolphthalein only works when base is added to acid
ABS-044 · medium · application · seq 10 · authored parallel of pool[23] (fresh mL/L pair) · mcq4
V(acid) = 89.0 mL and V(base) = 0.0620 L are to be substituted into M(acid) × V(acid) = M(base) × V(base). What must be done first?
Express both volumes in the same unit KEY
Nothing — the equation works with any mix of volume units
Convert both volumes into moles first
Convert the two molarities into grams
ABS-039 · medium · application · seq 11 · authored parallel of pool[8] (stem reworded; spec's permutational distractor set kept) · mcq4
Which formula is the salt made when sulfuric acid, H₂SO₄, meets lithium hydroxide, LiOH?
Li₂SO₄ KEY
LiSO₄
Li(SO₄)₂
Li₂(SO₄)₂
ABS-045 · medium · application · seq 12 · authored parallel of pool[24] (fresh values, same routine) · numeric
A 92.0 mL sample of hydrochloric acid requires 23.0 mL of 0.680 M potassium hydroxide solution to reach the endpoint; the two react one-to-one. What is the molarity of the acid, in M? Give your answer to 3 significant figures.
Answer: 0.17 M KEY
wrongValueDiagnostics
[
{
"value": 2.72,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.68,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 15.6,
"misconception": "you multiplied the known side but never divided by the acid's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(acid) = 92.0 mL\nM(base) = 0.680 M\nV(base) = 23.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(acid) the subject:\nM(acid) = M(base) × V(base) ÷ V(acid)\nSubstitute in the values, and calculate:\nM(acid) = 0.680 × 23.0 ÷ 92.0\nM(acid) = 0.170 M\nSanity check: the acid needed four times the base's volume, so it comes out a quarter as concentrated — 0.170 M against 0.680 M passes."
}
ABS-040 · medium · application · seq 13 · authored parallel of pool[10] (stem reframed; same equation family + distractor set) · mcq4
For the neutralization of barium hydroxide by hydrobromic acid, which is the correctly balanced equation?
2HBr + Ba(OH)₂ → BaBr₂ + 2H₂O KEY
HBr + Ba(OH)₂ → BaBr₂ + H₂O
2HBr + Ba(OH)₂ → Ba₂Br + 2H₂O
2HBr + Ba(OH)₂ → BaBr₂ + 2H₂
ABS-043 · medium · application · seq 14 · authored parallel of pool[19] (fresh volumes + hunch wording) · mcq4
Reaching the endpoint took 94.0 mL of sodium hydroxide solution for a 47.0 mL sample of hydroiodic acid; the two react one-to-one. A student claims the base is more concentrated 'since so much more of it was needed'. Which is actually more concentrated?
The hydroiodic acid KEY
The sodium hydroxide solution
The two are equally concentrated
It cannot be judged from the volumes
ABS-045 · hard · application · seq 15 · authored parallel of pool[25] (fresh values, same routine) · numeric
A 28.0 mL sample of lithium hydroxide solution requires 63.0 mL of 0.320 M hydrobromic acid to reach the endpoint; the two react one-to-one. What is the molarity of the base, in M? Give your answer to 3 significant figures.
Answer: 0.72 M KEY
wrongValueDiagnostics
[
{
"value": 0.142,
"misconception": "you swapped the two volumes — the unknown's OWN volume is the divisor",
"feedback": null
},
{
"value": 0.32,
"misconception": "you assumed the two molarities match — they match only when the two volumes match",
"feedback": null
},
{
"value": 20.2,
"misconception": "you multiplied the known side but never divided by the base's volume",
"feedback": null
}
]
feedback
{
"keyExplanation": "Write down the values in the question:\nV(base) = 28.0 mL\nM(acid) = 0.320 M\nV(acid) = 63.0 mL\nWrite down the equation:\nM(acid) × V(acid) = M(base) × V(base)\nMake M(base) the subject:\nM(base) = M(acid) × V(acid) ÷ V(base)\nSubstitute in the values, and calculate:\nM(base) = 0.320 × 63.0 ÷ 28.0\nM(base) = 0.720 M\nSanity check: the base needed well under half the acid's volume, so it comes out more than twice as concentrated — 0.720 M against 0.320 M passes."
}
ABS-043 · hard · application · seq 16 · authored parallel of pool[20] (fresh equal volumes) · mcq4
Exactly 67.0 mL of potassium hydroxide solution neutralizes a 67.0 mL sample of nitric acid at the endpoint; the two react one-to-one. Which is more concentrated?
Neither — the two are equally concentrated KEY
The nitric acid
The potassium hydroxide solution
It cannot be judged without knowing at least one molarity
ABS-037 · hard · transfer · seq 17 · authored parallel of pool[2] (claimant/context rotated) · mcq4
A study-guide draft states: 'neutralization produces NaCl, table salt, every time.' Which correction is right?
Every neutralization produces a salt, but which salt depends on the acid and base used. KEY
The claim is right — in chemistry, the word salt means NaCl and nothing else.
The claim is wrong because many neutralizations produce only water and no salt at all.
The claim is wrong because neutralization produces no salt — salts come only from mines and seawater.
ABS-038 · hard · transfer · seq 18 · authored parallel of pool[5] (stem reworded; same reverse design) · mcq4
An exactly completed neutralization leaves a solution containing only Li⁺ ions, NO₃⁻ ions, and water. Which acid and base produced it?
Nitric acid and lithium hydroxide KEY
Nitric acid and potassium hydroxide
Hydrochloric acid and lithium hydroxide
Lithium nitrate and water
ABS-041 · hard · transfer · seq 19 · authored parallel of pool[14] (claim wording rotated) · mcq4
A student explains titration to a friend: 'it tells you whether an acid is strong or weak.' Which correction is right?
A titration finds the acid's concentration — strength is a different property KEY
The student is right — the more concentrated an acid, the stronger it is
The student is almost right — a titration finds strength, but only for bases
The student is wrong because a titration measures nothing about the acid at all
ABS-044 · hard · transfer · seq 20 · authored parallel of pool[22] (ask rotated; spec-mandated instance kept per A-U11G4-4) · mcq4
May the equation M(acid) × V(acid) = M(base) × V(base) be used for a titration of sulfuric acid, H₂SO₄, with sodium hydroxide, NaOH?
No — H₂SO₄ gives two H⁺ per unit, so the pair reacts one-to-two, not one-to-one KEY
Yes — the equation applies to every acid–base titration
Yes — as long as both volumes are measured in the same unit
No — because sulfuric acid is too concentrated for titrations
ABS-040 · medium · application · seq 21 · authored parallel of pool[11] (seq-21 case family rotation: HNO₃ + Sr(OH)₂) · frq
A lab must neutralize a flask of strontium hydroxide solution using nitric acid. On paper, work out the balanced chemical equation for nitric acid, HNO₃, reacting with strontium hydroxide, Sr(OH)₂.
A lab must neutralize a flask of strontium hydroxide solution using nitric acid. On paper, work out the balanced chemical equation for nitric acid, HNO₃, reacting with strontium hydroxide, Sr(OH)₂.
(a) Give both products of the neutralization, including the salt's formula.
(b) Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
(c) Check your balanced equation by counting each element's atoms on both sides.
Part a. Give both products of the neutralization, including the salt's formula.
Model: Products: the salt Sr(NO3)2 (Sr(2+) criss-crossed with NO3(1-) — the nitrate keeps its parentheses) and water.
Part b. Write the unbalanced equation, then balance it. Explain your coefficients by counting the H⁺ each acid unit gives and the OH⁻ each base unit gives — change only coefficients, never a subscript.
Model: First write, products once each (all coefficients 1): 1HNO3 + 1Sr(OH)2 -> 1Sr(NO3)2 + 1H2O. Count the pairs: each HNO3 gives one H(+) but Sr(OH)2 gives two OH(-), so two HNO3 are needed and the pairs make 2H2O. Balanced (coefficients of 1 left unwritten): 2HNO3 + Sr(OH)2 -> Sr(NO3)2 + 2H2O.
Part c. Check your balanced equation by counting each element's atoms on both sides.
Model: Check: 4 H, 2 N, 8 O, and 1 Sr on each side.
Full model answer. (a) Products: the salt Sr(NO3)2 (Sr(2+) criss-crossed with NO3(1-) — the nitrate keeps its parentheses) and water.
(b) First write, products once each (all coefficients 1): 1HNO3 + 1Sr(OH)2 -> 1Sr(NO3)2 + 1H2O. Count the pairs: each HNO3 gives one H(+) but Sr(OH)2 gives two OH(-), so two HNO3 are needed and the pairs make 2H2O. Balanced (coefficients of 1 left unwritten): 2HNO3 + Sr(OH)2 -> Sr(NO3)2 + 2H2O.
(c) Check: 4 H, 2 N, 8 O, and 1 Sr on each side.
ABS-045 · hard · application · seq 22 · authored calculation FRQ (ABS-045 R15 routine; 045 has no production seed — frq_prod_seeded=false; pair HBr+NaOH per home-pair ledger, values bank-unique; unknown direction rotates acid; model keeps ONE scaffold stage-marker — 'the subject' — per the wave V-T9 canon) · frq
A 29.0 mL portion of hydrobromic acid is titrated with sodium hydroxide solution of known concentration, 0.350 M. The endpoint arrives after 58.0 mL of the known solution has been delivered; the two react one-to-one.
A 29.0 mL portion of hydrobromic acid is titrated with sodium hydroxide solution of known concentration, 0.350 M. The endpoint arrives after 58.0 mL of the known solution has been delivered; the two react one-to-one.
(a) Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(acid) the subject.
(b) Substitute the values and calculate M(acid). Give the result with its unit, to 3 significant figures.
(c) Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Part a. Write down the titration equation, state why it may be used for this pair, and rearrange it to make M(acid) the subject.
Model: The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(acid) the subject: M(acid) = M(base) × V(base) ÷ V(acid).
Part b. Substitute the values and calculate M(acid). Give the result with its unit, to 3 significant figures.
Part c. Run the volume sanity check: say which solution needed the smaller volume, what that predicts about the two concentrations, and whether your answer passes.
Model: Sanity check: the solution that needed the smaller volume must come out more concentrated — the acid needed 29.0 mL against the base's 58.0 mL — half the volume — so it should come out twice as concentrated: 0.700 M against 0.350 M passes.
Full model answer. (a) The two react one-to-one, so at the endpoint the moles of acid equal the moles of base and the titration equation applies: M(acid) × V(acid) = M(base) × V(base). Make M(acid) the subject: M(acid) = M(base) × V(base) ÷ V(acid).
(b) Values: V(acid) = 29.0 mL, M(base) = 0.350 M, V(base) = 58.0 mL.
Substitution: M(acid) = 0.350 × 58.0 ÷ 29.0
Result: M(acid) = 0.700 M
(c) Sanity check: the solution that needed the smaller volume must come out more concentrated — the acid needed 29.0 mL against the base's 58.0 mL — half the volume — so it should come out twice as concentrated: 0.700 M against 0.350 M passes.